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Departamento de Engenharia Mecnica, LEPTEN/Labtucal Centro Tecnolgico, Universidade Federal de Santa Catarina, 88040-900 Florianpolis, SC, Brazil
Departamento de Engenharia Mecnica, LEPTEN/Boiling Centro Tecnolgico, Universidade Federal de Santa Catarina, 88040-900 Florianpolis, SC, Brazil
a r t i c l e
i n f o
Article history:
Received 26 September 2012
Received in revised form 7 January 2013
Accepted 10 January 2013
Available online 4 February 2013
Keywords:
Film condensation
Condensing surfaces
Noncondensable gases
Inclined smooth surfaces
Grooved surfaces
a b s t r a c t
This paper reports experimental results for lm condensation on vertical and downward inclined smooth
and grooved surfaces subjected to ascending streams of a vaporair mixture. An experimental facility was
built in order to evaluate the heat uxes for different surface inclinations, surface sub-cooling temperatures and air to vapor ratios in the mixture. Two experimental procedures were employed to evaluate the
heat absorption rate during the condensation process. The employment of grooved surfaces resulted in a
10% enhancement of the condensation rate in the case of the pure vapor condensation and a negligible
effect when noncondensable gases (NCGs) were present in the mixture.
2013 Elsevier Inc. All rights reserved.
1. Introduction
The condensation heat transfer phenomenon is encountered in
a variety of engineering and industrial applications. Knowledge of
the physical mechanisms which drive condensation is important
for the design of several types of equipment.
The rst lm condensation model was proposed by Nusselt in
1916. It assumes negligible effects of the interfacial shear stress
at the vapor/liquid interface, and equates gravity and viscous
forces for a quiescent pure vapor environment in contact with an
isothermal vertical smooth plate. A linear temperature prole
was considered. Subsequently, a number of researchers improved
Nusselts model by removing some of the original restrictive
assumptions and including effects like sub-cooling, a nonlinear
temperature prole, inertial terms and interfacial stress [14].
The wettability of the condenser surface plays an important
role, as the interaction between the condensate liquid and the condensing surface dictates the mode in which condensation occurs.
The dropwise condensation mode is associated with higher heat
transfer coefcients when compared to lm condensation. Therefore, many researchers have directed their efforts to the development of suitable condensation promoters such as polymeric
lms, a monolayer of organic materials and ion-plating technology.
These techniques provide poor wettability of the substrate and
thus dropwise condensation is maintained for a longer period [5
Corresponding author. Tel./fax: +55 48 3721 9379.
E-mail address: marcia@emc.ufsc.br (M.B.H. Mantelli).
0894-1777/$ - see front matter 2013 Elsevier Inc. All rights reserved.
http://dx.doi.org/10.1016/j.expthermusci.2013.01.004
8]. However, as is well known, dropwise condensation is often difcult to maintain for all the period.
Wavy condenser surfaces, also known as Gregorig surfaces [9],
are used to produce better heat transfer rates for the lm condensation mode. The enhancement is caused by the variation in the
interface radius of the liquid lm over the substrate, which, together with the surface tension, produces a gradient pressure in
the condensate, driving the lm from the crest to the valley of
the surface grooves, improving the condensation performance.
The tests performed showed that this conguration results in heat
transfer coefcients up to ve times larger than those for smooth
surfaces, for the same projected area [1012].
In some practical operations, noncondensable gases (NCGs) may
be found in the condensing vapor, deteriorating the heat transfer
process. This is caused by the formation of a gas boundary layer
over the condensate liquid lm, reducing the partial vapor pressure
at the condensate interface. Several studies have been conducted
on stagnant and forced convection occurring over smooth plates
or inside and outside tubes in order to investigate the effect of
an NCG. For a quiescent condensing mixture on smooth plates,
the decrease in heat transfer rates could be around 50% with an
air fraction of only 0.5% (by mass) in the airvapor mixture. In
cases where the mixture ows, the reduction in the heat transfer
decreases since the stream disperses the gas boundary layer. This
effect is dependent on the Reynolds number of the mixture. Another effect that could spread the gas boundary layer is the undulation in the liquid lm condensation interface, which occurs in the
wavy and turbulent ow regime [1316].
