UNIVERSIDAD DE SAN CARLOS DE GUATEMALA

FACULTAD DE CIENCIAS QUMICAS Y FARMACIA

ESCUELA DE QUMICA
DEPARTAMENTO DE ANLISIS INORGNICO

CONSTANTES DE DISOCIACIN (IONIZACIN) A 25C

CIDO
Actico
Acetilacetona
Acrlico
AEDT

Alanina H+
Arsnico

Arsenioso
Ascrbico
Asprtico

Benzoico
Brico
Carbnico
Cianhdrico
Cinico
Ctrico

Cloroactico
Crmico
Fenol
Fluorhdrico
Frmico
Fosfrico

Fosforoso
Ftlico
Fumrico
Hidrazoico
Hipobromoso
Hipocloroso
Hipoyodoso
Lctico

CIDOS
EQUILIBRIO
HC2H3O2 H+ + C2H3O2CH3COCH2COCH3 H+ + CH3COCHCO-CH3
CH2=CH-COOH H+ + CH2=CH-COO(1) H4Y H+ + H3Y(2) H3Y- H+ + H2Y-2
(3) H2Y-2 H+ + HY-3
(4) HY-3 H+ + Y-4
NH3+CH2COOH H+ + NH3+CH2COONH3+CH2COO- H+ + NH2CH2COO(1) H3AsO4 H+ + H2AsO4(2) H2AsO4- H+ + HAsO4-2
(3) HAsO4-2 H+ + AsO4-3
(1) H3AsO3 H+ + H2AsO3(2) H2AsO3- H+ + HAsO3-2
C6H6O4(OH)2 H+ + C6H6O4(OH)OC6H6O4(OH)O- H+ + C6H6O4(O)2-2
NH3+CH(COOH)CH2COOH H+ + NH3+CH(COOH)CH2COONH3+CH(COOH)CH2COO- H+ + NH3+CH(COO-)CH2COONH3+CH(COO-)CH2COO- H+ + NH2CH(COO-)CH2COOHC7H5O2 H+ + C7H5O2HBO2 H+ +BO2(1) H2CO3 H+ + HCO3(2) HCO3- H+ + CO3HCN H+ + CNHCNO H+ + CNO(1) H3C6H5O7 H+ + H2C6H507(2) H2C6H507- H+ + HC6H507-2
(3) HC6H507-2 H+ + C6H507-3
ClCH2COOH H+ + ClCH2COO(1) HCrO4 H+ + CrO4-2
C6H5OH H+ + C6H5OHF H+ + FHCOOH H+ + HCOO(1) H3PO4 H+ + H2PO4(2) H2PO4- H+ + HPO4-2
(3) HPO4-2 H+ + PO4-3
(1) H3PO3 H+ + H2PO3(2) H2PO3- H+ + HPO3-2
(1) H2C8H4O4 H+ + H C8H4O4(2) H C8H4O4- H+ + C8H4O4-2
(1) H2C4H2O4 H+ + HC4H2O4(2) HC4H2O4- H+ + C4H2O4-2
HN3 H+ + N3HBrO H+ + BrOHClO H+ + ClOHIO H+ + IOCH3CHOHCOOH H+ + CH3CHOHCOO-

Pgina 1 de 2

Ka
1.8x10-5
1.0X10-9
5.5x10-5
1.0x10-2
2.1x10-3
6.9x10-7
5.5x10-11
4.5x10-3
1.3x10-10
6.0x10-3
1.1x10-7
3.0x10-12
6.0x10-10

pKa
4.74
9.00
4.26
2.00
2.67
6.16
10.26
2.35
9.89
2.22
6.98
11.53
9.22

3.0x10-14

13.52

6.8x10-5
2.8x10-12
1.0x10-2
1.3x10-4
1.0x10-10
6.6x10-5
6.0x10-10
4.6x10-7
5.6x10-11
4.9x10-10
2.2x10-4
8.3x10-4
2.2x10-5
4.0x10-7
1.26x10-3
3.2x10-7
1.3 x10-10
2.4x10-4
1.7x10-4
7.5 x10-3
6.2 x10-8
4.7 x10-13
5.0x10-2
2.6x10-7
8.0 x10-4
4.0 x10-6
9.6x10-4
4.1x10-5
1.9x10-5
2.5x10-9
3.0 x10-8
5.0 x10-13
1.4x10-4

4.17
11.56
1.99
3.90
10.00
4.18
9.22
6.34
10.25
9.31
3.66
3.08
4.66
6.40
2.90
6.50
9.89
3.62
3.77
2.12
7.21
12.33
1.30
6.59
3.10
5.40
3.02
4.39
4.72
8.60
7.53
12.30
3.85

