Absorption of Gaze

K
K

- -

Equilibrium Between Liquid and Gas

F=C-P+

KWF
KWP

KWC
CO

WECOF
F=-+=

K
ExAFCO

EyAFCO
K
PA = H XA

KAPA
KAxA

KH

xA
PAxAK
- -

Mechanism of absorption
Etow Film theoryF

EF

PAf
PAi
CAi
CAL

EF

- -

Rate of Absorption

NA = kG (PAG - PAi) = kL (CAi- CAL)

Emol \ unit Area unit timeFKANA

KkG
Emol \ unit pressure unit Area unit timeF
KkL

KPAG
K PAi

KCAi

KCAL

ECAi -CALFEPAG - PAiF

EF
D

PAG

PAG - PAi

PAi

PA

CAi - CAL

PAe

CAL

CAi

EF
- -

CAe

PAG PAi kL
=
CAi CAL kG

kL
kG

KkGkL
W
NA = kG (PAG - PAe) = kL (CAe- CAL)

KCAL PAe
K PAGCAe

EkC , kLF
N A = k G (PAG PAI ) = k L (C Ai c AL )

EkG , kLF

= k G (PAG PAe ) = k L (C Ae C AL )

1
1 PAG PAe
=

k G k G PAG PAi

1 PAG PAi
1 PAi PAe

k G PAG PA K G PAG PAe

- -

1 1 PAG PAi
=

kG kL CAi CAL
1
1 1 P P P P
= + AG Ai Ai Ae
kG kG kL CAi CAL PAG PAi
=

1
1 PAi PAe
+

KG KL CAi CAL

P PAe
H = Ai
C Ai C AL

1
1 H
=
+
kG k G k L

1 1
1
=
+
k k Hk
L
L
G

1
H
=
k
kL
G
kLkG
KkLkG
K

- -

Absorption Equipment

Packed Columns

KEF

EF
- -

EBerl saddlesFERingsF

EF

K
K

- -

Calculation of Height of Packed Columns

EFd

AVm dY = A Lm dX

KA

KVm

EFLm
K

KY
EFX
K

Vm A d Y = NA (a dV) = kG a (PAG - PAi) A d z
=kLa (CAi - CAL) A d z
Ka
Adz= dV

- -

Height of Columns Based on Condition in Gas Film

Vm AdY = K G a (PAG PAi )Adz

P = YA P
AG
1+ Y
KP

Y
Y
Gm dY = kG aP
i dz
1 + Y 1 + Yi

Y Yi
= K G aP
dz
(
)
(
)
Y
Y
1+ i
1+

Y
Z
Vm 2 (1 + Y ) (1 + Yi )
Z = dZ =
dZ

K
aP
Y
Y
i
G
0
Y1

Vm
Z
=

K G aP

Y2

dY
Y Y Yi LL (1)
1
Y<

Height of Columns Based on Conditions in Liquid Film

ALm dX = k L a(C Ai C AL )dZ

CA
=X
CT C A
EHFCA
EHFCT
KEHF

- -

Xi
X
L
dX
K
aC
=

L
T
dZ
m
(
)
(
)
X
X
1
+
1
+
i

Xi X
= k L aCT
dZ
(1 + X i ) (1 + X )
X
Z

Lm 2 dX
LL(2)
Z = dZ =

k
aC
X

X
L
T X1
i
0

J
Height of Column Based on Overd

EFKGaKGaY-YeY-Yi

Vm
Z
=

K G aP

Y2

dY
Y Y Ye LL (3)
1

EFKLaKLaX-XeXi-X

Lm
Z
=

K L aCT

X2

dX
X X e X LL(4)
1

Z
K
K

Absorption of Dilute Gases

y=Y

GMAdy= KGaAP( ye y)dZ

- -

ye = m x + c
y e1 = m x 1 + c
ye2 = m x2 + c
m =

y e1 y e 2
LL 5
x1 x 2

y L
x
m
Vm
x
1
Lm

Vm, y
1

Lm ( x1 x ) = Vm ( y1 y )
x = x1

Vm
( y1 y )LL(6)
Lm
y

2
K G aP
dy
dz
=
y y
Vm 0
y2 e

- -

()

y2

2
dy
dy
=
y y ye y m x1 + (Vm / Lm ) ( y y1 ) + c y
1
1

1 ln

y1 m x1 + c

mV
V
1 m y2 m x1 + m ( y2 y1 ) c
Lm
Lm

()()

ln y1 ye1
1
y y x x
1 e1 e2 1 2 y2 ye1 ye1 ye2 x1 x2 ( y1 y2 )
x x y y
x1 x2 y1 y2
1 2 1 2
y1 y2 ln

