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4
1. 85.
............................................................................. ............................5
2. 88.
............................. ..........................13
3. 89.
............................. ..........................22
4. 101.
.............. ..........................32
5. 102.
............................................................... ..........................37
6. 110.
........................................................... ..........................42
............................... ..........................50
3
3
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85
: .
: , ,
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, .
1
1.1
,
. .
, Al, Zn, Sn, Pb, Hg, Fe, Cu, Ag,
Au, Pt, Pd ,
.
. .
:
1.
.
2.
,
.
1 2 ,
( ).
1 < 2, 1 , 2(. 85.1). ,
1
2. 1 5 , 2
.
: 1, , 2,
.
,
,
85.1
(. 1).
, 1 2
, (.
85.1) ,
A2 1
(85.1)
' =
,
. '
.
EF1 EF2
,
,
EF 1
EF 2
" =
(85.2)
,
,
:
n1
" =
ln
n2
(85.3)
; n 1 n2 1
2 .
:
A2
1
'+
" =
+
(85.4)
1.2
. ,
,
0,
. ,
,
0,
. ( ),
.
. ,
,
() .7 ,
,
.
.
.
,
,
.
,
,
.
.
. (), ,
,
() ,
.
.
, ,
,
, .
, ,
,
,
.
. .
1 2 (85.2)
8 85.2
,
, ,
,
, (85.4)
= = 2 1 = 0 .
(85.5)
1 2 (. 85.2),
2 > 1
= 2 1 .
(85.6)
1 2 (85.4)
(85.6), :
n1
(85.7)
=
ln
( 2 1) .
n2
,
:
n1
(85.8)
= =
ln
,
n2
= 2 - 1.
n1
(85.9)
ln
n2
.
. (85.9) (85.8) :
(85.10)
= ,
(85.11)
=
,
= 1.
, .
,
.
(. 85.3).
85.3
.
.
, ,
. , ,
.
, .
( 1900) .
.
, .
( 700)
- -
.
10
2
1.
1. (. 85.3).
2. 0
.
3.
.
4. 5
=-0
.
5. .
85.1
1
2
3
4
5
6
7
8
9
10
..
T,
,
=f(T)
T
.
7. .
6.
2.
1. =f(T),
. ,
,
2 1
,
T2 T1
(85.12)
(T1; 1) (T2; 2) 1 2
=f(T).
11
2. (85.9)
.
3. .
1.
?
2.
?
3.
?
4.
?
5.
.
6. ?
7. ?
?
8. ?
9.
?
10.
?
11. ?
12. ?
13.
?
14. ?
15.
?
16.
.
12
88
:
,
.
:
, , , ,
, ,
, .
1
1.1
, ,
,
.
, ,
, .
.
88.1
13
.
,
(. 88.1).
. ,
,
.
.
88.2
,
D
, (. 88.2).
.
,
D
. , ,
.
,
, ,
.
n-. , ,
,
. , ,
14
,
, ()(. 88.3).
,
88.3
. ,
,
.
,
(. 88.4).
.
, ,
,
.
88.4
15
, .
(p-). ,
,
,
.
,
,
n- , p-
.
,
.
1.2 p-n-
-
.
n-
. n-
. ( 88.5)
p- n-
- .
,
.
.
n- p- p- n-.
p-n-
. 0
n- p- (. 88.5).
.
16
88.5
88.6
p-n- ,
n- , p .
0 . >>0,
p n-, .
(. 88.6).
p-n-
(
p-, n-),
0 ,
(. 88.7).
p-n-
17
,
, .
88.7
p-n-,
.
, .
.
.
(
).
-
p-n- . 88.8.
1888.8
p-n-
,
. p-n-
.
,
I I (U =
=const):
I
=
.
(88.1)
I
,
.
,
. 88.9.
2
1. . 88.9.
2. ,
.
3. ,
1-2, 5.
4. ,
0,5 ,
.
5. -
3-4,
,
.
19
88.9
6. ,
0,5 ,
.
7. (.. 2-6)
, 6.
8. .
88.1
U,
U,
U,
U,
9. -
.
,
.
,
.
10. (88.1)
.
11.
.
20
1.
?
2. ?
.
3.
? .
4.
n-.
5.
p-.
6.
?
7. ? ?
8.
.
9.
.
10.
?
11.
-
.
12. ?
13.
, ?
21
89
: ,
.
: , , ,
, ,
.
1
1.1
.
,
.
.
,
, .
N ,
, N . ,
,
N ,
.
. ,
() .
. , ,
,
,
. . 89.1
22
r
. , ,
, .
,
.
89.1
. ,
.
3
: , ( )
.
() .
( ) ,
. I
23
II III
(.89. 2).
89.2
.
, ,
.
. (
) ,
.
, ,
.
,
T = 0K ,
.
: (>1),
(<1).
r1 ( ),
r2 (
24
) (. 89.1). r1
. r2
,
.
,
.
1.2
.
(Ge, Si, Se)
(InSb, GaAs, CdS) .
,
,
.
. 3, ,
.
T = 0K ,
, ,
. (
)
,
.
, ( . 89.3
),
. (),
, .
.
,
, () ,
25
89.3
.
, ,
( n-).
(),
( p-). ,
.
.
,
(,
, ..).
EF
(.89.2).
. ,
T = 0K .
.
(T > 0K)
50%.
26
,
E (.89.2).
. ,
,
. ,
,
.
.
,
.
R0 :
R = R 0e
E
2 kT ,
(89.1)
R0 , k
, .
:
,
.
,
. 89.4. 2 6.
1,
.
5.
4. 3,
.
27
(89.1).
