Exerccio 10: Otimizao

12

FS P LIT2

11

FL AS H

10

MIX E R1
1

4
6

DES T

HEA T
REA CTOR

FS P LIT1

13

Antes da otimizao:
Heat and Material Balance Table
Stream ID

10

11

12

13

RE ACT OR

FLASH

FLASH

FSPLIT1

DE ST

DE ST

FSPLIT2

FSPLIT2

FSPLIT1

To

MIXER1

MIXER1

HE AT

RE ACT OR

FLASH

FSPLIT1

FSPLIT2

DE ST

MIXER1

MIXER1

Phase

VAPOR

LIQUID

MIXED

VAPOR

VAPOR

LIQUID

VAPOR

LIQUID

VAPOR

LIQUID

From

MIXER1

HE AT

LIQUID

VAPOR

VAPOR

Substream: MIXED
Mole Flow

kmol/hr

HYDRO-01

321. 7500

0.0

1036. 511

1036. 511

777. 5960

1. 007701

776. 5883

. 7053906 1. 46873E-4

. 7052437

62. 12706

714. 4612

. 3023103

NIT RO-01

1. 650000

0.0

20. 07021

20. 07021

20. 07021

. 0714360

19. 99878

. 0500052 6. 20374E-4

. 0493848

1. 599902

18. 39887

. 0214308

MET HA-01

6. 600000

0.0

76. 54035

76. 54035

76. 54035

. 7683576

75. 77199

. 5378503

. 2705922

. 2672581

6. 061759

69. 71023

. 2305073

BENZ E-01

0.0

100. 0000

107. 8813

107. 8813

21. 57625

19. 30459

2. 271663

13. 51321

13. 51321

2. 4765E-46

. 1817330

2. 089930

5. 791377

CYCL O-01

0.0

0.0

49. 04604

49. 04604

135. 3510

121. 7363

13. 61472

85. 21543

85. 21543

1. 5446E-46

1. 089177

12. 52554

36. 52090

Mole Frac
HYDRO-01

. 9750000

0.0

. 8034665

. 8034665

. 7541174 7. 05236E-3

. 8742947 7. 05236E-3 1. 48357E-6

. 6901388

. 8742947

. 8742947 7. 05236E-3

5. 00000E-3

0.0

. 0155577

. 0155577

. 0194642 4. 99943E-4

. 0225149 4. 99943E-4 6. 26641E-6

. 0483271

. 0225149

. 0225149 4. 99943E-4

MET HA-01

. 0200000

0.0

. 0593313

. 0593313

. 0742293 5. 37733E-3

. 0853052 5. 37733E-3 2. 73325E-3

. 2615340

. 0853052

. 0853052 5. 37733E-3

BENZ E-01

0.0

1. 000000

. 0836257

. 0836257

. 0209247

. 1351025 2. 55747E-3

. 1351025

. 1364971

2. 4235E-46 2. 55747E-3 2. 55747E-3

. 1351025

CYCL O-01

0.0

0.0

. 0380187

. 0380187

. 1312643

. 8519678

. 0153276

. 8519678

. 8607619

1. 5115E-46

. 0153276

. 0153276

. 8519678

NIT RO-01

Total Flow

kmol/hr

330. 0000

100. 0000

1290. 049

1290. 049

1031. 134

142. 8884

888. 2455

100. 0219

99. 00000

1. 021887

71. 05964

817. 1858

42. 86652

Total Flow

kg/hr

800. 7138

7811. 364

16434. 41

16434. 41

16434. 41

11769. 80

4664. 616

8238. 857

8231. 764

7. 092687

373. 1693

4291. 447

3530. 939

Total Flow

l/min

5917. 352

151. 9238 4. 73648E+5

33168. 78

27625. 46

259. 7613

18722. 46

181. 8329

236. 1503

11. 65556

1497. 797

17224. 67

77. 92838

Temperature

323. 1500

313. 1500

282. 8427

423. 1500

423. 1500

323. 1500

323. 1500

323. 1500

475. 3891

128. 6896

323. 1500

323. 1500

323. 1500

Pressure

atm

25. 00000

. 9869233

. 9869233

22. 69924

21. 71231

21. 21885

21. 21885

21. 21885

14. 80385

14. 80385

21. 21885

21. 21885

21. 21885

1. 000000

0.0

. 9361878

1. 000000

1. 000000

0.0

1. 000000

0.0

0.0

1. 000000

1. 000000

1. 000000

0.0

0.0

1. 000000

. 0638121

0.0

0.0

1. 000000

0.0

1. 000000

1. 000000

0.0

0.0

0.0

1. 000000

Vapor Frac
Liquid Frac
Solid Frac

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

