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1
ANSWERS, HINTS & SOLUTIONS
CRT II
(Paper1)
Q.
No.
PHYSICS CHEMISTRY MATHEMATICS
1.
C C B
2.
A D A
3.
C D B
4.
D A C
5.
B D A
6.
D C D
7.
C B D
8.
B C C
9.
C C A
10.
A C A
11.
B, D D A, B, D
12.
A, B, C A, B, C, D A, B, C, D
13.
A, B, C B A, B
14.
B, D A, B, C, D A, B, C
15.
A, B, D B, C, D A, D
1.
1 2 2
2.
7 6 3
3.
4 1 4
4.
3 2 0
5.
1 4 6
A
L
L
I
N
D
I
A
T
E
S
T
S
E
R
I
E
S
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2
P P h hy ys si i c cs s PART I
3.
2
e
dm
F v Av
dt
= =
2
( Av )H
2
t =
7.
2
H
mv
N qEcos
R
+ u = (i)
H
N 0 =
(
H
N horizontal component of normal force)
qER(1cos u) =
2
1
mv
2
qE
N
u
8.
3 2
F
0.02
A
10
n 10 kg/ ms 10 poise
2 dv
1 dx
 

\ .
= = = =
 

\ .
9. Velocity of bike V
b
=30 m/ s
Let velocity of car be V
c
f
obs
=f
actual
c so
b so
V V
V V
+
120 Hz =100 Hz
c
V
+
330
30 330
V
C
=30 m/s
Distance between initial and final pulse of horn
=V
so
At  V
C
At {At is duration of emission of sound}
=(330 30) 6 =1800 m
This wave train travels with 330 m/s and cross bike rider moving with velocity of 30 m/s towards
it.
time taken =
b so
V V
train wave of length
+
=
1800 180
5
330 30 36
= =
+
sec
11. Kinetic friction acts opposite to relative velocity w.r.t. contact surface.
12. X
L
=2X
C
C
X' =4X
C
L
X' =2X
L
L
X'
C
X' =2X
L
4X
C
=2[X
L
2X
C
] =0
14. Since vertical Impulse is acting on A
Hence momentum of A & B will constant in horizontal direction only.
and M.E. of A & B will remain constant
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3
SECTION C
1. Angular momentum Conservation
2
2 2
0
1 MR
MR mR '
2 2
 
e = + e

\ .
0
M
'
M 2m
 
e = e

+
\ .
U =
0
M
'R R
M 2m
 
e = e

+
\ .
2. M.E. Conservation
mg(4)
2 2
k 1
x mv
2 2
=
kx =55
mg +kx =ma
5520 =2a
a =17.5 m/sec
2
3. =
qBR
t
mg
 

\ .
=0.4
5. t =
 
2 2
dE B C M
1000sec
B mg
+
=
=1
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4
C Ch he em mi i s st tr r y y PART I I
SECTION A
1. In (C), the tautomeric form will be
O
C
6
H
5
C
6
H
5
H
5
C
6
H
5
C
6
OH
C
6
H
5
C
6
H
5
H
5
C
6
H
5
C
6
The tautomeric form, contains sphybridised carbon in ring, making it unstable.
tautomerism is not shown by (C).
2.
2AgBr 2OH

+ + OH O H
Hydroquinol
( ) ( )
2
2Ag s 2H O + + O O ( ) 2Br aq
+
Hydroquinone
3. PV
=constant
1
105V
P Constant
100
 
=

\ .
1
P 105
1
P 100
 
=

\ .
7
5
1
P 100
or
P 105
(
=
(
( for N
2
or O
2
=7/5)
P
1
=0.93P,
7% decrease in pressure.
4. O
2
is replaced by X
8/3
, so formula of spinel is MgAl
2
X
3
and deficiency by one anion.
5.
W RT
M V
t =
RT
Slope
M
=
3 3
0.082 293
M
4.65 10 10
=
5.16 10
6
g

