tnt;~'/2,{.'.:,t .. ii.Ti1i id~:;::! :l:~'\:.lDlo.~ El IilD:r:f;c(r;:.

~cl O~ ~de0
;' .J..

(;oJ:J

:~.'

-~

I
C.Z.: 67S5~ 1.69 By using the hasic rheo[ogical cquetioos for biniu)' solid composites witl: linear viscoelastic bciJ:l',-iul!r, [he IT - ;l11d I - lil: tuorplio-rlicologicn] coupling iutciections ;1[;: :Ul.1JYZed from the stentlpcnut ctpbenomcnolcgicul selection rules, nnt! the corresponding ullowcd rheological states of composite arc cstnblislicd for well defined rlieologicvl models.
Clurificarca r;ccc~it:>. rccvaluarca potcntialului rcolcgic efcctiv 01 rnatcrialclor cornpozite eu cornportare prccurn l!.:daSlic?i

si rcconsiderarea r\u:lf1Pt:1 a corclajiilor compicxe proprictii\i-SInlctura-compozilic-morfologic. Accast.i orientare estc sllgcr;\ta iudcosebi de ccrinja principinl.i a asigll!~i.rii suportului tcorctic ~i experimental ncccsar comp.n ihiliz.irii .ulccv.ue ;1 aspcctclcr Icnomeuologicc ~i rcspcctiv fizico-chimice pcnrru clasc brgi de m.ucri.ilc a c.iror ab.ucrc de l.i cornporrnrca fl:oh);~i(';ide tip clastic csrc scmnific.uiv.i l l-J OJ,
Rcznlt.uclc obiinute
frill abord.ir ilc tr.uliiicnalc,

ncconvcntionnki

a aspcctclor

fcnornenolcgice

spccifice,

111em: sc utilize;}!.ii

tclinici

couvcruionalc

bazarc

dircc!:! a unor I::arimi rcologico, de tipul rnodulului sau cornplianjci, rurnizcn:'! inform.ui! ":::Hisr:icI(o;m:" ;\1;11:1 limp c::r Ca(li~l'!'(k:~";;\I\!ilre sc limitcaz.i la un nivcl rcl.uiv formal <it: intcrprciarc. De ;tltCcI, priu I:J.'i;\~i natura [or, abord.irile de :ICL'Sl rip permit cvidcnticrca cfcctclor cxclusiv c.uititarivc. un:it'..::rca cfCL:fclor de rip calitativ ~l\';l~.HI consccintc .mportantc ~~[J.cpcntru aprofun.larca unor i:r()c('~c :~i

I".': \lllusirc:l

prnpri~t;lli relcvanic, c;:t .',~i pcntru idcruificarca b::JCi:c: de conditiilc concrete de utilizarc,
I':l
C~l/.tl1

conci!\:i!or

Gr[jn:~

de: valorificarc c!,,:pind:...::

a difcriiclor
ll',l ilt:il1;!t

I1J:~~~ri:llc;n
l:,_'

c()r:)p()n;l~:i ci
.'j1

v.iscoclaxticc. d~ (;ifcl'ilclL~

c;i~~ci r;~:-;puI1~;ul
\,jlr.~;.'.~~ (~..; v;lri:i(i~

,,\"(:Ld

variabilclor sr",~ciricc

n;()t()t~icc,

ale ;1CC:Jt<)r:l, l~l ::;pel(~i in

... L:~c;~[~,

cx ist.i p{):~i;JiIiLdh":~).
c.uc

d~sL'r~~r;i.