F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
91
Nomenclature
Alphabetic
NCG
Noncondensable gase
Q
Heat transfer rate (kW)
_
m
mass ow rate (kg s1)
Cp
Specic heat (kJ kg1 K1)
Tout
Outlet cooling water temperature (K)
Inlet cooling water temperature (K)
Tin
hlv
Latent heat (kJ kg1)
h
Mean heat transfer coefcient (kW m2 K1)
g
Gravity (m s2)
L
Surface length (m)
DT
Sub-cooling temperature (K)
A
Area (m2)
T
Temperature (K)
Sc=l/qD Schmidt dimensionless number ()
W
Air mass fraction ()
M
Molecular weight (kg Kmol1)
D
Diffusivity (m2 s1)
Pressure (atm)
Greek Letters
Density (kg m3)
h
Surface inclination ()
j
Thermal conductivity (kW m1 K1)
l
Dynamic viscosity (kg m1 s1)
Subscript
w
cond
liq
vap
sat
G
1
0
Cooling water
Condensate
Liquid
Pure water vapor
Saturation
Gas (liquid vapor mixture)
Bulk
Condensate interface
2. Experiment
2.1. Experimental apparatus
Fig. 1 shows a scheme of the experimental facility. It consists of
a test section and auxiliary equipment (steam generator, cooling
water system, NCG supplier and data acquisition system) which
were grouped into three main sections: boiler, vapor supply line
92
F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
and test section. All parts of the equipment were made of galvanized carbon steel plates, of 2 mm thickness, and were thermally
insulated using 50 mm rockwool sheets in order to reduce the heat
loss to the surroundings.
The boiler, which consists of a 600 mm 500 mm 270 mm
rectangular vessel, has electrical heaters inside to supply the controlled power needed to generate the steam. The NCG employed
was atmospheric air, supplied with the aid of an air blower through
a square duct with 50 mm of internal cross section and 300 mm of
length (see Fig. 1). The air was warmed to the same temperature as
the steam using a controlled electrical power source to provide
power for the air heater, so that the resulting mixture is kept in
the dry saturated condition. The air mass ow rate can be calculated by the thermal capacity of the air times the temperature difference before and after the heater measured by thermocouples.
The air-vapor mixture is created by these two streams, which meet
at the vapor supply line. The supply line is a cylindrical vertical
tube with 147 mm of inner-diameter and 1000 mm of length.
The test section, illustrated in Fig. 2, is a box with a square base
with 250 mm of edge and 350 mm of height. One wall of the chamber is made of glass to allow the visualization of the condensing
phenomenon. The mixture formed in the vapor supply line enters
the test section from the bottom and directly reaches the condensing surface. This surface is xed by pins located in the lateral walls,
allowing inclination variations.
Different inclinations of the cooling plate lead to variations in
the cross sectional area of the airvapor stream ow. Therefore,
the ow area beside the plate changes with the inclination, causing
different degrees of connement of the mixture. To keep approximately the same connement (same cross sectional area of the
ow) for all tested cases, plates with different lengths, which vary
according to their inclination, were constructed. Also, one of the
plates was tested with different inclinations to study the connement effect.
Smooth electrolytic copper plates with lengths of 116.2 mm,
142.8 mm and 200 mm were tested at inclinations of 30, 45,
60, respectively. This latter plate was tested at inclinations of
60 and 90 (vertical position).
To collect the condensed water, a drain was installed in the lower part of each surface, as shown in Fig. 2. Seven thermocouples
were inserted within small holes drilled in parallel and 0.1 mm below the condensing surface, in order to measure the surface temperature distribution, as can be seen in Fig. 3a.
The back face of the condensing test plate closes a small heat
exchanger, comprised of a hollow thermal insulated metallic parallelepiped box, where cooling water circulates at controlled rates
and temperatures, allowing different sub-cooling levels of the condensing surface (see Fig. 3b).
The inuence of the surface material and nishing on the condensation was tested by means of surfaces of the same length
(200 mm) and same inclination (60), made of smooth and grooved
aluminum 5052 alloy and grooved electrolytic copper plates. The
grooves were made in the longitudinal direction of a plate of the
same thickness as the smooth plate being tested, with a distance
of 2 mm between crests and 1.44 mm of depth. Fig. 4 shows the
testing surfaces with their main dimensions.
