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Q 2.
Q 3.
Out of AlCl3 and NaCl, which is more effective in causing coagulation of a negative sol and why ?
Q 4.
Write the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd
of tetrahedral voids.
Q 5.
Q 6.
Why do transition elements show variable states ? How is the variability in oxidation states of d-block
different from that of the p-block elements ?
Q 7.
(i)
(ii)
Q 8.
Calculate the time to deposit 1.5 g of silver at cathode when a current of 1.5A was passed through the
solution of AgNO3. (Molar mass of Ag = 108 g mol1, 1 F = 96500 C mol1)
Q 9.
(ii)
? CH COCl
CH3 COOH
3
OR
Arrange the following compounds in increasing order of their property as indicated :
(i)
(ii)
PAGE # 1
Q 10.
Q 11.
Q 12.
(i)
(ii)
Why are aquatic species more comfortable in cold water than in warm water ?
What happens when we place the blood cell in saline water solution (hypertonic solution) ? Given
reason.
(i) Name the method used for the refining of titanium.
(ii) What is the role of Zn in the extraction of silver ?
(iii) Reduction of metal oxide to metal becomes easier if the metal obtained is in liquid state. Why ?
(i)
E0 value for the Mn3+/Mn2+ couple is positive (+ 1.5 V) whereas that of Cr3+/Cr2+ is negative
2 MnO 4 16 H 5C2O 24
Q 13.
(i)
(ii)
On the basis of crystal field theory, write the electronic configuration for d4 ion if 0 < P.
(i)
CH3 C O
|
CH3
(ii)
C6H5CH2CH3
?
(b) H
conc. HNO 3 / H2 SO 4
COOH
(iii)
Q 15.
Q 16.
Q 17.
Write the names and structures of the monomers of the following polymers :
(i) Nylon-6,6
(ii) Bakelite
(iii) Polystyrene
(i) Which one of the following is a disaccharide :
starch, maltose, fructose, glucose
(ii) What is the difference between acidic amino acid and basic amino acid ?
(iii) Write the name of the linkage joining two nucleotides.
Vapour pressure of water at 20C is 17.5 mm Hg. Calculate the vapour pressure of water at 20C when
15 g of glucose (Molar mass = 180 g mol1) is dissolved in 150 g of water.
Q 18.
X+
X+
X+
X+
X+
X+
X+
X+
X+
th
th
Q 20.
Q 21.
Q 22.
Define adsorption with an example. Why is adsorption exothermic in nature ? Write the types of adsorption
based on the nature of forces between adsorbate and adsorbent.
Q 23.
Seeing the growing cases of diabets and depression among young children, Mr. Lugani, the principal of
one reputed school organized a seminor in which he invited parents and principals. They all resolved
this issue by strictly banning junk food in schools and introducing healthy snacks and drinks like soup,
lassi, milk, etc. in school canteens.
They also decided to make compulsory half an hour of daily physical activities for the students in the
morning assembly. After six months, Mr. Lugani conducted the health survey in most of the schools and
discovered a tremendous improvement in the health of the students.
After reading the above passage, answer the following questions :
(i)
What are the values (at least two) displayed by Mr. Lugani ?
(ii)
PAGE # 3
(iv)
Q 24.
Name the sweetening agent used in the preparation of sweets for a diabetic patient.
For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :
t/s
-1
(CH3COOCH31/mol L
(i)
(ii)
(a)
30
60
0.60
0. 30
0. 15
Show that it follows pseudo first order reaction, as the concentration of water remains constant.
Calculate the average rate of reaction between the time interval 30 to 60 seconds.
OR
For a reaction A + B P, the rate is given by
Rate = k [A]2[B]
Q 25.
(b)
(a)
(b)
(a)
(b)
(c)
(d)
(e)
OR
Which poisonous gas is evolved when white phosphorus is heated with conc. NaOH solution ?
Write tha chemical equation.
Write the formula of first noble gas compound prepared by N. Bartlett. What inspired N. Bartlett to
prepare this compound ?
Fluorine is a stronger oxidizing agent than chlorine. Why ?
Write one use of chlorine gas.
Complete the following equation :
CaF2 + H2SO4
th
th
PAGE # 4
Q 26.
(C7H7ON) A
Br2+KOH
C6H5NH2
NaNO2 + HCl
CHCl3 + NaOH
(a)
CuCN
H2O
E
D
OR
Write the structures of the main products when aniline reacts with the following reagents :
(i) Br2 water
(ii) HCl
(iii) (CH3CO)2O / pyridine
(b)
(c)
Give a simple chemical test to distinguish between the following pair of compounds :
(CH3)2 NH and (CH3)3N
PAGE # 5
Solution
CBSE 12th Board (Chemistry) Code No. A
Ans 1.
(I)
(ii)
Ans 2.
Ans 3.
Ans 4.
2
N:
3
= x2y3
Ans 5.
2, 2 - Dimethylpropan-1-ol
Ans 6.
Transition elements show variable oxidation states since in these elements there is a small energy
difference between 3d and 4s orbital therefore 3d and 4s both e participate in the bond formation hence
Ans 7.
th
th
PAGE # 6
Ag+ + e Ag(s)
108 gm Ag required =
1.5 gm Ag required =
Ans 8.