conrrclcaz.i

f"u;t. :;i1'.::1 gCI.lCfa[Ca :;t.irii

t'~:~}il: ... ::i

opcr.norilor

ici, a "inrcracuuni'or
pe baza
SCiLC~1CJl

c~~
rCD:,:),~j~.:~ ;'tL~

r,;\)l()~~ic~ a corn: .. :8zit:llui

st;!Jilur

co.nponcnj ilor ~i morfolog iilor. rcspcc.iv il~l~r:j;'~C~1re~t uuor "~'.::~u~i de prc~'i>~::;;-~~~~i s.firilc reclcgice nerrnise, respect iv inl crzisc. Dcz\,clt;:IC:l accstor

binc (L:Cl!::'~~c, C1;~ as!;::ct~ estc escr.~;0J;1 ~>~:J.i PJ

rr.=::::-~;l Itt iJ!I;1C~ a atord;~ri!(;l av.msatc, c:1!";lbi!~ :,tt permiui rnccclarca co!].:rol~ttJ :l p:'Jr~r~"2[2li~~;~:::~~1'':;~~:~'''': ;~l'",:c~~rf:;;(;~~i:c:~:r r:::~~k:, CC:::~~~::~;1~1d 1:1:-;.c~d ::;~;'[;:~i:ic:~l:": !:;r0r.~~~~i:~~ ;-..:~-:.::-;t:j:1;cla !t.:6:!:; ::..: C;~~~~--~:i.(~;~

L::;i~~ d:: :t;t.:CS[~~ !J(,::llru c:)rt~~;!)}:it~ c.i

C~~:I~~;C-:~ ~:~~I cu ,~or:-':~:':r~~:;...: !;::; :;ci>.l '..'(i:,r.(:~i:L~jt;c j;;.:~-';:;- ilj-

~ ;'j.

..:;, .:::. 1~r;.:~:z:t:'::1 .':;:;.~C :.:~c:r

.,'

~.'

------------636

( i . 1)

--.~
sun: controla]j de valorile par.irncrrilor rC,)l0gici Pc, p;, 1'2, , 1',;, ~ircspccriv 'ie, C]j. C]2, ... , 'In (n; ::; n). Ii] ph!!:, ~;I;lrC~l r~~ck'!~ic:~i {1.~}cor~~;Fullz::lfO:1r!~ cc~u\~ci :\'::ohJgic~ (1) (L. t:...~ C.~:r:~ idcr1!iC!c:u.:l prin v.rloriic l~~~~, d~>~;:~i~\.: l.."a:

-;
. I

rcologicc spccificc corcspunziitoarc suirii rcologicc RmRtl!<' . D~ D2 a, ". , ,'" sunt: . a,V, 0' ~l ["'I",,:c(1\ e, De L, D2 E, '" , D"R" Dup.i cum se stie, legilc fundarncntalc de cornportarc rcologica ill cazul unui cornpozit binar ai c.irui componenti se caracterizcaz.i printr-o cornportare vascoelastic.i Iinearii se objin prin gencralizarcn aproximajiilor "dcformarii uniforrnc" - in sens Voigt ~i respectiv "tensionarii uniforme" - in seDS Reuss [' 11-12J. Prill interpretarea accstor aproxiruatii ca reflcctare a unor interacriuni de cuplaj morfologic - n (in par.ilcl) ~i respcct iv -2: (in serie) spccificc, sc poarc rcaliza 0 unificarc satisfacatoare a scheruelor de rnodclarc reologic.i. a. Cuplajul morforeolcgic -11 corcspunde aproximniici deform.irii uniforrne (in sens Voigt), dcfinit.i prin relariile:
Tn consccim.i,

variabilelc

DmR.

>

.,

0,

11
:11

Een)
O'(n)

= e, = Eb

(2.1)

= vaO'a + YbO'b

11

11 1,
-J : 1

intrc v.iriabilclc rcalogicc naturale ale compozirului ~icoruponcntilor, spccificat] prin fractiilc de velum Vo. Vb (VI + \'1> = 1). Avant! III vcdcrc CI opcr.uorii rcolcgici ai componcntilor sunt Pa QJ ~i rcspcciiv Pi" Qu' rC1.\I:::1 C;1 "starc.i rcolagiea- Fl' a cornpozuului binar:l/b cstc dcscris.i de opcratorii rcclogici:

1
I

Pen) = P" Pb Qen) = vaPbQ + ybP"Qb

J

;j

'I
.I
1 .j

l!

