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SS: Flow Assurance: Validation of Wax Deposition Models Using Field Data
from a Subsea Pipeline
A. Singh, SPE, the University of Tulsa; H. Lee, SPE, and P. Singh, SPE, ConocoPhillips Company: and C. Sarica,
SPE, the University of Tulsa
Copyright 2011, Offshore Technology Conference
This paper was prepared for presentation at the Offshore Technology Conference held in Houston, Texas, USA, 25 May 2011.
This paper was selected for presentation by an OTC program committee following review of information contained in an abstract submitted by the author(s). Contents of the paper have not been
reviewed by the Offshore Technology Conference and are subject to correction by the author(s). The material does not necessarily reflect any position of the Offshore Technology Conference, its
officers, or members. Electronic reproduction, distribution, or storage of any part of this paper without the written consent of the Offshore Technology Conference is prohibited. Permission to
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Abstract
This paper describes an offshore production system with a subsea pipeline (12-inch diameter 23-km long) where wax
deposition has been the primary flow assurance challenge. This subsea pipeline has been transporting nearly 55,000 BOPD
from a central processing platform (CPP) to a Floating Production Storage Offloading (FPSO). The crude oil has been
characterized for wax potential by performing several laboratory analyses which have been entered into available wax
deposition models to predict the wax deposition rate inside the pipeline under various operating conditions. The transient
flow rate and pressure drop data from the field have been analyzed to estimate the average wax deposit growth rate. This
paper will share the findings from the field validation and application of the available wax deposition models. The results will
help pipeline design engineers to accurately estimate the required insulation level for wax deposition control and will also
assist in operating the pipelines with the optimum pigging frequency.
This study has confirmed that Film Mass Transfer (FMT) model gives higher wax deposition rate than Equilibrium
model (EM). The predicted deposition rates from both of the models have been much lower than the field data. Using
default viscosity, both EM and FMT models gave reasonable predictions of the wax deposition rate as compared to
deposition rate obtained from the field data. The field deposition rate is higher than the predictions by the EM model without
any shear removal. By incorporating aging process to the FMT model, it was found that the value of Ka parameter (as
defined in the aging model by Singh et al., 2000) of 1 matches the deposit wax content observed in the field. Matzain shear
removal model (2001) over-predicts the impact of shear on the rate of wax deposition; however, Venkatesan's shear removal
model (2003) shows a very small impact of the shear.
The deepwater project development and engineering design needs an accurate prediction of the wax precipitation and
deposition in subsea pipelines. A number of wax deposition simulators have been developed to predict the wax deposition
rate. Although there have been several attempts made to validate the wax deposition prediction models with laboratory data,
no reliable field verification study could be found prior to this study.
Introduction
Paraffin deposition takes whenever paraffinic oil gets in contact with a cold pipe wall or ambience below the Wax
Appearance Temperature (WAT) of the oil, solid paraffin crystals can precipitate and deposit on the pipe surface. Deposition
of wax from oil leads to a gradual decrement in production due to plugging of wells and/or pipelines and, in an extreme case,
can render a pipeline or production facility abandoned. Various measures including chemical and mechanical have routinely
been applied. Mechanical methods include pigging and wireline cutting to remove the deposited wax. Chemical methods
include paraffin inhibitors/dispersants to inhibit the formation of deposit and hot solvents to remediate the deposit already
formed. These methods to prevent and remediate wax deposit add significant operating cost to the production operation. .
Successful development of the offshore deep-water projects requires engineering designs of the facilities that can handle
the flow assurance challenges such as wax deposit problems. A robust design can only be obtained with an accurate
prediction of the wax precipitation and deposition. Therefore, an accurate modeling of wax precipitation and deposition is
imperative to facilitate a successful engineering design, development, and operation of deep-water offshore projects.
Researchers have already made significant progress in understanding the thermodynamic equilibrium and deposition
mechanisms of wax. Thermodynamic models have been developed based on precipitation of wax as multi-phase solids
solution to successfully describe the formation of solids wax as a function of temperature (Lira-Galeana et al., 1996,
Coutinho and Ruffier-Meray, 1997). The overall consensus is that the dominant mechanism of wax deposition is molecular
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diffusion in laminar boundary sub-layer driven by the radial Fickian diffusion of n-paraffins, the primary wax formers
(Brown et al., 1993 and Singh et al., 2000). Precipitation kinetics in laminar boundary sub-layer is included to describe the
turbulent flow wax deposition behavior (Lee, 2008). Several researchers also expressed that in turbulent flow, the shear
stress acting on a wax gel layer may slough off wax from the deposition layer. This effect has been considered as one of the
major mechanisms to reduce the deposit thickness in cases with high turbulent flow (Venkatesan, 2003).