t
C
6.
( )  
5 4
PBr s PBr Br
+
+
( ) ( )
2
2 5 2 3
N O s NO NO sp
+
+
( ) ( )
3 2
5 4 6
PCl s PCl PCl sp d
+
+
( ) ( )
3
2 6 2 4
Cl O s ClO ClO sp
+
+
P
Cl
Cl
Cl
Cl
Cl
Cl
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5
7.
H
(I)
H
(II)
H
(III) (IV)
(Conjugate base)
(Aromatic)
(Nonaromatic) (antiaromatic) (antiaromatic)
H
(III) and (IV) both are antiaromatic, but (IV) has more resonating structures than (III).
So, stability of conjugate bases: (I) >(II) >(IV) >(III)
And pk
a
order is: (I) <(II) <(IV) <(III)
8. pH =9.71,
10
H 1.95 10
+
(
=
2 3
PrNH HCl PrNH Cl
+
+ +
 
2
a
3
Pr NH H
K
PrNH
+
+
(
=
(
 
2 a
3
Pr NH K
H PrNH
+ +
=
( (
 
2
3
PrNH
0.1
PrNH
+
=
(
9. CH
2
COOH
Cl
dil
aq. NaOH
( ) A
CH
2
OH
COOH
H
+
O
O
CH
2
2 2 7
acidic
Na Cr O
COOH
COOH
8 4 3
Product(C H O ) O
O
O
A
10.
C
Me
CH
( )
2 2
H /Ni B
p 2 catalyst
CH
Me
CH
2
H
+
CH
Me
CH
3
Ring expansion
Me
CH
3
H
+
Me
Me
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6
11. CH
3
CH
3
CH
3
CH
3
Trans  1, 2  dimethyl cyclohexane
Trans  1, 3  dimethyl cyclohexane
No plane of symmetry in both the above isomers, hence optically active.
12.  
4
NO BF
+
B F F
F
F
No. of o bonds in
 
4
BF 4
=
=B. O. of NO 3.0
+
= , i.e. one sigma bond and two t bonds.
It has 5 sigma and two ,t bonds.
NO
+
is diamagnetic and
4
BF
is also diamagnetic
BF bond energy is lower in
4
BF
than in BF
3
, due to presence of back bonding in BF
3
.
13.
( )
2 2
2 o
10
2H / H 2H /H 2
p H
0.059
E E log
2
H
+ +
+
=
(
14. ( ) ( )
o o o
f f
H H products H reactants A = A A
=166 (51) = 115 KJ mol
1
AS
o
=266 243 =23J =0.023 KJ mol
1
K
1
AH
o
=ve
AS
o
=+ve
AG
o
=AH
o
 TAS
o
AG
o
will be ve at all temperature and the reaction is favour at temperature.
15. Formula of complex is : [Co(SCN)
2
(NH
3
)
4
]
3
[Co(ox)
3
]
Linkage isomerism is due to presence of SCN
O
Optical isomerism is exhibited due to presence of [Co(ox)
3
]
3
which has asymmetric structure.
Geometrical isomerism is exhibited by [Co(SCN)
2
(NH
3
)
4
]
+
part
SECTION C
1.
( )
3 2 2 3 2
Black ppt
AgNO H S O Ag S +
2.
Sb
F
F
F
F
F
F
Sb
F
F
F
F
F
Sbhybridisation is sp
3
d
2
=total 6 hybrid orbitals per sbatom.
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7
3.
O
O
3
RCO H
O
O
O
( ) Product X
The number of sp
2
carbon is X are 10, the sum 1 +0 =1
4.
( )
( )
n n s
nM nX M X ne L.H.S
+ +
For, ( )
n n
M X ne nM nX R.H.S
+ +
10
0.059 0.01
E log
n 0.1
=
n =2
5.
2 2
1 1
A B AB
2 2
+
A A B B A B
1 1
H e e e
2 2
A = +
100 =
x 0.5x
x
2 2
+
x =400 KJ mol
1
x =4 10
2
KJ mol
1
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8
M Ma at th he em ma at ti i c cs s PART I I I
1.
u xi 3xj = +
u u 2i u i =
( ) ( ) ( )
2 2
2 2
2 x x 2 3x x 1 3x + = +
2 2
4 x x x 1 4x 2x 1 + = +
Squaring, 16x
2
(x
2
x +1) =16x
4
+4x
2
+1 16x
3
4x +8x
2
16x
2
=12x
2
4x +1
4 32 1 2
x
8 2
= =
x = 2 1
u 2 1 2 1 = =
a =2, b =1
2. 2000x
6
+100x
5
+10x
3
+x 2 =0
( ) ( )
3
2
6
2
x 10x 1
2000x 2 0
10x 1
+ =
( )
( )
6
6
2
x 1000x 1
2 1000x 1
10x 1
1000x
6
1=0 or
2
x
2
10x 1
=
x =(10x
2
1)
2
1
x
10
= which is not possible
20x
2
+x 2 =0
1 161
x
40
= , m =1, n =161, r =40
(m +n +r) =200
3. Let P(a cos u, b sin u)
Slope of
b
cp tan
a
= u
2 2
a b
tan sin2
2ab
o = u
o
P(u)
y
C (0, 0)
o
x
2 2
2ab
sin2 tan
a b
u = o
Using sin 2u s 1 and
2
2
2
b
e 1
a
=
2
2
b
2
a
tan 1
b
1
a
o s
2
2
2 1 e
tan 1
e
o s
e
4
+4e
2
tan
2
o 4 tan
3
o > 0
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9
( )
2
2sin
e 2tan sec tan
1 sin
o
> o o o =
+ o
4.
( )
( ) ( )( )
( )
1
k
1 k 1 k k 1 k 2
T cos
k k 1 k k 1
 