Enthalpy

cal/mol

-175. 6519

12234. 41

-1169. 617

652. 1307

-3455. 201

-29350. 40

-1732. 891

-29350. 40

-22597. 81

-5898. 694

-1732. 891

-1732. 891

-29350. 40

Enthalpy

cal/gm

-72. 39179

156. 6232

-91. 81119

51. 19018

-216. 7875

-356. 3216

-329. 9806

-356. 3216

-271. 7745

-849. 8609

-329. 9806

-329. 9806

-356. 3216

Enthalpy

cal/sec

-16101. 42 3. 39845E+5 -4.1913E +5 2. 33689E+5 -9.8966E +5 -1.1650E +6 -4.2756E +5 -8.1547E +5 -6.2144E +5

-1674. 388

-34205. 18 -3.9336E +5 -3.4949E +5

Entropy

cal/mol-K

-5. 968814

-58. 68063

-9. 737959

-10. 47231

-19. 32699

-129. 5053

-8. 157159

-129. 5053

-113. 1974

-15. 07195

-8. 157159

-8. 157159

-129. 5053

Entropy

cal/gm-K

-2. 459941

-. 7512212

-. 7643987

-. 8220430

-1. 212621

-1. 572228

-1. 553302

-1. 572228

-1. 361378

-2. 171507

-1. 553302

-1. 553302

-1. 572228

Density

mol/cc

9. 29470E-4

. 0109704 4. 53941E-5 6. 48224E-4 6. 22092E-4 9. 16793E-3 7. 90713E-4 9. 16793E-3 6. 98708E-3

Density

gm/cc

2. 25527E-3

Average MW
Liq Vol 60F

l/min

1. 46123E-3 7. 90713E-4 7. 90713E-4 9. 16793E-3

. 8569388 5. 78292E-4 8. 25797E-3 9. 91502E-3

. 7551675 4. 15242E-3

. 7551675

. 5809694

. 0101420 4. 15242E-3 4. 15242E-3

. 7551675

2. 426406

78. 11364

12. 73937

12. 73937

15. 93819

82. 37054

5. 251494

82. 37054

83. 14914

6. 940776

5. 251494

5. 251494

82. 37054

294. 5679

147. 5152

1258. 627

1258. 627

1055. 097

248. 6167

806. 4804

174. 0317

173. 1195

. 9121667

64. 51843

741. 9620

74. 58500

Aps a otimizao:
Heat and Material Balance Table
Stream ID

From

10

11

12

13

MIXER1

HE AT

RE ACT OR

FLASH

FLASH

FSPLIT1

DE ST

DE ST

FSPLIT2

FSPLIT2

FSPLIT1

MIXER1

MIXER1

VAPOR

LIQUID

To

MIXER1

MIXER1

HE AT

RE ACT OR

FLASH

FSPLIT1

FSPLIT2

DE ST

Phase

VAPOR

LIQUID

MIXED

MIXED

MIXED

LIQUID

VAPOR

LIQUID

LIQUID

VAPOR

VAPOR

Substream: MIXED
Mole Flow

kmol/hr

HYDRO-01

321. 7500

0.0

653. 2242

653. 2242

360. 6259

6. 599011

354. 0269

. 6689362 4. 51028E-7

. 6689357

28. 48216

325. 5447

5. 930075

NIT RO-01

1. 650000

0.0

20. 24617

20. 24617

20. 24617

1. 011414

19. 23476

. 1025262 8. 18463E-7

. 1025254

1. 547474

17. 68728

. 9088879

MET HA-01

6. 600000

0.0

79. 46576

79. 46576

79. 46576

9. 890449

69. 57531

1. 002587 9. 29016E-5

1. 002494

5. 597471

63. 97784

8. 887862

BENZ E-01

0.0

100. 0000

121. 9160

121. 9160

24. 38320

24. 16836

. 2148364

2. 449926

2. 436126

. 0138002

. 0172840

. 1975524

21. 71843

CYCL O-01

0.0

0.0

866. 2657

866. 2657

963. 7985

955. 7898

8. 008667

96. 88761

96. 56378

. 3238333

. 6443130

7. 364354

858. 9022

. 9750000

0.0

. 3751752

. 3751752

. 2489617 6. 61582E-3

. 7848768 6. 61582E-3 4. 55584E-9

. 3167927

. 7848768

. 7848768 6. 61582E-3

Mole Frac
HYDRO-01
NIT RO-01

5. 00000E-3

0.0

. 0116282

. 0116282

. 0139771 1. 01399E-3

. 0426434 1. 01399E-3 8. 26730E-9

. 0485536

. 0426434

. 0426434 1. 01399E-3

MET HA-01

. 0200000

0.0

. 0456406

. 0456406

. 0548599 9. 91564E-3

. 1542483 9. 91564E-3 9. 38400E-7

. 4747581

. 1542483

. 1542483 9. 91564E-3