:
89.4
ln R = ln R 0 +
E 1
2k T
(2) (
(89.2)
1
, ln R )
T
(. . 89.5),
tg =
. 89.5 ,
28
E
.
2k
(89.3)
ln R 2 ln R1
1
1
.
T 2 T1
(3) (4), :
tg =
E ln R 2 ln R1
=
1
1
,
2k
T 2 T1
(89.4)
(89.5)
89.5
A = E = 2k
ln R 2 ln R1
1
1
,
T 2 T1
(89.6)
A = 2kT 1T 2
ln R 2 ln R1
.
T 1 T 229
(89.7)
A T (T 1 +T 2)
2T
R ( R1 + R 2)
=
+
+
.
A
T 1T 2
T 1 T 2 R1R 2(ln R 2 ln R1)
(89.8)
, , .89.5,
T 2 T 1 .
2
1. ,
.
2.
70, 5.
3. R = f1(T)
.
4. lnR = f2(1/T) ,
, (89.7)
.
, .
5. (89.8),
.
6. .
7. .
89.1
.
T,
R,
1
T
-1
lnR
T, K
30
R, ,
A
A
1.
.
2. , ,
?
3. ,
?
4.
.
5. ?
6.
.
7.
.
8.
.
9. ,
,
?
10. ?
11. ?
12.
?
13. ?
14.
31
101
: -
.
: ,
, , ,
, , .
1
1.1
, ,
. ,
.
,
,
(
).
. ,
,
32
,
.
,
.
. 101.1.
1 2
3 .
,
4. ,
3, .
, R ,
101.1
.
(10 4107) .
.
( ) .
. , ,
, .
.
,
.
33
= (10 2103) .
.
1.2
i
U
- .
, . 101.2.
R .
R U .
101.2
V. i R
.
- .
,
i
, U:
i
=
.
(101.1)
U
i
i i:
34
i = i + i ,
:
(101.2)
i = i i .
(101.3)
:
= ES ,
(101.4)
, S
. :
I
E= 2 ,
(101.5)
r
I , r
. (89.5),
(89.4) :
IS
= 2 .
(101.6)
r
(101.3) (101.6) (101.1), :
i i
=
.
(101.7)
ISU
2
1.
1. (. 101.2).
2.
i U.
3. r
i.
4. (101.7)
.
5. 3-
.
2. -
1.
U.35
2.
i = f(U) = 0.
3. r
. (101.3)
i = const
U, .1.
4.
r2 , .3.
5.
r3 , .3.
6. 3 -
,
, (i = f(U) =
=const).
7. .
1. ?
2. .
3. ?
4. ?
5.
?
6. ?
7. ?
8.
.
9. - ?
10. ?
.
11. ?
12. ?
13.
.
14. ,
?
36
102
:
.
: , , , .
1
1.1
.
,
.
, n-p-
( )
. ,
n-p-, .
, n- p-, , ,
,
.
. , ,
p-, .
n- p-.
, , p-,
.
37
, p-,
n-. n- p-
, .
...
.
.
. ...
0.5.
,
... .
, ,
.
.
1.2
, :
i
= .
(102.1)
S:
= ES .
(102.2)
,
, :
,
l2
(102.3)
I ; l
. (102.3) (102.2), :
IS
.
l 2 38
(102.4)
(102.4), (102.1) :
il 2
.
(102.5)
=
IS
,
(/).
, .
.
,
, - .
(n-p-
) (.102.1).
n-p-
,
( ,
, n-p-
(.1).
, .
, (
).
102.1
39
/.
, .
.
.
2
1.
1. i0,
.
2.
, ,
.
3. i'
.
4. 3- ,
.
5. (102.5)
, , i = i' i0.
2.
1. l
, .
, 10 l.
2. (102.4)
l.
3. .
102.1
.. ,
S, 2
l,
i0,
i',
40
i,
4. i = f().
5. .
1. ?
2. ?
3.
.
4.
?
5.
.
6. ?
7.
, ?
8.
?
9. ,
?
10. ?
11. ,
?
41
110
:
.
: , , ,
.
1
1.1 ()
p-n-
,
.
p-n-
,
. ,
,
1949 .
. , . . ,
1956 . (TRANSFER RESISTOR
) ,
.
, 42
,
.
.
, ,
(
50-80C).
.
n-p-n-
(. 110.1). ,
( )
(,
, ),
.
110.1
,
.
n-p-
43
( ), pn- (
).
,
.
U R ,
U R .
-
. ,
p- .
( ), ,
,
.
,
.
U,
, R U.
(.110. 2). p-n .
. ,
.
,
.
, ,
- ,
(n-p-n p-n-p-).
,
. 110.3.
-
, , ,
.
44
,
, . ,
,
.
, ,
, .
110.2
45
110.3
. , , ...
.
,
.
,
().
: ,
- .
, .
1.2
n-p-n
(.110.4). n-p-
,
.
.
46
110.4
U = I R -
(110.1)
R- -. ,
.
, (p-).
.
( 10100 ).
0.30.5 .
0.01 .
, ,
-.
. , -.
47
. -
U = I R ,
(110.2)
; R -
-.
I < I
R >> R ,
(110.3)
(110.1) (110.2)
U > U ,
(110.4)
U
.
U
48
(110.5)
110.5
1. ,
-.
2. U U 1.
3. U = f(U),
U , U .
4. U, U
- - .
5. (110.5)
.
49
6. /
.
7. .
110.1
. U, U,
U,
U,
1.
()?
2. .
3.
.
4.
.
5.
.
6.
.
7.
, U = f(U)?
8. ?
9.
?
10.
?
50
51