Professional Documents
Culture Documents
Hazard
Analysis
Critical
Control
Points
TheWorldBank
CompiledforRootsofPeacebyLouwTheronwithfundingprovidedbyTheWorldBankHorticulture
&LivestockProgram(HLP)andwithrecognitiontoColorsZA,Capespan,NDASouthAfrica,ICA
InternationalChemicalsPtyLtdandJ.D.ZachLea,RootsofPeace
FundingforthismanualhasbeenprovidedthroughtheWorldBankEmergencyHorticultureand
LivestockProject(HLP),ContractNo.MAIL/WB/HLP/Contract5185,IDAGrantNumber:H226AF
ProjectID:P098256.TheHLPisimplementedbytheMinistryofAgriculture,IrrigationandLivestock
(MAIL)oftheIslamicRepublicofAfghanistan.RootsofPeace(ROP),anAmericanNGOoperatingin
AfghanistanunderMinistryofEconomy,NGOregistration#165,wasasubcontractorfortheHLP.
Mr.LouwTheronwastheRootsofPeaceconsultant.Thecontentsofthispublicationarethesole
responsibilityofROPandcaninnowaybetakentoreflecttheviewsoftheWorldBank.
CopyrightRootsofPeace2010.Allrightsreserved.
Page ii
CONTENTS
1
2
3
Introduction.................................................................................................................2
DefinitionsandTermsusedinHACCP.........................................................................3
HACCPontheFarm.....................................................................................................4
3.1 Water....................................................................................................................4
3.2 ChemicalUseandStorageontheFarm...............................................................4
3.3 MaximumResidueLevels(MRLs).........................................................................5
4 HACCPinthePackHouse............................................................................................7
4.1 ThePackHouse....................................................................................................7
4.2 TheCartonStore..................................................................................................8
4.3 Implementsinthepackhouse.............................................................................9
4.4 PackHouseHygiene...........................................................................................10
5 RodentsandInsectControl.......................................................................................14
6 Conclusion.................................................................................................................16
7 ANNEXES....................................................................................................................18
7.1 ANNEX1TRAININGREGISTER..........................................................................18
7.2 ANNEX2NAMEREGISTERFORTRAININGEVENTS..........................................19
7.3 ANNEX3PACKHOUSEINSPECTIONREGISTER................................................20
7.4 ANNEX4MEDICINE/PLASTERREGISTER..........................................................21
7.5 ANNEX5BATHROOMCLEANINGREGISTER....................................................22
7.6 ANNEX6PERSONALHYGIENEREGISTER.........................................................23
7.7 ANNEX7PESTCONTROL/TRENDREPORT.......................................................24
7.8 ANNEX8CHEMICALSPRAYREGISTER..............................................................25
7.9 ANNEX9EXAMPLEOFAPACKHOUSECLEANER:SPOREKILL..........................26
Page i
1 Introduction
ThepurposeofthisHazardsAnalysisandCriticalControlPoints(HACCP)manualistoinform
and instruct producers, merchants and pack house staff on what HACCP is, the practical
applicationthereofandtheimportanceofapplyingtheHACCPprinciplestotheproduction
andpackingprocess.
AHACCPsystemisappliedthroughthe7principlesofHACCP:
Principle 1: Identify the potential hazard(s) associated with food production at all stages,
fromgrowth,packinganddistribution,untilthepointofconsumption.Assessthelikelihood
ofoccurrenceofthehazard(s)andidentifythepreventativemeasuresfortheircontrol.
Principle3:Establishcriticallimit(s)whichmustbemettoensuretheCCPisundercontrol.
Principle4:EstablishasystemtomonitorcontroloftheCCPbyscheduledtestingor
observations.Establishascheduleofinspectionsandkeeprecordsoftheinspectionsand
actionstakentobringCCPintocontrol.SeeinspectionrecordexamplesinANNEX.
Principle5:Establishthecorrectiveactiontobetakenwhenmonitoringindicatesthata
particularCCPisnotundercontrol.
Principle6:Establishtheproceduresforverificationwhichincludesupplementarytestsand
procedurestoconfirmthattheHACCPSystemisworkingeffectively.
Principle7:Establishdocumentationconcerningallproceduresandrecordsappropriateto
theseprinciplesandtheirapplication.SeeexamplerecordsinANNEX.
Page 2
2 DefinitionsandTermsusedinHACCP
CriticalControlPoint(CCP):Apoint,steporprocedureatwhichcontrolscanbeappliedand
afoodsafetyhazardcanbeprevented,eliminatedorreducedtoacceptablelevels.
