CHEMISTRY

IIT-JEE 2012
PAPER - 2

Hkkx - II : jlk;u foKku

[k.M

- I : ,d y lgh mkj iz
d kj

bl [k.M esa8 cgqfod Yi iz'u gSA gj iz'u d spkj mkj fod Yi (A), (B), (C) vkSj (D) gS]ft uesals,d gh lgh gSA

21.

Ans.
Sol.

NiCl2 {P (C2H5)2 } (C6H5)}2 rki vkfJr pq

Ecd h; O;ogkj vuqp qEcd h; (paramagnetic) / izfrpqEcd h; (diamagnetic)
2+
fn[kkrkgSA NI d hvuqp qEcd h; vkSj iz
frpqEcd h; voLFkkes
amilgla
;ks
t u T;kfefr;k(coordination gemetries) e'k%
(A) prq
"Q y d h; (tetrahedral) vkSj prq
"Q y d h; (tetrahedral) gSA
(B) oxZlery h; ( square planar) vkS
j oxZlery h; (square planar) gSA
(C) prq
"Q y d h; (tetrahedral) vkSj oxZlery h; (square planar) gSA
(D) oxZlery h; (square planar) vkS
j prq"Q y d h; (tetrahedral) gSA
(C)
[NiCl2 {PEt2Ph}], es
aNi2+ d k by sDVkfud foU;kl fuEu gSa%]
Ni2+ = [Ar] 3d84s0

mPp p .k voLFkk esa, ;g vuqp qEcd h;]sp3 lad fjr]prq"Q y d h; gksrk gSA
U;wu p .k voLFkk esa;g izfrpqEcd h;]dsp2 lad fjr]oxkZd kj lery h; gksrk gSA
22.

t yh; NaOH vkjS 'orsQ kLWQ kjsl (white phosphorus) d slkFkvfHkf ;kea
sQ kLWQ hu (phosphine) vkjS ,d nw
l jkQ kLWQ kjsl
;qDr ;kSfxd cursgSA vfHkf ;kiz
d kj ( reaction type) Q kW
LQ ks
jl d hvkW
Dlhd j.kfLFkfr (oxidation state) Q kW
LQ hu es
avkS
j
nwl jsQ kWLQ ksjl ;qDr ;kSfxd esa e'k%
(A) vi;ks
ipu vfHkf ;k(redox reaction) ; 3 vkSj 5 gSaA
(B) vi;ks
p u vfHkf ;k(redox reaction) ; 3 vkSj +5 gSaA
(C) vlekuq
ikrhvfHkf ;k(disproportionation reaction) ; 3 vkSj + 5 gSaA
(D) vlkeuq
ikru vfHkf ;k(disproportionation reaction); 3 vkSj + 3 gS
aA

Ans. (C)
Sol.

Na3PO4 rFkkPH3 es
aQ kWLQ ksjl

RESONANCE

d hvkWDlhd j.kvoLFkk+5 rFkk3 e'k%gSaA ;g fo"kekuqikru vfHkf ;kgSA

Page # 1

CHEMISTRY
23.

vt ZsUVkbV v;Ld (argenite ore ) lspknhd slk;ukbM fu"d "kZ.kiz e esiz;ksx fd ;st kusoky svkWDlhd kjd o vipk;d
d eZd (oxidizing and reducing agents) e'k%gSA
(A) O2 vkS
j CO
(B) O2 vkS
j ;'knjt (Zn dust )
(C) HNO3 vkS
j (Zn dust )
(D) HNO3 vkS
j CO

Ans.
Sol.

(B)

flYoj d sfu"d "kZ.k esaAg2S d k ok;qd hmifLFkfr esaKCN d slkFkfu{kky u (leached) fd ;kt krk gSA
Ag2S + NaCN + O2

Na [Ag(CN)2] + Na2S2O3

bl iz
d kj O2 vkW
Dlhd kjd gSA
2Ag(CN)2 + Zn [Zn(CN)4]2 + 2Ag
24.

ean fLFkfr (mild condition) esa

]lclsvf/kd ljyrklsfod kcksZfDly d j.k(decarboxylation) gks
usoky k;kSfxd fuEu gSA

(A)

(B)

(C)

(D)

Ans.
Sol.