+ +
= + 
+ + \ .
Let
1
x
k
= ,
1
y
k 1
=
+
( )
( ) ( )
2
2
2
1 k 1 1 k k 2
1 y 1
k 1 k 1
k 1
+ +
= = =
+ +
+
1 1
k
1 1
T cos cos
k 1 k
 
=

\ + .
, substituting n =2, 3, 4
1 1
n
1 1
S limcos cos
n 1 2 2 3 6
t t t  
= = =

\ + .
n
120
S
6 k
t t
= =
k =720
5. ZEAC =o 
ZEAB =o +
It is given that tan(o ), tan o and tan(o +) form a G.P.
Thus ( ) ( )
2 2
2
2 2
tan tan
tan tan tan
1 tan tan
o 
o = o  o +  =
o 
tan o =1, o =45, thus
A
B D C E
o


AD =DE =5 2, so that area A(ABC) =
1
BC AD CD AD 50tan
2
= = 
Now, cot o, cot(o ), cot  form an A.P.
2 cot(45 ) =1 +cot  cot  =3
( )
50
ABC
3
A =
6. ABCD is a trapezium and its area =
( )
1
a b h
2
+
Where
a b
EF
2
+
= (mid parallel)
Area =2r(EF)
Now equation of EF is y =x +c .. (1)
From equation (1) passes through (r, r)
c =2r
x +y =2r, hence E =(2r, 0) and F(0, 2r)
2 2
EF 4r 4r 2 2r = + =
Area ABCD =2r
2
2 2r 4 2r =
2
4 2 r 900 2 = , r
2
=225 r =15
7. A
2
2A +2I =0
Divide B by A
2
2A +21
B =(A
2
2A +21)(f(A)) +A I
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10
0 1
B A I
1 0
(
= =
(
8. FG =p
DE =q
HI =r
In AAFG
P AG AF
sinA sinB sinC
= =
bp
AG
a
= ,
cp
AF
a
=
A
B I C D
F
G
H
E
Now, incircle of AABC is the excircle opposite to A for AAFG the semi perimeter of AAFG is
AFG
1 bp cp Sp
S p
2 a a a
A
 