"[inand searna de rcolcgic - n. rczult.i:

,\ ~;;:(!;'" ca

fOiTIJa

opcr.uorilor

r'~o!;)giL'i Iundamcnrali

corcspunz.itori

cuplajului

morro

(2.3 )

urmarc ;, sirnctrici opcratorilor rC:Jill;,ici 1'(11;, Q(ll; ai compoziiului binar in raper: c., pcrmut.uca componcntilor, n:zult:l 0 propricrarc hinc dcfinit:t dc invarianpi rnorforcologic.i. Yn plus, sc Cliil"i:[[:-\ c.i p(n) este independent de compoz it:c, 10 tir:lp cc Q(:1) ,:S[G controlat de aceasta, In sf;,r:;;it, sc
oh~c:r\'~ dill

cazul cuplajului

rnorfolog!c

(Ie:lipId

n cstc

caractcristicii

0 lege de aditivit.uc

direct.i pcniru

':1

morlulul rcologic, cl(,

. . .. pnn r~Llp:.i:':;:
,

::': '.'

':,

,'1"):';

(3.3)
637

viltlllCa sirncirici opcr.uori!o: rcolllgici !\~}' Q\~) ;li cornpovitului hiuar 1;1]';11">[1 ell cornponcnj ilor. sc const;!l:l II propricr.uc Tccilic'\ de invmi:Hl\:i moriorcologic.i. 'I'n pin;. ,,: r;> rcrnarru tkp'~lld~.nia IUl PO:) de compoziuc, rcspccuv indcpcndcn]a CiC COHlrOZj{lC. III cazul lui QI)~)' in smr.~il. sc obscrv.i c.i pcntru cuplajul morfolcgic de ripul :::::cste caractcrj st ic.i 0 lege de .uncstcc de aditivitare dircctii peutru compliilIl(ii,;1.

l'rin

Ufl1l:1rl"liI

r;,'n,llIf:l,C;l
",

..

'

:~~) = VJ:I + VQ.~'

Cl.4)

rCSFcctI'.' component

ilor,

a. Cuplajul morforcologic
'fiD~1Dd scarr:a de forma (2.2), rezului:

- n.
opcratorilor rcologici

fundarncnrali

p(n),

Q(fl} c\'idcn~::ll:i

de rcaluii!c

f1\11)

= nl"

+ Inn
u"(Il))

(2.5)

urn)

= max. (u'rll)'
111"

unde:
n ' (11)

+ Ub' u"rn)

= mb + n

Prill urmare, starea reologicii - D a cornpozitului binar a/b, objinut.i ca rezultat al "interactiunii - Tl' (controlat.i morfologic) a st.irilor rcologice ale cornponeutilor, sc poare considcra ca fiind gcnerar:'\ conform rcprczcntarii:
a

n
!!I

+b

n (oil) b -'f (a/b)

!!Ib

n
IIlI
!!Il/lI

unr!c "\11)' Il(n) xc cxprim.i In Iuuctie de mo' 11"~i rcspcctiv b. Cupl.ijul morforcolonic -L
:\v:tIld

m,,, Ill> prin rcgulilc

de selccj ic (2.4). n.?),

fl~!.lli[:i:

In vcdcrc Iorm.i operatorilor

rcologici Iund.uncntnli
me::) =: rnax. (m'o:), m"U':)

1\:::1' QC:)'

couform

Uc:)
undc:

Do+llu

m '(2~i:::: 111:1 + D~,

i,., C')"'cCi,t'l
~ J. ~ ,.J Jl't', ...

!71'\:)

==

i!lb
\1,

-r
,'

11;,
.... .\l....... II, ~. dl< ~ . C-'l~'; .. ~

SI'l ..l rcoloe 1'-_' 'I' ... ci!