HACCP: A system which identifies specific hazards & preventative measures for their
control.
Hazard:Thepotentialtocauseharm.Hazardscanbebiological,chemicalorphysical.
High Pressure Hoses for Cleaning: Any hydrostatic pressure wet cleaning device working
withanoverpressureofmorethan6bar(=6x105Pa),whichisthenormaloverpressureof
tapwatersystem.
Illegal Residue: Substances (i.e. chemicals, drugs, food additives) remaining on or in a
productincommercethatexceedtolerancesestablishedbyregulatoryauthorities.Thisalso
includes substances for which no tolerance has been set or which is not Generally
RecognizedasSafe(GRAS)
Pathogen:Afood,waterorairborneorganismofpublichealthsignificancethatcancause
illnessinhumans.
Pesticides:Compoundsclassifiedassuchbytheregulatoryauthoritiesofthelocationwhere
a product is produced or shipped. These include, but are not limited to, fungicides,
insecticides,rodenticidesandherbicides.
AStep:Anystageinfoodproductionand/ormanufactureincludingrawmaterials,their
receiptand/orproduction,harvesting,transport,formulation,processing,storage,etc.
QualityProgram:Alogicalsequenceofactionsdesignedtoassurespecificproductquality
specificationsaremet.
QualitySystem:Theorganizationalstructure,policies,programsandproceduresneededto
manageproductquality.
Risk:Anestimateofthelikelyoccurrenceofahazard.
Traceability:Theabilitytoestablishtheproductionhistoryofallcomponentsofaproduct.
Undesirable micro organism: Any micro organism that is a pathogen, causing product
spoilage,orisanindicatorofunsanitaryconditions.
Page 3
3 HACCPontheFarm
Thefoodsafetyhazardsingrapecropproductionarebiological,chemicalandphysical.
Preventingcontaminationatthefarmlevelrequiresknowledgeandcareinhandlinggrapes
topreventthemcomingintocontactwithsourcesofcontamination.Becausewatercanbea
carrierofcontamination,itsqualitymustbeknownsothatappropriatestepscanbetaken
topreventcontamination.Topreventcontaminationbychemicalsusedonthefarm,all
chemicalsshouldbeappliedandstoredwithspecialcare.Thissectionprovidesadditional
informationandadviceonpreventingcontaminationonthefarm.Examplesoffoodsafety
hazardsare:
BiologicalHazards
Pathogenicbacteriainsoil,waterandfrompoorhygienepractices,e.g.Salmonella,
E.coli.
Pathogenicbacteriae.g.,Salmonella,E.colifromcontaminationwithanimalmatter.
ChemicalHazards
Chemicalcontaminantsandheavymetalcontentofwaterusedforirrigation,
fertilization,pesticidesorincontactwithanypartofthecrop.
PesticideResiduese.g.exceedingspecifiedMaximumResidueLevel(MRL),caused
byincorrectuse,incorrectapplicationofagriculturalchemicals.
Contaminationwithmineraloils,e.g.diesel,oil.
PhysicalHazards
LivingandDeadInsects
Personalarticles
Hair
Glass
3.1 Water
Water must be tested for chemical, biological and microbial contamination. This is to be
doneataregisteredandreputablelaboratorywhichislegallyentitledtoissuecertificates
dealingwithwaterquality.
3.2 ChemicalUseandStorageontheFarm
The storage and record keeping on all chemical and fertilizer applications is an important
means of assuring that food produced on the farm is safe for human consumption. Such
storageandrecordkeepinghasbecomeaprerequisiteformarketingagriculturalproductsin
certainmarkets.SeeexamplerecordofchemicaluseinAnnex8.Recordsmustbekeptof
chemicalstorageandusestating:
Nameandamountsofchemicalsstoredinthestorageplace.
Productusedineachapplication
Dateofapplication
Volumeapplied
Reasonforapplication
Page 4
Allchemicalsonthefarmmustbekeptinasecure,dryandlockableplace(specialbuilding,
room or cabinet/cupboard).The chemical store should be labeled as such and must be
lockedatalltimes.(Seephotosbelow.)Ifthefloorisinapoorcondition,thechemicalstore
mustbefittedwithshelvesorthechemicalsmuststandonpalletsofftheground.NoEntry
tounauthorizedpersonnelwillbepermittedandasignboardshowingthisshouldbevisible.
The chemicals in the store must be labeled and included in the recordkeeping practices
describedabove.
