13- 1.

11
13-

13C

.

 13C 13C
13C
13C

 -decoupling
13- nmr

.

nmr 13-
.

13-
250

TMS CS2 . 13
13C
( NMR ( )12-6 .)13-6

.


.
( ) 500 ppm
1000 ppm 10-15
ppm

Trichloro fluoro
methane CFCl3
. .

F - F = 2 - 300 HZ
( F - H = 40 90 HZ -6

.)14

H-P- J= 200 HZ

Two-Dimentional (2D) NMR Techniques

Two-
dimentional Techniques

splitting

two
dimentional

two radio
frequency pulses
.

Two-Dimentional (2D) NMR

Techniques H1-nmr H1-H1
Correlation Spectroscopy COSY

( .)17-6

 technique
H1-C13
Heteronuclear Correlation
Spectroscopy
HETCOR

)Magnetic Resonance Imaging (MRI

NMR
.

X-
Computerized
ray
Computerized
) Topography (CT
) Analogues Topography (CAT scanninig





X-ray

.

 1977


5

.

) (MRI


( .)18-6

MRI

.

.

MRI
.

MRI


MRI

MRI

.

()
. ( )19-6
.

2
10
0.5

.NMR

6
.

MRI
.CAT

( )1 :

.

50,000
0.3.

) :


7 0.4
.

 )3( :
MRI


.

452.4
.