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Historical Development of Dental Composites (1956-2005): a. b. Unfilled Resins: Preceded by Silicate Cements
MMA + PMMA
Filled Resins:
MMA + PMMA/Filler BISGMA + Macro-Filler BISGMA + Macro-Filler BISGMA + Macro-Filler BISGMA + Micro-Fillers BISGMA + Midi-Hybrid BISGMA + Midi-Hybrid BISGMA + Midi-Hybrid BISGMA + Midi-Hybrid BISGMA + Midi Hybrid BISGMA + Nano-Hybrid (1950) (1958) + Silane + Silane + Silane + Silane + Silane + Silane + Silane + Silane + Silane + (Enamel BA) + (Enamel BA) + (Enamel BA) + (Enam/Dent BA) + (Enam/Dent BA) + (3-Step Universal BA) + (3-Step Universal BA) (1992) + (1-or-2-Step Universal BA) (2005)
2.
Definition of Composites: a. Dental Composite (1) Matrix (2) Filler (3) Silane (4) Bonding System
Unfinished Composite Surface
= Matrix + Filler + Silane + (Bonding Agent) = Continuous Phase = Dispersed Phases = Internal Interface Coupling Agent = External Interface Coupling Agent
Enamel Surface
B.
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b. Filler Particle Size (Average): (--) Megafill Glass inserts for composites (1) Macrofill Large Particle Size (40 m) (ORIGINAL Composites) (2) Midifill Medium Particle Size (4 m) (TRADITIONAL; CONVENTIONAL) (3) Minifill Small Particle Size (NEW SMALL PARTICLE) (4) Microfill Very Small Part Size (.02 m) (MICROFILL; FINE PARTICLE) (--) Nanofill Atomic clusters (0.005 m) c.
Particle Size Distribution (or Mixture): (1) Hybrids = Mix of two particle size fractions of fillers (a) Midi-hybrid = Mix of microfillers and midifillers (b) Mini-hybrid (or micro-hybrid) = Mix of microfillers and minifillers (c) Nano-hybrid = Mix of nanofillers and midifillers (or minifillers)
MINI FILLER
MICRO FILLER
1 m
0.1 m
0.01 m
d.
Method of Filler Loading: (1) Homogeneous Filled Composites: mixture of resin and filler (2) Heterogeneous Filled Composites: mixture of pre-cured composite pieces with resin and filler. (Organic Filler = Pre-Cured Composite Resin Particles) Handling Properties or Texture: (1) Flowable Hybrid (2) Conventional Hybrid (3) Packable (Condensable) Hybrid
e.
2.
MATRIX Classification System: a. Matrix Composition: (1) BISGMA or BISGMA-like (2) Urethane Dimethacrylate Activation Method for Matrix Formation: (1) Auto-Cured (Self-Cured) (2) Visible Light-Cured (QTH, PAC, Laser, LED) (3) Dual-Cured (VL and Self-Cured) (4) Staged-Cure (2 Stages of Visible Light Curing)
b.
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Not Shown
Not Shown
B.
C.
Not Shown
Not Shown
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1997-2005: FLOWABLE COMPOSITES: AeliteFlo Crystal-Essence Filtek Flow FloRestore Flow-It Heliomolar Flow Revolution True-Look UltraSealt XT+ VersaFlow Wave Flowable Metafil Flo F F F F F F F F F F F F (Bisco) (Confi-Dental) (3M-ESPE) (Den-Mat) (Jeneric-Pentron) (Ivoclar/Vivadent) (Kerr) (Denpac) (Ultradent) (Centrix) (Ivoclar/Vivadent) (Sun Chemical)
1998-2005: PACKABLE COMPOSITES: Solitaire,Solitaire2 ALERT Condens. Surefil Prodigy Cond. Filtek P60 Pyramid Glacier Synergy Compact Definite Heliomolar HB P P P P P P P P P P (Heraeus Kulzer) (Jeneric-Pentron) (Dentsply/Caulk) (Kerr/Sybron) (3M-ESPE) (Bisco) (SDI) (Coltene-Whaledent) (DegussaP (Ivoclar/Vivadent)
2001-2005: MINI/MICRO-HYBRIDS Esthet-X POINT 4 VITALESSENCE GRADIA Direct H-MN H-MN H-MN H-MN (Dentsply) (Kerr) (Ultradent) (GC America)
2002-2005: NANOFILLS 1999-2000: pH CONTROLLING COMPOSITES: Supreme Simile H-NF (3M-ESPE) H-NF (Jeneric-Pentron) Ariston pHc ? Ivoclar/Vivadent
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C.
