1

1
1

C 1 4mol .L

: 1

V 1 10mL

S 2O 32

2Na

C 2 0.5mol .L 1

S 2O 32

2Na

S S SO 2 aq H 2O l

aq

2H

S 2O

15
15
0.3
3
0.3
3

0
0.4

360

300

240

180

360
0

300
0.0
1
0.0
1

240
0.0
2
0.0
2

-1
180
0.0
3
0.0
3-2

S 2O.32

-3
aq

-4

S 2O 32 aq

S 2O 32 aq

t s
.
-5

x f t

-6 t= 30 s
-7 , :
- .
- .
:2 1

aq

2H

2
3 aq

S 2O

:

:
0

C 2 0.5mol .L

S S SO 2 aq H 2O l

:
30
45
60
90
-1
30
45
60
90

0.2 0.2 0.16 0.11
.
6
0.2 0.2 0.16 0.11

-2 B
6
A
2

S 2O 3

V 2 40mL

2
3 aq

C 1 4mol .L

: 1

V 1 10mL

V 2 40mL

0.4

12
0
12
0.0
0
7
0.0
7

t s

t s
mol .L 1
S 2O

S 2O 32 aq mol .L 1
x mmol

2
3 aq

x mmol
t s

t s
S 2O 32 aq mol .L 1
S 2O 32 aq mol .L 1
x mmol
x mmol

S 2O 32
.

-3 .
-4
.

S 2O 32 aq

2
3 aq

S 2O

S 2O 32 aq

x f t

t s
-5
-6 t= 30 s
-7 , :

 S 2O 32

2Na

-
-

C 3 1mol .L 1

1 2

.

.
.

:2 1

S 2O 32

2Na

C 3 1mol .L1

1 2

-1
-2

2
3

2
3

S 2O 32 aq

S 2O 32 H 2O 2SO 2 2H 4e

90

45

60

S 2O 32 6H 4e 2S 3H 2O

0.16

0.11

S 2O 32 aq 2H aq S S SO 2 aq H 2O l
-3

14.5
:
CV
.
4 10
1 1
0.8mol .L 1
V 1 V 2
50
C 2V
. 2
0.5 40

0.4mol .L 1
V 1 V 2
50

-4

S S SO 2 aq H 2O l

aq

2H

2
3 aq

30

0.2

0.2
6

15
-7
0.3
3

t s

0
0.4

mol .L
1

2
3 aq

12

10

3.5

360

300

240

180

12
0

t s

0.0
0
S O 2
1 2 3 aq

0.0
2

0.0
3

0.0
7

19.5

19

18.5

16.
5

S 2O

-1

x mmol

20

: 1

.
:

SO / S O
S O /S

mol .L
1

S 2O

S 2O 32 aq

x mmol

:
( :

x max 20mmol
2

t1

:
(

t 1 45s
2

:2
2

C3 f C2

V
.

V
.

S 2O 32 aq

-2

.
A 1 B 2

.V 2x

x max

x max

.V 2x max

-5

V
. x

.V x max

S 2O 32 aq

S 2O 32 aq

: :

V
. x

V.

V
S 2O
.

2
3 aq

2
3 aq

S 2O 32 aq

S 2O

x S 2O 32 aq

x 0.4 S 2O 32 aq V mol
-6

V mol
50.10 mol
50 mmol
3

2
3 aq

x 0.4 S O
x 0.4 S O
x 0.4 S 2O

2
3 aq

2
3 aq

2
-I ) ( H2O2 C0 = 0.1 mol / L
F V1 = 20 mL
) ( C1
)( -K+ + MnO4
C2 = 0.02 mol /L

V2= 10 ml
:
2MnO 4 (aq) + 5H2O 2 (aq) + 6H +(aq) = 2 Mn 2 +(aq) + 5 O 2 (g) + 8
) H 2O (l

2
-I ) ( H2O2 C0 = 0.1 mol / L
F V1 = 20 mL
) ( C1
)K+ +
( -MnO4
C2 = 0.02 mol /L
V2= 10 ml
:
+
2MnO 4 (aq) + 5H2O 2 (aq) + 6H (aq) = 2 Mn 2 +(aq) + 5 O 2 (g) + 8
) H 2O (l

 -1 )( Ox / Red
.
-2
.
-3 C1 C2 V1
. V2
-4 C1
. F
-II

:

)(l

+ 2 H 2O

)(g

O2

)2 (aq

H 2O

t = 0 s mL V 0 =80
-C0=0.1mol.L V = 20 mL

.n(O2) = f ( t ) :
-1 .
-2
.
-3 .
.
-4
-5 ((t
.((t = 0 s
6
. t = 0 s
- 7

+ 8H (aq) + 5e= -1
= O2(g) + 2H+(aq) + 2e
+

)(aq

O2 (g) / H2O2 (aq) :