(coutrolat.i
conform

rnurfolopic)

sLiIilur

ic.i - ~, "'\ comro .itului t,in',r" 'b obtinur.i c rczult.u "1 "ic,''''C'':'''':: - .. ,. _, l/, ,_ !., " Lr r L .. rcologice ale componcutilor, sc ponte co.isidcra ca fiiJc! g'::;!~":;i:i
ljd.d~~

rcprczcnt.irii:

tt!~(:c m, ~~:'!]::; sc ~xp:-;s?i in

j'::1:C\ ic de []]J' llJ :~i r~sp'~C't:',' n;:;. IJ,:! F~iJ :':.:guEl(; (~C seL~C'~ ic (3.5\ C'~:~~:;.j~l~ rnoJ'fl)rccl:)~~:c,; t'uj:d;unc:nL:l~ d~.\~cri:;;tic ":(;;;c~ii:2 r~()lu~~cc"(2'()) ~i rc~;r>~ct~/ ;JLIC:J!"~i. d~~iUr:t~ rclariilor (2.3) .';\1 respccr iv (3.3) ale or:~Z"J[(j~.i(';r :-~clcg!ci, de rr(j~ri(;!2rC;l ~~:1~:-;:Li:

. . pnn

.. ..' rC:;lLZ;~i'i~:~ ::n:_'; ~1i..~"':~.~:~:<

(i')l:1

;-::,u;'l,..:n\ i~ur,
~'>;~!;_~liL; (:c: :l;'::!c('~:~~(2.5)}

C~ SI

cV'idc~~i~lLii

(:i~'s:-.:r:.r:~r-':,1 "',,~:j]DlliC:1[l'/a

'4

dL~-..'.::::~(~c:-;~~i ur:;i:~l,~~ ~i

(,C;~~S:):;!l/;:,t:)[

~;[:~~rii n..::~lu~~lc~ ;1 C'onlr0l::!;:i~.d d~ !ir;~! ~8EC~';~ ;;j i:l::.:;ac!it!.aii de C:l:.~.~.~ij rl':C'rf(;r,..:c!u,~:~:: .:; co::~r;{lIi-.;, in ~lc..!;atji t:n:p. I) cuuntificnrc a :;titrii rcolog!c~ !:f..;c:~:v':;;)cornpozitului t!J1;l~}(l sc(;n~a d~ sl~~r~;'.::
/\C~st~

n~oJo.~ic:..:C();-c:;punz;.-!.ioar~ cornponenulor. valori lcr "pararnctrilor" de cuplaj specifici

re.a.ii se r':~i\..:.~, formal, I;] 0 rcpr:,:,::-,:c:1f:1:-;2 p~ :':;~;:l (Tl), ~i respectiv (:::)i (i=1....,4) care intcrvin in rcgulile de:
RE'/!STA DE CI ILvUE -1>17 ;. Nr. 7 .) 1')')6

sckcjie

n. ('?'J)~i

Jl'~Fc:c(i\

L.

(3J),

;\~t[cJ: ()ji'\r

Ill(.):::

+ ()~111~1+

Chn.i.l- (),;

n:,

' .

"'"1\

\ .. I)

Uo ::: C) llUa + undc (.) scminific.i

02r1lb + (.)3U3

+ (')4JJb

(:1.7)

(n) sau (L), (rabele 1.1 ~i1.2)

r'~'-~-'-----"-~------'--------------'--------------'-------- -.--------.
!
1:1.1
oJ,."-

In

f)

o o
T;:;bc1ul1.2

o o

n"

(;[)i

m.1

mb

no 0

I1b

III

0 0 0 0

n
11 "

Stiiri reolcgice pcrmise ryi intcrzise

spccrrnlu St.ihilircn cxplicit.i, III CIZU! unui compozi: binar cu cornponcnri a c.iror stare rcoiogic.i apartine i comport.ir ii \':\SClh:Ia~I;('e lincarc, ;\ st.irii rcologicc corespunz.itoarc iutcracriunilor de cupl.ij
111

Iunrl.uncrualc. sc cxcmplificii, modele reo lor ice tipicc:

cclc cc

UIl11t:JZi'i,

prin luarca in conxidcrare

a unor st.iri definite

prin

- {H}, de tip Hooke (Ill::: 0, n:= 0); - {:'~V}, de Iii) Kelvin - Voigt (m::: 0, - {Z}. de tip ZC:Jlt:r (m = 1. f1::: J). - { .. \}, de lip :\IJ'rcy (m ::: 1, n::: 2);

Il :::

!).