= + + =

\ .
AFG
A Sp A
r S tan tan
2 a 2
A
= =
Since r =(s a)
A
tan
2
sp
s a
a
=
p a
1
a s
=
Similarly
q b
1
b s
=
r c
1
c s
=
9. Since the coefficient of
k in both A
and B
and B
can be
parallel is that f(t) =f(t), f'(t) =g(t)
The first differential equation, f(t) =f(t)
f(t) =p cos t +q sin t. (p, q e R) = ( )
2 2
p q sin t + +  ,
p
tan
q
 =
( )
2 2
max
f t M p q = = +
( ) ( )
2 2 2 2
A f t g t 1 p q 1 = + + = + +
is constant
10. A upon simplification (a +b +c) (a b) (b c) (c a)
The only way this can be 0 is (a +b +c) =0
fixed point is (1, 1)
11.
( ) ( )
x x
0 0
t f x t dt f t dt sinx cosx x 1 = + +
} }
( ) ( )
x
0
x t f t dt
}
=
( )
x
0
f t dt sinx cosx x 1 + +
}
( ) ( ) ( )
x x x
0 0 0
f t dt t f t dt f t dt sinx cosx x 1 = + +
} } }
Again differentiating
x f(x) +f(x) +f(x) xf'(x) f(x) >f'(x) sin x cos x
f(x) =f'(x) sin x cos x
Solving this linear differential equation
We get, f(x) e
x
=e
x
cos x +c
If x =0, f(0) =0 f(x) =e
x
cos x
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11
12. Let w be the event that the ball drawn is white
Then P(w) =
x
y
When, ball is lost P(w) =
x x 1 y x x x
y y 1 y y 1 y
+ =
When 2 balls is lost P(w) =
x x y x x
2 1 1 2
y y y
2 2 2
C C C y C x 2 x 1 x x
y 2 y 2 y 2 y
C C C
+ + =
Similarly for n =3, P(w) =
x
y
13.
v u z u z
w
uz 1 uz 1
= =
Let, w s 1
u z s uz 1
(u z)
( ) ( )( )
u z uz 1 uz 1 s
(u
2
1)(z
2
1) > 1
z
2
1 s 0
14. f(0
) =0, f(0
+
) =1, f(0) =1
discontinuous at x =0
f(1
+
+ +
=
n
2
1
2n 1
n
lim
2 1
n 1
n n
 
+

\ .
+ +
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12
Similarly
( )
2 n
2 n 1
lim
n
+
=
( )
n
2 n 1
lim 2
n
+
=
2.
( )
/ 2
3
1
0
I sinx rcosx dx
t
= +
}
=
/ 2
3 3 3 2 2 2
0
sin x r cos x 3rsin xcosx 3r sinxcos x dx
t
+ + +
}
=
3
2
2 2r
r r
3 3
+ + +
( )
/ 2
/ 2
0
2
0
2
I xcosxdx xsinx cosx
2
t
t t
= = + =
}
1 2
4r
I I I 2
2
= + =
t
2r
3
+3r
2
3r +2 =6
2r
3
+3r
2
3r 4 =0
1
3
r
2
=
,
12
3
rr
2
=
,
2
1
21
r
4
=
3. A event that die A was used in first two throws
B event that die B was used in first two throws
C event that next throws gives red face
E event that first two throws give red faces
2
2 2
1 4
A 4
2 6
P
E 5
1 4 1 2
2 6 2 6
 

  \ .
= =

\ .
   
+
 
\ . \ .
B 1
P
E 5
 
=

\ .
C 3
P
E 5
 
=

\ .
a =3, b =5
4.
( ) ( )
2
2
x
f x 2f f 6 x
2
 
= + 
\ .
( ) ( )
2
2
x
f ' x 2f ' x 2xf ' 6 x
2
 
= 
\ .
( ) ( )
2
2
x
f' x 2x f' f ' 6 x
2
   
=  
\ . \ .
( )
2
2 x
f ' f ' 6 x
2
 
> 
\ .
(if
2
2
x
6 x
2
> )
f'(x) is increasing
2
2
x
6 x
2
> x
2
>4
( )
2
2
x
f ' f ' 6 x 0
2
 
> 
\ .
when x <2 or x >2
f'(x) >0, when x e (2, 0) (2, )
a +b +c =0
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13
5. R =1 +sin u,
8
t
u =
c
1
c
2
=R +r
R r
sin
R r
u =
+
R sin u +r sin u =R r
R(1 sin u) =r(1 +sin u) (Put R =1 +sin u)
(1 +sin u)(1 sin u) =r(1 +sin u)
r =1 sin u
Rr =1 sin
2
u =cos
2
u
cos 2u =
( )
1 1 2 2
1 cos 1 cos
2 2 4 4
t +  
+ u = + =

\ .
a =2, b =4