H2

H2
1.
16
H2 1766

O2 H2
1787 1783

2.

hydro+genes

H2

22-1
(Antoine-Laurent de Lavoisier)

3.

1%
17%
11% 1.5%
H2

93%
100

22-2
NGC604

H2
1. H H2
H protonelectron
22-3
2 H
1

 H2 22-4 22-4 22-5

22-3H

22-4H2

22-5H2

2. O O2
O 22-6 8 8 8 2 6
6 2 8
O O O2 22-7
22-8

22-6O

22-7O2

22-8O2

3. H2O O2H2
O O H O H
O 8 8 8 H H2
O2 O H
H2O 22-9 22-10 22-11
H2O
2

 H2O

22-10H2O

22-9H2O

22-11H2O

22-12 H2O

4.

ATP

1,500 1,000
2% 25% O2
CO2 OH

Glucose 6 O2
3

 36 ATP
6 CO2 6 H2O YouTube

1 + 6 6 +6 + (ATP)+ +
Glucose

+6

O2

6 CO2

+ 6H2O

ATP

+ +

O2 36 ATPO2
ATP OH CO2
2% O2 OH OH
H2O
OH OH O H
H2OOH

O H

OH OH

DNA
DNA

O2
1. O2

O2 O2 CO2
H2O 100%
O2 CHO
S

22-13
Mitochondria
22-14
O2

22-14

22-13

ATP ATP
ADP
ADP ATP
YouTube
2. O2
O2 760mm Hg 1 atm
21%O2
O2 O2

3. O2
a.
OH
5

 ADD H2 O2
b. O2 OH
c.

O2 OH

4. O2
O2 O2
O2 ATP

O2 O2 O2
O2 22-15

NO

H2O2
OHNO3
NO2 22-15
O2

O2

OH

NO
OONO
H2O2
NO2
22-15O2

 22-16ROS

O2

OH Hydroxyl Radical

OH
O2 36 ATPO2
ATP
22-17 2% O2 OH O2
O2 OH 22-18
OH

NFKB

2%

O2

22-17

O2 OH

22-18O2 OH

OH

1. H2

O2 H2 O2 H2
H2 O2 H2 O2 H2 OH H2 OH
OH
H2 + O2 H2 OH H2
H2 H2
H2 OH OH
H2
H2 OH

H2

H2 22-19
H2
22-20
8

 22-20

22-19

2.

O2 ATP

22-22OH 7 8
8

22-21OH

22-22

OH 22-21
OH OH
H2 H2 OH OH
H2O H2
H2 H2
9

H2

H2

3.
OH
H2
OH H2
H2 O2
H2OHOH2O H2

O2 2H2O

2H2O2

2% H2 H2 H2
H2 RBC 22-23

22-23 1%~4% H2 H2 umol/L

10

NOH2O2
H2
OHOH O2
H2 H2 OH

OH

H2

H2
C E

H2
1.

a. H2
b. H2 +O2

c. 2.5~5 H2 H2+O2
d. H2
e. H2
2.
a.

11

b.
(i)
PPM

0. 3

120
3

0.3
0.1

0.1
0.3

(ii) pH
pH

6.8~9.0

120

6.8~9.0
6.8~9.0

(iii)

0.003mg/L

0.0005 mg/L

0.1 mg/L

0.05 mg/L

0.05 mg/L

0.8 mg/L

0.01 mg/L

0.01 mg/L

10.0 mg/L

1.0 mg/L

12

3. H2

2014 review paperH2 1.6 mg/L. Shigeo

Ohta, Molecular hydrogen as a preventive and therapeutic medical gas: initiation, development and
potential of hydrogen medicine. Pharmacology & Therapeutics 144 (2014) 111.
P. 3. Section 4.3. H2 can be dissolved in water up to 0.8 mM (1.6 mg/L).
1.6 mg/L = 0.16 mg/100 mL = 0.00016g/mL or 0.00016%
molarity: 1.6 2 = 0.8 mM.

Resources, Tools and Basic Information for Engineering and Design of Technical Applications!
Solubility of Hydrogen Gas - H2 - in Water

15H2 0.0017 g/Kg

= 0.00017 g/100 mL 0.00017 0.017 100
Molarity0.0017 g/Kg = 1.7 mg/L
1.7 mg 2 = 0.85 mM

13

 10.00017 H2 0.00016
2 H2 1.05 mg/L
0.105 mg/100 mL = 0.000105 g/100 mL = 0.00010%
Molarity = 1.05 mg/L H2 2, 1.05 mg 2 = 0.53 mM
0.53 mM H2 15 0.85 mM
Solubility of Oxygen - O2 - in Water

15O2 0.05 g/Kg Molarity = 50 mg/L

16, 50 mg 16 = 3.13 mM
0.05 g/Kg = 0.005 g/100 mL 0.005
30.005 H2 0.0043

2 Reference:
G.W.C. Kaye and T.H. Laby, "Tables of Physical and Chemical Constants," 15th ed., Longman, NY,
1986, p. 219. www.wiredchemist.com/chemistry/data/solubilities-gases

14

Solubilities of Gases in Water at 293 K

Gas

Solubility*

Gas

Solubility*

Gas

Solubility*

Acetylene

0.117

Chlorine

0.729

Methane

0.0023

Ammonia

52.9

Ethane

0.0062

Nitrogen

0.0019

Bromine

14.9

Ethylene

0.0149

Oxygen

0.0043

Carbon
dioxide

0.169

Hydrogen

0.00016

Sulfur dioxide

11.28

Carbon
monoxide

0.0028

Hydrogen
sulfide

0.385

*Grams of gas dissolved in 100 g of water when the total pressure above the solution is 1 atm.

1. H2 H2
2. H2 H2
H2O H O H2+O2
H2 66%O2 33%
3. O2 H2 H2
2-4% H2 O2 N2
H2 H2
4. H2 78% N2
H2 N2
O2 H2 O2 H2
H2
5. H2

15