Calculations

Surface Pressure & Surface Area per mole at Monolayer Formation

f
1
x ( ) 4 10
9

dyne
cm

mole x
cm
2
41.58
dyne
cm
+ :=
f
2
x ( ) 4 10
10

dyne
cm

mole x
cm
2
10.51
dyne
cm
+ :=
x1 1
cm
2
mole
:=
f
1
x1 ( ) f
2
x1 ( ) =
Given
f
1
x1 ( ) f
2
x1 ( ) =
x1 Find x1 ( ) 8.631 10
9

cm
2
mol
= :=

mono
f
1
x1 ( ) :=

mono
7.058
dyne
cm
=
T
room
294.15K :=
R 8.314 10
7

dyne cm
mole K
:=
A
m
T , ( ) R
T

:=
A
m

mono
T
room
,
( )
3.465 10
9

cm
2
mol
=
Surface Area per Adsorbed Molecule:
k
b
1.38 10
23

J
K
:=
T , ( ) k
b
T

:=

mono
T
room
,
( )
57.515 Angstrom
2
=
Orientation:
D A ( ) A
4

\
|
|
.
1
2
:=
A
normal
22Angstrom
2
:=
A
data
57.515Angstrom
2
:=
D
normal
D A
normal
( )
5.293 Angstrom = :=
D
data
D A
data
( )
8.557 Angstrom = :=
acos
D
normal
D
data
|

\
|
|
.
51.795 deg =
Orientation Relative to Surface is 90*-Angle Between

relsurf
90deg 51.795deg ( ) 38.205 deg = :=
Thickness of Monolayer
A
mono
A
m

mono
T
room
,
( )
:=
Z
mono
MW , A
m
,
( )
MW
A
m

:=

1prop
0.8034
g
cm
3
:=
MW
1prop
60.09
g
mol
:=
Z
mono

1prop
MW
1prop
, A
mono
,
( )
2.159 Angstrom =
Error Analysis
0.519
dyne
cm
:=
T 0.05K :=
A
m
T , ( )
T
A
m
T , ( )
d
d
|

\
|
|
.
2
T ( )
2

A
m
T , ( )
d
d
|

\
|
|
.
2
( )
2
+

(
(

1
2
:=
A
mono
A
m
T
room

mono
,
( )
:=
A
mono
2.548 10
8

cm
2
mole
=
Z A
m
,
( )
A
m
Z
mono
MW
1prop
, A
m
,
( )
d
d
|

\
|
|
.
2
A
mono
( )
2

(
(
(

1
2
:=
Z
1prop
A
mono
,
( )
0.159 Angstrom =
Z.mono = 2.159+/- 0.159 Angstroms
Percent Error of Surface Tension of Water vs. Last Dilution:
Error
water

lastdilute
,
( )

water

lastdilute

water
100 % :=

water
72.65
dyne
cm
:=

lastdilute
73.107
dyne
cm
:=
Error
water

lastdilute
,
( )
0.629 % =