:

[Co(NH3)6]Cl3
.
:
VBT )Valence Bond Theory ( 1.
CFT )Crystal Field Theory ( 2.
MOT )Molecular Orbital Theory ( 3.

:
() : ( 9191) ( )
. B A
NH3 : CH4 ( ).
()
EAN )Effective Atomic Number Rule

. (
) .
.


)Rn )Xe( 61 Kr( 45 ( ) . 61


-9

-2


-5

2
3
4
5
6

SP
SP2
SP3

:
..
:
/
/
molecular orbital theory :

.





B.E.= -q1q2/r

 ( ( )Ligand field theory (-: )Crystal field theory

)Bethe
)Van Vleck

. )1950
)20

.
)1935
. )Molecular Orbital Theory

)d
. )x , y , z )d :

 )dz2 )z
.
:
-1
. )% 111
-2
.
. )Ligand field
-3 )d

)d
.

 ( )d

-:
: (-: )6
)6 ) (M
) (Octahedral .

)eg

,y,z

(x

dx 2 y 2 , dz 2

) .
) dxy, dyz, dxz
.
. )t2g

 )eg )t2g
)10Dq ) 0 .

-: )10Dq
)t2g
)eg

-:

1

]) [Ti ( H O
2

) Ti

)d )t2g

) Ti .




:
)t2g
= ) 4Dq
)eg ) = . ) 6Dq
3

-1

) Ti ) 4Dq

)d . ) 2x 4Dq 8Dq

-2

)d . ) 3x 4Dq 12Dq

-3 )t2g

)d

)d

( -:

)eg , )t2g
)P )eg
. )t2g

)eg .

(t32g eg1)= d
4

) 3x 4Dq 6Dq 6Dq