Solutions 1

1
FIITJEE
JEE(Main)-2016
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(Main)
ALL INDIA TEST SERIES
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AITS-FT-I-PCM (Sol)-JEE(Main)/16
S. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
1.
For an adiabatic process PV y k

Here y = 3/2 and k = constant
3
PV 2 k
3
log v logk
2
P 3 v
0
P 2 v
V 2 P
V
3 P
V
2 P
2 2 4
100
100

V
9
3 P
3 3
logP
volume decreases by about

2.
4
%
9
contact po int 0
N
mg ma
R mg sin 30o R ma cos 30 o
a
3.
ma
mg
30o
0 I0
2
mR f 2mg
5
& f = ma = mR
10
10
f
mg
mg N
7
7
10
2
mg 5mg ,
7
7
4.
for ideal gas (i) and (iii) are correct

= for same pressure and no. of mole
PV1 PV2
V
V
1 2 T1 T2
nT1 nT2
T1 T2
5.
Conservation of linear momentum.
P
R
600
a
f
mg
4mg
P
L/6
C
L/2
J
J MVf Vf
J
M
3
Conservation of angular momentum

about C
L ML2
6J
J
2 12
ML
1
1
2J2
KE Icm 2 MVf2
2
2
M
6.
7.
8.
9.
Initially increase in temperature increases the density and after T = 4o C increase in temperature
decreases the density
5V
Let is the length on potentiometer i
1A
5R
1.5 A 3 2m
p
2
2
p p0 cos
x 0 p0 cos 1
2

6m 60HZ
r
E
10.
11.
8 2
5 3 10
9 109 50 106 9
103 4500 V / m
100
2
Vsound V0 Vwind
f
f
Vsound Vsource Vwind
f f
Place another identical hemisphere on given one, so that flat faces of two coincide. The total flux
Q
linked with cross- section of bottom half (lower hemisphere) is
as charge enclosed by given
2 0
hemisphere is zero. So flux linked with flat face of hemisphere is
12.
f T
T
Q
2 0
. (i)
mg
N
2 mg
f
N = mg + 2mg . (ii)
(T + f)R = 2mg R . (iii)
2f 2mg
N mg
1
min
3
4
13.
N m2r mg
g
5
0.506
2r 2
14.
17 m 1H1 18 m 0 n1 M 931 298
15.
7 1
x
R
3 0
16.
Required kinetic energy = m N m n m H m C 931 MeV

= 2.99 MeV
17.
10
18.
Time constant will be 2RC
19.
For refraction at bottom of slab

4
3
0 V1 40cm
3V1 2 45
For mirror
1
1
1
V2 30 cm
20 V2 60
For refraction at bottom of glass slab
3
4
45
0 V3
cm
2V3 3 10
4
For refraction at upper surface of slab
1
3/2
45
0 V4
cm
45
V4
2
45
20.
11
2
D 11 D
10
d 2 d
20
11
1.81
oI
cos cos 2
4r
oI
cos 0 cos135
d
2
x
135
oI
1
1
2d
2
d
dt
d
P
21.
5
d R2 B
dt
dR
B 2R
dt
2B Ro t 1 anticlock wire
22.
The current in wire AB, increase the flux through circular loop. Hence current in circular loop will
be anticlockwise.
23.
2F0 4ky1
4 ky1
8 ky2
y1
y2
F0 = Tension in the string

F0 = 8ky2
9F
y 2y1 y 2 0
8K
F0 8K
K eq
y 9
T 2
9m
8K
24.
C
2
Vx Vx i Vyj
P.D VBl
P.D = along y axis = VxBl2
P.D along x axis = VyB.l1
P.D along AC = VxBl2 + VyBl1
25.
Assume the hemisphere to be made of thin hemispherical layers.
26.
Co-efficient of mutual inductance = o n1n2 r12

0 r12
6
Hence M
27.
0 r 2
2R
200 g x 2 2 1 g
x 10cm
V x 3 1000cm3
28.
Electric field and magnetite field will be parallel and velocity will also parallel to electric filed
All three are parallel
Hence only electric force will act on it
29.
y 2R 2
mv o
2v o
qB
B0
2R
30.
VT
2r 2 g
d
9
2 102
2r 2 10
1.8 103 103

3600
9 102 101
r 1.77 10 6 m
D 2r 3.54 106 m
7
Chemistry
PART II
SECTION A
1.
K 2Cr2 O7 14HCl 2KCl 2CrCl3 3Cl2 7H2O

n-factor of HCl =
2.
6 3
14 7
CH3
CH2 Br
CH3
Br
(i)
(ii)
CH3
CH3
Br
(iii)
(iv)
(v)
Br
Br
3.
PV nRT P nRT / V
4.
PV const P V 1dV V dP 0
dP
dV

P
V
5.
Go 0.059logk nFE0cell k 1, G 0
6.
Br
0.01 2, Br 0.01 Ag
0.05
CaBr2
KBr
AgNO3
+
Both Br & Ag ions act as common ions, so larger the conc. of Br- or Ag+ more is the suppression
of ionization of gBr
7.
Because shielding effect and increase in effective nuclear charge are cancelled
8.
Not lies in same plane
9.
NOF has lone pair while NO2F has no lone pair
10.
Zn NaOH A Na2 ZnO2 H2 B

