‫ﻳﻮﻡ‪ 26‬ﺃﺑﺮﻳﻞ ‪ 2008‬ﺑﺎﻟﺜﺎﻧﻮﻳﺔ ﺍﻟﺘﺎﻫﻴﻠﻴﺔﻋﺒﺪ ﺍﷲ ﺍﻟﺸﻔﺸﺎﻭﻧﻲ‬ ‫ﺑﺴﻢ ﺍﷲ ﺍﻟﺮﺣﻤﺎﻥ ﺍﻟﺮﺣﻴﻢ‬

‫ﻭﺍﻟﺜﺎﻧﻮﻳﺔ ﺍﻟﻔﻼﺣﻴﺔ ﺑﺄﻭﻻﺩ ﺗﺎﻳﻤﺔ‪.‬‬

‫ﺍﻟﺰﺭﺍﻋﻴﺔ‪.‬‬
‫ﺷﻌﺒﺔ ﺍﻟﻌﻠﻮﻡ ﺍﻟﺘﺠﺮﻳﺒﻴﺔ ﻣﺴﻠﻚ ﺍﻟﺤﻴﺎﺓ ﻭﺍﻷﺭﺽ ﻭﺍﻟﻌﻠﻮﻡ ﺍﻟﺰﺭﺍﻋﻴﺔ‪.‬‬
‫ﺷﻌﺒﺔ‬ ‫ﻓﺮﺽ ﺭﻗﻢ ‪ 2‬ﺍﻟﺪﻭﺭﺓ ﺍﻟﺜﺎﻧﻴﺔ‬
‫ﻣﻮﺿﻮﻉ ﺍﻟﻔﻴﺰﻳﺎﺀ‪:1‬‬
‫‪ +(#  &'( "
# (1‬ا*
) ‪"# ، C1 = C 2‬آ   ا ا      
 ‪. C‬‬
‫‪ /‬ا‪"'34-1- .‬ات ‪ )1‬ا ا  ‪ )56-‬ا ‪. ',-" &'- U"4‬‬

‫‪ &.# (3‬ا ا  ا*‪- ?-‬ا‪ ,-" # :; . E = 6V " * "44 ),‬ه‪8‬ا ا ‪ )
'1-‬ا*‪.)7-‬ا ا=<‬
‫ 'ر ا"‪  C-‬ا‪6‬ارة   ا‪ .‬أ(‪.‬‬
‫‪1‬‬
 (‫ن‬1). q ‫) ا‬1 774  ‫') ا‬H( ‫ ا
د) ا‬G ;‫ (أ‬1-3
(‫ ن‬1). .)'H( ‫ 
د) ا‬I q (t ) = q m cos(ω 0 .t + ϕ ) ‫? & أن‬74 (2-3
(‫ن‬0,75)  'J <*I‫ وا‬C ‫ و‬L )56- ω o "'
4 L‫( ا‬3- 3
(‫ ن‬1). . 'J <*I‫ ا‬:;. LC )-8-8 ‫ارة ا‬6 TO ‫ص‬P‫ور ا‬6‫
'" ا‬4 N  ‫( ا‬4-3
‫ ن‬0, 5 ‫؟‬S8‫* آ‬4 ‫ ادارة؟ ذا‬U8‫* ه‬4 :- (5-3
(‫ ن‬1) . ϕ ‫ و‬q m ‫د‬6I (6-3
(‫ن‬0,75 ) .‫ ا‬,-" &'-) u c (t ) "4 ‫
'" ا‬4 N  ‫( ا‬7-3

:‫ﺍﻟﻜﻴﻤﻴﺎﺀ‬
2− 2−
S 4 O6 ‫ ت‬/" ‫ ;' آ‬-‫ت ر‬#/‫ وأ‬Sn 2+ "/67‫ت ا‬#/‫ أ‬,
 S 2 O3 ‫ ت‬/" ‫ت ا' آ‬#/‫ أ‬W Sn 4+ "/67‫ت ا‬#/‫ ( أ‬4

:)' ‫و ? ا

د) ا‬
4+ 2− 2+ 2−
Sn + 2 S 2 O3 Sn + S 4 O6
( aq ) ( aq ) ( aq ) ( aq )