Various simulators like TUWAX, OLGAs wax deposition module; PVTsims Depowax, etc. include some of the
progress made in our understanding of the thermodynamic equilibrium and deposition mechanisms of wax. These software
packages cannot be completely relied on because the models used in the software has their own assumptions and limitations.
For example, Singh et al. (2000) model works very well within laminar flow but for turbulent region it needs to be modified
(Venkatesan 2003). Since the complexity of the wax deposition phenomenon, these simulators do not capture all of the
physics and tend to ignore some of the critical aspects while simplifying the modeling parameters.
Validation of wax deposition models have been the focus of several research projects published in the literature. Model
systems comprised of food grade waxes dissolved in model oils (a blend of mineral oil and Kerosene) were used by several
researchers (Singh et al., 2000, Venkatesan, 2003, and Lee 2008) to perform the laboratory deposition experiments utilizing a
flow loop system. These researchers were able to fit the modeling parameters to match their experimental data. However,
limited attempts were made to validate the wax deposition models for real crudes using laboratory data. Tulsa University
Paraffin Deposition (TUPDP) consortium has extensively utilized South Pelto crude and Garden Bank condensate (Lund,
1998, Matzain, 1998, Apte et al., 2001, Hernandez, 2003, Couto et al., 2006, Espinoza, 2006, Bruno et al., 2008,) to obtain
experimental data to further study to predict wax deposition. Recently, a detailed experimental study was presented on a
North Sea waxy condensate (43API) using a laboratory flow loop system by Hoffmann and Amundsen (2010). In another
study, a west African waxy crude (36API) was tested in a flow loop deposition setup by Alboudwarej et al. (2006). With
these studies, significant progress made on wax deposition prediction, but scaleup of the data to the real field cases still
remains as a problem.
Very few attempts have been made to validate the wax deposition models using field data (Hsu et al., 1998, Klienhans et
al., 2000). Instead of true field scale systems, these studies utilized side streams and loops at the well site to generate data
using fresh produced fluids. Labes-Carrier et al. (2002) and Bagatin et al. (2008) utilized some of the operational experience
and qualitative information to validate wax deposition predictions.
This paper studies an offshore production system with a subsea pipeline where wax deposition has been the primary flow
assurance challenge. The crude oil has been characterized for wax potential by performing several laboratory analyses.
These data have been entered into available wax deposition models to predict the wax deposition rate inside the pipeline
under various operating conditions. The transient flow rate and pressure drop data from the field have been analyzed to
estimate the average wax deposit growth rate. Pipeline inlet and exit temperatures have also been analyzed to estimate the
overall heat transfer coefficient.
Field Description
The field layout of the offshore case studied is given in Fig. 1. A subsea pipeline transports waxy crude oil from a central
processing platform (CPP) to a Floating Production Storage Offloading (FPSO). The single phase crude oil pipeline has a 12
in. diameter and is 23-km long. A separate 16 in. gas pipeline transports the gas from the CPP to the FPSO. Flow rate of the
export oil is 55,000 BPD with a pipeline inlet temperature of 165F. The subsea water temperature is nearly 77F. Wax
appearance temperature of the crude is measured to be 136F by a cross-polarized microscope. The pipeline is un-insulated
and partially buried. Wax deposition inside the pipeline is managed by a routine pigging operation.
Subsea
PLEM
Gas - 16" x 23 km
Oil - 12" x 23 km
FPSO
Central
Processing
Platform
A sample field data of the pipeline operation for a 32-day production period is summarized in Fig. 2. Temperature of the
export crude at the pipeline inlet is maintained at ~165F. Crude oil flow rate stays around 55,000 BOPD during this period.
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The pressure drop data clearly shows the effectiveness of the weekly pigging operation. Due to the wax deposition, pressure
drop of the pipeline gradually increases from ~200 psi to ~300 psi in a week of continuous production. Pigging operation
clearly decreases the pressure drop back to ~200 psi just after the pig run. The deposition continues even after a week as
indicated by the gradual increase in the pressure drop between the two consecutive pig runs with no indication of a plateau
behavior in the pressure drop. A detailed set of crude properties has been discussed in the next section to accurately model
the wax deposition behavior of the crude oil using several models in TUWAX simulator.
8/1/2008 00:00:00
200
60
50
40
30
20
10
0
70
80
7/1/2008 00:00:00
350
150
250
100
150
50
50
12
16
20
Time (days)
24
28
0
32
Fluid Properties
A summary of the results of fluids analyses of the stock tank crude sample is presented in Table 1. The crude sample has
high normal paraffin content.