2.2. Data reduction
The experimental heat transfer rates were measured by two
methods. In the rst method, the heat absorbed by the cooling
water was calculated by multiplying the mass ux rate by the difference between the inlet and outlet water temperatures, using the
expression:
_ w T out T in
Q w mCp
_ cond hlv
Q cond m
F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
93
pure vapor, the theoretical heat transfer rate was determined using
the modied Nusselt model [2]:
314
0:943
Nusselt
Llliq DT
where qliq, jliq and lliq are the density, thermal conductivity and
viscosity of the condensed liquid density respectively, qvap is the
pure vapor density, jliq is the thermal conductivity, g is the force
of gravity, L is the surface length, h is the surface inclination from
the horizontal and DT is the difference between the temperatures
of the interface and the wall.
Thus, the heat transfer rate is obtained by:
where hNusselt is determined from Eq. (3), Asurface is the surface area
of each condensing plate and Tsat, Twall represent the temperatures
of the pure saturated steam at the interface and the surface temperature, respectively, measured by the thermocouples.
To account for the presence of NCG, the Rose model [10,13] was
used to predict the theoretical heat transfer. In this case, in contrast to the pure vapor, the saturation temperature at the interface
is not previously known, and thus the following equation is used to
estimate this parameter:
lliq qliq W 1 2 20
W0
Sc
21
lG qG w0
W1
!
8
lG qG
w0
5
w0
2
FX
W 0 28
3
F Sc lliq qliq
10FSc
100 W 1
w0
2
8Sc
21 W 0
W0
where qG and lG are the density and viscosity of the airvapor mixture, respectively, W0 is the air mass fraction at the condensate
interface, W1 is the air mass fraction of the mixture, Sc is the
Schmidt number for the gas mixture, F = jliq (T0 Twall) /lliqhlv,
where T0 is the interface temperature, w0 = W0 W1 and X =
(Mair Mvapor)/[Mair W1 (Mair Mvapor)], where Mair and Mvapor
are the molecular weight of air and water respectively.
The evaluation of the interface temperature therefore begins by
guessing a value for this parameter, which must be between the
temperatures of the surface and the initial mixture formation.
Therefore, F, in Eq. (5) can be computed and this equation is solved
for W0, the noncondensable air mass fraction at the interface. Since
the vapor mass fraction is equal to 1 W0, the partial pressure of
the vapor at the interface is evaluated by assuming equilibrium
at the interface and using Raoult and Daltons Law. With the partial
vapor pressure, the corresponding saturation temperature can be
ascertained from steam tables. If this new value for the interface
T 2:072
1
P1
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F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
400
Eq. (1)
Eq. (2)
Eq. (4) Nusselt
300
200
100
0
40
60
80
Table 1
Heat transfer results.
Surface temperature (C)
82.6
Heat ux (kW/m2)
Eq. (4) Nusselt
Eq. (1)
Eq. (2)
138.9
125.4
128.3
reduction in the partial pressure of the steam, decreasing the saturation temperature at which the condensation takes place, and,
therefore, reducing the heat ux. In other words, an additional
thermal resistance is built up, reducing the heat transfer rate. On
the other hand, the heat uxes predicted by the Rose model for
mixtures in quiescent environment are smaller than those observed in streams, where the ow hitting the condensation surface
spreads the NCG boundary layer. In the latter case, the saturation
temperature is not so strongly affected by the accumulation of
the NCG. In other words, Rose considered a stagnant environmental while in this work the mixture was in an upstream ow. For the
case with a 20% air mass fraction, the heat ux decrease, compared
with the pure vapor case, was between 15% and 22%, depending on
the surface temperature. Rose [13] reported that for a quiescent
mixture with a 0.5% air mass fraction the NCG caused a large thermal resistance, with a decrease of more than 50% in the heat ux.
Similar trends were observed for plate inclinations of 60, 45
and 30, as shown in Figs. 810, respectively, for smooth copper
plate
The Nusselt theory shows that the heat transfer for vertical
plates (in a quiescent environment) is larger than for tilted surfaces, as the gravity pulls the liquid lm downward. However, on
comparing Fig. 6 (vertical case) with Figs. 810 (tilted cases), it is
clear that this effect is not observed. It was noted that, as the surface approximates the horizontal position the ascending stream
tends to be more trapped by the condensing surface and the vapor
of the airvapor mixture exchanges more heat with the cooled surface, increasing the production of condensate and, therefore, the
heat transfer coefcient. It is well known that the mean liquid lm
thickness, which acts as thermal resistance, increases as the surface length increases (larger condensing area). As already explained, the length of the tested plates decreases as their
inclinations tend to the horizontal position, and therefore, the lm
thickness and the thermal resistance are expected to decrease.