:‫ ا ازن ه‬6 )'C''‫اع ا‬#[‫ ا‬U8‫"اآ'\ ه‬4

[Sn ]
4+
éq
−2
= 10 mol / L ،
2−
[ ]
S 2 O3 éq = 0,10mol / L
[Sn ]
2+
éq = 0,1mol / L ، [S O ] 4 6
2−
éq
= 0,11mol / L
(‫ن‬1) .( ‫) 
د) ا‬7 ‫ اا‬K ‫ ) ا ازن‬-; <*I‫( ا‬1-1
2− 2+
‫ و‬S 2 O3 ‫ت‬#/‫ & ا‬n3 = 2,1m.mol ‫ و‬Sn ‫ت‬#/‫ & أ‬n2 = 2m.mol ‫ و‬Sn 4+ ‫ت‬#/‫ & أ‬n1 = 1,2m.mol 
*# (2-1
2−
. V = 200mL ]I C ‫  _'" ل‬S 4 O6 ‫ت‬#/‫ & أ‬n4 = 1m.mol
(‫ن‬1) .)]‫ر ا‬,4  ‫د‬6I :; ( ‫رج ا‬a <*I‫أ( ا‬
(‫ ن‬2). x ‫م‬67 ‫) ا‬56- ( ‫رج ا‬a N  ‫ وا‬، (  (d‫م ا‬67 ‫ول ا‬6= ‫ء‬.#‫ب( أ‬
‫ن‬1). xéq = 0,087 m.mol :‫ ا ازن ه‬6 ‫م‬67 ‫') ا‬J ‫'& ان‬- (‫ج‬
، n3 = 0,21m.mol ، n2 = 2m.mol : & ‫ ن‬/ V = 200mL ]I C6- L'a )I  C7 ‫ر ا‬, ‫د  ا‬6I(3-1
(‫ن‬2). n1 = 1,2m.mol ، n4 = 10m.mol
f‫ا  'ــــــــــــــــــــــــــــــــــــــــ‬
:‫ء‬/\'(‫ا‬

∆q 25.10 −5 − 0
c= = = 16.10 −6 F = 16 µF ( 1-1 (1
∆t 15 − 0
------------------------------------------------------------------------------------------------
1 1 1 1 1 2
.)
*‫ ا‬h'(P4 <'‫ا ا "آ‬8‫ة & ه‬6C(‫ ا‬c1 = 2c = 32µF ⇐ = + = + = ( 2-.1-
c c1 c 2 c1 c1 c1
------------------------------------------------------------------------------------------------
c1
q = c.u = .u = 1,92.10 − 4 C ( 3-1
2
------------------------------------------------------------------------------------------------
− u BM − (−20)
R= = = 100Ω ⇐ u BM = − R.I : ‫ن أوم‬#J <*I (1-2(2
I 0,2
------------------------------------------------------------------------------------------------
i (t ) = 10t − 0,05 : [0,10ms] : ‫  ا]ل‬ ( 2- 2

2
 i (t ) = 0,05 A : [10,20ms ] : ‫  ا]ل‬
i (t ) = −5t + 0,15 [20,40ms]: ‫  ا]ل‬
------------------------------------------------------------------------------------------------
u AM di di
L= ⇐ u AM = L ⇐ r = 0 ‫ أن‬-‫ و‬u AM = ri + L :)
'1‫ ا‬,-" &'- "4 ‫( ا‬3-2
di dt dt
dt
= −5 ⇐ i (t ) = −5t + 0,15 [20,40ms ] : ‫  ا]ل‬
di
u AM = −0,35V : ‫ ا]ل‬+(#  &/6‫و‬
dt
− 0,35
L= = 0,07 H = 70mH : -‫و‬
−5
-----------------------------------------------------------------------------------------------
d 2q 1
2
+ q=0 ( 1-3(3
dt LC
------------------------------------------------------------------------------------------------
. )'H( ‫
ض  ا
د) ا‬# :; qɺ & j # (2-3
-----------------------------------------------------------------------------------------------

