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Authors: Lucas Rojek & Dharmendra Tiwary Date: July 2004 Version: 1.0 Program Mode: HYSYS State-State & Dynamics
Real Separator
1 Introduction
The HYSYS Separator unit operation normally assumes perfect phase separation, but it can also be configured to model imperfect separation by using the HYSYS Real Separator capabilities. The real separator offers the user a number of advantages: Includes carry over so that your model matches your process mass balance or separator design specifications. Predicts the effect of feed phase dispersion, feed conditions, vessel geometry, and inlet/exit devices on carry over.
This document will introduce the concepts needed to use these real separator features. An example is included to demonstrate a typical real separator application.
Real Separator capabilities like the carry over option were introduced to the HYSYS separator with the release of HYSYS 3.1. This option can be used to model imperfect separation in both steady state and dynamic simulation. Gas and liquid carry over can be specified or calculated. Three different correlations are available for this purpose.
Real Separator
Vessel Internals
Internals used to reduce carry over can be included in your separator model with some of the provided carry over correlations. Internals used to reduce the amount of phase dispersion entering the vessel are termed inlet devices. Internals used to reduce liquid carry over into the outlet gas product are termed exit devices. Weirs are used to improve heavy liquid - light liquid separation in horizontal vessels.
Nozzle Calculations
Included with the carry over correlations are calculation methods for inlet and outlet nozzle pressure drop. Inlet and outlet devices can be included in these calculations. The user can also specify pressure drop if the carry-over option is
not in use.
The dynamic model of a separator must account for changing pressure and flow due to liquid levels, nozzle pressure drop, and heat effects. As such, vessel geometry, including internals and nozzle geometry, and heat loss parameters
need to be specified. Modeling imperfect separation with the carry over option and a specifiable PV work term are also available. Level taps can also be set for monitoring the relative levels of the different liquid phases. All of these items can be set up via the Rating tab.
Real Separator
Real Separator
The Correlation Based model allows you to calculate the expected carry over based on the configuration of the vessel, the feed conditions and type of inlet/exit devices installed in the separator. This information is entered on the Correlation Setup, Dimensions Setup, DP/Nozzle Setup pages. The Correlation Setup group allows you to select the Correlation Calculation Type and how you want to apply the correlation. You can apply one correlation for all of the carry over calculations (Overall Correlation radio button). Alternately you can select a different correlation for each step in the carry over calculation sequence: 1. Inlet Calculations 2. Primary Gas-Liquid Separation 3. Primary Liquid-Liquid Separation 4. Exit Device (Secondary Gas-Liquid Separation) Calculations
Real Separator
Feed
G P as roduct
Inlet C alculations
O as il/G W ater/G as G il as/O W ater/O il G ater as/W O ater il/W W distributioninG ater as D eter vsflow iam O distributioninG il as D eter vsflow iam
S econdaryG / as LiquidSeparation
O as il/G O distributioninG il as D eter vsflow iam
W ater/G as
W ater/G as
W ater/O il
G ater as/W
O ater il/W
W P ater roduct
OP il roduct
Note: Only those parts of the correlation in use that apply to the particular sub-calculation will be used. Example: If the Generic correlation is used for the Inlet device and ProSeparator is used for primary L-L and G-L separation calculations, then the user-supplied data for the generic inlet calculations (i.e., inlet split and Rossin-Rammler parameters) will be used to generate the inlet droplet distribution. The ProSeparation primary separation calculations will then be performed using these inlet distributions. As ProSeparator correlations will not be used to calculate the inlet conditions, any ProSeparator inlet setup data is ignored. Likewise, any critical droplet sizes entered in the Generic correlation will be ignored as the ProSeparator is being used for the primary separation
calculations.
Real Separator
3 Correlation Details
There are three sets of correlations available to calculate carry over: Generic, Horizontal Vessel, and ProSeparator. After you have selected the type of correlation, you can click on the View Correlation button to view its parameters.
Real Separator
The primary liquid-liquid separation is also calculated using settling velocities for each droplet of liquid or gas in the liquid phases and residence time for each liquid phase. The settling velocities are calculated using the GPSA correlations for all dispersions, except for the water in oil dispersion for which the settling velocity is calculated by the method of Barnea and Mizrahi. A user defined liquid phase inversion point is used in the calculation of the appropriate liquid phase viscosities (i.e. water-in-oil and oil-in-water). A residence time correction factor can also be applied. A droplet is carried over if the vertical distance traveled during its residence in the vessel is less than the vertical distance required to rejoin its bulk phase. This effectively applies to horizontal vessels.
Real Separator
The ProSeparator correlations are rigorous but are limited to calculating liquid carry over into gas. There are no calculations of liquid-liquid separation or gas entrainment in the liquid phases (they are set to zero). Light liquid and heavy liquid entrainments are calculated separately and the total carry over is the sum of the separate light and heavy liquid carry over calculations.
Maximum droplet size is determined with ProSeparator using empirical correlations. Accurate physical properties of the fluids (particularly surface tension) are very important to this calculation.
Primary separation is based on critical droplet size; however, the critical droplet size is not user-specified but calculated based on the gas velocity through the vessel.
Real Separator
The complete topic of particle size analysis has been discussed by Allen (1981), and this work is an excellent starting point to explore the subject in greater depth than can be provided in this overview. A recent summary of the range of most modern techniques available for the characterisation of particles in liquids has been given by Svarovsky (1990).
It must be emphasized that the use of continuous size distribution functions to represent experimental data is almost always a compromise, since measured data rarely fit the models exactly. However, distribution functions have the advantage that they enable the comparison of a large amount of data using a few basic parameters. An important feature is the ability to represent the size distribution in cumulative form as a straight line by means of a scaling that is constructed so as to linearise the cumulative size distribution function.
