CHUYN 16: IN PHN

Cu 1: in phn dung dch cha NaCl v HCl c thm vi git qu. Mu ca dung dch s bin i nh th no
trong qu trnh in phn
A. sang tm
B. sang tm ri sang xanh
C. sang xanh
D.Ch mt mu
Cu 2: .in phn dung dch NaOH 10-2M v Na2SO4 10-2M .Tnh pH dung dch sau khi in phn. Gi s th tch
dung dch thay i khng ng k
A.pH =2
B.pH =8
C.pH=12
D.pH=10
Cu 3: Cho 4 dung dch mui :CuSO4,ZnCl2,NaCl,KNO3.khi in phn 4 dung dch trn vi in cc tr, dung dch
no s cho ta 1 dung dch baz?
A.CuSO4
B.ZnCl2
C.NaCl
D.KNO3
Cu 4: in phn 100ml dung dch cha AgNO3 0,1M v Cu(NO3)2 0,1M vi cng dng in I= 1,93A. Tnh
thi gian in phn (vi hiu sut l 100%)
1/ kt ta ht Ag (t1)
2/ kt ta ht Ag v Cu (t2)
A.t1 =500s, t2 =1000s
B.t1 =1000s, t2 =1500s C.t1 =500s, t2 =1200s
D.t1 =500s, t2 =1500s
Cu 5: .in phn 100 ml dung dch CuSO4 0,1M cho n khi v bt u si bt bn catot th ngng in
phn.Tnh pH dung dch ngay khi y vi hiu sut l 100%.Th tch dung dch c xem nh khng i. A.pH=1,0
B.pH=0,7
C.pH=2,0
D.pH=1,3
Cu 6: .in phn 100 ml dung dch cha NaCl vi in cc tr,c mng ngn, cng dng in I=1,93 A.Tnh
thi gian in phn c dung dch pH=12,th tch dung dch c xem nh khng i,hiu sut in l 100%.
A.100s
B.50s
C.150s
D.200s
Cu 7: .in phn 100 ml dung dch CuSO4 0,2 M v AgNO3 0,1 M.vi cng dng in I=3,86 A.Tnh thi gian
in phn c mt khi lng kim loi bm bn catot l 1,72g.
A.250s
B.1000s
C.500s
D.750s
Cu 8: in phn 500 ml dung dch CuSO4 vi cng dng in khng i th sau 600s,nc bt u b in phn
c 2 in cc.nu thi gian in phn l 300s th khi lng Cu thu c bn catot l 3,2g.tnh nng mol ca
CuSO4 trong dung dch ban u v cng dng in. A.0,1M;16,08A B.0,25M;16,08A C.0,20 M;32,17A
D.0,12M;32,17A
Cu 9: in phn 100ml dung dch CuCl2 0,08M.Co dung dch thu c sau khi in phn tc dng vi dung dch
AgNO3 d th thu c 0,861g kt ta.Tnh khi lng Cu bm bn catot v th tch thu c bn anot.
A.0,16g Cu;0,056 l Cl2 B.0,64g Cu;0,112l Cl2 C.0,32g Cu;0,112l Cl2 D.0,64g Cu;0,224 l Cl2
Cu 10: Cho mt dng in c cng I khong i i qua 2 bnh in phn mc ni tip,bnh 1 cha 100ml dung
dch CuSO4 0,01M, bnh 2 cha 100 ml dung dch AgNO3 0,01M.Bit rng sau thi gian in phn 500s th bn bnh 2
xut hin kh bn catot,tnh cng I v khi lng Cu bm bn catot cu bnh 1 v th tch kh(ktc) xut hin bn
anot ca bnh 1. A.0,193A;0,032g Cu;5,6 ml O2
B.0,193A;0,032g Cu;11,2 ml O2
C.0,386A;0,64g Cu;22,4 ml O2
D.0,193A;0,032g Cu;22,4 ml O2
Cu 11: .in phn 100 ml dung dch CuSO4 0,1M v AgNO3 0,2M vi in cc tr.Sau khi ngng in phn thu
c dung dch A cha 2 ion kim loi.Thm NaOH d vo dung dch A c kt ta.em nung kt ta ny ngoi
khng kh n khi lng khng i c mt cht rn nng 1,48g.Tnh th tch kh thu c bn anot(ktc).
A.22,4ml B.56ml
C.33,6ml
D.11,2ml
Cu 12: .in phn 100 ml dung dch CuiSO4 0,12M thu c 0,384g Cu bn catot lc t1= 200s; nu tip tc in
phn vi cng I2 bng 2 ln cng I1 ca giai an trn th phi tip tc in phn trong bao lu bt u si
bt bn catot ?
A.150s
B.200s C.180s D.100s
Cu 13: .in phn vi 2 bnh mc ni tip. Bnh 1 cha 100 ml dung dch CuSO4 0,1M, bnh 2 cha 100 ml dung
dch NaCl 0,1M. Ngng in phn khi dung dch thu oc trong 2 bnh c pH =13. Tnh nng mol ca Cu2+ cn