Table 1: Summary of Results of Crude Properties
Crude Property
Measurement Technique
Values
API @ 60 F
45
Density (g/cc)
0.8
Cross-Polarized Microscopy
58C (136F)
57C (135F)
TU MSI Model
55.5C (132F)
WAT in Pipeline
55C (131F)
29C (85F)
HTGC n-C19+
17
IP 143
0.03
Wax Content
High Temperature Gas Chromatography (HTGC) has been used to characterize the molecular weight distribution of both the
n-alkane and the all hydrocarbons as a function of the carbon number present in the stock tank sample. The results are
presented as the weight percent of all hydrocarbons containing a given carbon number and the weight percent of n-paraffin
(Fig. 3). Because the normal n-alkanes precipitate at higher temperatures than the iso-alkanes of the same carbon number,
they are responsible for higher cloud points and wax deposition issues.
Wax Appearance Temperature (WAT) and Pour Point Temperature (PPT)
WAT has been measured using cross polar microscopy. The sample has been preheated to 82C (180F) to remove any
thermal history and introduced inside a microscope capillary that has been placed on the stage at 80C (176F). PPT of the
stock tank sample has been measured using ASTM D5853-95 procedure with the beneficiated method that requires
preheating the crude to 82C to remove the thermal history and then gradually cooling the sample until it no longer pours.
The beneficiated method is usually the most applicable for crude production situations where the crude is flowing hot and
then allowed to cool when flow is stopped.
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10
All Hydrocarbons
n-Alkanes
Wt %
0.1
0.01
0
10
20
30
40
50
60
Carbon #
Figure 4 shows the viscosity predictions by TUWAX using default viscosity option as a function of temperature along with
the measured viscosity. The predicted viscosity values match well with the measured data above 60C. The program is not
taking into consideration the effect of the wax crystals on the bulk viscosity of the slurry.
Trapped Oil Content of Deposit
Several samples of the wax deposit collected from the pig trap were analyzed using HTGC for the wax content and the
trapped oil content of the deposit. The deposit seems to have the consistency of a shoe polish and melts at temperature well
above the WAT of the crude. Melting points of the deposit samples range from 95-100C. Figure 5 shows the percent wax
content of the deposit.
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35
30
25
20
15
10
5
0
1
# of Samples
Wt Fraction (%)
0
C1
C3
C5
C7
C9
C11
C13
C15
C17
C19
C21
C23
C25
C27
C29
Carbon Number
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Wax Content
0.18
Solids wt fraction
0.16
0.14
0.12
0.1
0.08
0.06
Pour Point
0.04
WAT = 55oC
0.02
0
0
10
20
30
40
50
60
70
80
Temperature (deg.C)
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10
0
0
10
15
20
25
10
-0.7773
y = 10.134x
2
R = 0.9997
0
1
10
100
Viscosity (cP)
Figure 10. Peak Deposit Thickness vs. Viscosity after 10 days of Deposition Using EM
0.005
y = 1837.8x0.0425
R2 = 0.9864
0.0045
0.004
0.0035
0.003
0.0025
0.002
y = 0.0022x-0.1219
R2 = 0.8186
0.0015
500
0.001
0.0005
0
0
20
40
60
80
100
0
120
Viscosity (cP)
dC/dT (1/F)
2000
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10
0
0
5000
10000
15000
20000
25000
Figure 12. Wax Thickness vs. Distance as Function of Viscosity using FMT.
In order to further quantify the effect of the viscosity, peak deposit thickness after 2 days is plotted as a function of the
viscosity in Fig. 13. A trend line with a power law perfectly describes the predicted results. The concentration driving force
varies significantly as a function of the viscosity (Fig. 14). Thus, in FMT model also, the impact of the viscosity is primarily
coming from the diffusivity.
Diffusivity Independent of Bulk Viscosity
As seen in the measured viscosity data, bulk viscosity of the waxy oil slurry below the WAT can be orders of magnitude
higher than the viscosity of oil in the continuous medium. The diffusion of wax occurs through the continuous media and is
slightly hindered by the presence of wax crystals because only 4-6% of the crystal volume fraction is occupied by the wax
crystals. Therefore, diffusivity of the wax molecules should depend on the viscosity of the continuous medium and should
not decrease orders of magnitude when the bulk viscosity of the waxy oil slurry increases by orders of magnitude.
