Recent Advances in High-Temperature PEM Fuel Cells
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About this ebook
Hydrogen and Fuel Cells Primers is a series focused on Energy applications. Its concise volumes present those coming into this broad and multidisciplinary field with the most recent advances in each of its particular topics. They bring together information that has thus far been scattered in many different sources under one single title, which makes them a useful reference for industry professionals, researchers and graduate students, especially those starting in a new topic of research.
This volume, Recent Advances in High Temperature PEM Fuel Cells, provides an up-to-date progress of High Temperature Polymer Electrolyte Membrane Fuel Cells (HTPEMFCs), including three critical subjects for this type of fuel cells: Membrane Electrode Assembly (MEA) development, stack development and systems development. The MEA and stack development sections cover the recent advances in this area and highlight the areas in most need of improvement. The systems development section focuses on stationary systems, mainly Combined Heat and Power (CHP), based on HTPEMFCs. Finally the conclusions summarize the recent advances of HTPEMFCs in all these areas and provide some insights for future developments.
Prof. Bruno G. Pollet, Series Editor
- Presents the most current knowledge in membrane electrode assembly, stack, and systems development for HTPEMFCs
- Highlights the areas that need improvement in electrode assembly and stack development
- Examines stationary high temperature PEMFC systems, including CHP
Sivakumar Pasupathi
Sivakumar Pasupathi is programme manager for HySA Systems competence centre, one of three national centres under Hydrogen South Africa (HySA), hosted by the South African Institute for Advanced Materials Chemistry (SAIAMC) at the University of the Western Cape (UWC), South Africa. He is also a senior lecturer at the University of the Western Cape. He obtained his PhD from the University of Pisa, Italy and has been working in the field of hydrogen and fuel cells since late 1990’s. He is a NRF rated scientist and principal investigator in several bilateral projects with international partners. In his role at HySA Systems, he is managing combined heat and power (CHP) programme. His current focus is on developing components and systems, covering the whole value chain of PEM fuel cells, for CHP and FCXV applications. His interests include PEM based fuel cells and electrolysers. He has published over 100 publications including papers in peer-reviewed international journals and conference proceedings, and is an inventor of 11 patents and counting. He has been spoken at several events and successfully organized international workshops and conferences.
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Recent Advances in High-Temperature PEM Fuel Cells - Sivakumar Pasupathi
conferences.
Chapter 1
Introduction
Abstract
Fuel cells are entering the commercial market, especially in the stationary and transport sectors in Asia, with those of Europe and United States next. Of the various types of fuel cells, polymer electrolyte membrane fuel cells (PEMFCs) are in the vanguard in the drive to commercialization. One type of PEMFC, the high-temperature PEMFC (HT-PEMFC) has huge potential in the market because of its simplicity and its positive application in the stationary sector, particularly in the Combined Heat and Power sector. This section introduces the HT-PEMFC.
Keywords
Fuel cell; low-temperature PEMFC; high-temperature PEMFC; R&D; competing technologies
1.1 Fuel Cells
A fuel cell is a device which converts chemical energy directly into electrical energy, electrochemically. The device operates at various temperatures (up to 1000°C), converting a fuel (e.g., hydrogen) and an oxidant (air or pure oxygen) in the presence of a catalyst into electricity, heat, and water. There are currently five major types of fuel cells; (1) the proton exchange membrane fuel cell (PEMFC) including (a) low-temperature PEMFCs (LT-PEMFCs), (b) high-temperature PEMFCs (HT-PEMFCs), and (c) direct methanol fuel cells (DMFCs), (2) the alkaline fuel cell (AFC), (3) the phosphoric acid fuel cell (PAFC), (4) the molten carbonate fuel cell (MCFC), (5) the solid oxide fuel cell (SOFC). A representative diagram of various types of Fuel Cells and their operating temperatures is given in Fig. 1.1 (Pollet et al., 2012).
Figure 1.1 Types of fuel cells and their operating temperatures. Source: From Pollet, B.G., et al., 2012. Current status of hybrid, battery and fuel cell electric vehicles: From electrochemistry to market prospects. Electrochim. Acta 84, 235–249.
1.2 Fuel Cells in the Future Energy Mix
The increase in global energy demand, along with increasing awareness of using greener and cleaner power sources, has placed an emphasis on renewable energy technologies to cater for our future energy needs. Owing to the intermittent nature of renewable sources, energy storage has become a key parameter in realizing the potential of this technology. Hydrogen and batteries are considered the most suitable renewable energy storage media in the long run. Renewable hydrogen coupled with fuel cells for generating electricity and heat is widely envisioned in an ideal
green economy scenario. However, the current high-cost and durability issues of hydrogen and fuel cell technologies are hampering their mass deployment and