li trong bnh 1, th tch dung dch c xem nh khng i
A.0,05M
B.0,04M C.0,08M
D.0,10M
Ton in phn:
Cu 14: in phn 2 lt dung dch CuSO4 vi in cc tr v dng in mt chiu c cng I=10A cho n khi
catot bt u c kh thot ra th ngng thy phi mt 32 pht 10 giy. Nng mol CuSO4 ban u v pH dung dch
sau phn ng l bao nhiu?(Cu=64;Ag=108;S=32;N=14;O=16)
A. [Ag(NO3)]=0,5M, pH=1
B. [Ag(NO3)]=0,05M, pH=10
C. [Ag(NO3)]=0,005M, pH=1
D. [Ag(NO3)]=0,05M, pH=1
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Cu 15: in phn c mng ngn in cc tr 100ml dd MgCl2 0,15M vi cng dng in 0,1A trong 9650 giy.
Tnh nng mol cc ion trong dung dch sau in phn bit th tch dung dch thay i khng ng k.
A. [Mg2+]=0,01M, [Cl-]=0,02M
B. [Mg2+]=0,1M, [Cl-]=0,2M
2+
C. [Mg ]=0,001M, [Cl ]=0,02M
D. [Mg2+]=0,01M, [Cl-]=0,2M
Cu 16: in phn dung dch CuCl2 vi in tr, sau mt thi gian thu dc 0,32gam Cu catot v mt lng kh X
anot. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng nng
NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH
l?(Cu=64)
D. 0,05M
A. 0,15M
B. 0,2M
C. 0,1M
(Cu 27 TTS i hc khi A nm 2007)
Cu 17: in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr c mng ngn xp). dung dch
sau in phn lm dung dch phenolphtalein chuyn sang mu hng th iu kin ca a v b l(bit ion SO42- khng b
in phn trong dung dch)?
C. b<2a
D. 2b=a
A. b>2a
B. b=2a
(Cu 32 TTS i hc khi B nm 2007)
Cu 18: in phn c mng ngn 150 ml dd BaCl2. Kh thot ra anot c th tch l 112 ml (ktc). Dung dch cn li
trong bnh in phn sau khi c trung ha bng HNO3 phn ng va vi 20g dd AgNO3 17%. Nng mol
dung dch BaCl2 trc in phn l?(Ag=108;N=14;O=16)
A. 0,01M
B. 0.1M
C. 1M
D.0,001M
Cu 19: in phn 200 ml dung dch mui nitrat kim loi M ha tr I in cc tr cho n khi b mt catot xut hin
bt kh th ngng in phn. trung ha dung dch sau in phn phi cn 250 ml dd NaOH 0,8M. Nu ngm 1
thanh Zn c khi lng 50 g vo 200 ml dung dch mui nitrat trn, phn ng xong khi lng l Zn tng thm 30,2%
so vi khi lng ban u. Tnh nng mol mui nitrat v kim loi M?
A. [MNO3]=1M, Ag
B. [MNO3]=0,1M, Ag
C. [MNO3]=2M, Na
D. [MNO3]=0,011M, Cu
Cu 20: in phn 400 ml dung dch cha 2 mui KCl v CuCl2 vi in cc tr v mng ngn cho n khi anot
thot ra 3,36lt kh(ktc) th ngng in phn. trung ha dung dich sau in phn cn 100 ml dd HNO3. Dd sau khi
trung ha tc dng vi AgNO3 d sinh ra 2,87 (gam) kt ta trng. Tnh nng mol ca mi mui trong dung dch
trc in phn.(Ag=108;Cl=35,5)
A. [CuCl2]=0,25M,[KCl]=0,03M
B. [CuCl2]=0,25M,[KCl]=3M
C. [CuCl2]=2,5M,[KCl]=0,3M
D. [CuCl2]=0,25M,[KCl]=0,3M
Cu 21: in phn hon ton 200 ml mt dung dch c ha tan Cu(NO3)2 v AgNO3 vi cng dng in l 2 gi,
nhn thy khi lng ca catot tng thm 3,44gam. Nng mol ca mi nui trong dung dch ban u
l?(Cu=64;Ag=108)
A. [AgNO3]=[Cu(NO3)2]=0,1M
B. [AgNO3]=[Cu(NO3)2]=0,01M
C. [AgNO3]=[Cu(NO3)2]=0,2M
D. [AgNO3]=[Cu(NO3)2]=0,12M
Cu 22: in phn 200 ml dd CuSO4(dung dch X) vi in cc tr sau thi gian ngng in phn th thy khi lng
X gim. Dung dch sau in phn tc dng va vi 500ml dd BaCl2 0,3M to kt ta trng. Cho bit khi lng