- {H}, de tip Brankov (m::: 2.11 = 2). [n virtutca ::\:Ll~iilor c!c simcuic caracre risticc (2.3) ~i (3,3), r~z:lIUi c;'1 dill ccle .5 x 5 ::::'25 de cazuri pu.';iiliic se obrin 5 + (23-5):2 = 15 cazuri distinctc, im,l pcutru a exisra posibiliiatca corupar.irii difcrite lor tipuri (I:.: cuplajc se i.iclud I:J tabelul sl{lrilof rcologice waft: cclc i)'cic cazuri (rabelul '2). Dcsigur, prin n.:ulu0ic.:: d,~ <.:c~.Ja~,)i tip S~ sublufclc~ :;t:~ri r:.~D;C'::::C~, dcscrise d~ ~cca(.ii n:()l!),I~ic:; de; .icclasi IJrcl:n, dal' cu p{l[arjJ~:;i rC:)!f_;;_~:ci dir~ri!i. Pcutru evidcnuerca

:~(.:jccti:~sunt prczcm.ne
coinpozuului ~in;::1d

)i rnarimilc

pc buza ciirora
C')1

S~

stabi!c?~

mcriului conc.c: de obrincre a rC.julilur d:; in rr:od ctccrr. ordinul st.irii rcologice ~1
-r:>

:,,':::::-:r;1:1

de ordincL:

C~,;p1.UJi:j~();~IC

st;:i;:-i~.~r

;~j,.: CC1Tl~)l)ncrl~ilor,

conform

rcl.u iiior (2.5) ~;i (3.5). Consi.icrarca u~~or ~-!1f)d:.:!(; {~!'ric..:: si["n~;j..: de CCi;:r(jr.;.:;~ d'~ solid ';~\sCt)e!;~~::c ljil:.:;:~r permitc \;"'!(:l::!~;C;-':':;i n:'::1:~j;'.;\'~;:~:. ~;;j:-:.i(_~:,t:;i.rir;ifilur :.:r;1rii r~n;i':.::;-:(; :t C'_~r;-:~:(.I/~;_'..!:~::, ft,:~;~~cliv Ide~1!ific~tr~:l
'I

ii:l~p:~ c:!r;~c:\..~i:;li~i(':~~l ri''::C;~:I!:''::~:'':'''':;H':ictcri~;{ic~) ~;i c;;!-r;;:(;z;~Ll~l..i.i r'...:i'~~..:c:~~ C~lr~'tct~:::~;tic:!'''': prucc~c!t)r

~,p..;c;rjc~ Ci)nJ~;(;;!C:;liICj.

1:1 j}I'J:-:, P(;~1!~}il;t;.~:C{1'd~1(;; cV:_t~'~~!"'~ j:r:.:!i!T..~;;;l;-(':; a ~)tjr:Jor r;;olc6ic2

permisc

(:~lC~

:-iI)~ciilC(:, oi"(:!-:!!d i.-J~'~:;Tn~qii r:..::!t..:','~~!!!(,; pri',.':nd criicriilc

r!l(Jrr\)ll),~:~i. pcntru U0!!11...:rc:: unui C~)ill~Ozil cu

pr~:cr;c::; d:: ~il(;~...:r~~l c~~jn~)!.;!~cr.!;!ur ~i fl:spt,;cllv

propricr.u: impuse.

REVISTA

D!~ C1-mlifE ~ 47 ~ Nf. 7

.1)

1996

639

r-

Nr
crt 1

Cornpozit

!ll"

11,

Illb

no
0 1 0 1 0 2 0
2

m,,+rnb

n,+llb

H/ll
jt

0
()

'I

0 0 0
1

-;-1
I.J

I11b+ll"

I\,t-Ilb

!ll(ll)

I\n)

In(L)

I\L)

0
1

0
()