Chemicalstoredoorwithwarningsignsandshelvesinstoreshowingchemicalsstoredoff
theground
3.3 MaximumResidueLevels(MRLs)
Grapes being marketed to certain markets will be tested at a toxicity laboratory to
determine if they contain any pesticide residues exceeding the Maximum Residue Levels
(MRLs) allowed by health authorities. The table below shows the MRLs for the chemicals
typically used on grapes. The use of any other chemicals must be checked against a data
baseofknownMRLsasthisisaCriticalControlPointinHACCP.
MaximumResidueLevels(MRLs)forChemicalsusedin
GrapeProduction
Sulfur
50PPM
CopperOxychloride
20PPM
GibberellicAcid(GA)
GA has no MRL as it is sprayed
earlyforberryenlargement
Page 5
Herearerecommendationsforuseofotherchemicalscommonlyusedingrapeproduction:
WetablePowder(WP)nottobeusedafterberriesreach5mmsize
WetableSulphur.Theonlydangerisvisualresidueattimeofpacking.
TheSafetyperiodbeforeharvestforDryPowderis14days
GA can cause eye and skin irritation and lower gastric tract problems; so, care should be
usedtoavoidcontactwithGAwhileapplyingittograpes.
Page 6
4 HACCPinthePackHouse
HACCPinthepackhouseistiedtothewholeprocessofproductionandmustbeseen
holistically.Biological,chemicalandphysicalfoodsafetyhazardsinthegrapepacking
processaresimilartothoseonthefarm.Additionalsourcesofcontaminationinthepack
housecomefromtheadditionalchemicalsusedinthepackhouseforcleaningandpest
control,lubricantsandhydraulicoilandpossiblyfromsulfiteinsulfursheets.Additional
physicalhazardsarisefromtheadditionalworkersandthebuildingitself.Examplesoffood
safetyhazardsare:
BiologicalHazards
Pathogenicbacteria,e.g.E.coliandSalmonellafrompoorhygienepracticesand
environment
ChemicalHazards
Cleaningchemicals
Lubricantsandhydraulicoil
Pestcontrolchemicals
Sulphite(Sulphursheets)allergen
PhysicalHazards
Livinganddeadinsects
Personalarticles,e.g.jewelry,watches,sizingrings
Plasterfromwallsandceilingofpackhouse
Piecesoffiber,towel
Glass(forexample,frombrokenlightbulbs)
Hair
Woodfrombroken/damagedboxesorpallets
Dustinpackaging
Stones
Metalpiecesfrombadlymaintainedclippingscissors
4.1 ThePackHouse
The pack house should be constructed in a manner that facilitates keeping it clean and
protectingitfromanimalinfestation.
Window sills should be sloping slightly and corners should be rounded to prevent
dustgathering.
This also applies to ventilation holes. The ventilation holes should be covered with
finemeshtopreventbirdsorinsectsentering.
Thefloormustbeabletodraineasilyandfacilitatewaterremoval.
Waterhosesmustbeavailableforpowerwashingthepackhousefloors,wallsand
equipment.
Two separate doors must be available. One for the personnel to enter the pack
houseandotherforfruittoenterandleave.
Plastic curtains in front of doors will help prevent insects, dust and heat from
enteringthepackhouse.
HACCP Manual for Afghan Grape Pack Houses
Page 7
Acementedareaaroundthepackhousewillminimizethecarryingofsandandother
undesirablesubstancesintothepackhouse.
Nodogs,catsorbirdsaretobeallowedinornearpackhouse.
Drainagepipesshouldbeclosedoffwithwiremesh
Regularpestcontrolwiththeaidoftrapsmustbeapplied.
Litterbinsmusthavelids.
Clearlymarkedbinsfordiscardedfruitmustbeprovided.
Signsmustbedisplayedprominentlyinthepackhouseshowing
NoEating
NoSmoking
Washhands
Movementofmachinery
Differentsignstouseinpackhouse
4.2 TheCartonStore
The Carton Store should be directly linked to the pack house with only a door
allowingaccesstothecartonstore.
ThesameHygieneprinciplesapplytotheCartonStoreasthePackHouse.
Neatnessinthestoreisimperativeandservestokeepcartonsclean,dustfreeand
clearofotherforeignmatter.
Cartonsmustbepackedonpalletstoavoidcontactwiththefloor.
Thecartonstoremustbemonitoredforrodentandinsectactivity.
Afirehydrantorfireextinguishermustbeavailablenearthecartonstore.
