2013-cY ‘Test Paper Code : CY ‘Time: 3 Hours Maximum Marks 100 INSTRUCTIONS 1. This quesioncamansver okt tas $B tao gusto Pee ge tt aiepy ofthe gue anne bok hve econo conan al te qstns ‘Wits your Regtraton Nember, Name and ‘Moun fhe Tet Centre appepe ‘ace povided enh ip see >, Wael anwes toh ceive eos nly in te Anrwer Table for Objective ecstions, poised on Page No, 8. Do tat 4. Eat cbse gusto rd chk ive auton fa 4 ches fr i fer (A) (B) (©) and (D} Only ONE of SE te Grete a he fegnive ‘marking. fr wong answers ‘Sifetve questont. The Tolowing mari ef ete mtn sal ow Gy"For eck comets aren, you ll be to Renee). Me Fores reng arr, 900 i fede (Negative a ma (© Multiple nner 10 a quesion wi Metered sr wong aver (@) Foreac uratenpled question, you wil Seg fret pa wil be © Skedovriotetod nei 5. anchor the fil in the Bank ype and eevee avers ony toe ape proved afar eh queton There wil be fo egative marks fr fil in the Bank and evcpve ype questions. 6, Bo not writ ore tan ane answer fr the Same sn caze you tempt fl i titer ep genom han ey plwe ‘cancel the answer) Som nse wong Others, one ashe Spearng at il be evausted. 7. Al anew at betes Musblak! edie i ony. Ske pn, pelo a ‘tan ofr sau sould abe ed Alleah work shouldbe done in he space frowdel and sored out aly. 4, No supplementary sets wl be povided © the cansiter me 10.Chip br og tables side roe ear {hs an trone psn ay frm ae ROT alot Non Progammable elt elloned 11-The quetoneumanswer booklet most be Tet in teeta ta the vigor tote lain he examination hal. Bo at ‘move ay page om is Dokl A 2013-CY READ INSTRUCTIONS ON THE LEPT SIDE OF THIS PAGE CAREFULLY REOISTRATION NUMBER Namie [Rex Cenes Do not write your Registration Number Jor Name anywhere else inthis question-cum-ansyrer booklet. Fave read abide by them Te iasinicions aad shal] Signature of the Candidate [Wave verified the information Bled by he] ‘Candidate shove. ‘Signature ofthe Invgilatora2 Q3 a4 Qs (PORTANT NOTE FOR CANDIDATES ‘Questions 1-10 (objective questions) entry fan marks each, questions 1-20 (Gil in the blaake ‘qvestion) carry three marks each and questions 21-30 (descriptive questions) cary five marks cach, ‘The marking cheme forthe objective type question, is a ollons: (@) Forcach coeet nse, you wl be aware 2 (Two) mas, (6) Farcachowonganonr you il be avrded 0.5 (eqatve half) mar (©) Maple nse tos question wl be weeds a og answer. {@) Forenchuatempted qoeston, yo wl be yard (Zero) mk (G) News mar for abject st il be cred vero fea marks. “There is no negative markiog for Glin the blank questions. ‘Write the answers tothe objective questions inthe Answer Table or Obsctive Questions provided ‘onpage 3 onl. Objective Questions. “The most polar compound amnong the following is (A) SF ®) BF, © xr (D) S05 Which one of the folowing order of the carbonates is CORRECT for their decomposition temperature? (A) BiCO,>CaCO}>S1CO> MgCO;__(B)_BaCO4> S1C05> CaC0s> MgCOs (©) MgCOs>CaCO;>S1CO;> BaCO; (D)._ MgC0s> CaCO5> BaCOs> SrCOs ‘The CORRECT order of CO vibrational stetcing fequency in the following complexes is 1 (PFMo(CO)s I: (PCL)Mo(COs lt: {P(OMe)s};Mo(CO}, @ len @) must (© Uctem — @) m Ma (aq) + Za (a) + HO For the above reaction i the euilivim constant al 298K is represented by 10%, then the val of Kis qu {ven Th sin ota == 24-V and 2202 095 29) ane Q18 The rotational energy barier between the most stable an the least sable conformations of 2,3-dimethylbutane slong C2-C3 bond eal mot [Given: The energies (Keal mol") for H/CHy elipsing = 18, CHCH, eclipsing = 2.9 and CHYCH, gauche ~ 0.9) 7 . ; ane: QueA Descriptive questions, Q21 A mistere of CsHl and oxygen in IL closed vessel has sn internal pressure f 4 atm at 100°C. ‘When the mixture is ignited, the reaction produces COx(2) ard H0(g) uni ll the oxygen is ‘consumed. fier the reaction, pressure of the vessel is 42 atm atthe same temperature Calculate the weight of oxygen present before the reaction. [Gas constant, 082 L atm mol KC") Spice forthe sercvs usu ap jgQ22 The following eaction is catied outat 1 atm and 300 K. 2H (@)* 03) > 2H20 AU forthe sbove reaction is 550 KJ. Assuming ideal gus behavior for Hy and Op, calulate the value of AH, The value of gas constant, R= 0.082 L atm mol K" = 8.314 J mol K" [Givens The volume of! mol of liquid waters 18 mal. under the above reaction condition} Space forthe answer evsisur 95005A 23 At298K, calculate the solubility of metal sulfide, MS(, ina saturated solution of HS where the concentraion of HpS and pH are msintined at 0.1 M and 3.0, respectively. Given 21298 K, HES (9) + 1,0 () == 1,0" (09) + BS" (a) 07 MS (5) +140 () === M"* (ag) + HS"(ag) + “OH (aq) K=5 10°" cy.032us og nj eg evansA Q.24 For cach of the following metallo-prcins identify the mets-ion atthe acivesite and the fneton ofthe proteins: ‘eoxy-hemoglabin, deoxy-myoglobin, oxy-hemoeyanin, eytochrome-c and carbonic anhydrase, Sys for the never | | | cyana py 30s cyag a & ¢ A A solution containing 280 pom of CuSO, 51.0 (formula weight= 250) has an absorbance of ‘01 measured in 1 em cell at 600 nm. Calculate the molar absorptivity (6) of CuSO, S10 in LiM'em' When 25 mL of the above solution is tizated against NagEDTA (aq) solution, it ‘consumes 50 mL of NasEDTA. (aq) solution. Calculate the concentration of NagEDTA (aq) selution in molesTansee es cy-1s32A 0.26 Assume the complex [Ni(PPh)j(SCN),] is paramagnetic. The analogous complex of Pal) is fiamagnetic, Draw all the probable isomers for both the complexes considering SCN isan ambidentate ligand, space forthe nevervce 9 9865Q.27 Write the structures of Ato F inthe fllowing eaction sequence: Q we a Seg memes ie 1, KOH Eton Space forthe newer cvsnr p20) 365 cy982Q.28 Write the structures of F to Jin the fllowing reaction scheme ° PPhyHesSCl | LnBLiHOHO 5 _ Kou | ann bias ((1 equiv) Sle Guzn isobutane] Spe forthe sercyA 29 Propose a mechanism for the following reaction. Show stepwise coneet reactive pestis ; f + meno _ Nek. 80° ma —a t 4 Space forthe veras py 8g930 Complete the following reaction sequence and write structures of K 0 O, WK, A8uLi mcPBA LBW KG BULL | |— . Tere y 8 carbene i Hot Meow 40 ‘Spc forthe answercy.asis2 sas 29 085Space for rough work cy-26832‘Space for rough work cva7s2Space for rough work cya8i2Space for rough wark cysSpace for rough work cy-30n2 EdSpace for rough work‘Space for rough work evn