Manipulation: 1. Cavity Preparation Considerations: a. Cavity Liners (1) Calcium Hydroxide Cement Liners (use sparingly) (2) Zinc Oxide Eugenol Based Liners (DO NOT USE !!!) (3) Visible Light-Cured Glass Ionomer b. Beveling (for esthetics but do not bevel margins that on functional paths) c. Acid Etching: Liquid 37% H3PO4, Gel 37% H3PO4, PAA, EDTA, Citric Acid d. Bonding Systems (1) Enamel and Dentin Bonding Systems: (2) Universal Bonding Systems (Enamel, Dentin, Metal, Ceramics, GI, ) Product Selection: a. Application: III, IV, V, and I/II b. Activation System: Auto-Cured, Light-Cured, Dual Cured, Staged Curing Shade Guides: a. Color Matching: (1) Match to moist tooth structure (2) Tooth structure changes color with time
2.
3.
4.
Placement: a. Composite Syringes (minimize porosity problems) b. Delrin Instruments or Plastic Coated Instruments (non-stick) c. Alcohol Wipes (help to let instruments release sticky composite) Polymerization Techniques: a. Incremental Additions (<1.5-2.0 mm / dark shades more difficult to cure) b. Curing Cycles (20-40 s historically; depends on curing system) c. Post-curing (Good idea) Air-Inhibited Layer = 1-5 m thick superficial layer of resin that does not cure while it is in contact with oxygen from the surrounding air. As soon as an increment of restorative material is added, the air is displaced, the oxygen concentration drops, and the material copolymerizes with the restorative material on top of it.
5.
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6.
Visible Light-Curing: a. Variables: Output (>300mW/cm2); Wavelength ( = 474 nm), Distance ( 1 mm); Time (20-40s)
Bulb frosting or degradation Light reflector degradation Optical filter degradation Fiber-optic bundle breakage Light-guide fracture Tip contamination by resin buildup Line voltage inconsistences Sterilization problems Infection control barriers Light tip direction Access to restoration DISTANCE from surface Size of tip Tip movement TIME of exposure Restoration thickness Cavity design Filler - amount and size Restoration shade Monomer ratios
Procedural Factors
Restoration Factors
b.
Equipment Maintenance: (1) Minimum Output Level = 300 mW/cm2 (check with radiometer) (2) Clean curing lights regularly
c.
Visible Light-Curing Units: (1) Quartz Tungsten Halogen (3M XL-3000, Kerr/Demetron Optilux 501) (2) Quartz Tungsten Halogen [staged] (ESPE Elipar Highlight, VIP Light) (3) Plasma Arc Light [PAC] (4) Laser Curing Light (5) Light-Emitting Diode Light [LED Light] (ESPE Freelight 2, LEDemetron)
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7.
Finishing and Polishing: a. COARSE (Gross) Reduction or Finishing = 10-100 m scratches (1) White Stone, Regular Diamonds (2) Do not use at the margins b. FINE Finishing = 1 -10 m scratches (1) 6 or 12 fluted carbide finishing burs (e.g., Midwest #7901) (2) Fine Finishing Diamonds (Brasseler) c. Polishing (or Final Finishing): (1) Medium, fine, and superfine discs (3M SOFLEX) = 1-0.1 scratches (2) Finishing strips (3) Composite diamond polishing pastes
SURFACE ROUGHNESS = Ra Average up-and-down geometry = 20 m
COARSE finished
2 m
FINE finished
0.2 m
Polished
Fine grooves
TWO CRITICAL FACTORS for Finishing and Polishing: (1) Abrasive size (2) Filler particle size
8.
Product Package Notes: a. Components: Shades, Bonding System, F/P equipment, expiration date b. Shelf Life: typically 12 (8-18) months
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D.
Properties: Structure/Properties vs Clinical Performance 1. Physical Properties: a. Polymerization Shrinkage: Produces marginal gaps --> debonding, microleakage, staining
5 65% Conversion 50% Filler 25% Bis-GMA 25% TEGDMA
SHRINKAGE (%)
Porosity Formation
15-25% = Gellation
(Internal Contraction)
Bond Stretching
(External Contraction)
1 0 0 25 50
Flow
75 100
CONVERSION (%)
b. Cyclic Thermal Expansion and Contraction: Produces marginal fractures --> microleakage, staining (e.g., [3600 m] [45x10-6 ppm/C] [50C] = 7 m )
2.