BENZ E-01

0.0

1. 000000

. 0700216

. 0700216

. 0168331

. 0242299 4. 76292E-4

. 0242299

. 0246073 6. 53548E-3 4. 76292E-4 4. 76292E-4

. 0242299

CYCL O-01

0.0

0.0

. 4975342

. 4975342

. 6653680

. 9582246

. 0177552

. 9582246

. 9753917

. 1533601

. 0177552

. 0177552

. 9582246

Total Flow

kmol/hr

330. 0000

100. 0000

1741. 118

1741. 118

1448. 519

997. 4591

451. 0604

101. 1116

99. 00000

2. 111588

36. 28870

414. 7717

896. 3475

Total Flow

kg/hr

800. 7138

7811. 364

85588. 17

85588. 17

85588. 17

82528. 68

3059. 489

8365. 863

8317. 227

48. 63557

246. 1419

2813. 347

74162. 82

Total Flow

l/min

5917. 352

151. 9238 3. 66884E+5

27061. 44

17997. 53

1846. 899

9498. 384

187. 2186

244. 7233

73. 32583

764. 1637

8734. 220

1659. 680

Temperature

323. 1500

313. 1500

300. 5188

423. 1500

423. 1500

323. 1500

323. 1500

323. 1500

480. 3052

381. 3437

323. 1500

323. 1500

323. 1500

Pressure

atm

25. 00000

. 9869233

. 9869233

22. 69924

21. 71231

21. 21885

21. 21885

21. 21885

14. 80385

14. 80385

21. 21885

21. 21885

21. 21885

1. 000000

0.0

. 5041611

. 5831909

. 4279957

0.0

1. 000000

0.0

0.0

1. 000000

1. 000000

1. 000000

0.0

0.0

1. 000000

. 4958389

. 4168091

. 5720043

1. 000000

0.0

1. 000000

1. 000000

0.0

0.0

0.0

1. 000000

Vapor Frac
Liquid Frac
Solid Frac

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

Enthalpy

cal/mol

-175. 6519

12234. 41

-17925. 53

-14213. 17

-20937. 57

-34698. 13

-3072. 722

-34698. 13

-27679. 43

-11938. 85

-3072. 722

-3072. 722

-34698. 13

Enthalpy

cal/gm

-72. 39179

156. 6232

-364. 6586

-289. 1382

-354. 3535

-419. 3689

-453. 0114

-419. 3689

-329. 4683

-518. 3438

-453. 0114

-453. 0114

-419. 3689

Enthalpy

cal/sec

-16101. 42 3. 39845E+5 -8.6696E +6 -6.8741E +6 -8.4246E +6 -9.6139E +6 -3.8500E +5 -9.7455E +5 -7.6118E +5

-7002. 763

-30973. 64 -3.5402E +5 -8.6393E +6

Entropy

cal/mol-K

-5. 968814

-58. 68063

-74. 98275

-68. 10230

-88. 25471

-139. 0364

-9. 316640

-139. 0364

-122. 7212

-28. 75377

-9. 316640

-9. 316640

-139. 0364

Entropy

cal/gm-K

-2. 459941

-. 7512212

-1. 525372

-1. 385403

-1. 493649

-1. 680423

-1. 373552

-1. 680423

-1. 460751

-1. 248389

-1. 373552

-1. 373552

-1. 680423

Density

mol/cc

9. 29470E-4

. 0109704 7. 90948E-5

Density

gm/cc

2. 25527E-3

Average MW
Liq Vol 60F

l/min

1. 07232E-3 1. 34141E-3 9. 00121E-3 7. 91469E-4 9. 00121E-3 6. 74231E-3 4. 79956E-4 7. 91469E-4 7. 91469E-4 9. 00121E-3

. 8569388 3. 88807E-3

. 0527122

. 0792591

. 7447500 5. 36844E-3

. 7447500

. 5664376

. 0110546 5. 36844E-3 5. 36844E-3

. 7447500

2. 426406

78. 11364

49. 15702

49. 15702

59. 08665

82. 73891

6. 782882

82. 73891

84. 01240

23. 03269

6. 782882

6. 782882

82. 73891

294. 5679

147. 5152

2406. 697

2406. 697

2176. 690

1766. 709

409. 9803

179. 0899

176. 9048

2. 185053

32. 98372

376. 9965

1587. 620

Aps a otimizao a vazo molar de ciclohexano na corrente de fundo do destilador aumentou

de 85.2 kmol/hr para 96.6 kmol/hr e a frao molar aumentou de 0.861 para 0.975.