S GIO DC & V O TO

LONG AN
CHNH THC

K THI TUYN SINH VO LP 10 - H CHUYN

Mn thi : HO HC
Ngy thi : 05 - 7 - 2012
Thi gian thi : 120 pht (khng k pht )

Cu 1 (2 im)
1/ 3 hp cht ca natri l X, Y, Z c mi quan h sau:
+ dung dich Z
+X
+ CO2
t0
X
Y
Y
Z
CO2
Xc nh cng thc ha hc ca X, Y, Z v vit cc phng trnh phn ng theo s trn.
2/ Vit phng trnh phn ng nhit phn n khi lng khng i ca: KMnO 4, KClO3,
Mg(HCO3)2.
Cu 2 (2 im)
C 4 ng nghim, mi ng cha mt dung dch mui ( khng trng kim loi cng nh gc axit )
l clorua, sunfat, nitrat, cacbonat ca cc kim loi Ba, Mg, K, Ag.
1/ Hi mi ng nghim cha dung dch mui no?
2/ Trnh by phng php ha hc phn bit 4 dung dch mui trn.
Cu 3 (2 im)
T C, H2O, khng kh, cht v c, iu kin v xc tc cn thit coi nh c . Hy vit cc
phng trnh phn ng ho hc to ra axit gluconic, natri etylat, etyl axetat.
Cu 4 (2 im)
- Cho 41,175 gam hn hp hai kim loi Na, Ba tc dng vi 59,725 gam nc thu c dung
dch X v c 10,08 lt kh thot ra (ktc).
- Trn 400 ml dung dch A (cha HCl) vi 100 ml dung dch B (cha H 2SO4) c dung dch C.
Ly 10 ml dung dch C trn vi 90 ml nc c dung dch D.
- Dng 1 gam dung dch X trung ho va dung dch D trn, thu c kt ta Y. C cn
phn dung dch th thu c mt lng mui khan Z. Tng khi lng Y v Z l 0,83125 gam.
a/ Tnh nng phn trm cc cht c trong dung dch X.
b/ Tnh nng mol ca cc cht c trong dung dch A, B, C, D. Cho rng th tch ca dung dch
thay i khng ng k.
Cu 5 (2 im)
t chy hon ton 0,2 mol mt hp cht hu c A c cng thc phn t dng C nH2n, ton b
sn phm chy c hp thu ht vo 295,2 gam dung dch NaOH 20%. Sau khi hp thu xong, nng
ca NaOH cn li trong dung dch l 8,45%. Cc phn ng xy ra hon ton.
1/ Xc nh cng thc phn t ca A.
2/ Hn hp kh X gm A v H 2 c t khi so vi hiro l 10,75. un nng X vi bt Ni lm
xc tc n khi phn ng hon ton thu c hn hp Y.
a/ Chng minh rng hn hp Y lm mt mu dung dch brom.
b/ Tnh thnh phn phn trm th tch mi kh trong hn hp X; hn hp Y.
Cho: H = 1, C = 12, O = 16, S =32, Cl = 35,5, Ba = 137, Na = 23.
Lu : Th sinh khng c s dng bng h thng tun hon cc nguyn t ho hc.
-- Ht--

S GIO DC & O TO
LONG AN

K THI TUYN SINH VO LP 10 H CHUYN

Mn thi : HO HC
Ngy thi : 05 - 7 - 2012
Thi gian thi : 120 pht (khng k pht )

CHNH THC
CU

P N

Cu 1
1/ (1,25 im) Xc nh cng thc ho hc ca X, Y, Z v vit cc
(2im) phng trnh phn ng:
X l NaOH; Y l NaHCO3; Z l Na2CO3
NaOH + CO2 NaHCO3
t0
2NaHCO3
Na2CO3 + CO2 + H2O
CO2 + H2O + Na2CO3 2NaHCO3
NaOH + NaHCO3 Na2CO3 + H2O
2/ (0,75 im) Vit cc phng trnh phn ng nhit phn:
t0
2KMnO4
K2MnO4 + MnO2 + O2
t
2KClO3
2KCl + 3O2
t0
Mg(HCO3)2
MgO + 2CO2 + H2O
0

Cu 2
(2im) 1/ 4 dung dch mui l: BaCl2, MgSO4, K2CO3 v AgNO3
2/ Phn bit 4 dung dch mui:
- Thuc th: dung dch HCl v dung dch Na2SO4
Nh dung dch HCl vo 4 mu th
Mu th phn ng to kt ta trng l dung dch AgNO3
AgNO3 + HCl AgCl HNO3
Mu th phn ng si bt kh l dung dch K2CO3
K2CO3 + 2HCl 2KCl + CO2 + H2O
Nh dung dch Na2SO4 vo 2 mu cn li
Mu th phn ng to kt ta trng l dung dch BaCl2
BaCl2 + Na2SO4 BaSO4 2NaCl
Mu cn li l dung dch MgSO4
Cu 3
T C, H2O, khng kh, cht v c, iu kin v xc tc cn thit coi
(2im) nh c . Hy vit cc phng trnh phn ng ho hc to ra axit
gluconic, natri etylat, etyl axetat
C + O2 t CO2
Clorophin
sng
(-C6H10O5-)n + 6nO2
6nCO2 + 5nH2O nh
0

Axit
(-C6H10O5-)n + nH2O t nC6H12O6
o

Dd NH3

C6H12O6 + Ag2O t C6H12O7 + 2Ag

o

Men ru

32 C
C6H12O6 30
2C2H5OH + 2CO2

2C2H5OH + 2Na 2C2H5ONa + H2

C2H5OH + O2 Men gim CH3COOH + H2O
0

H2SO4 c

THANG
IM
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,5

0,25
0,25
0,25
0,25
0,25
0,25

0,25
0,25
0,25
0,25
0,25
0,25
0,25

Ghi
ch

C2H5OH +CH3COOH t CH3COOC2H5+ H2O

0

Cu 4
(2im)

a. Tnh nng phn trm cc cht c trong dung dch X.

