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What Is Equilibrium?
Consider
When
What Is Equilibrium?
As
Equilibrium
Eventually
Equilibrium
The
N2O4(g)
2NO2(g)
Equilibrium
The
Equilibrium
Catalysts
Equilibrium
products
K
coefficients
reactants
coefficients
Equilibrium
Equilibrium
Equilibrium
For
example
A
K 2
C [ D ]
3
K = [NH3]2
[H2]3
[N2]
K =
[CO2]
[CO]
K =
[ O ]3
2
[ O3 ]
2
[NH4+]
K = [OH-]
[NH3]
1
[H2]2 [O2]
Le Chteliers Principle
Regaining Equilibrium
Le Chteliers Principle
If
Changing Concentration
Adding
Changing Concentration
1) Consider the reaction
X + Y A + B
If the concentration of X is increased,
the reaction will shift to the _____.
right
Changing Concentration
2) Consider the reaction
X + Y A + B
If the concentration of Y is decreased,
the reaction will shift to the _____.
left
Changing Concentration
3) Consider the reaction
X + Y A + B
If the concentration of A is increased,
the reaction will shift to the _____.
left
Changing Concentration
4) Consider the reaction
X + Y A + B
If the concentration of B is decreased,
the reaction will shift to the _____.
right
Changing Temperature
Reactions
Changing Temperature
Adding
Changing Temperature
5) Consider the reaction
2 SO2 + O2 2 SO3 + heat
If the temperature is decreased, the
reaction will shift to the _____.
right
Changing Temperature
6) Consider the reaction
N2 + O2 + heat 2 NO
If the temperature is decreased, the
reaction will shift to the _____.
left
Changing Temperature
7) Consider the reaction
2 SO2 + O2 2 SO3
H is negative
If the temperature is increased, the
reaction will shift to the _____.
left
Changing Temperature
8) Consider the reaction
N2 + O2 2 NO
H is positive
If the temperature is increased, the
reaction will shift to the _____.
right
Changes in Pressure
An
Changing Pressure
9) Consider the reaction
N2O4(g)
2NO2(g)
If
Changing Pressure
10) Consider the reaction
2H2(g) + O2(g) 2 H2O(g)
If
Changing Pressure
11) Consider the reaction
CO2 (g) + H2 (g) + heat CO (g) + H2O (g)
If
Adding a Catalyst
If
H = 92.4 kJ
How can the yield of NH3 be increased by
manipulating the following?
a) (add or remove) more N2
b) (increase or decrease) the pressure
c) (increase or decrease) the temperature
Calculating Equilibrium
If
Calculating Equilibrium
K,
Calculating Equilibrium
13) H2(g) + I2(g) 2HI (g) H = 10.4 kJ
If
Shifting
Entropy
Entropy
of a
solid
A solid
Entropy
of a
liquid
Entropy
of a
gas
Problem
14a) Which side of the reaction has
greater entropy?
(left)
Problem
b) Which side of the reaction has greater
entropy?
(right)
Problem
15a) Predict the change in entropy (increase
or decrease).
(increase)
Problem
15b) Predict the change in entropy (increase
or decrease).