Answer Solution

AITS-CRT-III-PCM(S)-JEE(Mai n)/14
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1

ANSWERS, HINTS & SOLUTIONS
CRT III
(Main)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
A B A
2.
A D D
3.
C A B
4.
A A C
5.
C D A
6.
C A C
7.
A A D
8.
D B C
9.
B A B
10.
C A B
11.
A B C
12.
D C B
13.
D D A
14.
C B B
15.
C C C
16.
A D B
17.
B C B
18.
B C A
19.
B A C
20.
D B A
21.
A C C
22.
C D C
23.
C D D
24.
A D A
25.
C C B
26.
C C C
27.
A D C
28.
C D D
29.
A C B
30.
C B B

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

FI I TJEE JEE (Main), 2014
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4

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3
7
2
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P
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a
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h
a
v
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b
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A
w
a
r
d
e
d

a

R
a
n
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(
A
d
v
a
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c
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d
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,

2
0
1
3


2
P P h hy ys si i c cs s PART I

1. V =Es ;
E =
2
2sm
qt

2
2
2s m
V
qt
= =11.375 Volt

.2
'
sin30 sin60
=

' 3 =
' 'cos30 vcos30 e =
cos60 (v ' ') cos60 (2v) v e = + e = =
e =v/ =
40 3
400
0.1 3
= rad/s

e
30
120

'
e'
v

3. for x<0
It will oscillate like SHM
Time period
1
m
T
k
= t
For x>0
It will perform periodic motion under constant force

2 2
2E
T 2
mg
=
Hence time period
1 2
T T T = +

2
m 2E
T 2
k mg
= t +

4
2
0
0
mv
ev B
R
=

0
mv
B
eR
=

2 2
a R b R + =

2 2
b a
R
2b
=

0
2 2
2bmv
B
(b a )e
=


3
5. Here the total time is given T
Time spent m the region is ( 2 ) t + u
Hence total time spent

2
T
2
t + u | |
=
|
t \ .

u
u
u
2 t + u
v
2 t u
v

6. Torque of Internal force is always zero. All other quantities will vary.

8. Static friction depends on tendency.

9.
2 2
2
ML 3ML
sin 60 2
12 24
=

10. When impulse of external force is zero.

11. Balance forces.
N

R
mg
m
2
L cos
N

( )

12.
I
I

13. y(x, t) =
2
a
x
t
b
e
| |
|
\ .
(
(
v =b

15. 2L =m (
1
/2) =
m T
2f 9

L =n (
2
/2) =
n T
2f 4

m =3n =3 1 =3

16. cos | =1 | =0 eL =1/eC

17. f
B
=f f
0
=
0
0 0
0
v v sin30
f f
v v sin30
+ | |

|

\ .

=
0 0
0
2v f
2v v


4
18.
2
1
mv h
2
= v

19. | =D/d, is minimum for violet.

20.
PG PC CG

V V V 2xj 2i = + = +

Hence, for the paritcle,
V
x
=2m/s and V
y
=2x =4t
a
x
=0 a
y
=4m/s
2

x =2t, y =2t
2

a
Total
=4m/s
2

(a) (along Y-axis)
and trajectory
2 2
x x
y 2.
4 2
= =
when N a a

t = , a cos u =a sin u u =45
So, V
x
=V
y
=2 V =2 2

2
C o
N
V 4 2
R 2 2
a 4.cos45
= = = m =
4
m
2


5
C Ch he em mi i s st tr r y y PART I I

2.
O
O
H
+
O
OH
O
OH
O
OH
H
O
OH
Tautomerise
O
OH

3.
D
+
H
D
H
D
H
D
3
D O
+
D
D
D
D
D
D

4. Talc has empirical formula Mg
2
(Si
2
O
5
)
2
Mg(OH)
2
which ( )
2n
2 5
n
Si O

units of two dimensional sheet
silicates.
5.
O
H
O
H
97
o
It has half open book like structure having dihedral angle 97
o

6. ( ) ( ) ( ) ( )
o o 1
r r 2 4
H 2 46.1 187.8 2 285.8 H N H kJ / mol
A = + + A
=- 241.0 kJ /mol
-1

( ) o
2 4
r
H N H 50.6 kJ / mol A =
Decomposition enthalpy =- 50.6 kJ /mol.
9. Radius ratio for MgO is =0.464 which reflect the coordination number 6 and radius ratio for MgS
is 0.353. Which reflect the coordination number 4.