Page 8
4.3 Implementsinthepackhouse
Thepackingsystemmustbedesignedtofacilitatecleaninganddisinfection.
Firehydrant
AModernPackHouse
Powderfireextinguisher
Page 9
All lights in the pack house must have covers (Perspex or Plastic) to prevent glass
fallingintheproductandmustbewithineasyreachforcleaningpurposes.
Scalesmustbecoveredwhennotinusetoprotectagainstdust.
Harvestingbaskets(lugs)mustbesterilizedbeforetakingthemtothevineyard.Two
bathsareusedforthispurpose.Thefirstcontainsthesterilizingagent(seeAnnex9
onSporkillasanexampleofageneralcleaningagentforpackhouses).Thepicking
baskets are washed in the first bath. The second contains clean water to wash off
anyresidueanddirt.
Clipping Scissors must be sterilized before use in the pack house. Two buckets or
bowls are used with the 1st containing the sterilizing agent and the second
containing clean water for rinsing. Paper towels can be provided for drying of
scissors.
Pickingbasketsandscissorsmustbecleanedregularlyduringthepackingday.
The pack house should be equipped with a water system which can preferably be
used under high pressure to clean and disinfect the pack house after each days
work.
Cleaning agents used must not contain chloride (See Annex 9 on Sporekill as an
exampleofageneralcleaningagentforthepackhouses)
Theloadingoutareadoorshouldhaveaplasticcurtain.
An inspection schedule must be in place. See Annex 3 for example of cleaning
schedule.
Allcleaningagentsmustbekeptinaseparateclearlymarkedarea.
Cleaningequipmentsuchasbrooms,mopsandbucketsmustbecolorcodede.g.red
forcleaningbathroomsandblueforcleaningthepackhouse.
All water should be of a potable quality and tested before the season by a
recognizedlaboratory.
Firefightingequipmentshouldbeavailableinthepackhouse.
4.4 PackHouseHygiene
Pack house hygiene is extremely important as it is the first line of defense against
contamination.
Personalfacilitiesforpersonnel
Bathroomsmustbecleanedandinspectedregularly.
Bathroommusthave:
o liquidsoapdispensers
o disposablepapertowels
o dustbinswithlids
o Visiblesigninginrelevantlanguages
Page 10
ExampleofsignS
Eatingfacilitiesforpersonnel
Eatingfacilitiesmustbeseparatetothepackhouse
Handbasinsmustbeinstalledattheentrancetothepackhouseforuseaftereating.
Personnelmustwashtheirhandsbeforeenteringthepackhouse
Thesebasinsmustbefittedwithliquidsoapdispensersanddisposable
papertowelsB
Basinsatanentranceofapackhouse
Providepaperhandtowels
Dustbinswithlidsmustbesupplied,emptiedandsterilizedonadailybasis.
Separate facilities where personal belongings can be stored during working hours
mustbeavailable.
Hygieneforpackhousepersonnel
Place food safety signs such as no eating, no smoking and wash hands in visible
placesinthepackhouse.
Page 11
Handsmustbewashedeverytimepersonnelenterthepackhouseoraftertheyhave
usedthebathroom.Handsmustbewashedwithanapproveddisinfectingsoap.
Nojewelrysuchasearrings,chainsorringsexceptforweddingringsandwatches.
Hairmustbecoveredbymopcaps.
Beardandmoustacheshouldbecovered.
Fingernailstobekeptshortandclean.
Anycutsorabrasionsornoninfectioussoresmustbekepteffectivelycoveredbya
coloredfirstaiddressing(plaster).
Coloredglovesshouldbeusedtocoverdressingsonhands.
Smokingindesignatedareasonly.
HealthIssues
Staff must exclude themselves from the pack house if they are suffering from any
diseaseorconditionliabletobetransmittedviafood,including:
o Sores,boilsorinfectedcuts,
o AnyIntestinalinfection,
o Followingcontactwithanyonesufferingfromanyoftheaboveconditions.
Protectiveclothingshouldbecleanatalltimesandinagoodcondition.
Clothingshouldnothaveoutsidepocketsduetofoodcontaminationhazards.
Pesticides and associated equipment should not be allowed to come into contact
withfood,foodcontainers,packingmaterialorworkingsurfaces.
Anymixingofpesticidesshouldtakeplaceexternaltothepackhouseperimeter.
AnyPesticidespillageshouldbereportedtothepackhousemanagerimmediately.
Pest control equipment must be kept in such a condition that there can be no
spillageorleakingofmaterial.
