www.bibliophy.sup.

fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

‫ﻣﻜﺘﺒﺔ ﺍﻟﻌﻠﻮﻡ ﺍﻟﻔﻴﺰﻳﺎﺋﻴﺔ‬

http://www.bibliophy.sup.fr/

ELGHZIZAL’S DOCUMENTS SCRIBD 1

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

ELGHZIZAL’S DOCUMENTS SCRIBD 2

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

7pts : 
. "#(Acide Ibuprofène )   !     I 

. S0 ()) C0 &'(11
n m
C0 = =
V0 M .V0
0,75pt
0,2
C0 = ≈ 0,01mol.l −1
206 × 0,1
S0 ()) pH = 3,17 *+ (12
1,25pts . "#   ! ,- .!/ ( (121
?
 
 RCOOH + H2O RCOO- + H3O+



(mol) 



   0 C0.V0  0 0
  x C0.V0 – x  x x
   x = xf C0.V0 – xf  xf xf
   x = xmax C0.V0 – xmax  xmax xmax
5'6 4  0   ! 1 2 ,'#  3 
Xmax: 78+9 :;

-2 -1 -3
C0.V0 – xmax =0 ⇒ xmax= C0V0 = 10 .10 =10 mol
Xf .<=6 :;

[ ]
x f = n( H 3 O + ) = H 3 O + .V0 = 10 − pH .V0 = 10 −3,17.0,1 = 6,76.10 −5 mol

ELGHZIZAL’S DOCUMENTS SCRIBD 3

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà
 ! 1 @6# τ 〈1 ?3 τ =
xf
=
6,76.10 −5
= 6,76.10 − 2 = 6,76 0 0 τ .<=6 :; '>

x max 10 −3
:A#
- +
RCOOH + H2O
RCOO + H3O

: Qr  ! BCD (122

(0,5pts ) Qr = [H 3O ] [RCOO ]
+ − 2
i i x 2 / V0 x2
= =
[RCOOH ]i C 0 .V0 − x / V0 (C 0V0 − x.).V0
1pts : +G, : EF6 (123
: 6 Qr , #
2
x2 xf
Qr = ⇒ Qr ,éq =
(C0V0 − x.).V0 (C0V0 − x f ).V0
xf
τ= ⇒ x f = τ .xmax
xmax
τ 2 x 2 max τ 2 .x 2 max
⇒ Qr ,éq = =
V0 (C 0V0 − τ .xmax ) V0 ( xmax − τ .xmax )
τ 2 .xmax
Qr ,éq =
V0 (1 − τ )
0,75pts : *C  ! >; K    + (124
τ = 6,76.10 −2
xmax = 10 − 3 mol
V0 = 0,1L

Qr ,éq =K=
(
10 −3 6,76.10 − 2
= 4,9.10 − 5
)2

0,1(1 − 6,76.10 − 2 )
 JK 7) ' C; / # I; – II

0,75pts  ! A,#(21

RCOOH + HO − → RCOO − + H 2O
2 2 ; 3 6(22
ni ( HO − ) = C B .VB = 3.10 −2.60.10 −3 = 1,8.10 −3 mol
n A ( RCOOH ) = C0 .V0 = xmax = 10 −3 mol

(0,5pts) M  2A# K # K3 HO- L>3 2A# K 1 @6#

ELGHZIZAL’S DOCUMENTS SCRIBD 4

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà
: .; HO- 2,# (23
1pts : N 6 (321
.) ! O)P # 20ml . .; HO- 2A# K C A .V A,éq = n( HO − )rest
- C A .V A,éq = n( HO − )rest = 27,7.10 −3.10 −2 = 2,77.10 −4 mol
VB=60ml . ; HO 2A# K nT "#
nT ( HO − ) = 3.n( HO − ) rest = 8,31.10 − 4 mol
nr(HO-) = n0(HO-) – nT  "# ) ! HO- L>3 2A# K Q6'6
nr (HO-)= 1,8.10-3 – 8,31.10-4 = 9,69.10-4mol

0,5pts  )K (232

-
nr(HO ) = n(RCOOH) = mA/M(A)
-4
m(A) = nr.M(A) = 9,69.10 .206 =0,199g=0,2g ≈ 200mg
 JK 7) ' C; / 3 Q6'>

ELGHZIZAL’S DOCUMENTS SCRIBD 5

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà
2pts 5T (# . L;T _ 6 LR 1
. UV6  ,WX :A8 2> (1
24 β−
11 Na →1224 Mg + −10 e 0,5pts (11
0,69 ln 2
0,25pts λ= ≈ 1,28.10 −5 s −1 : @6# λ = 3 Y),> (12
15(3600) t1 / 2
(2
0,5pts . : . "V :A8 86 2A# K &'(21
: . ,W Z+6 >+ 5' n0 =C0.V0 = 10-3.5.10-3 =5.10-6 mol 5'6
−λt1 1, 28.10 −5 ×3 ( 3600 )
n1 = n0 e −6
= 5.10 e −
: @6# n = n0 .e − λt ⇔ N = N 0 e − λt
n1= 4,35.10-6mol [.L
0,25pts t1= 3h \) 6 6, UV> (22
a1 = λ .N1 = λ .N A .n1 = 3,35.1013 Bq
: ] ^- # A;! : Y  (23
n1= 4,35.10-6mol : 0 3h C# , @)K ] :A . 7;_ # 1 I_ # 
. n2 = 2,1.10-9 mol 0 V2 = 2ml Y : ) 
Y  _6 +G `60 1 @)K ' . '># \6# ! [ # 24 :A8 86 3 
] 6 : Y V &
#> : 24 :A8 86 2A# K

n2 = 2,1.10−9 → 2.10−3 L
n1 = 4,35.10−6 → V 0,5pts
4,35.10−6 × 2.10−3
⇒V = = 4,14 L
2,1.10−9

