Everand Logo

Welcome to Everand!

  • Discover millions of ebooks, audiobooks, and so much more with a free trial

    Only $11.99/month after trial. Cancel anytime.

    Catalytic Reactions: The Organic Chemistry of Palladium
    Catalytic Reactions: The Organic Chemistry of Palladium
    Catalytic Reactions: The Organic Chemistry of Palladium
    Ebook204 pages4 hours

    Catalytic Reactions: The Organic Chemistry of Palladium

    By Peter Maitlis

    ()

    Read preview

    About this ebook

    The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Industrial applications can re-oxidize the palladium metal back to Pd(II) in situ, making the reactions catalytic. The text also discusses certain reactions that can form C-O bonds as part of an oxidative process. The book also describes significant reactions that can be catalyzed by palladium metal, such as in the hydrogenation of multiple bonds, in the carbonylation of certain olefins and acetylenes, and in the catalytic cracking of high molecular weight hydrocarbons. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the book truly useful.
    LanguageEnglish
    PublisherAcademic Press
    Release dateDec 2, 2012
    ISBN9780323159616
    Catalytic Reactions: The Organic Chemistry of Palladium

    Related to Catalytic Reactions

    Related ebooks

    Chemistry For You

    View More
    View More

    Related podcast episodes

    Related articles

    • Article

      Super Catalyst Turns Chemical ‘Trash’ Into Treasure

      Dec 28, 2018

      Researchers have developed a catalyst that combines strength and finesse to make an inert carbon-hydrogen bond reactive—effectively turning chemical “trash” to “treasure.” For decades, chemists have aspired to do carefully controlled chemistry on car

      3 min read

    • Article

      Inverters Explained

      Apr 29, 2021

      Inverters Explained
      9 min read

    • Article

      Metal Turns Vexatious Plastic Into A Sustainable Feedstock

      Dec 11, 2022

      Polyethylene is one of the most common types of plastic in the world. Easy to make, it's devilishly difficult to break down again, making re-use and recycling tricky. In Science, US chemists showed they've figured out a new way to return polyethylene

      1 min read

    • Article

      What Are The Noble Gases?

      Nov 26, 2020

      What Are The Noble Gases?
      1 min read

    • Article

      Technologue

      Aug 26, 2022

      Technologue
      2 min read

    • Article

      The Classic Metal Behind the Origins of Life: A collection of metal atoms called the “metallome” helped drive evolution.

      Mar 24, 2016

      When we think of life, we usually think of soft, squishy, and wet things. Or we might think of the “omes”: the genome, which carries our heredity code; or the proteome, which is the collection of proteins these genes assemble; or the metabolome, smal

      4 min read

    • Article

      Technologue

      Nov 19, 2021

      Might lithium-sulfur batteries push solid-state aside as The Next Big Thing in battery technology? Silicon Valley battery tech company Lyten just came out of stealth mode at September’s Motor Bella car show/mobility conference in metro Detroit after

      3 min read

    • Article

      Ask a Scientist: In Search of a ‘Green’ Electric Car Battery

      Jul 13, 2022

      Jessica Dunn, a senior analyst in our Clean Transportation Program, answers an inquiry from a UCS supporter, Allison D., in Caro, Michigan, who wrote: “I was wondering what might be on the horizon for alternatives to lithium batteries for EVs. I was

      8 min read

    • Article

      Cheap Sodium Battery Works as Well as Pricey Lithium

      Oct 10, 2017

      A new sodium-based battery can store the same amount of energy as a state-of-the-art lithium ion at a substantially lower cost. As a warming world moves from fossil fuels toward renewable solar and wind energy, industrial forecasts predict an insatia

      2 min read

    • Article

      The Utilization of Rare Earth Elements as Colorants in Transparent Ceramic Glazes as an Innovative Approach

      Mar 13, 2024

      Based on pertinent scientific papers, published reports, and chemical elements, REMs (or REEs) are composed of a set of 17 chemical elements as listed in the Periodic Table. Furthermore, the 17 rare earth materials include 15 lanthanides, plus scandi

      10 min read

    • Article

      Using Hydrogtn As An Alternative To Fossil Fuels

      Sep 26, 2019

      I have mentioned in a number of previous articles featured in this magazine that the future of the mains gas grid in the UK is likely to involve the increased use of hydrogen. There are tests currently being carried out in Leeds with higher concentra

      2 min read

    • Article

      The Innovators

      Jul 8, 2022

      The Innovators
      2 min read

    • Article

      How Doped Nanomaterials Could Cut Fuel Cell Costs

      Jan 7, 2018

      Nitrogen-doped carbon nanotubes or modified graphene nanoribbons could be effective, less costly replacements for expensive platinum in fuel cells, according to a new study. The tricky bit is making a catalyst that is neither too strong nor too weak…

      2 min read

    • Article

      Under The Hood

      May 18, 2023

      Under The Hood
      4 min read

    • Article

      ‘Decorated’ Nanotubes May Be Ready For Next-gen Materials

      May 29, 2018

      Scientists have found a way to enhance boron nitride nanotubes using a chemical process called the Billups-Birch reaction. The work suggests boron nitride nanotubes are primed to become effective building blocks for next-generation composite and poly

      2 min read

    • Article

      Copper Gets Us Closer to Using CO2 Pollution as Fuel

      Jun 13, 2017

      A new study describes the mechanics behind an early key step in artificially activating carbon dioxide so that it can rearrange itself to become the liquid fuel ethanol. Solving this chemical puzzle may one day lead to cleaner air and renewable fuel.

      3 min read

    • Article

      How Are EV Batteries (actually) Recycled?

      Oct 25, 2023

      Using recycling processes with high mineral recovery rates and lower environmental impact is critical.

      5 min read

    Related categories

    Reviews for Catalytic Reactions

    0 ratings

    0 ratings0 reviews

    What did you think?

    Tap to rate

    Review must be at least 10 words

      Book preview

      Catalytic Reactions - Peter Maitlis

      Enjoying the preview?
      Page 1 of 1