ELGHZIZAL’S SCRIBD DOCUMENTS

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‫
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א‬#$

pH0>7
(
 ‫
)

א‬VA = 0


 ‫( 

 
א‬1


:
 ‫(
('&
א‬2
CH 3 NH 2 + H 3 O +
CH 3 NH 3+ + H 2 O
     )
       
: (  # 71 "  !
  % & # # % 
( !   ' ( & ) :  % % 
,&  90  88 " *&+    % :  % % 
: (%


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(pHE = 6 ; 25ml )

A

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m
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CB
*









m



n M
CB = = ⇒ m = CB .V .M C A .VA = CB .VB
V V -./ (5
V = 0, 5l CV 0,1 × 25
CB = A A = 0
= 5.10−2 mol.l −1
M = 12 + 14 + 5(1) = 31g .mol − VB 50
%
⇒ m = 0, 775 g  % ( 1
"2 0 & 34 1
 1 5(
  6 7 8
  + 



 ‫

א‬#M,,C‫
א‬-N

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א‬pH0
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א‬3'
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I
،
J‫
א‬K
2‫
א‬.*
&L
&C‫א‬0(


pH = pK e + log CB


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7'‫
א‬O-.*
:
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pH ≈ 11, 6
#67VA = 0
11, 6 ≠ 14 + log 5.10−2 = 12, 7 :
D7 ,'‫

























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א‬K
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pH

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א‬YZ‫
א‬-N
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א‬H3O+
(
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Xr
P35'

Xf


W

-X
PT4'‫
א‬pH
&3
www.pc1.sup.fr 1
ELGHZIZAL’S SCRIBD DOCUMENTS


Xr =  H 3 O +  VS = 10− pH .VS = 10−6 (25 + 50).10−3 = 7, 5.10−7 mol
f

X r = C A .VA − X f
⇒ X f = C AVA − X r

:


#$
−3 −7 −3
X f = 2,5.10 − 7, 5.10 ≈ 2, 5.10 mol

Xm = CBVB = 5.10-2.50.10-3 = 2,5.10-3 mol  ‫ و‬CB.VB - Xm=0




$

\‫

א‬xm
E5=

Xf



P:
‫
א 
<;א‬.* τ=
Xm
=1

^,,C‫


א‬




‫ا د‬ ‫ام‬ CH NH + H 3O +

CH NH +
+ H O
3 2 3 3 2

‫ا 
ا‬ X=0 CB.VB ni =CA.Vi A * * 0 ‫و‬

 ‫ل ا‬ X CB.VB - X ni(H3O+) - X * * X ‫و‬

 !‫ا 
ا‬ Xf CB.VB - Xf ni(H3O+) – Xf * * Xf ‫و‬
+

‫ی‬#$‫ا 
ا‬ Xm= CB.VB - Xm ni(H3O ) – Xm * * Xm ‫و‬

CA.VA,E

X m=

#$
(
Q-6
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א‬M‫א‬,9
)
_‫
א‬.,‫
א‬I
7'‫`
א‬3Z‫
א‬-
>SZ‫א
א‬G46


VA = 10 ml

&"/<


Y2‫
א‬U
7,'‫(
א‬6
Xm = CAVA = 10-1.10.10-3mol = 10-3mol =1mmol


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a/
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&5'6(7

pH = pK A + log
[CH 3 NH 2 ]
CH 3 NH 3+ 


[CH 3 NH 2 ] ⇔ 10 pH − pK A = [CH 3 NH 2 ]
⇔ pH − pK A = log
CH 3 NH 3+  CH 3 NH 3+ 



CBVB − X éq
[CH 3 NH 2 ] =
(VA + VB )
=
CBVB − X éq
CH 3 NH 3  + X éq X éq


(VA + VB )
:

b‫א‬,'‫

א‬$
D65'‫
א‬$
\‫
א‬$


CBVB − X éq
10 pH − pK A =
X éq



`3Z‫

א‬10ml
ae9



pH
&3
 79

VA
&'d
6
pH
B‫א‬Qc,'
3‫


א 
א‬Xéq
&3
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א‬



X

S'
CBVB
$

pKA$

pH

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א'&
א‬f
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pH ≈ 10,2 :
 79
2, 5.10−3 − X éq


10 10,2 −10,7
= ⇒ X éq (1 + 10−0,5 ) = 2, 5.10−3
X éq
−3
X éq ≈ 2.10 mol
www.pc1.sup.fr 2
 ELGHZIZAL’S SCRIBD DOCUMENTS





(5

f
‫?א‬5'‫&

א‬6Mh‫א‬$

f
#65=
i
VA =10ml
&"/<



X f &T4'‫&
א‬37'‫(
א‬8
τ = 1 ⇔ Xf = Xm

:

'

(9

CH 3 NH 3+ 

:
#$
10 pH − pK A
=
[CH 3 NH 2 ]
:
DC
j

'
K = éq

CH 3 NH 3+  [CH 3 NH 2 ]éq  H 3 O +  éq

1 pK 110,7 10

D"‫

א‬I$
P:
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א
"!
א‬M
Q:
K

k$ K = 10 pH − pK .  H O +  = 10 pH − pK .10− pH = 10 = 10 ≈ 5.10
A

A A
 3  éq


8
‫?א‬5'‫&
א‬S,9

 
( ‫م‬#‫دی‬#$‫دا ) هروآ ا‬#$‫ل ا‬#' ‫رﺏ( و‬#+‫ﺱ‬-‫ ا‬. / ‫ل ا‬#'‫دراﺱ
ﺕ  ا‬ (I

HA(aq) + HO- (aq)
A- (aq) + H2O















(11

(21


[H3O ] = 10
+ -pH
= 10-4 mol/l ⇔ pH = 4

























(121
Ke
 HO −  = = 10−10 mol.l −1













:

'
(221
 H 3 O + 

nf(HO-) = [HO-]. (VA + VB) = 1,72.10-12 mol :

‫
و‬


(321


‫ا د‬ ‫ام‬ HA(aq) + HO- (aq)
A- (aq) + H2O

‫ا 
ا‬ CAVA CBVB * * 0 ‫و‬

 ‫ل ا‬ CAVA - X CBVB - X * * X ‫و‬

 !‫ا 
ا‬ CAVA - Xf CBVB - Xf * * Xf ‫و‬




Xf = CB.VB = 1,44.10 mol : ‫ و‬CBVB - Xf
=
0



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E5=
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 HO −  n0 ( HO − ) − n f ( HO − ) 2,88.10−2.10.10−3 − 1, 72.10−12
reagit


τ = = = ≈1
 HO −  n0 ( HO − ) 2,88.10−2.10.10−3
0

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א‬m
 
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www.pc1.sup.fr 3
ELGHZIZAL’S SCRIBD DOCUMENTS



pKA
&3

D7 ,'‫(
א‬512
 A− 
pH = pKA + Log 

[ AH ]





:
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א‬$
\‫


א‬AH
n: *$

A-
n: *
(
'
Xf
 A 
−
VA + VB Xf 1, 44.10−4
= = = =1
[ AH ] C AVA − X f C AVA − X f 2,88.10−2.10.10−3 − 1, 44.10−4


VA + VB
 A− 
log = 0 ⇒ pH = pK A = 4
[ AH ]
K
b‫א‬,'‫&
א‬,6o
(13
 A−   A−  .  H 3O +   A−  K
eq eq eq 1 eq
K= = = . = A = 1010
[ AH ]eq  HO−  eq
[ AH ]eq .  HO−  .  H 3O + 
eq eq
 HO  .  H 3O  [ AH ]eq .  H 3 O 
−
eq
+
eq
+
eq
Ke

.
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(
‫ی‬pH ) pH ‫ ا  ﺏ س‬6‫( ﺕ‬II

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א‬B‫

א‬+5=

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dpH/dV :
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PI
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pH>7 (32



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#'‫ ا‬78‫ا‬#+‫( ا یة ﺏ ﺱ ل ا‬III

www.pc1.sup.fr 4
ELGHZIZAL’S SCRIBD DOCUMENTS

(13

?"-,'‫@&
א‬79
Lv*
#"@9‫&
א‬7@
G'‫
א‬$n -'‫
א‬m
I
+C‫
א
א‬au-'‫
"!
א‬pH =8

k(23

VA >SZ‫
א‬f
(M‫`
א‬3Z‫&
(
א‬3: (33

n(AH) =CAVA = 2.10-2.14,4 = 2,88.10-1 mmol

. ‫" ! ص واﺡ‬# ‫( آ ا‬43

0,288mmol "‫ ه‬10ml '(‫" ا*) ا‬# ‫دة‬-.-‫ ا'دة ا‬/‫ أن آ‬/‫آ‬1‫ ا‬2* - ‫أ‬
.  '( 9! 100ml "# ‫ ! ص واﺡ‬5‫ ) إذا‬8 – ‫ب‬
: "''5‫ و‬n = 10(0,288mmol) "‫" ! ص واﺡ ه‬# ‫ 'دة ا‬/‫ أن آ‬:
;‫ﻥ‬
m(AH)= n.M(AH) = 2,88.10-3.176=507.10-3g ≈ 500mg
5 &'‫

א‬KY‫
א‬0u<


I$

www.pc1.sup.fr 5