MnO4
)H2O2(aq
)(aq

)+ 4H2O(l

/ Mn2+

)(aq

MnO4-

)(aq

2+

Mn

)(l

+ 2 H 2O

)(g

O2

)2 (aq

H 2O

.
t = 0 s mL V 0 =80
-C0=0.1mol.L V = 20 mL


.n(O2) = f ( t ) :
-1 .
-2
.
-3 .
.
-4
-5 ( ( t
.( ( t = 0 s
6
. t = 0 s
- 7

t1/2 = 10min :

-5
V ( t ) = d X / d t :
-6
t = 0 s: V0 = tang = 4 / 14 = 0.28 m.mol .min-1
H2O2 : t = 0
-7

 :
-2
2+
MnO4 (aq) + 5 H2O2(aq) =2 Mn (aq) + 5 O2(g 2
) ( mol
0
C2 V 2
C1 V 1
00 00
-

XE
C2V2- 2 XE
C1V1-5XE
2X 5XE

E

-3
C1V1 5 X E = 0
C2V2 2 X E = 0 :
C1 = 5 C2V2 / 2 V1 :
) C1 = ( 5. 0.02. 10 ) / ( 2. 20
C1 = 0.025 mol.L-1
F = 0.1 / 0.025 = 4 :
-4
II
:
-1

)H2O2 (aq
= O2 (g) + 2 H2O

) ( m.mol

0
C0V0 = 8
0

)X(t
X (t) 2 8
)X (t

Xf
Xf28
X f
n (O2) = X (t ) :
-2
mmol = 4.10-3 4 = :
-3
mol
)X f = n f (O2
t = t1/2 : X1/2 = Xf / 2 = 2 m.mol :
-4

] 8 2 ) = [H2O2

Vvol (H2O2) = - d[ H2O2] / dt

:
Vtot / ( X
) Vvol (t) = ( 2 / Vtot ) ( d X / dt
t = 0 : Vvol (0) = ( 2 / 0.1 ) . 0.28 = 5.6 m.mol.L-1.min-1
; ( FeCl3
-8
(.

V 1=50 ml

- l t=0

C1 =0,056 mol/l

K ++I
) (aq

) H 2 O2 (aq

)I (aq

) :(.
-6

V 2=50 ml

XE

.
C3

VE

5 C3 .V E
.

lll
)n I =f (t
). ( 2

C2 =0,2 mol/l

:
.
)+ I 2 (aq )+ 2 H 2 O(l

)+ H 2 O2 (aq )+2 H (aq

) 2 I (aq

-1
-2
-3
-4

)(OX /

.
.
.

ll
) (t .
V p=10 ml

) (t

-1
-2
-3
-1

.



.t=600 s
t=360 s
.

C3 =0,04 mol /l

:

360 510 720 900 1080 1440

VE

-4

270

160

60

)t(s

:
XE :

VE(ml
0,0 2,2 4,8 6,5 7,5 9,0 10,5 11,5 12,5 13,5
)

-1

)(OX /

-2
-3
-4

)I 2 ( aq) / I (aq

2
)2 /S 2 O3(aq
)S 4 O 6 ( aq

:

-1
.

-1

I2 / I

) (OX / :

,8
=1,4 mmol
2

t 1 /2 =330 s

:
-2
1 dx
=v
V dt

)( H 2 O 2 / H 2 O

:
-2
n ( H 2 O2 ) =C1 .V 1=2 ,8 mmol

t=600 s
.
X =n(I 2) :
:

1 dn(I 2) 1 21
mmol

=1,67 102
V
dt
0,1 600
L.s

-3

:
)+ I 2 (aq )+ 2 H 2 O(l
)+ H 2 O 2 (aq )+2 H (aq
) 2 I (aq

2,8

=v

.t=360 s
-3
n ( I 2) =5 C3 . V 3=5.0,04 .7 .5=1,5mmol

) ( mmol

C3 .V E
2

= )n ( I 2

:
C .V
100
n ( I 2) = 3 E
=5 C 3 . V E
2
10

.
.
.
XE

-5

C3. V E
2

= ) X E=n ( I 2

10

X
0

n ( H 2 O2 ) =2,8 X=2,81,5=1,3 mmol

X
Xmax

10-2X
X-2,8

10-2Xmax Xmax-2,8

Xmax

Xmax :
-4
Xmax=2,8 mmol : :

.

:
-1

2
)+S 4 O6(aq
)2 2 I (aq
)I 2 (aq) +2 S 2 O3(aq
-2
-3

.


2
)+S 4 O6(aq

)2 2 I (aq
)I 2 (aq) +2 S 2 O3(aq

)n

I2

I2

(n

I2

(n

XE

) ( mmol
0

C3.V3

2X

C3.VE-2X

)-X

XE

2XE

C3.VE-2XE

)-XE

n
:
-4

.

.