::

fl':'V

o
0 0 1 0
1

I
I I

0 1 1
1

,I
I
I

0 0 0 1 1 1
1

I"
1
I

0 J 1
I

0
1

:1
4

KV Ili H/Z Z/II H/A A/H H/B B/H

1 0 1 0 2 0 2 1
1

0 1 1
2 1

1
I

1 1

1 1

1 1 1
1 2
"1

5 6 7 8 9 10 11 12
13 14

J 1 :2 2
2

1 2
:2
2

1 2 2 2

1
2 :2

1
0
2

2
:2
2

0
2

2 2 0 1 1
1 1

2
2 2

0 0
1

0 1
1

"-

2
1
I

2
2

2 1 2 2 2 2 3 3 :2 3
7,

2
1

KV/KV KV/Z Z/KV KV/A A/KY

KV/13

0 0
I

0 1 1
1 I

1 2
I

2
:2 3
3

2 :2
3 3

1 1 2

0 1 0 :2 0 1 1
1

1 2 1 :2 1
1

2
"l

2
2

0
1

:2
"1

:2
')

2
3

15 1G

1
2

::
::
:2
2

3 :2 :2
2

3
3

2 :2
2

:1
3
2

13/KV '/.,/Z
Z/A

::
1 1
I

3 2 3 :2 3

3 :2 3

17 1:3

1 1 :2 1

:2 3 3
,)

2 1 :2
I 1 I
"1

2
2

19
20

/'.1 Z
Z/B

:2
3 3

I I
1 :2
1

3
3
.)

3
3
,)

II
1

21

I I

fJ/Z
,\ 1:\

:2

-::3
2~

,'1

II

I
:\ I B B/A BIG

1 1

:: ::
:2 :2

.c,

I
I

::
:::
3
<.\

I
I
I

:1
3

I
I
I

I
II
I

3
I

3
"

3
"1

. I - I ~
"

I I
I

.J

,)

.)

-r

I I
I

:2

I 4
4

I
I

"

::

1 :2

:2
']

J.

I
i
i
I I

.,
,j

.! .\
4

I
I

3
,

2S

:2

..

.;

"

~ !

I I I

I
I

.-~

I I

640

REVISTA DE Cl-lIMIE

47 ~ Nr, 7

1996

Prill unu.uc.

in c.izul

COI11PU/illliui binnr

rczult.i,

l'OIli'Cl1U

d.uclor

jlrc;;.CIILllcin

t:lbdu12,

un numiu hiuc

(rcspcctiv dixtiuctc). Astfcl, penlnl cuplajul fU;1tl;1I11ent;d - II, ~L~ obtine 0 Sillt.l~j stare ; c:' !0::;ic;i F2rr:1i~~ (C) 0), 3(~) st.iri (0 1),2(1) ;;tJri (1 1), G(3) s;;~ri (l 2),3(2) s;;;,ri (22), S (3) Si.lii (2 :1),2(1) SI;i.ri (33),2(1) sliiri (3 4) si respcctiv 0 st.uc (t 4). Pc de ,llli pane, cuplajul CUncl<lDlCnlal -2; conduce, 10 general, 1:\0 stare rcolcgica pcrmis.i (00),4(2) SI;'iri(1 1),0 stare (1 2),7(4) (22),2(1) st.iri (23),6(3) (3 3), 0 stare (3 -1-)~ircxpectiv 3(2) sl;iri (4 -1-),in (imp ce starea (01) ccnstituie 0 stare rcolcgici iutcrzis.i.

delJJl!l de: C:V.llli posibilc

stm

stan

Fkclcle

rcolojice

de lip c.uuirativ

iunilor (L~
r.:l'1~;:;i)l;~:11i!l.)r

starca

rl~t)ll),~!cl

~l

salt calit.uiv [10]. [11) constimie conseciate ncmijlocitc ale cornpozirului rt~~~ndSJ dtfcn.~culliLlfi\' S:HI calit.uiv de s(;'ijil~
- I].
c\;r~'~;!il!:!/;lh.1!"

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de Iip ('b~;lic (CreCf L':!fJ!i!~~ri':);i;l rcstul c.izurilor Cl'll1F\~n,~;\li se c;lI:1cr':riz,:.az:l rrul comport.iri rcolouicc de orriiuul (0 1), (1 1), (i 2) ~i (22)
I1l;U coruplcxc dcc.it celc ale

- c.iud ambii sc ob!in srjri

I'c't)!ogicc .ilc cornpozimlui

ccrnpoucruiior.

