BAC2014 PC

)/2

. )1
( 11

X
X=0

xq

cv

cv-x
cv-xq

xq

xq

!" ! $% &' % (12

,( 22

:+

AH ( aq ) + HO ( aq ) A ( aq ) + H 2O( l )

(23
:./

1 2( 123

$0

A (aq) + H3O+

AH (aq) + H2O ( l )

= (H3O+) . [H3O+]q + (A) . [A (aq)]q

xq
[H3O+]q = [A (aq)]q =
:
V
xq
= [(H3O+) + (A)] .
V
.V
xq =
(H3O + ) + ( A )

xq =

7,18.10 2.100 .10 6

1,86.10 4 mol .
3
38,62.10
[H3O+]q =

pH = log H 3O +

xq

pH

(13

1,86.104
x
2,73
= log q = log
v
0,1
.

Qr,q

(14

[H O ] .[A ]
=
+

Qr ,q

cA

[AH ]q =

4(223

cv xq
v

([H O ] )
=
c [H O ]

C BVB , E = C A .VA C ' A =

C 'A =

C BVB , E

0,2 15
= 0,2mol .L1
15

VA

Qr,q

Q
+

2( 2, 73)

= 10 pH

'

[H O ] = [A ]

VB , E = 15 mL

[AH ]q

:
pH E = 8,2

= c H 3O +

102 pH
c 10 pH

10
=
103
5.103 102,73

:*

BAC2014 PC

$ %& *)( ' + -+ ./ 0 ( 233

!" #

1 02
( 9 7, + )
) 3 -5 2 = -> : 3 . ? : , 6
# 0
: BC

2 A + @ /Tolune)

2 7 E 9 F G

- #2 + H # . HIJ@; 5 ! *K

(dean stark )

] [ ]

[A ]

[A ]

[H O ] [AH ]
[A ] = Q .10

0 3+

J ,

[AH ]q

[AH ]q

Qr ,q

4 (234

pH 2,8
H 3O + Q . A

Qr ,q =

P %P )

[A ]

VB = 6 mL / 56 ! '7

[AH ]q

10 pH

[AH ]q

r ,q

pH

= 10 3.10 2,8 = 0,63

) /3
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5 4 5 !G 7 R S LM ;N! 4 O + P Q (1

O + X1 ( G S2 U V W :

Qr ,q

#2 $ S2 V W
Y #2

$ v=

(2

g.h

,( 23

v = 10.6.106 = 2453.m.s 1
P (-#

(3

= v.T = 245.18.60 = 2,645.10 = 264,5Km

h

= v.T =

5 Z 2!

nexp
ntheo

xq
xmax

3,85.10 2
= 0,077 = 7,7 0 0
0,5

4*5 2+ 6 7 8 9 : ;5 2
(4

v
v
f = = C ste =
f

2 7 [ # Z 2 R S

r=

( 7 > 9? "3@ )+ / 89! , 2:

: A! ,

I U 7

Z 2! O + X1 \7 ] I P Q v = g.h *#

'B C72

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! D E% 2: 6

& $ F B ! G;H 6 AI

BAC2014 PC
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E
) (1 e
R
%
# di E t % #+ -Y 2
=
e
dt R.
= ) i(t

t
t
E
L E E

(1 e ) +
=e
R
R R.
R

(5

H ' 8 _ ` (15 9 5

! 0 #7P d C2 P E

! % V&' F . d %M O +9

= 120Km

M d = 100Km ` _ H ' 8 9 a5[ ?+

(52 O + G H O + 2 2 H d c

6 I

1
E E
L.R
E
1
( e + 2 e = E.e
)
R R
R .
R
R. L
1
1
L
= = 0
R. L
R
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L
# = = 2.10 3 s $% %
R

6 6 ) O + F [ # P (-# .( e J
120
= 1,2rad
100

L
R
L = R. = 2.10 3.200
L = 0,4 H

/2 .

/1 .L

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/22 `uC/t
=r

(21

''& )i(t

U R (t ) + U L (t ) = E
) di (t
=E
dt
L di (t ) E
i (t ) + .
=
Ri (t ) + L.