HandWashing
Handsmustbewashedaftervisitingbathroomsandamenityareas.
Alwayswashhandsafterhandlingpesticides.
Wheneverdirtyorcontaminated.
Handsmustbewashedonenteringanyfoodassociatedarea.
Approvedliquidsoapmustbeused.
Papertowelsandcovereddustbinstobeprovided.
HACCP Manual for Afghan Grape Pack Houses
Page 12
Examplewashroomlayoutandsignage
Dispenserforhandsanitizer
Signforhandwashinginstructions
Page 13
5 RodentsandInsectControl
Rodentsandinsectsarecommonaroundpackhouses;therefore,itisimportanttocombat
them to prevent contamination of food in the pack house. The pack house manager will
develop a plan for monitoring and controlling insects and rodents. The plan will include a
descriptionofthetypesofcontrolandmonitoringunitsareused,theirlocationinthepack
house.Onapackhouseplan,nameeachareainthepackhouseandmarkwhereeachinsect
or rodent control unit is. Number and indicate the type of each insect or rodent (bait
station) control unit or monitoring unit on the plan. The pest control plan will include a
schedule for inspecting and maintaining the insect and rodent control units, a form for
recordingobservationsandactionstakenandwillgivethenameofthepersonresponsible
formakingtheinspectionsandmaintainingthecontrolunits.
Identifyareaswhererodentactivityinspectionistobeheld.
Externalrodenttrapsmustbeinstalledaroundtheoutsideofthepackhouse.
Internalrodenttrapsmustbeinstalledinhighriskareasinsidethepackhouse.
Insectmonitors(stickyboardtype)canbeinstalledinsidethepackhouse.
Mothpheromonetrapscanbesuspendedinsidethepackhouse.
Electric insect killing equipment can be used as long as there is no danger of
contaminationofgrapesinsectsfallingintograpesorcartons.
Conductregularinspectionsandmaintenanceofinsectandrodenttraps.
On inspection, the responsible person must complete a rodent and insect activity
formandsignit.
SeeexampleofrodentactivityforminAnnex7
Electricinsectkillingdevice
Stickyboardinsecttrap
Rodenttrap
Useofpesticidesinthepackhouse
Accreditedpesticidesmustbeusedinandaroundthepackhouse.
Onlyusepesticidesasprescribed.
Theuseofsafetyequipmentmustbeadheredto.
Afterusepesticidesmustbestoredinthedesignatedarea.
Handsmustbewashedafteruse
HACCP Manual for Afghan Grape Pack Houses
Page 14
Whenpesticidesareusedinandaroundthepackhouseanactionreportisrequired
stating:
Reasonforuse
Areaofuse
Methodofapplication
Commercialnameofpesticide
Quantityofpesticideused
Nameofapplicator
Dateoffollowupinspection
RodentTrap
NB;Allbaitsandpesticidesmustmeettheclientstandards
BaitStations
Mustbeweatherresistantandnonabsorbent
Accesspanelmustbesecurelyattachedi.e.lockable
Strongenoughtoresistentrybynontargetspecieslikecatsanddogs
Entranceholeswhichonlyallowtargetanimals
Internaldesignshouldpreventspillage
Shouldnotbeattractivetochildrennobrightcolors
Properprecautionarystatementmustbedisplayedonbox
Date of inspection of bait boxes must be clearly recorded inside the lid of the box
withpermanentmarker,inspectorsnametobenotedateachvisit
Keystopreventaccesstotheinteriorofboxtobeleftonsiteinthecareofthepack
housemanager
Positionsofbaitstationsmustbemarkedonafloorplanofthepackhouse.
Sign boards should be used to indicate the location of rodent bait stations. See
examplesignbelow.
Page 15
Exampleofboardmarkingrodentbaitstation
Page 16
6 Conclusion
TheprocessofimplementingaHACCPstrategyintheAfghanTableGrapeIndustryispartof
ourresponsibilityasproducersandpackerstoourreceiversandthefruitbuyingpublic.We
mustensurethatthatFoodSafetyistreatedwithasmuchimportanceasProductionand
Packing.Implementingthe7HACCPPrinciples(summedupinthequestionWhatcango
wrong?)ensuresthatwecandelivergrapestoourmarketswithoutfearofcontaminants,
betheyMicrobial,BiologicalorPhysical.HavingaproperlyimplementedHACCPPlangoesa
longwaytoensureeventualaccreditationforGLOBALGAPwhichistheprerequisitefor
entryofgrapestoClass1markets.