1 1
ω0 = = = 945rad / s ( 3-3
LC 0,07.16.10 − 6
2.π
TO = = 2π LC = 6,65.10 −3 s = 6,65ms ( 4-3
ωO
-----------------------------------------------------------------------------------------------
. ' /"]4 7'74 <
/  ‫ء‬1 ‫ا‬8‫) وه‬6
 )
'1‫) ا‬7 ‫[ن‬. )'‫ارة ا‬6‫( ا‬5-3
-----------------------------------------------------------------------------------------------
q m = c.u m = c.E = 16.10 −6.6 = 96.10 −6 C : ‫و‬ ϕ =0 ( 6- 3
-----------------------------------------------------------------------------------------------
u (t ) = 6 cos 945t ⇐ q = 96.10 −6 cos 945t (7-3
-------------------------------------------------------------------------------------------

:‫ا''ء‬
:‫ ) ا ازن‬-; (1-1
2−
[ S 4 O6 ]eq × [ Sn 2+ ]eq
k= 2−
= 110
[ S 2 O3 ] 2 eq × [ Sn 4+ ]eq
------------------------------------------------------------------------------------------------
-(‫(أ‬2-1
−3 −3
2.10 10
2− 2+
[ S 4 O6 ] × [ Sn ] 0,2 0,2
Qr , i = 2− 2
= −3
× = 75,58
4+
[ S 2 O3 ] × [ Sn ] 1,2.10 2,1.10 −3 2
( )
0,2 0,2

Qr< k
"1 ‫ر  ا ا‬,  )]‫ا‬
-------------------------------------------------------------------------------------------
3
 –‫ب‬

: / ‫م ه آ‬67 ‫ول ا‬6=

( ‫
د) ا‬

m.mol ‫آ'ت ادة‬ ‫م‬67 ‫ا‬ )‫ا‬

n1 = 1,2 n3 = 0,21 n2 = 2 n4 = 10 0
)'C6 ‫ا‬
1,2 − x f 0,21 − 2 x f 2+ xf 10 + x f xf
)'C‫ا‬
m.l :‫ ب‬:]‫) ا
'" & ا‬,/"1 m.mol :‫
" & آ'ت ادة ب‬#
2−
[ S O ] × [ Sn 2+ ] (2 + x)(1 + x)
Qr ,i = 4 62− 2 = ×V
[ S 2 O3 ] × [ Sn ] (1,2 − x).(2,1 − 2 x)
4+

)‫ر=) ا‬6‫    

د) & ا‬، )/6] "'l )7/"m) x f = 0,087 m.mol  ‫ ا
د) ل‬I ‫ول‬4 5 ?7  (‫ج‬
.(‫ إ ا‬d 4 &‫و‬
. K = #‫? & آ‬7  Qr "'
4  ‫م‬67 ‫') ا‬J ‫
ض‬# :;
(2 + 0,087) × (1 + 0,087)
Qr = × 200 = 109,89 ≈ 110. = K
(1,2 − 0,087) × (2,1 − 0,174) 2
. x f = 0,087 m.mol : ‫ ا ازن‬6 ‫م‬67 ‫') ا‬J ‫إذن‬
------------------------------------------------------------------------------------------------
n4 n2
2−
[ S 4 O6 ] × [ Sn 2+ ] 2 × 10 × 200
Qr , i = 2− 2
= V × V = ≈ 75,6 × 10 3 > K (3-1
[ S 2 O3 ] × [ Sn ] n1 ( n3 ) 2 1,2 × (0,21)
4+ 2

V V
."1 ‫'" ا‬l ‫ر ا])  ا‬, 4

SBIRO ABDELKRIM E-MAIL sbiabdou@yahoo.fr msn : sbiabdou@hotmail.fr

G#‫رودا‬4 ) )-'# )/4 ‫د‬5‫و‬q- #‫و‬.(.‫ ا‬r‫ ا‬6  )''‫ه‬q ‫) ا‬/#‫') وا‬Ip(‫) ا‬/#- ‫ء‬/\'(‫  '"و ا ذ دة ا‬:/"‫ا‬6