Actually this is not observed. Taking Fig. 7 (vertical case) and 8
(60 case), although the tested surface is the same (and so the same
mean liquid lm thickness), the heat transfer rate for the inclined
surface is larger than for the vertical case. Therefore, the tests show
that the effect of the liquid lm thickness is less important than the
inuence of inclination. Consequently, the condensation heat
uxes were higher for an inclination of 30 (Fig. 10) than for 45
(Fig. 9) and 60 (Fig. 8).
It is interesting to note that during the experiments and for all
slopes tested, no condensate drops were observed to fall from the
cooling surface. Instead, all of the condensate liquid lm ran down
the downward condensing surface and was collected by the drain.
This means that all the condensate formed over the condensing
surface was collected in the drain, improving the quality of the
experimental data.
Also, one should note that the heat transfer calculated using Eq.
(2) is always larger than that calculated using Eq. (1) for all inclined
testing cases, although most of the data lie within the experimental
uncertainty range. This is not observed for the vertical case. Even
though it is not possible to explain exactly why this happens, it
is believed that this difference is due to the different stream congurations over the condensing plates in both positions. More investigation would be need to a deep understanding of this
phenomenon. In spite of this difference the comparison between
the heat transfer determined by Eqs. (1) and (2) is better than with
the results of the literature theoretical models.
The inuence of other surface materials was also investigated in
this study. Samples of aluminum and copper, in the smooth and
grooved surface congurations, were tested for an inclination of
60. In the following plots the theoretical results and degrees of
uncertainty are not shown, as no new information other than that
previously discussed herein can be obtained.
F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
Eq.1PureVapor
Eq.2PureVapor
Eq.1 - 20% NCG
Eq.2 - 20% NCG
Rose - 20% NCG
Eq. 1 - 30% NCG
Eq. 2 - 30% NCG
Rose - 30% NCG
Eq. 1 - 40% NCG
Eq. 2 - 40% NCG
Rose - 40% NCG
Eq. 1 - 50% NCG
Eq. 2 - 50% NCG
Rose - 50% NCG
30
95
20
10
0
40
60
80
Eq.1PureVapor
Eq.2PureVapor
Eq.1 - 20% NCG
Eq.2 - 20% NCG
Rose - 20% NCG
Eq. 1 - 30% NCG
Eq. 2 - 30% NCG
Rose - 30% NCG
Eq. 1 - 40% NCG
Eq. 2 - 40% NCG
Rose - 40% NCG
Eq. 1 - 50% NCG
Eq. 2 - 50% NCG
Rose - 50% NCG
40
30
20
10
0
40
60
80
50
Eq.1PureVapor
Eq.2PureVapor
Eq.1 - 20% NCG
Eq.2 - 20% NCG
Rose - 20% NCG
Eq. 1 - 30% NCG
Eq. 2 - 30% NCG
Rose - 30% NCG
Eq. 1 - 40% NCG
Eq. 2 - 40% NCG
Rose - 40% NCG
Eq. 1 - 50% NCG
Eq. 2 - 50% NCG
Rose - 50% NCG
40
30
20
10
0
40
60
80
In Figs. 1113, the heat ux is plotted against surface temperature for the condensing surfaces at 60 degrees of inclination, for
grooved copper, grooved aluminum and smooth aluminum surfaces, respectively. In the case of the grooved surfaces, the heat
uxes were evaluated based on the apparent projected surface
area.