/23

U C (t ) + U b (t ) = u G = ki (t ) k

) di (t
U C (t ) + ri (t ) + L.
) = ri (t
dt
) di (t
( R + r ) i ( t ) + L.
) = ri (t
dt
du
d 2uc
dq
di
=i
= c. c
=c
dt
dt
dt
dt 2
2
d uc
du
du
u c (t ) + Lc
+ r .c c = r c
dt
dt
dt 2
d 2uc
u c (t ) + Lc
=0
dt 2

BAC2014 PC
2
t
T0

/23.

uc (t ) = U 0 cos

: O [0;3s ] : N L

duc 2
2
=
U 0 sin
t
dt
T0
T0

t = 0

*$7 ? 2G ? 2

! 7 P

d 2uc 4 2
2
=
U cos
t
2
2
dt
T0
T0

.G

R 0 : Q!K 7%
.

4 2
2
2
t + LC
U 0 cos
2
T0
T0
T0

U 0 cos

2
4 2
t 1 LC.
= 0 T 2 0 = 4 2 LC
2
T0
T0

U 0 cos

dvG
= 4m.s 2
dt

= aG

h [3;4s] :f g 27 ] 52 7

T0 = 2 LC

" ;39 U k-5 %9

O : [0;3s] : N L

r r
r
r
= maG T + P = maG

* '#

i 9

j2

H / (12 H3 +

/24.

!K 7

! l

ext

)(O ; Z

T P = maG

) T = m(aG + g
T = 400(9,8 + 4) = 5,52.103 N
h [3;4s ] f g

@
T 2 0 = 4 2 LC

T 20
4.10 3
=C
=
1.58.10 6 = 1.58F
4 2 .L 40 0.4

T P = 0 T = mg = 400.9,8 = 3,92.103 N .

(21 F k H j - + #
= c = 0,5 x 20 = 1,58 x

# #7n

Kg.m-1
'B (11

?K D3 L

25 7 4

] [ f ] = [k ].[v
[ f ] = [m][. a] = [M ][L][. T ]2 .
[v]2 = [L]2 .[T ]2
2
[K ] = [ f 2] = [M ][2L][. T2] = [M ][. L]1
] [v] [L] .[T

M K H F j - + #
?2

ext

/2

#% :

c + 20
= 43,16 0 0
0,5

r
r r r
=0T +P =0

: ' 4

BAC2014 PC
1 2
EC = m x ; EP = E pp + EPe : S9 0 (1
2

G 2K 7 27 ] EPP X1 qE2 U (

G N gi

P Q

Ci G

G + r 2 +

$ EPP = 0 X1 #O

v o ` p -Y 2 #+ 4 3]M(22

r r
r
r
= ms aG f + P = maG
r
r
dv r
kv 2 j + ms g . j = ms . j
dt
dv k 2 k
2,7
g=
v ;
+
=
= 9.10 2 u.i
dt ms
ms 20
r

ext

2
ste
qs t 0 p 9G K 7 EP = EPe = 2 Kx + C

: %P cste = 0 $ Epp=0 u

x=0 O
EP = EPe =

'S
1 2
Kx
2

g = 9,8m.s 2 9,8 =

dv
+ 9.10 2 v 2
dt

9,8 =

dv
+ 9.102 v 2
dt

9 5

`(23

v0 = 0 0! t =0 5 : e C + k-5 " #2
EPe (0) 0 P %P x/0` = x0

7 EC/0` =0 P %P

5 LM (

; N

vlim

dv
=0
() j F
dt

9,8 = 9.10 2 vlim

vlim =

1 Em

0 , 3

R/ T ! O( 2

Em = 2z10{3 J : $0 5 " U
: S9 0 (3
Em = EPe (max) =

9,8
= 10,4m.s 1
2
9.10

1
2
Kx0
2

2 Em
2.2.10 3
=
= 2.10 2 m
K
10
r
1
2
WAaO ( F ) = EPe = ( x 2 A xO ) = EPe ( x0 )
2
(4
r
3
WAaO ( F ) = Em = 2.10 J
x0 =

: V3 , W! D% J , C D% : R2A "
h~elghzizal@hotmailzcom

-Y 2 #+

:q P
ai =

(24

v vi+1 vi
=
vi+1 = vi + ai .t
t
t

dv
= 9,8 9.10 2 v 2
dt
: 95
2 2
ai = 9,8 9.10 .v i

v2 = v1 + a1.t
a1 = 9,8 9.102.v 21
a1 = 9,8 9.102.(2,75) 2 = 9,12m.s 2
v2 = 2,75 + 9,12.2,4.102 2,97m.s 1

.
(1