( ‫ ان ا

دة اء ) ر‬

ni ( I 2 ) = nr ( I 2 ) + n( I 2 ) ⇒ n( I 2 ) = ni ( I 2 ) − nr ( I 2 ) :  ‫و‬ :‫اء‬
:MB ‫ ا *د ا‬4%N ‫ دة‬B‫ آ‬4‫ ه‬n( I 2 )  -1
− +
C6 H 8O6 + H 2O C6 H 7O6 + H 3O : ‫  د  ا‬-1
n ( I 2 ) = n ( AH ) = 3, 35.10 − 5 mol
n( AH ) m( AH )
4) (P ‫ ا‬Q-  ‫ و‬10mL 4) ‫*ﺝ*دة‬B ‫ ا‬B= ‫ ا‬OB‫ ﺕ‬B= ‫ه?> ا‬ AH = C6 H 8O6  C = =  -2
n( AH ).82 V M ( AH ).V
nt ( AH ) = = 2,89.10−4 mol . 78mL :*‫  ه‬2‫ا &(ﺕ‬ 0,5
10 .C = = 1, 42.10−2 mol.l −1 :  ‫و‬
. m = nt ( AH ).M ( AH ) = 0, 05 g : 4‫ ه‬M= ‫و ا‬ 176.0.2
-3
:‫  اازن‬-4 − +
− p K A1 C 6 H 8O6 + H 2 O C 6 H 7 O6 + H 3O
K A1 10
K = = = 1 0 − p K A 1 + p K A 2 = 1, 4 1 -1 C.V ‫ﺏ*)(ة‬ 0 0 %& ‫  ا‬$ ‫ا‬
K A 2 1 0 − p K A2
C.V − x f -------- xf x f &(-‫ﺕ‬.‫ن‬. 
.‫*ر‬R‫ ﺕ‬I *B-B ‫ أي أن ا‬Qr ,i = K = 1, 41  -2
C.V − xm -------- xm xm (/‫ﻥ‬.‫ن‬. 
:‫ا!یء‬
:‫وی‬#‫ ا‬$%‫ا‬ xf
:‫ )ن‬45* ‫ول ا‬- ‫ ا‬73 ‫ و‬τ = :‫م‬2 ‫& ا‬3‫ﻥ‬
14
6 C → 174 N + − 10 e :S ‫  د  ا‬-1 xm
. N (t ) = N o .e− λ .t :4 TU‫ ا‬VK ‫ﻥ*ن ا‬K -2  H 3 O + 
⇐ τ= ⇐ x f =  H 3O +  .V ‫ و‬xm = C.V
N C
. N (t 1 2 ) = o  JX ‫ ه* ا‬:WP ‫( ا‬B W( ‫ ﺕ‬-3
2 10− pH
W(  ‫ ا‬73  .‫ود‬$  ‫ ⇐ ا‬τ = = 0, 07 = 7%
C
− λ .t 1 N 1
N (t 12 ) = N o .e 2 = o ⇒ e − λ.t 12 =
2
 H 3O +  .  A−   H 3O + 
2 2 Qr ,eq = eq eq
=  ‫ رج ا‬-3
ln(2) [ AH ]eq C −  H 3O + 
λ= ⇐ λ.t 1 2 = ln(2) : -‫ ﻥ‬ln ‫ل‬Y‫د‬Z‫و ﺏ‬
(10 )
2
t 12 − pH