96500 C
96500
1. 5
108
= 1340.2 C
Q
i
1340 .2
t=
1.5
t=
t = 893.5 sec.
Ans 9.
(i)
Zn Hg / HCl
(ii)
PCl5
or
(i)
(ii)
aquatic species is more comfortable in cold water than in warm water it is due to the more dissolution
of O2 in cold water
(ii)
dissolution of gases is a exothermic procees means at low temperature gases more dissolve in
Water
2AgCN2 Zn ZnCN4
2Ag( s )
Mn 3
Mn 2
Couple is positive
Mn3+ Mn+2 due to stable half filled (d5) electronic configuration it has reduction tendency..
Cr 2 Cr 3 have oxidation tendency
(ii)
(iii)
PAGE # 7
(ii)
If 0 < P then
1
3
d4 t 2g e g
(iii) [ Fe (CN)6 ]3
hybridisation d2sp3
shape actahedral
H N NHCONH 2
CH3 C N NHCONH 2 H2O
CH3 C 0 2
|
|
CH
CH3
3
( a ) KMnO
(ii)
4
C 6H5 CH2 CH3
C 6H5 COOH
(b ) H
COOH
(iii)
hexamethylenediamine
, formalaldehyde
O
H
(iii) Polystyrene
(ii)
NO2
Bakelite
Mnoner Phenal
OH
COOH
Con
HNO3 + H2SO4
Monomer Styrene
CH=CH2
Maltose
acidic amino acid have COOH > NH2 group
where as basic amino acid have NH2 > COOH group
th
th
PAGE # 8
W A = 150 gm
W B = 15 gm
MA = 18 gmmol1
MB = 180 gm mol1
PA PS
PA
WB MA
MB WA
17 5 Ps
15 18
17 5
180 150
PS = 17 . 325 mm Hg
CH3
CH = CH2
CH3
+
H
H2 O
CH CH3
OH
O
Br
C C6H5
Br
(ii)
An. AlCl3
C6H5
(iii)
CH3
CH2
COCl
CH
CH3
CH3
CH = CH CH3
Br
Alc KOH
OR
(i)
acetone
C 2H5 Cl Na I
C 2H5 I NaCl
PAGE # 9
(ii)
dryether
2C 6H5 Cl 2Na C 6H5 C6H5 2NaCl
(iii)
P-nitrophenol
(ii)
due to resonance bond length of C O bond in phenol is shorter than that is methanol.
(ii)
CH3
|
CH3 3 C Br CH3O Na H3 C C NaBr CH3 OH
||
CH2
Since 3 alkyl halide gives more preference for elemination reaction as compared to substution reaction
Ans 21. G = 2.303 RT log KC
G = 2.303 8.314 298 log 1010
G = 57058.483 J/mol
= -5. 7104
G = nF E cell
G
nF
( 5.7 10 4 )
1 96500
E cell =
E Cell
E Cell 5 9 10 1 V
Ans 22. AdsorptionThe accumulation of molecular species at the surface rather than in the bulk of a solid
or liquid is called adsorption.
e.g. water molecules adsorbed by silicagel
* during the adsorption process there is a force of attraction between adsorbate and adsorbent
hence energy is released.
* Two types
(a) Physisorption
(b) Chemisorption.
th
th
10
PAGE # 10
2.303
a
log
t
ax
2.303
0.60
log
K1 =
30
0.30
.303
2
K1 =
log 2
30
K1 =
Case 2
2 303
a
log
t
ax
2 303
0 60
K2
log
60
0 15
2 303
K2
2 log 2
60
.
K2 = 2 303 log2
30
K2
R
t
0 15 0 30
=
60 30
0 15
=
30
1
=
200
average rate
= 5 10-3 sec
OR
(a)
(I)
11
PAGE # 11
(II)
(b)
Second order
N
2 303
log 0
t
N
K=
___________(1)
K=
2 303
log 2
K
23 1
2 303
K
2 log 2
t
t = 46.2 minute
Ans. 25 (a)
(i)
in NH4+ and NH3 nitrogen is SP3 hybridised but due to lPbP replusion bond angle in NH3 but
there is no lP in NH4+ hence its bond angle is 10928 but in NH3 it is 107
(ii)
(iii) due to higher oxidation state of Cl and high oxygen content in HClO4 it is more acidic then HOCl.
in HClO4
O.S of Cl = +7
in HClO
O.S of Cl = +1
th
th
12
PAGE # 12
(b)
O
(i)
S
O
HO
(ii)
OH
F
Xe
F
O
OR
(a)
(c)
due to low dissociation bond enthalpy and High hydration enthalpy F2 is a strong oxidising agent.
(d)
(e)
N2 Cl
CN
C NH2
(A)
N=C
(B)
(C)
(D)
COOH
(E)
13
PAGE # 13
OR
Br
NH2
(a)
(i)
3Br2
Br
H O
2
Br
NH3Cl
+
NH2
(ii)
NH2
HCl
NH2
NH
Py
(iii)
O
C CH3
CH3 CO 2 O
(b)
(c)
CH3 2 NH
C 6H5 SO 2 Cl CH3 2
C6H5
O
(CH3)3 N does not react with Hinsberg reagent
th
th
14
PAGE # 14