6
10. ( ) ( ) ( ) ( )
2 3 4
H O ClO aq ClO aq 2H aq 2e
+
+ + +
( ) ( ) ( ) ( )
3 2 2
2H aq ClO aq 2e ClO aq H O
+
+ + +
( ) ( ) ( )
3 2 4
2ClO aq ClO aq ClO aq

+

o
cell
E 0.33 0.36 0.03 = =

o
cell
RT
E lnK
nF
= (at equilibrium)

0.059
0.03 logK
2
=
logK =- 1
K =0.1

3 4 2
2ClO ClO ClO
Initially .1 0 0
equilibrium .1 2x x x

+

( )
2
2
x
K
.1 2x
=

( )
2
2
1 x
x 0.019M
10
.1 2x
= =

12. Probability of finding an electron is zero, i.e.
2
0 = .
( )( )
2
3/2
2 /2
0
1 1
1 8 12 e 0
a 16 4
o
(
| |
( ( o o o + =
|

(
\ .

( )( )
2
1 8 12 0 o o o =
On solving for o we get
o =1, 6, 2 and
0
2r
a
o =
For o =1;
0
0
a 2r
1 r
a 2
=

0
0
2r
2; 2 r a
a
o = =

0
0
2r
6; 6 r 3a
a
o = = =
13. n-factor of H
3
PO
2
is 4/3 for the reaction.
14.
b b
T K m i A =
2.08 =0.52 1 i
i =4
This implies that the salt on dissociation gives 4 ions. Thus, the salt that gives four ions is
K
3
[Fe(CN)
6
].

7
15.
D
H
O
CH
3
H
+
D
H
O
+
CH
3
H
OH
H
CH
3
D
-D shift
OH
D
CH
3
H
H
+
OH
D
CH
3

16. O
2
SeO
O
O
OH
Bezilic acid rearrangement
OH
COO
( ) B
( ) C

18. It is a non-degradable pollutant.
19. Colloidal silver bromide solution is used in photography.
20. Stability of carbonates increases down the group. Carbonates of alkali metals are more stable
than those of alkali metals.
21.
2px
t and
2py
t have one nodal plane each. In o1s there is no nodal plane and in case of
*
2px
t there
are two nodal planes.
22. Le-Chatelliers principle.
25. COOH
2
SOCl
COCl
3
AlCl / A
O
Zn/Hg
HCl

26.
4
NH Cl Nesseler's reagent Browncolour of iodide million's base. +


8
M Ma at th he em ma at ti i c cs s PART I I I

1. Using T =S
1
take midpoint (h, k) then equation of PQ is
xh +yk (h
2
+k
2
) =0 .. (1)
mx y +2m =0 .. (2)
Compare (1) and (2) eliminate m

2. As f(x) is continuous decreasing function on (0, ), so 0 <f(8x) <f(6x) <f(4x)
So
( )
( )
( )
( ) x x x
f 6x f 4x
lim1 lim lim
f 8x f 8x
< <
By squeeze play theorem
( )
( ) x
f 6x
lim 1
f 8x
=

3. The given lines will be parallel to lines ax
2
6xy +y
2
=0
So,
2
y y
6 a 0
x x
| | | |
+ =
| |
\ . \ .

m +m
2
=6 .. (1)
Which gives m =3 or 2
and mm
2
=a .. (2)
From (2) a =27 or 8
Hence sum of all possible value of a =19

4.
( ) ( )
2
x
4
lim
x
2
e lng 2 x lng 2
(

0
form
0
| |
|
\ .