NaOH P4 C NaH2PO2 PH3
NaOH NH4 Cl NaCl NH3 D H2 O
11.
Due to low electronegativity of N in compound C basic character decreases. Due to umbrella

effect, A is least reactive.
12.
Non super imposable mirror Image
13.
Due to cyclopropyl unique stability.
14.
In (II) negative charge present on O atom while positive on C. (I) is most stable due to neutral.
15.
Each ring contributes 1DBE.
8
16.
Ring expansion will take place
17.
Aniline is
NH2
H3C
COOH
18.
Facts.
19.
NaCl H2 SO 4
NaHSO 4 HCl
Craft process
NaCl NaHSO 4
Na2 SO 4 HCl
20.
Bond strength thermal stability
21.
Fact.
22.
3
10OH 3H2O 2 2CrO24
X 2Cr
green
yellow
Y CrO
2
4
2H2 O2 2H 2CrO5 3H2O Cr2O3 7 / 2O2 H2 SO4 Cr2 SO 4 3 3H2 O
blue
23.
Fact
24.
Fact
25.
(cis/trans) i.e. Geometrical
26.
Due to strong ligand t 62g eog
27.
Self reduction
Cu2 S 2Cu2 O 6Cu SO2
28.
P = KH x
logP logK H logX
29.
Electraode potential is intensive property while gibbs free energy is extensive
30.
A
2B C
Pi
Pi P
0
2P
0 Pr essure at t 0
P Pr essure at any t
Pt Pi 2P
or P
K
Pt Pi
2
Pi
2.303
log
t
Pi P
Pi
2.303
log
Pt Pi
t
Pi
2.303
2Pi
log
3Pi Pt
9
Mathematics
PART III
SECTION A
1.
x
1 m
0
2
1 x
1 x
1 2 sin3x 3
0
1
1
1
3 2 sin3x
n int egral value of
1
1
2 sin3x
m n
2.
at the point sin x
3
2
2 3
P ,
3 2
3
3 2
.
a
2
2 3
3
3
a
,
a
3
3
2
2
i
3.
fP eP
1 2 ...P
i P P 1
2
2
eP
i 1
1
n
lim fn lim e 2
n
4.
z 1
x iy 1
real,
real
i
i
x 1
y real x 1 0, x 1
i
z 1
1
sin1
sin y 1 y 1
i
Re z x 1, 1 lm z 1
16
5.
i 1
1
P
e2
S
r 1
8r
4r
16
1
1
2
2
2
2
2r 2r 1
r 1 2r 2r 1 2r 2r 1
r 1 2r 2r 1
1
1
1
1
1
1
1
...
481 545
1 5 5 13 13
16
8r
1 1088
2 1
545 545
10
6.
7.
13, a1, a2 . A20, 67 are in AP

13 67
a1 a2 .... a20 20
800
2
AM GM
a a 2 a3 .... a20
20
1
40
20
Maximum value is (40)20.
2 cos cos x.cos sin cos x sec

4
4
2 cos cos x
4
1 cos cos x 1
4
2A 2
8.
9.
99
50
2
3
2
2
x sin2 , cos y cos 2
yx 1
1
1
n

2
cos
sin
2n
2
2
2n
2
n

2 cos
2
4 2n
n

cos
4 2n 2 2
n 6, cos
10.
6
2
sin x 0 & sin3x 0

log2 2sin x sin3x 0
2sin x.sin3x 1
3x 0, 2,3
2
x 0, ,
3 3
for 2sin x sin3x 1
2 sin2 x 3 4 sin2 x 1
4
8 sin x 6 sin x 1 0
2 sin2 x 1 4 sin2 x 1 0
11
1
1
1
1
sin x
sin x
sin x sin x 0
2
2
2
2
1
1
sin x
2
2
2 3
x , ,
3 4 3 4
2 3
finally x ,
3 4
11.
12.
1 1 1 1
Required no = 5!
2! 3! 4! 5!
1
1 1 1
120
2 6 24 120
60 20 5 1 44
1 x x
n
x4
1 x 1 x 3
1 x 1 x 3
1 n C1x n C2 x 2 ... n C1x n 1 n C1x 3 n C2 x 6 .... n Cn x 3n
Coefficient of x15
n C5 n C0 n C4 n C3 n C3 n C6 ... n C2 n C9 n C3 n C12 n C6 n C15
5
n C5 r n C3r
r 0
13.
P A B
P A B
B P B A B
P
A B
P A B
Now P A B PA P A B
P A B P A P A B
7 1
1

10 2 15
Also P A B P A P B P A B
14.
7 3 1 4
B 1
, P
10 5 2 5
A B 4
Putting x = 0, a0 = 1
Differentiate both side and putting x = 0 we get a1 = 4a
Differentiate again and putting x = 0
a 2 6a2 4b
a30 a13 a32 3a0 a1a2
a0 a1 a2 0
1 4a 6a 4b
1
5
a ,b
4
32
12
15.
a11 = 0, a12 = 3, a21 = 3, a22 = 0