: 3 Q6'> VN =5L 0 ( :) +! b ) ?A, '> 6 : Y 3 

VP = VN – V =5,00 – 4,14 ≈ 0,86 L = 86mL

ELGHZIZAL’S DOCUMENTS SCRIBD 6

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

ELGHZIZAL’S DOCUMENTS SCRIBD 7

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

(5pts ) dF LR,_ c = : 2 

dF W : I 

1pts : )e! A, (11
U C (t ) + U R (t ) − E = 0
q = CU C (t )
dq dU C (t )
i= =C
dt dt
U C (t ) + Ri − E = 0
dU C (t )
⇒ RC + U C (t ) = E
dt
−t A,  # I; (12
τ
U C (t ) = E (1 − e )
−t
dU c (t ) E τ
= e
dt τ
: #
 , τ = RC ( E
−t −t
3 6 (13
⇒ RC. e + E (1 − e τ ) = E
τ

[R ][. C ] = [I ][. t ] × [U ] = [t ] τ
[U ] [I ] −t
RC
E( − 1)e τ = 0 ⇔ RC = τ , RC( fX
τ
>F @6 , #

 # (14
τ 1
C= = 3
= 10 − 4 F = 100.10 − 6 F = 100 µF
R 10.10

ELGHZIZAL’S DOCUMENTS SCRIBD 8

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà
0 ,75pts Y< :\6 . dF ^- # >
P : <= +T (15
1 1
E e = CE 2 = .10 − 4.12 2 = 7.210 −3 J
2 2
− t1
dF# g! – .>F 

U C (t1 ) = 360.e r .C
− 2.10 −3 1pts 6 UC(t) , #(21
⇒ 132,45 = 360.e r .10 −4

− 2.10 −3
r= = 20Ω
−4 132,45
10 ln
5' 360 @6# i/3 τ  3 5 dF) [_3 g! h (22
0,5pts i/ 3 #;# τ ' = rC ,

ELGHZIZAL’S DOCUMENTS SCRIBD 9

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

ELGHZIZAL’S DOCUMENTS SCRIBD 10

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

6pts Y\6 ;F (# . 5)/ Y'k U;_ _CA c j> 3 

 U;' _CA : (9 

 (1
: .>F > >+ (11
l68 : _C  
(01 : ;T m; Ak
= n T m;
:@6# O; @>  l68 "hP
∑F



= ⇔ =



i
ma P ma
. ;' +G, U;_1
⇒g=a

: 6 )b o,> ?M (O, i , j ) Y),

a x = 0 ⇔ Vx = C ste ⇔ x(t ) = V0 x t + x0
1 2
a y = g ⇔ y (t ) = a y t + V0 y t + y0
2

:LT, #
−1
. x ( t ) = − 50 t + 450 : @6# x 0 = x A = 450m  V0 x − 50ms ?3 V0 x 〈0 
y (t ) = 5t 2 : @6# y 0 = 0  a y = g = 10ms −2  V0 y = 0 

pC9 ]T' :TCR \(12

y(t) 6#
 A, # @6# ys = H= 405m  pC9 7X l68 8 ts \) 6
ys H
y s (t s ) = 5t s ⇒ t s =
2
= = 9s
5 5
: C' A,#(13
6#
 A, # #
 .8;>

ELGHZIZAL’S DOCUMENTS SCRIBD 11

www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà
x − 450
x ( t ) = − 50 t + 450 ⇒ t = −
50
2
 450 − x 
y = 5t ⇒ y = 5
2
( −2
 = 5 9 − 2 . 10 x )2

 50 
⇒ y = 2 . 10 − 3 x 2 − 1,8 x + 405

: ` U;' _CA : qF 

 (2
)e! A, (21
: 6 .>F >; 


dV
∑ F = P + f = m dt

: (0,


i ) 7) U;_
dV
− 100V + mg = m
dt
dV 150 100 100
= .g − V = 10 − V
dt 150 150 150
dV 2
= 10 − V
dt 3

: U;')
 #
    ' (22
.< :\6 2 ; ;(23

: . ( 3 ;- A (24

ELGHZIZAL’S DOCUMENTS SCRIBD 12
www.bibliophy.sup.fr@ óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà

a 4  V4 + A6
dV 2
= 10 − V )e! A, #
dt 3
∆t = 0,1〈〈τ "# V4 = a3 .∆t + V3   dV  2
a4 =   = 10 − V4 : 6
 dt  t4 3

V4 = 8,12 × 0,1 + 2,80 = 3,612ms −1 &' 

2 2
a 4 = 10 − V4 = 10 − × 3,612 = 7,59ms − 2 a4 &'
3 3 

6- * 5TP  >F <

! :), f_3 : ' (

i
: .>R  (8R k : ; oM0 ( I), 3 C'!_ 3 \G# K
h_elghzizal@hotmail.com
www.phy123.sup.fr : "+) [k 3

ELGHZIZAL’S DOCUMENTS SCRIBD 13