CIDO
Maleico
Mlico
Nitroso
Oxlico
Pcrico
Propanoico
Saliclico
Succnico
Sulfmico
Sulfhdrico
Sulfrico
Sulfuroso
Tartrico
Tricloroactico

BASE

EQUILIBRIO
cis-HOOCCH:CHCOOH H+ + cis-HOOCCH:CHCOOcis-HOOCCH:CHCOO- H+ + cis--OOCCH:CHCOO(1) H2C4H3O5 H+ + HC4H3O5(2) HC4H3O5- H+ + C4H3O5-2
HNO2 H+ + NO2(1) H2C2O4 H+ + HC2O4(2) HC2O4- H+ + C2O4-2
(NO2)3C6H5OH H+ + (NO2)3C6H5OH
CH3CH2COOH H+ + CH3CH2COOC6H4(OH)COOH H+ + C6H4(OH)COO(1) H4C6O4 H+ + H3C6O4(2) H3C2O4- H+ + H2C6O4-2
NH2SO3H H+ + NH2SO3(1) H2S H+ + HS(2) HS- H+ + S-2
(2) HSO4- H+ + SO4-2
(1) H2SO3 H+ + HSO4(2) HSO4- H+ + SO4-2
(1) H2C4H4O6 H+ + HC4H4O6(2) HC4H4O6- H+ + C4H4O6-2
Cl3COOH H+ + Cl3COO-

Ka
1.5x10-2
2.6x10-7
3.5 x10-4
8.9 x10-6
5.1 x10-4
5.6 x10-2
5.2 x10-5
4.2x10-1
1.3x10-5
1.0x10-3
6.5 x10-5
3.3 x10-6
1.0x10-1
1.0x10-7
1.2x10-13
1.0 x10-2
1.3 x10-2
6.3 x10-8
3.0 x10-3
6.9 x10-5
1.3x10-1

pKa
1.82
6.59
3.46
5.05
3.29
1.25
4.28
0.38
4.89
3.00
4.19
5.48
1.00
7.00
12.92
2.00
1.89
7.20
2.52
4.16
0.89

BASES
EQUILIBRIO

Kb

pKb

NH3 + H2O NH4 + OH

1.8x10

-5

4.74

CH3(CH2)2CH2NH2 + H2O CH3(CH2)2CH2NH3+ + OH-

4.1x10-4

3.39

C10H7NH2 + H2O C10H7NH3+ + OH-

9.9x10-11

10.01

C6H5NH2 + H2O C6H5NH3+ + OH-

4.6x10-10

9.34

C10H7NH2 + H2O C10H7NH3+ + OH-

2.0x10-10

9.70

(CH3CH2)2NH + H2O (CH3CH2)2NH2+ + OH-

8.5x10

-4

3.07

Dimetilamina

(CH3)2NH + H2O (CH3)2NH2+ + OH-

5.9x10-4

3.23

Etanolamina

HOC2H4NH2 + H2O HOC2H4NH3+ + OH-

3.2x10-5

4.49

C2H5NH2 + H2O C2H5NH3+ + OH-

5.6x10-4

3.25

NH2C2H4NH2 + H2O NH2C2H4NH3+ + OH-

8.5x10-5

4.07

NH2C2H4NH3+ + H2O NH3+C2H4NH3+ + OH-

7.1x10-8

7.15

C6H5N2H3 + H2O C6H5N2H4+ + OH-

1.6x10-9

8.80

HOOCCH2NH2 + H2O HOOCCH2NH3+ + OH-

2.3x10-12

11.64

Hidracina

N2H4 + H2O N2H5+ + OH-

3.0x10-6

5.50

Hidrxido de zinc

Zn(OH)- + H2O Zn+2 + OH-

4.4x10

-5

4.36

Hidroxilamina

NH2OH + H2O NH2+ + OH-

6.6x10-9

8.18

Metilamina

CH3NH2 + H2O CH3NH3+ + OH-

5.0x10-4

3.30

Piperidina

C5H11N + H2O C5H11NH+ + OH-

1.3x10-3

2.89

-9

8.64

Amonaco
1-Butilamina
-Naftilamina
Anilina
-naftilamina
Dietilamina

Etilamina
Etilendiamina
Fenilhidracina
Glicina

Piridina

C5H5N + H2O C6H5NH+ + OH-

2.3x10

Quinolena

C9H7N + H2O C9H7NH+ + OH-

1.0x10-9

9.00

Trietilamina

(C2H5)3N + H2O (C2H5)3NH+ + OH-

2.6x10-4

3.58

(CH3)3N + H2O (CH3)3NH+ + OH-

6.3x10-5

4.20

(HOCH2)3CNH2 + H2O (HOCH2)3CNH3+ + OH-

1.2x10-6

5.92

Trimetilamina
Tris(hidroximetil)ami
nometano

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