ring dung dch CuSO4 l 1,25g/ml; sau in phn lng H2O bay hi khng ng k. Nng mol/lt v nng %
dung dich CuSO4 trc in phn l?
A. 0,35M, 8% B. 0,52, 10% C. 0,75M,9,6% D. 0,49M, 12%
Cu 23: in phn nng chy a gam mt mui X to bi kim loi M v mt halogen thu c 0,896 lt kh nguyn
cht (ktc). Cng a gam X trn nu ha tan vo 100 ml dd HCl 1M ri cho tc dng vi AgNO3 d th thu c 25,83
gam kt ta .Tn ca halogen l:
A. Flo =19
B. Clo=35,5
C. Brom=80
D. Iot=127
Cu 24: in phn nng chy a gam mt mui X to bi kim loi M v mt halogen thu c 0,224 lt kh nguyn
cht (ktc). Cng a gam X trn nu ha tan vo 100 ml dd HCl 0,5M ri cho tc dng vi AgNO3 d th thu c
10,935 gam kt ta .tn ca halogen l:
A. Flo =19
B. Clo=35,5
C. Brom=80
D. Iot=127
Cu 25: Tin hnh in phn 200ml dung dch gm HCl 0,6M v CuSO4 1M vi cng dng in 1,34 A trong
thi gian 4 gi. Bit hiu sut in phn l 100%. Th tch kh (ktc)
thot ra trn anot l A. 1,344 lt.
B. 1,568 lt.
C. 1,792 lt.
D. 2,016 lt.
Cu 26: Tin hnh in phn (in cc tr, mng ngn xp) 1 dung dch cha m gam hn hp CuSO4 v NaCl cho ti
khi nc bt u b in phn c 2 in cc th dng li, thu c 0,448 lt kh (ktc). Dung dch sau in phn c
mi trng axit v c th ho tan ti a 0,68 gam Al2O3. Gi tr ca m l A. 4,955 gam. B. 5,385.
C. 4,370.
D. 5,970 gam.
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Cu 27: Trong 500ml dung dch A cha 0,4925g mt hn hp gm mui clorua v hiroxit ca kim loi kim. Dung
dch A c pH =12. Khi in phn 1/10 dung dch A cho n khi ht clo th thu c 11,2ml kh clo (2730C v 1atm).
a) Xc nh kim loi
b) 1/10 A tc dng va vi 25ml dung dch CuCl2. Tm nng mol ca dd CuCl2
Cu 28: Tin hnh in phn 150ml dung dch CuSO4 1M vi hai in cc tr, sau mt thi gian, khi ngng in
phn thy khi lng dd gim 8 gam. S mol CuSO4 cn d sau phn ng l :
A. 0,05mol
B. 0,1 mol
C. 0,09 mol
D. 0,07 mol
Cu 29: in phn c mng ngn hai in cc tr 100ml dung dch hn hp CuSO4 0,1 M v NaCl 0,1 M vi I = 0,5
A, sau mt thi gian thu c dd c pH = 2( th tch dung dch khng i). Thi gian in phn l: A. 193s
B. 1930s
C. 2123s
D. 1727s
Cu 30: in phn c mng ngn hai in cc tr 2 Lt dung dch cha 0,2 mol CuCl2 v 0,4 mol BaCl2 n khi c
dd c pH= 13 th ngng in phn. Xem th tch dd khng i. Tnh th tch kh ln lt thot ra catot v anot?
A. 6,72 v 2,24 lt
B. 2,24 v 6,72 lt
C. 4,48 v 2,24 lt
D. 2,24 v 4,48 lt
Cu 31: Tin hnh in phn c mng ngn, hai in cc tr 500ml dd hn hp HCl 0,02M v NaCl 0,2 M. Sau khi
anot thot ra 0,448 lt kh ( ktc) th ngng in phn. Gi s th tch dung dch khng i, pH ca dd sau in phn
l:
A. 1,7
B. 1,22
C. 12,78
D. 12,3
IN PHN N MN KIMLOI
Cu 32: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra (DHKA 08)
+
A. s kh ion Na+.
B. s kh ion Cl .
C. s oxi ho ion Cl .
D. s oxi ho ion Na .
Cu 33: in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu
c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8
gam bt st vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x
l A. 2,25.
B 1,50. C. 1,25. D. 3,25. (DHKB 2010)
Cu 34: C 4 dung dch ring bit: A (HCl), B (CuCl2), C (FeCl3), D (HCl c ln CuCl2). Nhng vo mi dung dch
mt thanh st nguyn cht. S trng hp n mn in ho l
A. 1.

