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weet MATERIAL SAFETY DATA SHEET ttree version Date..........- 01/05/2001 ARCAL COMPOUND 302 Print Date 03/30/2004 SECTION 1 COMPANY NAME WHO SENT MSDS.. COMPANY ADDRESS...... EMERGENCY PHONE NUMBER. MSDS VERSION NUMBER. . HAZARD RATING (HMIS) HMIS DESIGNATION KEY PRODUCT IDENTIFICATION J.W. HARRIS COMPANY 4501 QUALITY PLACE MASON, OHIO 45040 (513) 754-2000 (800) 424-9300 3 ARCAL COMPOUND 302 HEALTH-1 REACTIVITY-2 FLAMMABLITY-1 OTHER-2 4-SEVERE HAZARD 3-SERIOUS HAZARD 2-MODERATE HAZARD 1-SLIGHT HAZARD O-MINIMAL HAZARD ECTION 2 HAZARDOUS COMPONENTS WOTERLAL {BY WEIGHT CAS NUMBER OSHA PRL ACGIH TL (Ka/M3) SBC 313 AYDROCHLORTC ACID B 1640-01-41 5 eK 138 YBTALLIC CHLORIDES cn SECTION 3 BOILING POINT MELTING POINT VAPOR PRESSURE. VAPOR DENSITY (AIR SOLUBILITY IN WATER. SPECIFIC GRAVITY. EVAPORATION RATE.... APPEARANCE AND ODOR. 10025-77-1 1932NG/KG BATS oR >1 PARTIALLY SOLUBLE 1.46 D1 YELLOW PASTE WITIH ACID ODOR SECTION 4 FLASH POINT Page 1 SECTION 4 FIRE AND EXPLOSION DATA CONT'D EXTINGUISING MEDIA.............. SPECIAL PROCEDURES... UNUSUAL HAZARDS..... WATER, DRY CHEMICALS, FOAM, USE SELF CONTAINER BREATHING APPARATUS WHEN INVOLVED IN FIRE. KEEP CONTAINER COOL ACIDIC PRODUCT REACTS WITH METALS TO PRODUCE HYDROGEN SECTION 5 REACTIVITY DATA STABILITY 7 ef STABLE CONDITIONS TO AVOID.. sesee+. NONE KNOWN HAZARDOUS POLYMERIZATION. INCOMPATABILITY. . HAZARDOUS DECOMPO: oe WILL NOT OCCUR CONCENTRATED ALKALIS AND METALS HYDROGEN CHLORIDE AND CHLORINE WITH INCOMPLETE COMBUSTION SECTION 6 HEALTH HAZARD DATA ROUTES OF ENTRY... HEALTH HAZARDS . CARCINOGENICITY. . SIGNS & SYMPTOMS OF EXPOSURE... MEDICAL CONDITIONS FROM EXPOSURE EMERGENCY & FIRST AID..........- SKIN CONTACT, BYE CONTACT AND INHALATION SKIN BURNS ON SKIN DUE TO PROLONGED CONTACT; EYES DAMAGED ON CONTACT; BREATHING VAPORS AND MIST WILL DAMAGE THE RESPIRATORY TRACT. NA SEE HEALTH HAZARDS SEVERE BURNS ON SKIN, IRRITTATION OF SKIN, RESPIRATORY TRACT. SEVERE SKIN BURNS WITH ULCERATION. REMOVES CALCIUM FROM TISSUES EYE-IF SPLASHED INTO EYES, FLUSH WITH WATER 15 MINUTES, IF IRRITATION PERSISTS, CALL PHYSICIAN. SKIN-REMOVE CONTAMINATED CLOTHING AND WASH SKIN THOROUGHLY WITH SOAP AND WATER OR DILUTION OF ZEPHRIAM OR Page 2 HEALTH HAZARD DATA CONT'D ADDITIONAL INFORMATION CALCIUM GLUCONATE. INHALATION-IF OVERCOME BY VAPOR, REMOVE FROM EXPOSURE, CALL DR. IMMEDIATELY. IF BREATHING IRREGULAR OR STOPPED, START RESUSCITATION, ADMINISTER OXYGEN. INGESTION-DO NOT INDUCE VOMITING SEEX IMMEDIATE MEDICAL ATTENTION. PRECAUTIONS FOR SAFE HANDLING AND USE SPILL AND LEAK PROCEDURES WASTE AND DISPOSAL METHOD HANDLING AND STORING PRECAUTIONS OTHER PRECAUTIONS FLUSH SMALL AMOUNTS TO DRAIN, COLLECT AND TREAT LARGE AMOUNTS WITH SODIUM BICARBONATE TO COUNTERACT ACIDITY AND DISPOSE TO SOLID WASTER. PH ADJUSTMENT AND DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. STORE IN COOL DRY PLACE MINIMIZE BREATHING VAPOR, MIST OF FUMES AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. REMOVE CONTAMINATED CLOTHING, LAUNDER OR DRY-CLEAN BEFORE REUSE. REMOVE, CONTAMINATED SHOES AND THOROUGHLY CLEAN BEFORE REUSE; DISCARD IF SOAKED. CLEAN SKIN THOROUGHLY AFTER CONTACT BEFORE BREAK AND MEALS, AND AT END OF WORK PERIOD PRODUCT IS READILY REMOVED FROM SKIN BY WATERLESS HAND CLEANERS FOLLOWED BY WASHING THOROUGHLY WITH SOAP AND WATER. DOT: HYDROCHLORIC ACID SOLUTION/8 (CORROSIVE) /UN1789/PKG. GRP. IT CONTROL MEASURES RESPIRATORY MEASURES VENTILATION. ..... USE SUPPLIED AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES IF NEEDED USE ONLY WITH VENTILATION SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED EXPOSURE LIMIT OR BUILDUP OF EXPLOSIVE CONCENTRA- TIONS OR VAPOR IN AIR. Page 3