2Na + 2H2O 2NaOH + H2
x
x
x
0,5x (mol)

Ba + 2H2O
Ba(OH)2 + H2
y
2y
y
y (mol)
23x + 137y = 41,175
0,5x +
y = 0,45
n NaOH = 0,45 ( mol)
n Ba ( OH ) 2 = 0,225 ( mol)
C% NaOH =
C% Ba ( OH ) 2

0,45.40.100
=18(%)
41,175 + 59,725 0,9
0,225.171.100
=
= 38,475(%)
41,175 + 59,725 0,9

b. Tnh nng mol ca cc cht c trong dung dch A, B, C, D.

100g dd X c 0,45mol NaOH v 0,225mol Ba(OH)2
1g dd X c 4,5.10-3mol NaOH v 2,25.10-3mol Ba(OH)2
HCl + NaOH NaCl + H2O
a
a
a
a
(mol)
2HCl + Ba(OH)2 BaCl2 + 2H2O
b
0,5b
0,5b
b
(mol)

H2SO4 + 2NaOH
Na2SO4 + 2H2O
c
2c
c
2c (mol)
H2SO4 + Ba(OH)2 BaSO4+ 2H2O
d
d
d
2d (mol)
BaCl2 + Na2SO4 BaSO4 + 2NaCl
n NaOH = a + 2c = 4,5.10 3 (mol)

0,25
0,125
0,125

pthh
pthh

0,125

H pt

0,125

2 s
mol

0,125
0,125

0,125

pthh

0,125

pthh

0,125

pthh

0,125

pthh

0,125

pthh

0,125

pt (*)

0,125

pt (**)

n Ba ( OH ) 2 = 0,5b + d = 2,25.10 3 (mol)

(a + b) + 2(c + d) = 9.10-3 (*)

m mui = (23+ 35,5)a + (137+71)0,5b + (23.2+96)c + (137+96)d =
0,83125(g)
35,5(a + b) + 96( c + d) = 0,4195(**)
Gii (*) v (**)
n HCl = 10 3 (mol); n H 2SO 4 = 4.10 3 (mol)
Trong 100ml D c:
C M ( HCl ) =

10 3
= 0,01( M )
0,1

C M ( H 2SO 4 ) =

4.10 3
= 0,04( M )
0,1

Trong 10ml C c:

0,125

C M ( HCl ) =

10 3
= 0,1(M )
0,01

C M ( H 2SO 4 ) =

4.10 3
= 0,4(M )
0,01

0,125

10ml C c 10-3mol HCl v 4.10-3mol H2SO4

500ml C c 0,05mol HCl v 0,2mol H2SO4
0,05

Trong A c: C M ( HCl ) = 0,4 = 0,125(M )

Trong B c: C M ( H SO
2

4)

0,125

0,2
=
= 2( M )
0,1

Cu 5
(2im) 1/ (1 im)
t0
0,25
CnH2n + 1,5nO2
nCO2 + nH2O

0,2 mol
0,2n mol 0,2n mol
0,25
CO2 + 2NaOH Na2CO3 + H2O
0,2n mol 0,4n mol
Khi lng NaOH phn ng: 0,4n . 40 = 16n mol
0,125
Khi lng NaOH ban u: 295,2.20% = 59,04 gam
0,125
Nng ca NaOH trong dung dch sau phn ng:
0,125
59,04 16n
.100%= 8,45%
C% =
295,2 + 0,2n.44 + 0,2n.18
n = 2, A l C2H4
0,125
2/ (1 im)
a/ Hn hp X c x mol C2H4; y mol H2
Khi lng mol trung bnh
28x + 2y
MX =
= 10,75.2= 21,5
0,125
x+ y
Suy ra: x = 3y
Ni ,t0
0,25
C2H4 + H2
C2H6
y mol y mol
y mol
C2H4 d: (x y) mol, nn hn hp Y lm mt mu dung dch brom
0,125
b/ Phn trm th tch mi kh trong hn hp X
0,125
3
.100% = 75%
%VC2H4 =
3+ 1
0,125
%VH2 = 25%
Phn trm th tch mi kh trong hn hp Y
0,125
2
.100% = 66,7%
%VC2H4 =
2+ 1
0,125
%VC2H6 = 33,3%
Lu :- Vit ng phng trnh nhng thiu cn bng hoc thiu iu kin tr 0,125
- Th sinh gii theo phng php khc: ng vn cho trn im.
- Nu th sinh gii phng php khc nhng khng trn vn, th gim kho chm im
tng ng theo p n.