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Introduction:
What are they?
How are they made?
QuickTime and a
Microsoft Video 1 decompressor
are needed to see this picture.
Excitons
We call the electron-hole pairs
excitons.
Excitons for a given semiconductor
material have a particular size (the
separation between the electron and
the corresponding hole) called the
exciton Bohr radius.
So What?
In a bulk semiconductor the excitons are only confined to
the large volume of the semiconductor itself (much larger
than the exciton Bohr radius), so the minimum allowed
energy level of the exciton is very small and the energy
levels are close together; this helps make continuous
energy bands.
In a quantum dot, relatively few atoms are present (which
cuts down on splitting), and the excitons are confined to a
much smaller space, on the order of the materials exciton
Bohr radius.
This leads to discrete, quantized energy levels more like
those of an atom than the continuous bands of a bulk
semiconductor. For this reason quantum dots have
sometimes been referred to as artificial atoms.
Small changes to the size or composition of a quantum
dot allow the energy levels, and the bandgap, to be finetuned to specific, desired energies.
Practical Applications:
Optical Storage
LEDs
Organic Dyes
Quantum Computing
Security
Solar Power
Image courtesy of TDK
Optical Storage
Quantum dots have been an enabling technology
for the manufacture of blue lasers
The high energy in a blue laser allows for as much
as 35 times as much data storage than conventional
optical storage media.
Less affected by temperature fluctuations, which
reduces data errors.
This technology is currently available in new highdefinition DVD players, and will also be used in the
new Sony Playstation 3.
Organic Dyes
In vivo imaging of biological
specimens.
Long-term photostability.
Multiple colors with a single
excitation source.
Possible uses for tumor
detection in fluorescence
spectroscopy.
Possible toxicity issues?
Image courtesy of Invitrogen
Quantum Computing
Pairs of quantum dots are candidates for qubit
fabrication.
The degree of precision with which one can measure
the quantum properties of the dots is very high, so a
quantum computer (which functions by checking the state
and superposition of the quantum numbers in entangled
groups) would be easily constructed.
Security
Quantum dots can be used in the fabrication of
artificial dust set up to emit at a specific frequency
of infrared light.
This dust could be used in any number of security-related
applications.
Placing the dust in hostile, difficult-to-monitor terrain would
allow the tracking of forces moving through the area, as it
would stick to their clothing and equipment.
This taggant causes any coated object to become
highly visible when viewed through night-vision goggles.
Solar Power
The adjustable bandgap of quantum dots allow the
construction of advanced solar cells.
These new cells would benefit from the adjustability
of the dots, as they would be able to utilize much more
of the suns spectrum than before.
Quantum dots have been found to emit up to three
electrons per photon of sunlight, as opposed to only
one for standard photovoltaic panels.
Theoretically, this could boost solar power efficiency
from 20-30% to as high as 65%
Conclusion
A number of additional applications exist or are being
developed that utilize quantum dots.
Quantum dots provide an example of the possibilities
that research at the nanoscale can provide.
The future is bright for this new and innovative
technology.
References:
R. D. Schaller and V. I. Klimove,
Phys. Rev. Lett. 92, 186601 (2004)
Michael J. Bowers II, James R. McBride, and Sandra J. Rosenthal
J. Am. Chem. Soc.; 2005; 127(44) pp 15378 - 15379
http://www.ivitrogen.com/
http://www.evidenttech.com/
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http://en.wikipedia.org/wiki/Quantum_dots
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