0 3
A
A 9
3 0
A 1
16.
0
1 0 3
9 3 0
1
3
CD
16 5 181
4 25
1
3
29
AD = 3
CA 2 9 29 38
2
Equation of circle is x 3 y 1 38
17
shortest distance will take place along the common normal

Equation of normal for y2 = 4ax at (at2, 2at)
y tx t t 3
If it passes through (6, 0) then
t3 5t = 0
t 0, t 5
A 5,2 5 , C 5, 2 5
PA PC 1 20 21; OP 6
Minimum distance =
18.
21 5 units
Let the mid point of chord be P(h, K); its equation will be
xh yK = h2 K2
h
K 2 h2
x
K
K
It should be same as y mx
a
m
h
a K 2 h2
and
K
m
K
2
2
K h h
a
K 2 a K 2h.h3
K K
h3 K 2 h a
m
Locus is x = y (x a)
19.
equation of tangents is SS1 = T2

x2 y2
2 9 x 3y
1
1
4
4
9
9 4 9
Right angle a + b = 0
Solve it get = 2
13
b
20.
f x
21.
sin x
sin x
xa
x
x
lim c lim xa b c
c
x 0
x 0
x
sin x
sin c .x c
c
x
x
The value of limit is non-zero only
a+bc=0
lim
x 1
lim
2tdt
x 1
2f x f x
1
x 1
2f 1 .f 1
8f 1
22
y = f(x)
x f 1 y
f x x tan x
y f 1 y tan1 f 1 y
y g y tan g y
x g x tan g x
Differentiate
1 g x sec 2 g x .g x
g x
23.
1
1
1 sec 2 g x 2 g x x 2
f x cos x 2ax b
cos x 2ax b
f x sin x 2a
fx 0
sin x 2a 0
a
24.
1
2
Let xx = t
x log x log t
1
dt
t
t 1 log x dx dt
log x 1 dx
I
25.
1
2
t t 1
dt sec 1 x x c
1K 2K 3K ...nK
lim 2K
n
nK 1
14
1 r
2K lim
n
nn
1
xK 1
2K
2K xK dx 2K

K
1
K
1
0
0
26.
I 2
1
x dx
2 x
2 zez dz
z z
2 zez e z 2 2e2 e2 0 2e2

1
27.
Area = sin y dy cos y dy
cos y 04 siny 2
4
28.
1
2
1 1
1
2
2 2 sq unit
dy
sin y x 2 .ex
dx
x cos ydy sin ydx x 2 e x dx
x cos y
d x.sin y x 2 ex dx
x siny x 2 ex 2 x.e x dx
x 2 e x 2xe x 2e x c
x siny e x x 2 2x 2 c
29.
a b . a c d

a b . a.d c c.d a

a.d abc c.d abc

a.d abc
30.
let the plane ax + by + cz = 1
&
here
x y z

6 4 3
When 6a + 4b + 3c = 0
2a b = 1
3a 4b + 5c = 1
29
27
22
a
,b
,c
85
85
85
29x 27y 22z 85

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1

ALL INDIA TEST SERIES

For an adiabatic process PV y k

volume decreases by about

for ideal gas (i) and (iii) are correct

Conservation of linear momentum.

Conservation of angular momentum

17 m 1H1 18 m 0 n1 M 931 298

Required kinetic energy = m N m n m H m C 931 MeV

Time constant will be 2RC

For refraction at bottom of slab

F0 = Tension in the string

Assume the hemisphere to be made of thin hemispherical layers.

Co-efficient of mutual inductance = o n1n2 r12

1.8 103 103

K 2Cr2 O7 14HCl 2KCl 2CrCl3 3Cl2 7H2O

Not lies in same plane

NOF has lone pair while NO2F has no lone pair

Zn NaOH A Na2 ZnO2 H2 B

Due to low electronegativity of N in compound C basic character decreases. Due to umbrella

Non super imposable mirror Image

Due to cyclopropyl unique stability.

Each ring contributes 1DBE.

Ring expansion will take place

Bond strength thermal stability

2H2 O2 2H 2CrO5 3H2O Cr2O3 7 / 2O2 H2 SO4 Cr2 SO 4 3 3H2 O

(cis/trans) i.e. Geometrical

Due to strong ligand t 62g eog

Electraode potential is intensive property while gibbs free energy is extensive

at the point sin x

13, a1, a2 . A20, 67 are in AP

2 cos cos x.cos sin cos x sec

sin x 0 & sin3x 0

1 n C1x n C2 x 2 ... n C1x n 1 n C1x 3 n C2 x 6 .... n Cn x 3n

a30 a13 a32 3a0 a1a2

a11 = 0, a12 = 3, a21 = 3, a22 = 0

shortest distance will take place along the common normal

equation of tangents is SS1 = T2

2 zez e z 2 2e2 e2 0 2e2

Area = sin y dy cos y dy

let the plane ax + by + cz = 1

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