A Short Compendium of Particularly Delightful Formulas

an2 n n2 n3 Z = 1 + B(T) V + C(T) v + D(T) v + ... P + 2 (V - nb) = nRT V (x-xo) (x-xo)2 (x-xo)3 (x-xo)n f(x) = f(xo) + f'(xo) 1! + f"(xo) 2! + f"'(xo) 3! + ... + f(n)(xo) n! 8a a Vc = 3b Tc = 27bR Pc = 27b2 dU = dq - PextdV + F dx CP(A) = a(A) + b(A)T + c(A)T2 1 V = V ( )P T V= -Vo P dw = d = f dx = mg dh = dqi w = zi F dq dq dt (dq) dt= H Cp = dT= dt dT dt p P ( ) = T V V = Vo T V =Vo

1 V = = V ( )T P

V-Vo =Vo (T - To) + Vo 2

U U V U ( ) =( ) +( ) ( ) T V T T
P V T

(T - To)2 2 U V CP - CV = ( ) + P ( ) V T T P T JT = ( P

e (T - To)
2 TV

CP - CV = H

( T )

=(
V

H H P ) +( ) ( ) T P P T T V

)
H

H ( ) P T H ( T ) P

( P )

= - JT Cp

T2 V2 CV ln T = nR ln V 1 1 CV(T2- T1) = - P2 (V2 V1) rHT2- rHT1 = rCpT

c c V1T1 = V2T2

P2V2 = P1V1

c=

Cv nR

Cp = Cv

nRT2 nRT1 CV(T2- T1) = - P2 P P 1 2 b 2 2 c 3 3 rHT2 = rHT1 + a(T2 - T1) + 2 (T2 -T1)+ 3 (T2 -T1) )

b c rHT = rHo + aT + 2 T2 + 3 T S = k ln W -w qH+qL = q = q H H dq dq oT 0 S T CP V dS = T dT - T dP S = CV ln T2/T1 CP nR dS = T dT - P dP S = CP ln T2/T1 S = -nR ln P2/P1

CV P dS = T dT + T dV nR CV dS = T dT + V dV S = nR ln V2/V1