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AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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1





ANSWERS, HINTS & SOLUTIONS
CRT IV
(Paper-1)


Q.
No.
PHYSICS CHEMISTRY MATHEMATICS
1.
A B C
2.
A A D
3.
B D A
4.
D C A
5.
C C A
6.
D B D
7.
D A A
8.
D C A
9.
B A D
10.
C C A
11.
B, C
C, D
A, B, D
12.
A, B, C A, C A, B, D
13.
A, B
A, B, C, D
A, B
14.
B, C
A, D
B, D
15.
A, D
A, D
A, D
1.
8 2 2
2.
0 3 2
3.
2 3 4
4.
4 3 1
5.
1 8 4

A
L
L

I
N
D
I
A

T
E
S
T

S
E
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S

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5
4

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AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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P P h hy ys si i c cs s PART I


1. There will be no change.
h' =h


h'
A


2. c =
0
o
c

v
A
v
B
=
0 0
(b) (a)
o o

c c

W =Q(v
A
v
B
) =
0
Q
(b a)
o

c


3. e =0 +1 10 =10 rad/sec
2

v =re =1 10 =10 m/s

0
3
q(v r)
B
r

=
4t
|B|=
0
2
qv
4 r

t

B =
7
2
10 0.1 10
(1)


=10
-7
T

4. conservation of momentum
M 2gh m 2gh =MV
1
+mV
2
(1)

1 2
V V
1
2 2gh

= (2)

2
V 3 2gh =

2
2
V
h' 9h
2g
= =

5.
1 2
1 1 1
C C C
= +
=
0 0
x a b x
A A

+
c c

C =
0
A
a b
c


6. FBD of B and C


a B
2g
T
a C
3g
T


T 2g =2a . . . (i)
and 3g T =3a . . . (ii)
T =
12g
5

AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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for A


a A
mg
T'=2T


T =mg
2
12g
5
=mg m =4.8 kg.

7. W =
/ 2
0
mgR
f.Rd
2
t
t
u =
}
=1 joule.
9. a =
( ) ( ) v g a m g a
m
+ +
=20 m/s
2

t =
2h
a
=1 sec
11. Angular momentum =
nh
2t

kinetic energy
2
1
n

De-broglie wavelength =
h
mv
so as v increases decreases.

14. Relative velocity of B w.r.t. A along vertical direction should be zero
20 sin u =10
sin u =1/2
x =20 cos 30
1
2
=5 3m
15. Change in angular momentum =angular impulse
L =5t
I =
2
ma
3

K =
2 2
2
L 75
2I 2ma
t
=

Section -C
1. Conservation of energy
2
1 3
mv mg mg m 3 2
2 2 2 2
| |
= + |
|
\ .

g
v 8g =

60


2. Potential across capacitor is zero, hence energy stored is zero.

3. v
A
v
B
=} E. dx =10 (1)
=10 volt.

AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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4. Z =
2 2
R X + =
2
9 X +
but cos | =
R 3
Z 5
=
X =4 O.

5.
E
2
=E ir
i =
E
2r
. . . (i)
2E =i(3 +r) . . . (ii)
r =1 O
AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

FI I TJEE Ltd., FI ITJ EE House, 29-A, Kal u Sarai , Sarvapri ya Vi har, New Del hi -110016, Ph 46106000, 26569493, Fax 26513942
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C Ch he em mi i s st tr r y y PART I I


SECTION A
1. K
c
=4 10
-19


( )
1
2
Ag 2CN Ag CN
0.03 0.1 0

+
( +



( )
1
2
Ag CN Ag 2CN
t 0 0.3 0 0.04
0.03 x x 0.04 2x

+
( +

=
+



( )
2
19
c
x 0.04 2x
K 4 10
0.03 x

+
= =
(


0.04 2x 0.04 + ~
0.03 x 0.03 ~

( )
2
19
c
x. 0.04
K 4 10
0.03

= =
x =7.5 10
-18

2. PV =nRT
As PV constant
n
1
T
1
=n
2
T
2

n
1
. 300 =n
2
. 400
n
2
=
1
300
n
400

1
3
n
4
=
4. Energy of
e
in H-atom =- E
Energy of
e
in Li
+2
=- 9E
Energy supplied by photon =
2
1
IE mv
2
+
IE |E | =