HACCPisnotjustachecklistoftasks;itmustbeamindsetwhichensuresFoodSafetyfrom
theVinetotheTable.
Page 17
7 ANNEXES
7.1 ANNEX1TRAININGREGISTER
Date
From
Time
To
From
Natureof
course/training
orlecture
To
NamelistNo
Signatureof
packhouse
manager
Page 18 of 33
7.2 ANNEX2NAMEREGISTERFORTRAININGEVENTS
NameofCourse,TrainingorLecture:__________________________________
NameorpersongivingTraining:______________________________________
ListNo:__________________
Date
Nameof
Trainee
Comments
Signatureof
Trainee
Signatureof
Trainer
Page 19
7.3 ANNEX3PACKHOUSEINSPECTIONREGISTER
Date:_________________Thisinspectionshouldbecarriedoutonceperday.
Nameofresponsibleperson:__________________________________
Order Area/Item
Condition
Problem
Signatureof
No
1
Packingmaterialstore
2
Packhousefloor
3
EmptyPickingbaskets
4
Clippingtables
5
Gradingarea
6
Weighingstation
7
Packingtables
8
Closingarea
9
Labelingarea
10
Toilets
11
Handwasharea
12
Lightsandlightcovers
13
Areaaroundthepackhouse
Page 20
7.4 ANNEX4MEDICINE/PLASTERREGISTER
Nameof
personne
l
Dat
e
Diagnosis/Injury/Plaste
r
Typeof
medicine
prescribe
d
Dosage/amoun
t
Signature
of
superviso
r
Page 21
7.5 ANNEX5BATHROOMCLEANINGREGISTER
Nameof
responsibl
eperson
Dat
e
Toilets
cleane
d
Hand
basin
cleane
d
Floors
swept
&
washe
d
Bins
emptie
d&
cleaned
Soap
Problem
dispenser s
s&paper
towels
Signature
of
superviso
r
Page 22
7.6 ANNEX6PERSONALHYGIENEREGISTER
Nameof
responsibl
eperson
Dat
e
Hands
washe
d
Jewelry
remove
d
Hair
covere
d
Protectiv
e
clothing
General Problem
neatnes s
s
Signature
of
superviso
r
Page 23
7.7 ANNEX7PESTCONTROL/TRENDREPORT
Nameofresponsibleperson______________________________________
Date_________________________Thisinspectionshouldbecarriedandrecorded3
timesaweek.
NameofPest
Quantityfound
Signature
Rats
Mice
AmericanCockroach
GermanCockroach
Ants
Storedproductmoths
Storedproductbeetles
Fishmoths
Birds
Others
Infestationdetailrecord
ThefollowinginformationshouldappearontheInfestationRecord:
0=NilInfestation
CR=CrawlingInsects
R=Rats
SPI=StoredProductInsects
M=Mice
B=Birds
C=Cockroaches
Page 24
7.8 ANNEX8CHEMICALSPRAYREGISTER
Nameofproducer____________________________________
Nameofresponsibleperson____________________________
Date
Commercial
Active
Dosage
Reasonfor
nameof
ingredient
per100L application
spray
water
Signatureof
operator
Page 25
7.9 ANNEX9EXAMPLEOFAPACKHOUSECLEANER:SPOREKILL
SPOREKILLSACITIVITYISTESTEDANDPROVEDBY
VARIOUSSOUTHAFRICANRESEARCHINSTITUTES*
AGAINSTPLANT&HUMANPATHOGENICMICRO
ORGANISMS
Plantpathogenicbacteria:Acidovorax,Clavibacter,Erwinia,
Pseudomonas,Ralstonia,Streptomyces,Xanthomonas,Xylophilus
Otherpathogenicbacteria:Acinetobacter,Agrobacterium,Bacillus,
Bordetella,Clostridium,Corynebacterium,E.coli,Haemophilus,
Klebsiella,Lactobacillus,Micrococcus,Ornithobacterium,Pasteurella,
Proteus,Pseudomonas,Salmonella,Shigella,Staphylococcus,
Streptococcus,Vibrio
Plantpathogenicfungi:Alternaria,Aspergillus,Botrytis,Cercospora,
Colletotrichum,Fusarium,Geotrichum,Mildews,Monilinia,Penicillium,
Phoma,Phytophthora,Pythium,Rhizoctonia,Sclerotinia,Sclerotium,
Septoria,Stemphylium,Verticillium
Otherpathogenicfungi:Aspergillus,Candida,Saccharomyces,
Trichophyton
Alsovariousviruses,mycoplasma,andalgae.
