Example 10.

3
For the system methanol (1) / methyl acetate (2)
ln  1  Ax22 , ln  2  Ax12 where A  2.771  0.00523T

3643.31 2665.54
ln P1sat  16.59158 
T  33.424
, ln P2sat  14.25326 
T  53.424

Assuming the validity of (10.5) , calculate : P , xi ; T = 318.5 K , y1 = 0.6

(b) DEW POINT calculation : for T = 318.5 K , y1 = 0.6
 Star with assuming  1  2 1
1
P
 Calculate P by y1  y2
P
1 1
sat
 2 P2sat
y1 P
 Calculate x1 by x 1 
 1 P1sat and x 2  1  x1

 Substitute xi into the activity coff. Eq (  ,  ) and compare with the assumed value
1 2

 Return to the first step.

 Another data:
3643.31
P1sat : ln P1sat  16.59158 
318.5  33.424
;P 1
sat
 44.51kPa

2665.54
P2sat : ln P 2
sat
 14.25326 
318.5  53.424
;P 2
sat
 65.64kPa

A : A  2.771  0.00523(318.5)  1.107

 1 :  1  exp  1.107   x2  
2
 
 2 :  2  exp  1.107   x1  
2
 

ɤ1 ɤ2 P/kPa x1 x2 ɤ1(new) ɤ2(new)

1 1 51.08828 0.688676 0.311324 1.113261 1.690496
 1.113261 1.690496 63.63977 0.770593 0.229407 1.059989 1.929676
1.059989 1.929676 62.99139 0.801076 0.198924 1.044779 2.034777
1.044779 2.034777 62.90411 0.811612 0.188388 1.040069 2.073413
1.040069 2.073413 62.89377 0.815153 0.184847 1.038549 2.086676
1.038549 2.086676 62.89261 0.816331 0.183669 1.03805 2.091122
1.03805 2.091122 62.89248 0.816722 0.183278 1.037885 2.0926
1.037885 2.0926 62.89247 0.816851 0.183149 1.037831 2.09309
1.037831 2.09309 62.89247 0.816894 0.183106 1.037813 2.093252
1.037813 2.093252 62.89247 0.816908 0.183092 1.037807 2.093306
1.037807 2.093306 62.89247 0.816913 0.183087 1.037805 2.093324
1.037805 2.093324 62.89247 0.816915 0.183085 1.037804 2.09333
1.037804 2.09333 62.89247 0.816915 0.183085 1.037804 2.093332
1.037804 2.093332 62.89247 0.816915 0.183085 1.037804 2.093332
1.037804 2.093332 62.89247 0.816915 0.183085 1.037804 2.093332

 P  62.89274kPa, x1  0.816915, x2  0.183085,  1  1.037804,  2  2.093332 Q.E.D.

Navapon Pittayaporn
50290015 CHE