14
12
10
6
y = 11.586x-0.5082
R2 = 0.9962
0
1
10
100
Viscosity (cP)
Figure13. Peak Deposit Thickness vs. Viscosity after 2 days of Deposition Using FMT
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0.012
0.01
y = 0.0011x0.4702
R2 = 0.9976
0.008
0.006
0.004
0.002
0
0
20
40
60
80
100
120
Viscosity (cP)
10
0
0
10
15
20
25
Figure 15. Wax Deposit Thicknesses after 10 Days for Three Trapped Oil Fractions Using EM
10
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14
12
10
8
y = 2.1038x(1-)-1
6
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
Figure 16. Peak Wax Deposit Thicknesses after 10 Days vs. Oil Fractions Using EM
Equilibrium Model Prediction after 2 days
14
12
10
0
0
10
15
20
25
Figure 17. Wax Deposit Thicknesses after 2 Days for Three Trapped Oil Fractions Using FMT
14
12
10
8
y = 2.2848x(1-)-1
6
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
Figure 18. Peak Wax Deposit Thicknesses after 2 Days vs. Oil Fractions Using FMT
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11
10
8
6
Default (Maxwell Corr.)
User defined = 1
User defined = 2
User defined = 3
4
2
0
0
10
15
Distance (km)
20
25
14
12
10
8
6
4
2
0
0
10
15
Distance (km)
20
25
12
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model has very high shear removal rate resulting in a significant lower deposit thickness. The value of parameter a needed
to be increased to 2.0e-10 (from the default value of 0.8e-12) to bring the shear removal rate to about 50%.
Ka = 1
Ka = 5
Ka = 10
Ka = 25
7
6
5
4
3
2
1
0
0
10
15
Distance (km)
20
25
Ka
Ka
Ka
Ka
=
=
=
=
1
5
10
25
30
Ka = 1
Ka = 5
Ka = 10
Ka = 25
25
20
15
10
5
0
0
10
15
Distance (km)
20
25
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13
Ka
Ka
Ka
Ka
=
=
=
=
1
5
10
25
No Shear Removal
Matzain Model
Venkatesan Model (a=2.0e-10, b =1.9)
14
12
10
8
6
4
2
0
0.00
5.00
10.00
15.00
20.00
25.00
Location (km)
Figures 26 and 27 show the results of a parametric study to analyze how the values of parameter a and b affect the
shear removal rate in the field pipeline.
120
100
80
60
40
20
0
1.0E-13
1.0E-12
1.0E-11
1.0E-10
1.0E-09
1.0E-08
14
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140
Venkatesan's Model a = 1.0e-9
Venkatesan's Model a = 2.0e-10
Venkatesan's Model a = 2.0e-11
120
100
80
60
40
20
0
0.0
1.0
2.0
3.0
4.0
5.0
To get some reasonable rate of the shear removal, the value of a should be at least two orders of magnitude greater than
the default value of 0.8e-12.
Analysis of the Field Data
Export pressure and temperatures and crude oil flow rates were monitored at CPP while the arrival pressure was measured at
the FPSO. The pipeline operating data obtained from the field has been summarized in Fig. 2. The export temperature at the
CPP was maintained near 165F. The arrival pressure at the CPP was maintained around 350 psig. The temperature of the
pipeline fluid arriving at the FPSO ranged between 80 and 85F. Table 3 provides some of the pipeline design parameters.
Average seabed temperature is 77F. Temperature of crude oil entering the pipeline has been around 165F. Thermal
conductivity of the steel pipeline is 44 W/m/K with a clean pipe roughness of 50 m.
Table 3. External Heat Transfer Coefficient (EHTC) Used in Simulations for Non Insulated Half Burried
Pipeline
Pipeline Segment
Segment Length (m) Segment ID (mm)
Segment OD (mm)
EHTC* (W/m2/K)
(CPP Seafloor to base
22 (50 mm concrete over
23,000
305
324 (12.75 in.)
of Flexible Riser)
steel)
* Computed for Heat Flux at Steel Pipe OD
Pressure Drop Study
To quantify the effect of wax deposition on the pressure drop of the pipeline, Blasius (1913) friction factor correlation is
selected based on the range of the Reynolds number (104<Re<105) as calculated for the steady state pipeline flow conditions.
(1)
f = 0.079 Re 0.25 .
The pressure drop of the pipeline can be given as
1.75
(2)
where Ri is the effective radius of the pipeline with the deposition and Rio is the clean pipeline radius.
P 0.158 L 0.25 0.75
3.5
= 1.75 =
(2 Rio ) .