( )
( )
( )
( )
( )
x 0
2
g' 2 lim 1
2
g 2
2
g' 2 x
2x
1 g 2 x
e e e
2x e
= = =

5.
( )
1/ n
0
n
2
f t dt
I lim
1
n
=
}

0
form
0
| |
|
\ .

Using : L Hospital and using Leibnitz rule

3
2
n n
1 1
n f
n 1 n n
I lim lim f
2 2 n
| || |
| |
\ . | | \ .
= =
|
\ .

Put
1
n
h
= hence

( ) ( )
( )
h 0
1 f 0 h f 0 1
I lim f' 0
2 h 2
| | +
= =
|
\ .

6. For xy =1
2
dy 1
dx
x
=
Slope of normal to xy =1 for x
2
>0 (x = 0)
Slope of line (given) =
( )
2
2
log 1 5a a
0
5
+
>
So 1 +5a a
2
>1

9
a
2
5a <0 hence a e (0, 5)

7.
2
a
3
=

1 1 2 2 2
ah
2 2 3
3 3
A = = =

( ) ( )( )
( )
abc 2 1 1 3 3
R
4
3 4 2 2 2
= = =
A

A
1 1
M
a
B C
2
3

1
3

1
3

8. Area of the parallelogram outside the circle
=Area of parallelogram Area of sector OPQ
=
( )
1 1
sin 2 sin f
2 2 2
u | |
u u = u = u
|
\ .

Q
R
P
O
u
r =1

9. Using
( )
( )
n n 1 n 2
r r 1 r 2
n n n 1
C C C
r r r 1

= =
is equal to

10. We have |(A
1
) adj(B
1
) adj(2A
1
)| =
2 2
1 1 64
A
B A
=
64
8
2 1 4
=

(By using |A
1
| =
1
A
and |adj B| =|B|
n1
where n is order of square matrix)

11. This distance between the given parallel lines (h) is
1
5

length of the side of triangle is =
2h
3

Area of triangle =
2 2
3 4h h 1
4 3
3 5 3
= =

12. The volume of tetrahedron =
1 0 0
1 1 1
OA OB OC 1 1 0
6 6 6
0 1 1
(
= =

Area of base = ( ) ( )
1 1

i j i j k i i k
2 2
+ + = =
( )
1 1
2
2 2
=
Hence height =
3 volume 3 2 1
Area of base 6
2
= =

13. C =20

1
ab
2
A =
S a =7
S b =13
a b =6 .. (1)
a
2
+b
2
=400
C
b
A 7 D 13 B
a


10
(a b)
2
+2ab =400
ab =182

1
ab 91
2
A = =

14. Let

r xi yj zk = + +

Comparing x =t
2
+t 2 y =t +2 z =t
2
+6t +9
Hence z x =5t +11 z x =5(y 2) +11 x +5y z +1 =0

16. a b a b 8
(
=

2
a b 8 =

2
2
2
a b sin 8 u =

2
2
8
b 16
1
1
2
= =

b 4 =

17. If
2 2
2 2
x y
1
a b
+ = , a >b
So x
1
x
2
=y
1
y
2
=b
2

3d =49
3d 7 =

(x
1
y
1
)
(x
2
y
2
)
y
1
y
2

18. f'(x) =sec x cosec x
f'(x) =0 at x
4
t
=
Also f " 0
4
t | |
>
|
\ .
so f(x) is minimum at x
4
t
=

/ 4 / 2
0 / 4
f sec d cosec d
4
t t
t
t | |
= u u + u u
|
\ .
} }
=
2 1
ln
2 1
| |
+
|
\ .
=
( )
2ln 2 1 +