2
p
1
E 9E mv
2
= +

( )
p
2 E 9E
v
m

=
9.
4 2 3 3 2
FeSO Fe O SO SO
A
+ +
12.
o
2
1
H e H E 0.0 v
2
+
+ =

2
H /H
0.059 1
E E 0 log
1 H
+
+
= =
(


0.059 7 0.413 = =
So,
2
2
H /H Ni /Ni
E E
+ +
<
Ni will deposit at cathode

2 2
2H O 2e H 2OH

+ +
AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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2 0.059
E 0.83 log OH
2

( =


0.83 0.059 7 = +
=- 0.417
13. Both have Cr
+3
(d
3
), and C.N. is 6. Hence d
2
sp
3
.
Pd
+2
(d
8
) complexes with C.N. is 4 are square plannar and magnetic moment is zero.
14.
3 2 2
FeCl FeCl Cl
A
+
Dil. CuCl
2
is blue due to [Cu(H
2
O)
4
]
2+
PH
3
is obtained by heating white P with NaOH
All are reducing because of weak P H bond.
SECTION C

1.
A =H
2
C
CH
3
Br
C =
CH
3
Br
Br
CH
3



B =
Br
CH
3
Br
C H
3
E =
CH
3
Br
CH
2
Br
H
D = inactive



2.
3
KNO
2 2
2
1
O KNO +
2 2 3
2
1
O NaNO NaNO + =

2 3
) ( 2 NO Pb 2
2 2
4 O NO PbO + + ( ) ( )
2 3 2 3
, NO Sr NO Ca ,

3 4
NO NH O H O N
2 2
2 +
2 3
) (NO Pb do not respond to the test.

2 3
) ( 2 NO Ca
2 2
4 2 O NO SrO + +
( )
2 3
2 NO Mg
2 2
4 2 O NO MgO + +


3.
O S
O
O
H S OH
O


4.
b b
T K m i A =
2.08 =0.52 1 i
i =4
( )
3
6
K Fe CN ( '''


AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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5.
Cl Cl
Cl Cl
A

O H OH
O H OH
O
O
( ) X ( ) Y
( ) Z




AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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M Ma at th he em ma at ti i c cs s PART I I I


1.
( ) | | | | | |
1 1
2 1
I x 1 1 1 dx x 1 0 1 dx

( = + + + + +

} }


2. Here,
( )
( )
1
f x , if 0 x
2
1 1
g x f , if x 1
2 2
3 x , if 1 x 2

s <

| |
= s s
|

\ .

< s



4. Let
A
CAD
3
= Z = u
By m n theorem,
(1 +1) cot o =1 cot 2u 1cot u
A
B C
D
o
u
2u


6. Here, z
2
z
3
=i(z
1
z
3
)
ACB
2
t
Z =

13
AC
2
= ; AC =BC

9. (0, 0) lies on the director circle

10.
1/ 3 1/ 2
2/ 3 1/ 3 1/ 2
x 1 x 1
x x
x x 1 x x

+
=
+


12.
1 1
3
a b 1 1 1
a b
x y z 3 ;
2 x y z 2
| |
+
|
+ | | \ .
+ + = + + =
|
\ .


14. Here, f
1
(x) =a x a +

SECTION C

1. Equation of tangent is
( ){ }
y f ' x | = o o
Also,
( )
( )
2
f '
f ' 1
| o o
o =
o +

Thus,
2 2
dy 1 y x
dx 2 xy
| |

= |
\ .

Thus, equation of curve is x
2
+y
2
2x =0

2. Equation of normal is
( )
n
n 1
1
y a x a
na

=
AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

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4. Here, A
1
=d(a
1
a
2
)(a
2
a
3
)(a
3
a
1
) =2d
4

Also, A
2
=2d
4


5. sin
2
x[sin
2
x +sin x +2] =0
sin x =0, where x =0, t, 2t, 3t