Situatia

cstc similani ~iill cazul

cornpozirclor {I(V}/{Z}, {KV}/{B}, {Z}!{A}, {Z}/fI3} ~i{:\}/[B} In tirnp ce pcntru compozitcle {Il}/{KV}, {H}/{Z}, {H}!{A}. {I-1}!{B}, {K\' }/{,\}. prin cuplajul rnorfologic - I1 al st;iri.!or rcologice ale cornponcntilor

rczulr.i sr.iri reolcgice sirnilarc calirativ cu cere ale componentului cu starea reologici mai cornplex.i. Pc de altl parte, In cazul cuplajului - :t, conform regulilor de selcctic. numai pentru compozitul
st.uca rcologic.i a cornpozitului este similara calitativ cu eea a ambilor cornponenti, iar pcntru {H}/{Z} ~i{H}/{l3} starea reclogicii a cornpozirului estc similarii eu starea cornponentului en comportare rcologic.i rnai cornplcxii. Exccprand acestc cazuri, in care cfcctele reologicc rczultate III urrna intcractiuuilor de cuplaj morforeologic sum de tip caniitativ, in rcstul cazurilor - {H}/{KV}, {H}/{A},

t II}/{H}

cornpozitclc

{KV}!{Z}, {KV}/{A}, {KV}/{l3}, {Z}!{Z}, {Z}/{A}, {Z}/{B}, {A}/{B}, pre cum ~iarunci cand arnbii compoueu]i sunt de tipul {KV}, {Z}, {A} si {l3} sc obtin pcnrru compozitul binar stari rcologice calirativ rnai complcx c dccat cele ale cornponcntilor. In consccint.i, particulariratca distinctivii a abord.irii fcnomcnolcgicc pe baza utiliziirii tehnicii opcr.u orilor rcologici consta in posibilitatca idcnt ificiirii celci mai avautajoasc lcgi de amesrcc pentru un tip distinct, biuc dcfinit, de stare reologica.

Concluzii Int crprctarca rclaj iilor ex istcnic intrc vnriabilclc rcoicgicc naturale ale compozirului, pc de 0 parte, ~i cclc ale cornponcntilor, pc de altii parte, en cx prcsic Icuomcnologic.i :1 uncr intcract iuui specificc .lc L'llpl:tj morforcologic, permitc aprofundarca consccintclor aplic.irii - in cazul cornportiirii v.iscoclasticc 1;J:~,!f'~ - a tchn icii opcr.uorilor rcologici. Asucl, pc baza legilor de: cornportarc rcolog ica cstc posibil ca i'r:illr-n ,l:l;t!iz:-l adccvat.i s:\ se idcat ificc, corcspuuz.uor cuplajclor morfologice fundarncutalc - fI 5i rcspcct iv -::=, cx istcnta un or rc~:uii de sclcciic bill': dei"initc care dcrcrmin.i, ill ultim.i inSI.1f::!:l. 5{:;re:1 rcologic.i pcr.n is.i a compoziiului.
Cuplajcle Iund.uucntnlc cme:spll;J(j de rapt illtcr:lqiullii dircctc a componcnulor, divcrsitatca ~i complex irntca I1lorfologiilur corncozuclor rcalc implic.md. in mod Iiresc, contributia unci multitudiui de cupiajc lit difcritc nivcluri, care trcbuic evaluate ~i pondcr.ue in concordanta ell particulariuiple fizice s. chirnicc ale cornpozitului I

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H. ~i L)()Ei'~i:::;CU, V., P:;!:('I;lL:~ Bl:1L. B~ri;;1. 2, !1}3(), p. 727 12. PA Vi::"!, H. ~i [)()Bf{ESCU, V., ?'':'.'. Cl.irn. n~uc:.H~~.;ti;. ~2, ;1:. i;, !lj;n, p. 5.~f); !r.::. C>:::1. r.:I~::. ::-1.,r.r. I, 1~~~)~ p. 1:27
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<> 1996

REVISTA DE CHI1:iIE ~ 47 ~ NT. 7

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