SOUTHAFRICANRESEARCHINSTITUTES
ARCInfruitecNietvoorbij
ARCPlantProtectionResearchInstitute
ARCRoodeplaat
Outspan(Capespan)
SouthAfricanBureauofStandards(SABS)
UniversityofPretoria
UniversityofStellenbosch
UniversityoftheFreeState
DuRoiQMSandPathologicalServices
HACCP Manual for Afghan Grape Pack Houses
Page 26
CRI(CitrusResearchInternational)
MaterialSafetyDataSheet
ICAInternationalChemicalsPtyLtd
28PlankenStreet
PlankenbrugIndustrial+27(0)218869812(Tel)
Stellenbosch+27(0)218868209(Fax)
7600
SouthAfrica
1)Dateissued:29/10/2003
2)MaterialIdentification:
Productname:Sporekill
CASnumber:Seesection3
Molecularformula:Mixture
Chemicalname:(active)N,NDidecylN,NdimethylammoniumChloride
3)Hazardouscomponent:
Chemicalname:N,NDidecylN,NdimethylammoniumChloride
CASno:7173515
Approx.Wt%:12%
ExposureLimit:Noneestablished
4)PotentialHealthEffects:
Primaryrouteofentry:
Skincontact:(X)Eyecontact:(X)Inhalation:(X)Ingestion:(X)
Effectsofoverexposure:
Basedonanimaltestdataonthismaterialandadjustedforthepercentageactive
concentration,thefollowingeffectscanbeanticipated:Directskincontactcanproduce
slightirritation.Directeyecontactwillproduceseveredamagetoeyes.Inhalationofspray
mististoxicandcancauseirritationanddamage.Ingestionmaycauseimmediateburning,
paininthemonth,throatandabdomen,andswellingofthelarynx.
Overexposurethatmayaggravateexistingconditions:
Noeffectsindicated.
Materiallistedascarcinogen:
NationalToxicologyProgram:No
I.A.R.CMonographs:No
O.S.H.A:No
5)FirstAidMeasure:
Skincontact:
Forskincontact,washwithplentyofrunningwaterandsoapifavailablefor15minutes.
Removeandcleancontaminatedclothingandshoes.
Eyecontact:
Foreyecontact,immediatelyflusheyeswithrunningwaterforatleast15minutes.Hold
eyelidsaparttoensurerinsingoftheentiresurfaceoftheeyesandlidswithwater.Get
medicalattention.
Ingestion:
Ifswallowed,give34glassesofmilk,eggwhites,gelatinesolution(ifunavailable,water).
DONOTinducevomiting.Ifvomitingdoesoccur,givefluidsagain.Getmedicalattentionto
determineifvomitingorevacuationofstomachisnecessary.
Inhalation:
Removepersontowellventilatedareaawayfromspraymist.
HACCP Manual for Afghan Grape Pack Houses
Page 27
Notetophysician:
Probablemucosaldamagemaycontraindicatetheuseofgastriclavage.Measuresagainst
circulatoryshock,respiratorydepressionandconvulsionmaybeneeded.
6)FireandExplosioninformation:
Flashpoint:64C
Decompositiontemperature:Notknown
Selfignition:Notknow
Lowerexplosionlimit:Notknow
Upperexplosionlimit:Notknow
Extinguishingmedia:Carbondioxide,DryChemical,Alcoholfoam,Water.
Specialfirefightingprocedures:None
7)Accidentalreleasemeasures:
Measuresafterspillage/leakage/release:
Dikeandcontainspillwithinertmaterial(sand,earth,etc.).Transferthesolidandliquidto
separatecontainerforrecoveryanddisposal.WereallowedbyFederal,Stateorlocal
regulations,thesimplestmethodofdisposalinvolvesdilutiontolowconcentrationsinorder
toallowthebiocidetodegradenaturally.Atlevelsbelow10partspermillion(active),no
detrimentaleffectsonfunctioningwastetreatmentsystemsortheenvironmenthavebeen
noted.
8)Specialprecautionsforhandling:
Packagingorbottlingmaterial;Recommended;PlasticTobeavoided;Metal
9)Exposurecontrols/Personalprotection
Ventilation:None
Respiratoryprotection:Preventinhalingspraymist
Protectivegloves:Userubbergloves,whenneeded,topreventskincontact.
Eyeprotection:Wearsafetyglasseswithsideshieldsundernormaluse
conditions.