The results for the heat uxes show that the behaviors of the
smooth and grooved surfaces follow the same trend, that is, an in-
96
F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
Eq.1PureVapor
Eq.2PureVapor
Eq.1 - 20% NCG
Eq.2 - 20% NCG
Rose - 20% NCG
Eq. 1 - 30% NCG
Eq. 2 - 30% NCG
Rose - 30% NCG
Eq. 1 - 40% NCG
Eq. 2 - 40% NCG
Rose - 40% NCG
Eq. 1 - 50% NCG
Eq. 2 - 50% NCG
Rose - 50% NCG
50
40
30
20
10
0
40
60
80
50
Eq. 1PureVapor
Eq. 2PureVapor
Eq.1 - 20% NCG
Eq. 2 - 20% NCG
Eq.1 - 30% NCG
Eq. 2 - 30% NCG
Eq.1 - 40% NCG
Eq. 2 - 40% NCG
Eq.1 - 50% NCG
Eq. 2 - 50% NCG
40
30
20
10
0
40
60
80
40
Eq. 1PureVapor
Eq. 2PureVapor
Eq.1 - 20% NCG
Eq. 2 - 20% NCG
Eq.1 - 30% NCG
Eq. 2 - 30% NCG
Eq.1 - 40% NCG
Eq. 2 - 40% NCG
Eq.1 - 50% NCG
Eq. 2 - 50% NCG
30
20
10
0
40
60
80
enhancement of around 150% was achieved for ascending Freon113 (comparing grooved with smooth surfaces). In the study reported herein, the vapor ows upwards and the grooves are not
able to hold the vapor for long and, therefore, the improvement observed is due to an increase in the condensing area, while Markowitz et al. [11] attributed the improvement to the surface tension
and the augmentation of the liquid vapor lm curvature.
For different types of surfaces, it is observed that with an increase in the NCG in the airvapor mixture the heat uxes for
the four different surfaces tend to assume the same value. This
can be clearly observed, for instance, in the case of 50% of NCG.
In other words, copper and aluminum with a grooved or smooth
surface showed the same behavior for high amounts of NCG. As explained by Markowitz et al. [11], the NCG tends to accumulate in
the grooves, blocking the access of the condensate liquid to the valley regions, reducing the efciency of the surfaces.
In summary, when airvapor mixture ascending ows reach
condensing surfaces, the enhancement provided by the channels
F.F. Czubinski et al. / Experimental Thermal and Fluid Science 47 (2013) 9097
97
40
Eq. 1PureVapor
Eq. 2PureVapor
Eq.1 - 20% NCG
Eq. 2 - 20% NCG
Eq.1 - 30% NCG
Eq. 2 - 30% NCG
Eq.1 - 40% NCG
Eq. 2 - 40% NCG
Eq.1 - 50% NCG
Eq. 2 - 50% NCG
30
20
10
0
40
60
80
was observed only in the case of the pure vapor. With NCG, the values for the heat transfer rate are similar for different condensing
surfaces.
4. Conclusions
Film condensation of ascending ows of airvapor mixtures
was experimentally investigated on vertical and downward inclined surfaces, in relation to the effects of different inclination angles, sub-cooling levels and the presence of NCG in the upstream
ow, for smooth and grooved surfaces of copper and aluminum.
The test results were evaluated based on the Nusselt and Rose
theories as benchmarks. Although the presence of NCG had an effect on the decrease in the heat transfer rate, the conguration of
the condensation system plays the main role since the mixture
ows upstream freely inside the condensing chamber.
Reverse trends were observed in the heat transfer rates for the
test results and the theory predictions, considering the effect of
inclination. The experimental results show that the heat uxes increase as the plate inclination decreases from the vertical to an
inclination of 30. As the amount of NCG increases, a systematic
reduction of the heat transfer rate is observed. Due to the mixture
ow, the formation of the NCG boundary layer over the condensate
liquid is disturbed and the decrease in the heat transfer rate was
not so strongly affected by the NCG, as observed in the literature
for quiescent mixtures. The heat transfer variation with the condenser surface sub-cooling level follows the same trend as predicted by the theoretical models.
Furthermore, the enhancement of the heat transfer rates for
grooved surfaces was small and observed only in the case of the
pure vapor, especially for the copper samples. The effect of grooves
was negligible for streams with NCGs.
Acknowledgement
The authors would like to acknowledge the nancial support
provided by Petrobras and CNPq for this research.
References
[1] L.A. Bromley, Effects of heat capacity of condensate, Industrial and Engineering
Chemistry 44 (1952) 29662969.
[2] W.M. Rohsenow, Heat transfer and temperature distribution in laminar lm
condensation, Journal of Heat Transfer 78 (1956) 16451648.