19.
( )
( )
a a
0 0
cos a x
ln cota tanx dx ln dx
sina cosx
| |
+ =
|
\ .
} }

=
( )
a a a
0 0 0
lncos a x dx lnsinadx lncosxdx
} } }

I(a) = ln (sin a) a
I(1) = ln (sin a) =ln |cosec 1|

20. Let
1/ x
x 1
x 0
1
A lim 2
2
| |
= +
|
\ .
(1

form)
=
x
x 1
x 0 x 0
1 1 2 1
lim 2 1 lim
x 2 2x
e e

| |
(
+ |
(
\ .
= =
1
ln2
2
e 2 =


11
21.
( ) ( )
( ) ( )
( ) ( )
n
1 n 2 n 1 1 1
U
n 1 n 2 n 1 n 2 n 1 n 2
+ +
= = =
+ + + + + +

n
n
n 1
1 1 1 1
S
n 1 n 2 2 n 2
=
| |
= =
|
\ + + . +

Hence
n
n
1
limS
2
=

22.
( )
100
z 1 i 3 = +
=
100
100
2 cos isin
3 3
t t (
+
(

=
100
100 100
2 cos isin
3 3
t t (
+
(

=
100
2 cos isin
3 3
t t (

(

=
100
1 3
2 i
2 2
(

(

( )
( )
1
Re z 1
2
Im z
3 3
2
= =

23. |wz 1 w
2
| =a
|z +1| =a
|a 1 +2| =a
|z 1| +2 > a
0 s a s 4

24. Since RHS is even. So LHS is also even integer so either both x and y should even or both
should odd integer. Now
x
4
y
4
=(x y)(x +y)(x
2
+y
2
)
(x y), (x +y), (x
2
+y
2
) must be an even integer
Therefore (x y)(x +y)(x
2
+y
2
) must be divisible by 8
But RHS is not divisible by 8
So given equation has no solution

25. Given numbers can be rearranged as
1, 4, 7 .. 3n 2 (3 2) type
2, 5, 8 .. 3n 1 (3 1) type
3, 6, 9 .. 3n 3 type
This means either both the numbers should from (3 type) or one number each from (3 2) type
and (3 1) type
So total number of ways
( )
2
n n n 2
2 1 1
n n 1 3n n
C C C n
2 2

+ = + =


12
26. (1 +x +x
2
+x
3
)
5
=a
0
+a
1
x +a
2
x
2
+a
3
x
3
+a
4
x
4
+.. +a
15
x
15

Put x =1 and x =1 and add

( )
5 15
0 1 2 3 4
15
0 1 2 3 4
5
0 2 4 14
4 a a a a a ..... a
0 a a a a a ..... a
_____________________________
4 2 a a a ............... a
= + + + + + +
= + +
= + + + +

a
0
+a
2
+a
4
+.. +a
14
=512

27. f'(x) =3x
2
+2ax +b
y =f(x) is increasing x e R
f'(x) > 0 x e R
So (2a)
2
4 3 b s 0
a
2
3b s 0
This is true for exactly 16 ordered pairs (a, b) 1 s a, b s 6
So required probability =
16 4
36 9
=

28.
( )
2 2 2 2 2 2
1/ 6
6 6 6
ab ac bc ba ca cb
a b c
6
+ + + + +
>
So a(b
2
+c
2
) +b(c
2
+a
2
) +c(a
2
+b
2
) > 6abc

29.
r r 1
1
r r 1
2 2
tan
1 2 2
| |
|
\ + .

=
( ) ( )
n
1 r 1 r 1
r 1
tan 2 tan 2

=
(

=tan
1
(2
n
) tan
1
(1)
=tan
1
(2
n
)
4
t

30.
( )
cotA cotC sin A C sinB
cotB sinA sinC cosB
+ +
=

=
2
sin B
sinA sinC cosB

=
2 2
2
4R b
4R accosB

=
2
b
accosB

=
2
2 2
2b 2
2001
2002b b
=

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AITS-CRT-III-PCM(S)-JEE(Mai n)/14

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