Chemical Properties: a. Degree of conversion (DC, %) is low (complete = 55-65%; undercured = <55%) b. Characteristics shape-of-cure: c. Limited depth-of-cure (mm):
Curing Light
3. DEPTH-OF-CURE 0 mm 1 2 Z100
3 4
d. e.
Matrix absorption of water and other intraoral fluids Adverse reactions of matrix additives - contribute to yellowing
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3.
Mechanical Properties: a. Tensile Fatigue: produces marginal fractures b. WEAR: Causes loss of composite volume (1) Microfracture Theory (Leinfelder) (2) Hydrolysis Theory (Soderholm) (3) Chemical Degradation Theory (Wu) (4) Protection Hypothesis (Jorgensen, Bayne, and Taylor)
FOOD BOLUS
INTER-PARTICLE SPACING
c.
Repair: Rebonding failed areas of composite restorations (1) Mechanical roughening of enamel and composite surfaces (2) DBA applied to enamel and composite surfaces (3) Restore surface with new composite
4.
Biological Properties: a. Degradation (by esterase, CP) decomposition into H20 and HCHO b. Desorption release of BPA, BISGMA, other monomers
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MULTIPLE CHOICE STUDY QUESTIONS: (Answers are bolded) The three major components of composite restorative materials are: a. Resin -- Silane -- Filler b. Silane -- Filler -- Bonding System c. Bonding System -- Filler -- Acrylic Resin d. Acid Etchant -- Bonding Agent -- Acrylic Resin e. Acid Etchant -- Bonding Agent -- Filler What is the role of silane in composite? a. Coupling agent b. Bonding agent c. Conditioning agent d. Acid etchant e. Polishing agent Which ONE of the following is NOT a component of bonding agents used with composite restorations? a. Reinforcing filler b. Inhibitor c. Initiator d. Low MW monomer e. BIS-GMA Which ONE of the following methods is NOT used to categorize composite restorations? a. Weight percent filler level b. Volume percent filler level c. Method of matrix activation d. Filler particle size (or distribution) e. Composite shade Earlier generations of composites (macrofills) contained which ONE of the following volume percent levels of filler? a. 30 v/o b. 40 v/o c. 50 v/o d. 60 v/o e. 70 v/o 50 v/o filler corresponds to what w/o filler? a. 25 w/o b. 45 w/o c. 65 w/o d. 75 w/o e. 90 w/o Which ONE of the following products contains the MOST filler? a. Macrofill Composites b. Pit-and-Fissure Sealants c. Microfill Composites d. Heterogeneous Microfills e. Hybrid Composites
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Which ONE of the following products contains ONLY very small filler particles? a. Macrofill Composites b. Midifill Composites c. Minifill Composites d. Microfill Composites e. Hybrid Composites Which ONE of the following materials is NOT a commercial composite? a. Delton b. Filtek Z250 c. Prodigy Condensable d. Heliomolar e. Revolution HELIOMOLAR is classified as a: a. Heterogeneous Microfill b. Megafill c. Midifill d. Micro-hybrid d. Flowable SIMILE is classified as a: a. Microfill b. Minifill-Hybrid c. Midifill-Hybrid d. Megafill e. Nanofill-Hybrid Z250 is classified as a: a. Midifill b. Macrofill c. Microfill d. Heterogeneous Microfill e. Midifill Hybrid Which one of the following is a flowable composite? a. Prodigy b. AeliteFlo c. Filtek Z250 d. Surefil e. TPH Spectrum Which one of the following is a packable composite? a. Prodigy b. AeliteFlo c. Filtek Z250 d. Surefil e. Prodigy Which of the following hybrid filler systems would not be clinically practical? a. Macrofill + Microfill b. Midifill + Microfill c. Minifill + Microfill d. Minifill + Nanofill e. Microfill + Nanofill
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What does a heterogeneous filler contain? a. Organic and inorganic phases b. Two different inorganic phases c. Porosity within the filler particle d. Crystalline and non-crystalline ceramic phases Which one of the following systems is currently NOT used for curing composites? a. Ultraviolet-light curing b. Visible-light curing c. Chemical curing d. Dual curing e. Very high intensity light curing Which one of the following produces the LEAST depth-of-cure? a. Laser curing b. Very high intensity light curing c. Chemical curing d. Visible-light curing e. Dual curing The typical shelf life of composite restorative materials is: a. 3 months b. 6 months c. 12 months d. 18 months e. 24 months The batch number on the composite package is a code for: a. The date of BISGMA resin manufacture b. The date of glass silanation c. The date of composite manufacture d. The date of transport from the factory e. The date of expiration of the package Microfilled composites are retained principally by: a. Resin tags b. Gross mechanical retention c. Chemical bonding to enamel d. Chemical bonding to dentin e. Chemical bonding to enamel and dentin Which one of the following acids is generally recommended for etching? a. Maleic acid b. Polyacrylic acid c. Tartaric acid d. Phosphoric acid e. EDTA In which of the following categories is dentin bonding of critical importance? a. Class III and IV restorations b. Class V and Erosion-Abrasion Restorations c. Class I and II restorations