 ‫ و‬Qr ,eq = = 8,9.10−5 : ‫أي أن‬

.λ =
ln(2)
= 1, 242.10−4 ans −1 : λ ‫ب‬3 C − 10− pH
5580ans .. pK A = 4, 05 ⇐ K A = Qr ,eq = 8,9.10−5
:*‫  ﻥ_ط  ه‬-4 - II
a(t ) = λ.N (t ) = λ.No .e−λ.t = ao .e−λ.t ⇒ a(t ) = ao .e−λ.t : ‫ ﻡد ا‬1-2
C 6 H 8 O 6 + O H − → C 6 H 7 O 6− + H 2 O
a(t ) = ao .e− λ .t  -5 : <)= ‫  ا‬2-2
>?‫ ه‬n(C6 H 8O6 ) = n(OH ) = CB .VBE = 2,88.10−4 mol
−
a (t )  a (t ) 
 ‫و‬ = e − λ .t ⇒ ln   = −λ .t ⇐ CB ‫ دة‬B‫ ⇐ آ‬VA = 10mL 4) ‫ ﺕ*ﺝ‬4 ‫ ا‬B= ‫ ا‬4‫ ه‬B= ‫ا‬
ao  ao 
‫ و‬Vs = 100mL 4) ‫?اﺏ‬B ‫دة ا‬B ‫ ا‬B‫ آ‬4‫(ص ه‬2 ‫ ا‬4) F‫ﺱ=*رﺏ‬I‫ا‬
 a (t )  1
t = ln   . = 3341, 49ans 2,88.10−4 mol → VA = 10mL
 ao  λ ns = 2,88.10−3 mol ⇐ : 
ns → Vs = 100mL
‫ أي‬3341, 49ans − 1995ans = 1346ans ‫ ش )(*ن‬-6
.a‫& ا ر‬K ‫ ﺱ‬1346 4) ‫اﻥ ش‬ :4‫(ص ه‬2 ‫ ا‬4) ‫*اﺝ‬B ‫ ا‬C J ‫ دة ا‬B‫آ‬
:&‫اﻥ‬ ns = 2,88.10−3 mol
uuur : J‫ *ﺕ‬ 4‫ﻥ‬O ‫ا‬ ‫ﻥ*ن‬2 ‫ا‬
ur ur
b&R‫ﺏ‬ -r1 : mg ‫ ا ب‬3-2
: -‫ ﻥ‬AX ‫*ر‬$B ‫ ا‬LM c2‫ﺱ‬Z‫ و ﺏ‬P + R = m.a m
ns = ⇒ m = ns .M ( AH ) = 0,5 g = 500mg
‫ و‬Rx = 0 :‫ )ن‬MBd ‫=ك‬I‫ أن ا‬B‫ و ﺏ‬Px + Rx = m.ax M ( AH )
:  ‫ و‬Px = m.g.sin (α ) . 500mg LM ‫*ي‬$ C J) ‫(ص‬K ‫أي آ‬
‫(آ‬$ ‫ و  ا‬ax = g .sin α = cte ⇐ m.g.sin α = m.ax : ni ( I 2 ) %& ‫ ا *د ا‬4%N ‫ دة‬B‫ آ‬:  -3
. ax = 5m.s −2 : ‫رع‬3 ‫م و ا‬/‫(ة ﺏﻥ‬h B23 ‫ أن‬B‫ ﺏ‬ni ( I 2 ) = C2 .V2 = 5,3.10−3.10.10−3 = 5,3.10−5 mol
1 n( I 2 ) MB ‫ ا *د ا‬4%N ‫ دة‬B‫ ا *د *ﺝ ﺏ*)(ة )ن آ‬4%N
: x = a.t 2 + Vo .t + xo :X ‫ د  ا‬B ‫ ا‬-2
2 . 2‫ ا &(ﺕ‬4) ‫*ﺝ*دة‬B ‫ ا‬F‫ﺱ=*رﺏ‬I‫ ا‬CB n( AH ) ‫ دة‬B‫وي آ‬3‫ﺕ‬
x = 2,5.t 2 :‫ أذن‬Vo = VA = 0 ‫ و‬xo = xA = 0 .MB ‫ ا *د ا‬4%N ‫ دة‬B‫د آ‬$
::2&B ‫ ا‬nr ( I 2 ) ‫ ا *د‬4%N ‫ دة‬B‫ آ‬$‫ ﺕ‬J=B ‫ﻥ‬O ‫ (ة ا‬B ‫ﺏ‬
 ‫ و‬VB = 5.tB :(3 ‫ب ا‬3 -3
n( S 2O32− ) 5.10−3.7,8.10−3
nr ( I 2 ) = = = 1,95.10−5 mol
2 2
 xB 2