( y1 ye1 )
( y1 ye1 ) ( y2 ye2 ) ( y2 ye )2

y1 y2
( y ye ) ln

Z=

Vm
y1 y2
KG aPT ( y ye ) ln

Lm
x1 x2
=
Z

KLaCT (x xe ) ln

a kLKG(KLa)(KGa)

x xy y
K

- -

EFEF

{ pa{ paCO
COxA k CO

P =H xA

PA =

{ pa

atm
{

= { atm

H = 0.186 104

atm
mol fraction

0.1316
0.186 104
= 7.07 105

xA =

- -

EFEF
kilo mol{ kil

HS

HS

Ye = X k

kilo mol{ k HSHS

k mol
W

0.015

sm2

KJ

k mol

NOGJ
0.04
= KG aP
sm 2

Z=

Vm Y1 Y2
KG aP (Y Ye )

V
y1 y2
Z= m

KG aP ( y ye )

Vm
Y

1
100

* 0.03

y =Y

Lm
X2 = 0

Vm
Y1
0.03

Lm
X1

0.013
- -

Ye = X

= x {

Ye = X

= x zero
= zero
Vm = { k mol / sm

(Y Ye ) = (Y1 Ye1 ) (Y2 Ye 2 )

Y1 Ye1

Y2 Ye 2
Y1 Ye1 = 0.03 0.026 = 0.004
Y2 Ye 2 = 0.003
(Y Ye ) =

0.004 0.0003
0.004
ln

0.003

0.0037
= 0.00143
2.59
0.015 (0.03 0.0003)
Z=
0.04
0.00143
= 7.8m
=

Z = H OG NOG

- -

K= NOG
K= HOG

H OG =

Vm
KGa

0 . 015
= 0 . 375 m
0 . 04
7 . 8 = 0 . 375 N OG
=

N OG =

7 .8
= 21
0 . 375

- -

EFEF
K mol %

k{ mol/hEHF

K{ pa
K mol %{ mol fract
KJ W
K{J

V m , Y1

Lm , X

y = 0.02
2

X 2 = 0.005

Vm , Y1

Lm , X1

y = 0.25
11

y = Y Y = y

1+ Y
1 y
X
X
X=
X =
1+ X
1 X

Y
X

- -

Vm (Y1 Y ) = Lm ( X1 X )
L(mX 1 , Y1 )
( X1 X ) + Y1 Lm
Y=
Vm
Vm

( X- Y )
E operatinglineF

EX , YF
pLm
EF

x
max

EF
KXi-XXe-XY-YiY-Yep

- -

atmyA

xA

{
{
{
{
{
{
{

{
{
{
{
{
{
{

{
{
{

{
{
{

{
{

{
{

{
{

{
{

Y1 =

y1
0.25
=
= 0.333
1 y1
1 0.25

Y2 =

y2
0.02
=
= 0.02
1 y2
1 0.02

X2 =

X2
0.005
=
= 0.005
1 X 2
1 0.005

- -

p( X, Y )

( X, Y )

(L m \ V m )min
Vm = {{

= { k mol/h

=Lm = {

- -

{ kg CO /kg kEFCOJ

CO{ atmwater

{kpak{ mJ
{kg mol/hEF{m
EFx = {y = {y = {

KGa{kg mol/h=

{ mol fractionJ
K

K{kg/msEFkg/msEF
xyeye = {x

- -

EF

W rev/min { m

J
J

EF

- -

EF

WEF

N = rev / min
r = {L={ m

WEF

Fc
= . . ( )
Fg

r = { m

WEF

Fc
2
= 0.001118 0.2032 (1000 )
Fg

= 227.2 gravities.
EF

- -

K

PA = H XA
APA
AXA

H
K

F=CP+

=WC

=WP
F=+=

EF

=
K

K
- -

KK

K
K

- -