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. B+C# D#+1 Qr •
( D>
1E ) D>
+ Qr =K •
: =,!"#
FG (21
:
-
=
!
$" :%G (121
C6H5-COOH(aq) + H2O(l)C6H5-COO-(aq) + H3O+(aq) .1
2 Al(s) + 3 Cu2+ (aq) 2 Al3+ (aq)+ 3 Cu (s) .2
I2 (aq)+ 2 S2O32- (aq) 2 I- (aq)+ S4O62- (aq) .3
: 5
% -
: :&-
/
01 &2 / Qri = [C6H5-COO-]i.[H3O+]i/[C6H5-COOH]I .1
.1 H#8" ;
=I-
.( Al # Cu )
@
897
/
01 &2 / Qreq = [Al3+]²eq / [Cu2+]3eq .2
) J $ )-
!
)
+-
6
*7
% Qr = [I-]².[S4O62-]/([I2].[S2O32-]²) .3
.
σ = λ(H3O+).[H3O+]éq + λ(C6H5COO-).[C6H5COO-]éq
[H3O+]éq = [C6H5COO-]éq : (
ا
د ) و اول ا إا
σ "#$ % 'ض
σ = (λ(H3O+) + λ(C6H5COO-)).[H3O+]éq
[H3O+]éq = σ / (λ(H3O+) + λ(C6H5COO-))
[H3O+]éq = 2,03.10-2 / ( 35,0.10-3 + 3,23.10-3)
[H3O+]éq = 0,53 mol.m-3 [H3O+]éq
[H3O+]éq = 5,3.10-4 mol.L-1
K = Qr éq = ([H3O+]éq.[ C6H5COO-]éq)/[ C6H5COOH]éq .3
Qr ,init =
[C ]init [D ]init
c d
[A]init
a
[B]binit W A (aq) + b B (aq) = c C (aq) + d D (aq)
. !" / --
$^_ D>
" ) --
Qr,init = K o
2
www.bibliophy.sup.fr *
QI
K = 1,9 × 10 37 : D>
1E
:
K
.($b-
T5-
) V"
D" T5 ) !" -- Qr ,init 〈 K DG -1 # ; -
. L*F-
M-C 1 )+
:8C
.1
. -
--
),
!
T5 K+C .2
: =!
pKA 9#K-
: 5
4
www.bibliophy.sup.fr *
D>
1E# )+
*, : : --
!" T5 ++5 .2
. e*7
# L*F/
M-C 01 Q5
)-
!
K = Qréq = [HCOO-]éq.[NH4+]éq / ([HCOOH]éq.[NH3]éq)
: 012 34,5% [ H3O + ]
+,-
g1 ]8
# ,-
c$f*
K = ( [HCOO-]éq.[ H3O+ ]éq / [HCOOH]éq ) . ( [NH4+]éq /.( [ H3O+ ]éq .[NH3]éq))
= KA1 / KA2
: h#
K = 10 - 3,8 / 10 - 9,2 = 10 5,4 = 2,51.10 5 > Qrinitial
`S"# V"
KK>
Qrinitial KK>
T5 ) --
Di h# K 0 $?QG Qrinitial
.$b-
T5-
# U !
. =I-
4
# B+8%G " (23
:
5-
-*
C1 = 0,030 mol.L-1 N%$"(III) ++5
#
% 4
5 0V1 = 20 mL
C2 = 0,020 mol.L-1 j: N%$" (II) ++5
=$% 4
5 0V2 = 20 mL
C3 = 0,10 mol.L-1 : N%$" (II) R5
=$% 4
5 0V3 = 10 mL
R5
\58 010 g
Cu2+ / Cu # Fe3+ / Fe2+ : =9#K-
. I R5
1
K :%G .1
. 18
!
)+
:8C
.2
K = 3,8.10 40. : )!* . --
),
!
T5 K+C .3
5
:
K .1
3+ - 2+
Fe + e Fe ) x 2
Cu Cu2+ + 2 e- ) x 1
2 Fe3+ + Cu 2 Fe2+ + Cu2+
V = V1 + V2 + V3 = 5,0.10 - 2 L Wf* : G .2
6