(3)
vo
(2 Ri )4.75
Equation 3 shows that the term should increase as the deposit thickness increases, and it must be a constant for a clean
pipeline (just after the pigging run when there is no wax deposit on the pipe wall) as shown in Fig. 28. The minimum value
of this term is nearly 107 psi/(m/s)1.75. For a length of 23-km with 12 in. diameter, 800 kg/m3 density, and 10cP average
viscosity, the theoretical value of the term with no wax deposit is calculated to be 110.6 psi/(m/s)1.75. Thus, the Blasius
correlation can be used to estimate the frictional losses.
To understand roughness effects on the deposit, the data is analyzed as shown in Fig. 29. It was observed that the term
increases very slightly (~5%) even when the flow rate reduced significantly (~40%) for a short period (as shown by one of
the ellipses in Fig. 29 during the second week of November). If there would be additional roughness due to the wax deposit,
the term should change more dramatically with this much reduction in the flow rate. Thus, the assumption of smooth wax
deposit is reasonable for this field case and Blasius correlation can be applied for calculating the frictional pressure drop.
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15
70000
500
450
60000
400
350
300
40000
250
30000
200
DP/vo^1.75
50000
150
20000
100
10000
50
0
1-Jul-08
31-Jul-08
30-Aug-08
29-Sep-08
29-Oct-08
28-Nov-08
0
28-Dec-08
Date
Figure 28. and Liquid Flow Rate History Plot
500
70000
450
60000
400
350
300
40000
250
30000
200
DP/vo^1.75
50000
150
20000
100
10000
50
0
1-Oct-08
16-Oct-08
31-Oct-08
15-Nov-08
0
30-Nov-08
Date
Figure 29. Deposit Roughness Effect
(4)
R
1
=
=
=
i
Using the above analysis, average thickness of the wax deposit has been calculated and shown in Fig. 31. The average
thickness increases rapidly initially at 3-4 mm/day and then the deposit growth rate significantly slows down.
16
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300
Run 1
Run 2
Run 3
Run 4
Run 5
Run 6
Run 7
280
Kappa (psi/(m/s)^1.75)
260
240
220
200
180
160
140
120
100
0
10
15
20
25
20
25
Time (days)
25
20
15
10
0
0
10
15
Time (days)
Figure 31. Average Deposit Thickness vs. Time Based on Pressure Drop Measurements
Result and Discussion Comparison of Model Predictions with the Field Data
Predictions were made using several options available in the TUWAX simulator (Fig. 32). It can be seen that the predictions
from both the EM and FMT models with the experimental viscosities of the crude are significantly lower as compared to the
deposit thickness obtained from the field data. The average trapped oil fraction of 0.72 is used as found in the field deposits
collected from the pig. Using default viscosities, the predictions from both of the models increased significantly with the
FMT model predictions closer to the field data. Singh aging model was run with the FMT model and the parameter Ka was
varied to match the wax content data measured from the pig trap solids. Figure 33 shows the wax content data as a function
of time. It was found that Ka=1 gave a realistic predictions of the wax content of the deposit during the aging process.
The deposit thickness trend calculated by the FMT model with Singhs aging model was shown in Fig. 34. There is no
significant difference between the wax deposition results obtained from either the constant assumption or the Singh aging
model assumption. Thus, the value of Ka=1 gave a realistic predictions of both the deposition rate and wax content of the
deposit during the aging process.
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17
30
Run 1
Run 2
Run 3
Run 4
Run 5
Run 6
Run 7
25
20
15
10
EM Model, =0.72
default, No aging
EM Model, =0.72
exp, No aging
0
0
10
15
20
25
Time (days)
25
20
15
10
0
0
10
15
20
Time (days)
Figure 34. Aging vs. No Aging Predictions Using Singh et al. (2000) Model
25
18
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Viscosity
Aging
Shear
Removal
Comparison to field
data
EM
Measured
No
no
significantly lower
FMT
Measured
No
no
significantly lower
EM
Default
No
no
somewhat lower
FMT
Default
No
no
reasonable Match
FMT
Default
Singh
no
reasonable match
C wEqm
D
interface
thermodynamic equilibrium concentration of wax in the liquid phase at deposit interface temperature
molecular diffusivity of wax in the oil
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f
k
L
r
Re
Ri
Rio
T
Ti
v
Ka
19
friction factor
thermal conductivity of the oil
length of the pipeline
radial location near the deposit interface
Reynolds number
effective radius of the pipeline with the deposition
clean pipeline radius
temperature of the fluid at a radial location r
temperature at the deposit interface
fluid velocity in the pipeline
fitting parameter in aging model
Greek symbol
deposit thickness
oil content of the deposit
viscosity of the crude oil
density of the oil
parameter defined in Eq. 3
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1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
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