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Which ONE of the following does not affect the depth-of-cure of double bonds in composites? a. Method of activation b. Incremental addition c. Post-curing d. Composite Color e. Finishing Procedure What is the reason for choosing a self-curing (or dual curing) composite rather than light-curing one? a. Large size of the restoration b. Poor access for the curing light c. High level of filler content d. Type of filler in the composite e. Ease of finishing What is the minimum acceptable level for visible curing light outputs? a. 50 mW/cm2 b. 150 mW/cm2 c. 300 mW/cm2 d. 550 mW/cm2 e. 1500 mW/cm2 Which one of the following curing systems has the highest energy output? a. 3M XL 3000 b. ESPE Elipar c. Kerr Demetron 501 d. Caulk Prolite e. Vivadent Vivalux 2 Which one of the following materials is not a retarders or inhibitors of chain reaction polymerization? a. Eugenol b. Calcium Hydroxide c. Water d. Air e. Hydroquinone What component of air is responsible for producing an air-inhibited layer on free radical initiated acrylic resin systems? a. O2 b. N2 c. NO2 d. H2 e. CO2 Which ONE of the following materials should not be used as a base or liner below a composite resin restoration? a. Zinc Oxide Eugenol Cement b. Calcium Hydroxide Cement c. Zinc Phosphate Cement d. EBA Modified ZOE Cement e. Polycarboxylate Cement
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What is the main reason for avoiding the use of green stones, white stones, or coarse diamond burs for finishing a composite? a. Heat generation b. Battering of enamel margins c. Poor abrasivity d. Scratch width e. Discoloration of the composite What range of scratches would be considered FINE finishing? a. 100-1000 m b. 10-100 m c. 1-10 m d. 0.1-1 m e. 0.01-0.1 m Which ONE of the following finishing procedures produces the smoothest surface on a composite? a. Talc b. Soflex discs c. Finishing strips d. Fine diamonds e. Carbide burs Which ONE of the following finishing procedures produces the smoothest surface on a composite? a. Talc b. Finishing strips c. Diamond finishing burs d. Carbide burs e. Diamond finishing pastes What is the primary problem resulting from polymerization shrinkage? a. Marginal gap formation and microleakage/staining b. Separation of the filler and matrix phases c. Markedly increased water absorption d. More rapid occlusal wear e. Matrix discoloration What is the typical level of polymerization shrinkage for most dental composites? a. < 0.25 % b. 0.25-2.0% c. 2.5-4.0 % d. 6.0-10 % e. 10-12 % What is the percentage conversion for a well-cured composite restoration? a. 100% b. 80-90% c. 65-80% d. 55-65% e. 45-65%
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What is depth-of-cure possible for an A2 shade of hybrid composite ? a. 5-10 mm b. 4-5 mm c. 2-3 mm d. 1-2 mm e. 1 mm Which of the following MECHANISMS best explains the WEAR of surfaces of posterior restorations? a. Microfracture Theory b. Hydrolysis Theory c. Chemical Degradation Theory d. Protection Theory What do dental composites produce when they undergo superficial decomposition over long times? a. Monomers b. Formaldehyde and water c. Acrylic acid d. Bisphenol-A e. Oligomers What is the objective of "rebonding"? a. Repairing voids at margins during composite insertion b. Bonding together of adjacent composites at proximal contacts c. Bonding of composite to glass ionomer cement bases d. Bonding of new over old composite for esthetic improvement e. Re-application of dentin bonding agent DISCUSSION STUDY QUESTIONS: What classification of composite material (e.g., microfill) would you choose for an MO restoration in a second molar? Defend your choice in terms of wear resistance. What is the predominant mechanism of failure in a Class I posterior composite restoration? When would you expect to encounter secondary caries with 10 year old posterior composite resin restorations? What treatment would you suggest for a partially worn Class III restoration which is now collecting substantial surface stain? What is the difference in discoloration mechanisms between older macrofill composites and microfill composites for anterior Class III restorations? What composite or combination of composites might be used to restore a deep Class III preparation?