Otherprotectiveequipment:Runningwatertotreatpossibleexposure.
10)Physicalanchemicalproperties
Form:Limpidliquid,colourless,foaming
Colour:Clear
Odour:Slightbittersmell,Bittertaste
Meltingpoint:Notapplicable
Boilingpoint:Notknown
Specificgravity:~1kg/Lat20C(IP365)
Bulkdensity:Notapplicable
Viscosity:70at25C(Brookfield)
CopperCorrosion:1(IP154)
Watersolubility:Soluble
Phvalue:58
Compatibility:Notcompatiblewithconcentratedanioniccompounds.
Tolerance:Tolerantofbothacidandalkalinemedium(3,59pH).
Inertchemicals:Doesnotcontainphenol,iodine,aldehyde,hypochloriteor
Bromide.
ICAInternationalChemicalsPtyLtd
11)Stabilityandreactivity:
Stability:
Stable(X)Unstable()
Conditionstoavoid:Notknown
Dangerouspolymerization:No
Page 28
Dangerousincompatibilitywithwater:No
DangerousReactions:WithStrongoxidizingagents
12)Toxicologyinformation:
Sporekill:
AcuteoralLD50(Rat):>4000mg/Kg
AcutedermalLD50(Rat):>2000mg/Kg
AcuteEyeIrritation(OECD405):Riskofseriousdamagetoeyes&codeR41
AcuteDermalIrritation(OECD404):Irritatingtoskin&codeR38
AcuteInhalationLC50rat:0.161mg/Lair
SkinSensitisationGuineaPig(OECD406):nonsensitizer
Mutagenicity
Salmonella:notmutagenicwithorwithoutmetabolicactivation
Notmutagenic
ForDidecyldimethylammoniumChloride:(Ames,CHO/HGPRT,CHO,DNASynthesis)
Rat:
Noevidenceofchromosomaldamageinthebonemarrowofratstreatedwith
2000mg/kg(12%active).
Reproductivetoxicity:
rat:notteratogenic
treatmentwith40to210mg/kgondays6to15gestation(12%active)
Rat:
ForDidecyldimethylammoniumChloride:noreproductiveeffectfortreatmentatorbelow
mildtoxiceffectslevel.
NotcastogenicinChinesehamsterovarycellswithorwithoutmetabolicactivation.
Subchronictoxicity:
Dermalrat:
Testperiod:90days
ForDidecyldimethylammoniumChloride:nosystemictoxicity
Chronictoxicity:
Oraldog:
Testperiod:1year
ForDidecyldimethylammoniumChloride:notargetorganeffects
Pharmacokinetics:
Dog:
ForDidecyldimethylammoniumChloride:thismaterialdoesnotaccumulateinbodytissues
13)EcotoxicologyandEcologyinformation
Fishtoxicity(LC50):
Salmon:
Testperiod:96hours
ForDidecyldimethylammoniumChloride(100%active):1mg/l
ToxicityforDaphnia(EC50):
Daphniamagna:
Testperiod:48hours
ForDidecyldimethylammoniumChloride(100%active):0,94mg/l
DietaryToxicityTest:
LC50oral:>5620ppm
ForDidecyldimethylammoniumChloride(100%active):(bobwhitequailandmallardduck)
AcutecontactLD50toHoneybee
Apismelliferra:
LD50>100ga.i./bee(relativelynontoxic)
Page 29
ForSporekill(12%active)
14)Transport:
NotclassedasaDangerousGoodbytheSouthAfricanandAustralianCodeforThe
TransportofDangerousGoodsbyroad,railandair.
WHOclassification:U(Unlikelytopresenthazardinnormaluse)
EUDangersymbols&RiskPhrases:Xn;R22C,R34
15)Disposalconsiderations
Disposal
Product:DisposeofincompliancewithallFederal,Stateandlocallawsandregulations.
Incinerationisthepreferredmethod.
Packaging:Disposeofcontainerafterthoroughrinse.Thenofferforrecyclingor
reconditioning,orpunctureanddisposeofinasanitarylandfill,orincineration,orifallowed
byauthorities,byburning.
Thisinformationconcernsonlytheproductconformingtoitsspecificationsandlimitsto
theuseshereinstated.Thissheetcomplementsthetechnicalsheetofusebutdoesnt
replaceit.Theinformationcontainedonthissheetisbasedonknowledgeoftheproduct
ondateofpublication.Itisgiveningoodfaith.
Page 30
Page 31