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Real Separator
Where: F = fraction of droplets larger than d dm is related to d95 x = RR index d95 = 95% of droplets are smaller than this diameter for the specified dispersion RR Index = exponent used in the RR equation (also known as the spread parameter) * mode = is the commonly occurring diameter (peak of the histogram / frequency curve), as compared to other different measures of central tendency such as mean or median diameters. ** spread is a measure of degree of deviation from the central tendency; its value is characteristic of the substance / system being considered Another way of expressing this is: ln(F) = (-d/dm)x or ln (ln(1/F)) = B + x ln(d) Where: B = constant = ln (1/dm) Therefore plotting ln(ln(1/F) against ln(d) can be used to calculate the R-R parameters. Should such a plot not yield a straight line, it would follow that the particle distribution cannot be adequately described by the Rossin-Rammler function. For more information on particle size analysis and particle size distributions please refer to the Aspentech Process Manuals. (2)
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Real Separator
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Real Separator
5 Tutorial Examples
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Real Separator
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Process Overview
Real Separator
Workshop
Process Description
In this workshop, a 3-phase Separator is used to separate an oil/water/gas mixture. Entrained liquids in the gas product have been identified as a potential process issue. The HYSYS Real Separator will be used to account for liquid entrainment in the model. Carryover of liquids can be troublesome, especially if the gas is then passed through a turbine/compressor where liquid droplets can cause major damage to the internals of the machine. We will determine if a demisting pad is appropriate to prevent carryover and how to size it appropriately.
4. Add a 3-phase Separator and specify it with the following information: In this cell Connections Name Inlets Vapour Light Liquid Heavy Liquid Enter V-101 Feed Vapour LLiquid HLiquid
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Real Separator
5. Open the separator unit operation and select the Worksheet tab. What is the vapour fraction and molar flow of the product stream? Vapour ______________________
3. Examine the product streams and the C.Over Results page and compare to the ideal separation case.
What is the vapour fraction of the vapour product stream? ______________ What is the rate of liquid carryover (kgmole/h)? ________________________
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Real Separator
The Setup and Results views will be different depending on which correlation is used. Refer to page 6 for a detailed description of each correlation and its required parameters.
4. DP / Nozzle Setup (radio button): Enter the following values for nozzle location (this is the horizontal or radial distance from the feed location): Feed 0.0 m, Vapour 6.0 m. Keep the default values for nozzle diameter and height.
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Real Separator
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Real Separator
b) Open the Rating tab and select the C.Over Results page. To view the carryover details, click the View Dispersion Results button. You should see results similar to this:
We need to eliminate all droplets larger than 50 microns (0.05 mm). Do we need an exit device to do secondary separation? _____ Open the Rating tab and select the C.Over Setup page. Click the View Correlation button and open the Results tab.
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Real Separator
Exercise 1
It is expected that the inlet hydrocarbon flow to the separator may vary by up to 25%. Anticipating that the separator may not be able to handle this increased flow, the engineer decides to model the new conditions in the separator and design a demister pad to remove the larger droplets. 1. Increase the flowrate of the To LP Sep Clone stream by 25%. 2. Select the C.Over Results page, then click the View Dispersion Results button. What is the Total Carryover with no mesh? With 150mm of mesh? _______________________________________________________ What is the removal efficiency of 50 micron droplets? _______________________________________________________ Based on this predicted dispersion, the engineer decides to install a thicker mesh pad. How would you suggest the engineer use HYSYS to determine the correct thickness? Perform the analysis yourself; how thick should the mesh pad be? _______________________________________________________ Now what is the vapour fraction of the Vapour product stream? ________________________________________________________
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Real Separator
Exercise 2
Connect the real separator into the two-stage compression loop to replace the ideal separator that is currently in use. Keep the Water feed stream connected. Is the real separator still capable of stopping 50 micron drops reaching the compressor suction?
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Real Separator
Demonstration
1. 2. 3. 4. Open Dynamic Real Separator.hsc. Click on the strip charts to bring them to the foreground. Click the Dynamic Mode button. Start the Integrator. When the liquid carryover flow achieves a steady value, stop the integrator. 5. Change the position of VLV-100 to 25% open. Re-start the integrator. When the liquid carryover flow achieves a steady value stop the integrator. 6. Change the position of VLV-100 to 75% open. Re-start the integrator. When the liquid carryover flow achieves a steady value stop the integrator. Is the mesh pad thick enough to account for all process conditions? _________________________________________________________________ A thick pad creates more pressure drop; are there other mitigations to consider?________________________________________________________ 7. Open Controlled Dynamic Real Separator.hsc; repeat the same exercise. What effect does controlling the liquid level have? ________________________________________________________________
6 Reference
Horizontal Vessel: GPSA, Vol 1, 10th Ed., January 1990. Separation Mechanism of Liquid-Liquid Dispersions in a deep-layer Gravity Settler, E. Barnea and J Mizrahi, Trans. Instn. Chem. Engrs, 1975, Vol 53. Droplet size spectra generated in turbulent pipe flow of dilute liquid-liquid dispersions, A J Karabelas, AIChE, 1978, vol. 24, No. 2, pages 170-181. ProSeparator Model: Society of Petroleum Engineers papers: SPE36647 Separator Design and Operation: Tools for Transferring "Best Practise" SPE21506 Proseparator a novel separator/scrubber design program
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Real Separator
Rossin-Rammler Distributions: Aspen Process Manuals Mini Manual 1: Gas & Particle Properties; Part 8 Particle Size General References: Aspen Process Manuals Gas Cleaning Manual: Vol 1 Introduction Vol 2 Demisting Vol 10 Applied Technology
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