:$%‫(ب ا‬+ -4 VB = 5m.s −2 : ‫ و‬. ‫ع‬.‫ ت‬t B = = 1s ⇐ xB = 2,5.t B

2,5
1 ur r
Ee1 = C.uC2 = 0.5.0, 2.10−6.102 = 10−5 J ⇐ t = 0  P = m .a :J‫ *ﺕ‬4‫ﻥ‬O ‫ﻥ*ن ا‬2 ‫ ا‬b&R‫ ﺏ‬: JX ‫ ا‬J ‫ د‬B ‫ ا‬1 -4
2
Ee 2 = 0,5.0, 2.10−6.52 = 25.10−7 J ⇐ uC = 5V ‫ أن‬t = 4T  ax = 0  Px = m.ax = 0
 ⇐
∆Ee = Ee1 − Ee 2 a y = g  Py = m.a y = mg
r
- II ‫*ر‬$B ‫ ا‬LM B/ B23 ( B, i ) ‫*ر‬$B ‫ ا‬LM ‫(آ‬$ ‫و  ا‬
-1 r
x = V Bx t + x o :X ‫ د  ا‬B ‫ ( و  ا‬B, i )
‫&دة‬B ‫ ا‬KR ‫ ا‬C* ‫ ﺏ‬F ‫ﻥ ا ?ﺏ?ﺏت و ذ‬5 *‫*  ه‬B ‫دور ا‬ r
. r  T* ‫و ا‬2 4) ‫ *ل ﺝ*ل‬B‫ﺏ‬ ‫م‬/‫(ة ﺏﻥ‬h B23 ( B, j ) ‫*ر‬$B ‫ ا‬LM ‫(آ‬$ ‫و ا‬
 ‫ د‬B ‫ ا‬L ‫ إ‬5*‫ ﻥ‬2‫ﺏ‬3 ‫ ا‬2(R ‫ ا‬t‫ ﺏ‬:Mr ‫ د  ا‬B ‫ ا‬-2 1
x y = a y t 2 + V By t + y o
2
d u r − K duC 1 2
. 2C + + .uC = 0 ⇐ :  ‫ ا‬Mr ‫ا‬ ur
dt L dt LC VB :  =_ ‫ ا‬73
. K = r ‫ أن =*ن‬7- -3 V B x = V B co s α x = 0
- III y  ‫و‬ o t = 0 
. uR (t ) OB Y2 ‫ و‬Z f R ‫ن‬I u (t ) OB Y1 -1 
 V B y = V B sin α  y o = 0
U 4  x = VB cos α .t
 ‫ و‬Z o = m .R = .20 = 40Ω  -2  x = 4,3.t 
U Rm 2   1 2 :  ‫و‬
 y = 5.t + 2,5.t  y = gt + VB sin α .t
2

. Z o = R + r ⇒ r = Z o − R = 40 − 20 = 20Ω  2
1 x
⇐ Lω = :J‫  ا (ﻥ‬: L BK ‫ب‬3 ‫ و‬t= :n3‫ ﻥ‬x X ‫ د  ا‬B ‫ ا‬J :‫ ﻡد ا(ر‬2-4
Cω VB cos α
1 1 g
N o = 50 Hz  . L = = = 0,5 H y= x 2 + x.tan α : ‫ إذن‬y  ‫ د‬B ‫ ا‬4) C*  ‫ﺏ‬
C.ω 2
C.(2π .N o ) 2
2VB .cos (α )
2 2

Um U .Q-MT J ‫* &رة‬d)
. Io = = Rm = 0, 07 A :‫ة ا ر‬T -4 :‫*ط‬23 ‫ ة ا‬3-4
2.Z o 2.R
:  ‫ و‬xI = HI = 4,3m  ‫ و‬x = 2,15.t
: WO=B ‫ ا‬4R‫ (ﺏ‬J‫ ا *ﺕ( ا  ل ﺏ‬BK -5
1 1 x 4, 3
U c = Z c .I o = .I o = .I o I R2 ‫ ا‬L ‫*ل إ‬5*M K(h3B ‫ة ا‬B ‫ ا‬4‫ ه‬t = = = 1s
Cω C.2π .N o 4, 3 4, 3
: )(‫ ا‬4-4
U L , r = r 2 + ( Lω ) .I o = :  T* ‫ ا‬4R‫ (ﺏ‬J‫ا *ﺕ( ﺏ‬
2
ur Vx = x& = 4,3
t = 1s ‫ )ن‬I R2 ‫  ا‬V 
Vy = y& = g.t + VB sin α
2
 1 
Z BM = r2 +  Lω −  ⇐ M ‫و‬ B J‫ﺏ‬ (‫ا *ﺕ‬ - 6
14243 Cω  ur Vx = 4,3m.s −1
=0 ‫و‬ V I 
−1
Vy = 10.1 + 5.1 = 15m.s
U BM = r.I o  ‫ و‬J‫ه(ة ا (ﻥ‬u
VI = Vx2 + Vy2 = 4,32 + 152 = 15, 6m.s −1
:‫ا*)ء‬
uc + uL = 0 :  ‫) ا *ﺕ(ات‬r‫ﻥ*ن إ‬K b&R‫ ﺏ‬1-
d 2uC r duC 1 di
2
+ + .uC = 0 ⇐ uC + ri + LC = 0 ⇐
dt L dt LC dt
duc 1 1
 ‫ و‬i = C ‫ و‬Et = C.uC2 + L.i 2 :M= ‫ ا‬KR ‫ ا‬-2
dt 2 2
2
1 1  duC 
. Et = C.uC + L  C.
2

2 2  dt 
dEt duC du d 2u
= C.uC . + LC 2 . C . 2C :M= ‫ ا‬KR ‫ق ا‬2T‫ ﺏ‬-3
dt dt dt dt
2
d u
uC . + LC 2C = −r.i :  Mr ‫ د  ا‬B ‫ ا‬73
dt
dE du d 2u
. t = C. C (uC . + LC 2C ) = i. ( −r.i ) = −r.i 2 ⇐
dt dt dt