B. 2.

C. 3.

D. 0.

Cu 35: in phn mt dung dch gm NaCl v CuSO4 c cng s mol n khi catot xut hin bt kh th dng in
phn . Trong c qu trnh in phn trn sn phm thu c anot l ?
xA: kh Cl2 v O2

B : H2 v O2

C : Cl2 D : Cl2 v H2

Cu 36: in phn dung dch X 0,2 mol CuSO4 ; 0,12 mol NaCl vi I = 2A . Th tch kh (ktc) thot ra anot sau
9650 s l :
A : 2,24 lit

B : 2,912 lit

xC : 1,792 lit

D : 1,344 lit

Cu 37: in phn dung dch AgNO3 (vi in cc tr). Nu dung dch sau khi in phn c pH = 1, hiu sut in
phn l 80 %, th tch ca dung dch c coi nh khng i (100ml) th nng AgNO3 trong dung dch ban u l
A. 0,08.

B. 0,1.

C. 0,325.

D. 0,125.

Dng cho cu 38, 39: in phn 200ml dung dch X gm NiCl2 0,1M; CuSO4 0,05M v KCl 0,3M vi cng dng
in 3A trong thi gian 1930 giy vi in cc tr, c mng ngn v hiu sut in phn l 100%. Th tch dung dch
coi nh khng i.
Cu 38: Tng nng mol/lt ca cc cht trong dung dch thu c sau in phn l
A. 0,2M.

B. 0,25M.

C. 0,3M.

D. 0,35M.

C. 1,82 gam.

D. 1,50 gam.

Cu 39: Khi lng kim loi thot ra trn catt l

A. 0,64 gam.

B. 1,23 gam.

Cu 40: in phn 200ml dung dch Y gm KCl 0,1M v Cu(NO3)2 0,2M vi cng dng in 5A trong thi gian
1158 giy, in cc tr, mng ngn xp. Gi s nc bay hi khng ng k. gim khi lng ca dung dch sau
khi in phn l
A. 3,59 gam. B. 2,31 gam.

C. 1,67 gam.

D. 2,95 gam.

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Dng cho cu 41, 42: in phn 200ml dung dch cha Cu(NO3)2 0,2M v AgNO3 0,1M vi ant bng Cu, cng
dng in 5A, sau mt thi gian thy khi lng ant gim 1,28 gam.
Cu 41: Khi lng kim loi thot ra trn catt l
A. 2,8 gam.

B. 4,72 gam.

C. 2,16 gam.

D. 3,44 gam.

Cu 42: Thi gian in phn l

A. 386 giy.

B. 1158 giy.

C. 772 giy.

D. 965 giy.

Cu 43: in phn dung dch B gm 0,04 mol CuSO4 v 0,04 mol Ag2SO4 trong thi gian 38 pht 36 giy vi in
cc tr, cng dng in 5A. Khi lng kim loi thot ra catt l
A. 9,92 gam. B. 8,64 gam.

C. 11,20 gam. D. 10,56 gam

Cu 44: Ho tan a mol Fe3O4 bng dung dch H2SO4 va , thu c dung dch X. in phn X vi 2 in cc tr
bng dng in cng 9,65A. Sau1000 giy th kt thc in phn v khi trn catot bt u thot ra bt kh. Gi
tr ca a l A. 0,0125.
B. 0,050.
C. 0,025.
D. 0,075.

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