(B)

25.

fn, gq, mikkd kiz;ksx d j]C2H2 esa,d CC cakd hcgqv kcUk t kZ(multiple bond energy ; kJ mol1) d kifjd y u
d hft ,A og t kZfuEu gS(CH cak d h cUku t kZ350 kJ mol1 y sa)

Ans.

fod kW
cks
ZDlhyhd j.kes
a-d kcZu vkos'kxz
fgr d jrkgSA t c Hkh vkos
'kLFkk;hRo izkIr d jrkgS]fod kW
cks
ZDlhyhd j.kljy
gkst krk gSA (B) esa;g C = O d s ,oam lsLFkk;h gksrk gSt ksfn, x, fod YiksaesaloksZke gSA

2C(s) + H2(g) C2H2(g)

H = 225 kJ mol1
2C(s) 2C (g)
H = 1410 kJ mol1
H2(g) 2H(g)
H = 330 kJ mol1
(A) 1165
(B) 837
(C) 865
(D)

(D) 815

Sol.

26.

H = +1410 + 330 (350 2) CC = + 225

CC = 1740 700 225 = + 815 KJ/mol.

XeO2F2 v.kqd kvkd kj fuEu

gS
A

f=kleurk{kf}fijS
feMh(trigonal bipyramidal)
(C) prq
"Q y d h; (tetrahedral)
(A)
Ans.

oxZlery h; (square plannar)

(D) <S
d qy h;kofy roxZ(see-saw)
(B)

(D)

RESONANCE

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CHEMISTRY
Sol.

XeO2F2 f=kd ks
.kh;

f}fijkfeMh; T;kferh; j[krkgS

A fuj{kh; fLFkfr ij ,d kd hbys
S
DV
kW
u ;q
Xe mifLFkr gks
usd sd kj.klh&lkW

vk fr gksrhgSA

27.

nh xbZf ;k vuq e esaeq[; mRikn H D;k gS

CN

95% H SO

2
4

H
CH3CH2COCH3 G
"ek

Ans.

(A)

(B)

(C)

(D)

(B)
95% H SO

CN

Sol.

28.

HCN

,d vok"i'khy fo|qr vui/kj; (non-volatile non-electrolyte) foy s; d s 2.5 g d ks100 g ikuh esa?kksy uslscusruq
foy ;u d sfy ,]ikuhd sDoFkukad (boiling point) d ksmUu;u , 1 atm ij 2C lsgksrkgSA foy s; d hlkUnzrkd ksfoy k;d
d hlkUnz
rklscgq
r d e ekursgq
, foy;u d kok"i nkc (vapour pressure mm of Hg) fuEu gS( Kb = 0.76 K kg mol1 ys
)
a
(A) 724

Ans.
Sol.

2
4

(B) 740

(A)
Tb = 2C ;

(C) 736

(D)718

ma = 2.5 g
msolvent = 100 g
Kb = 0.76 K. kg. mol1
Psolution = ?

Tb = Kb m
2 = 0.76 m

m=

P0 P
= m MM 103
P

760 P =

36
P
760

2
0.76

2
760 P
=
18 103
0
.
76
P

760 =

796
P
760

796
torr = 725.6 torr 724 torr
P = 760
760

RESONANCE

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CHEMISTRY

[k.M

- II : v uq
PN sn izd kj
bl [k.M esas3 v uqPN snksa(Paragraphs) l sl EcfU/kr 6 cgqfod Yi iz'u gSaA ft u esalsvuqPNsn ij nksiz'u gSaA gj iz'u
d spkj mkj fod Yi (A), (B), (C) vkSj (D) gS]ft uesalsd soy ,d l gh gSA
iz'u 29 l s30 d sfy , v uqPN sn
fn;k gqv kfo|qr jklk;fud lsy ,d lkanzrk lsy gSA
M|M2+ ,d vYifoy s
; y o.k d k lar`Ir foy ;u MX2)|| M2+ (0.001 mol dm3) |M
bld klsy foHko (emf) nksuksaby SDVksM ksaM2+ vk;u d hlkanzrkij fuHkZj gSA bl lsy d kemf 298 K rki ij 0.059 V gSA
29.

Ans.
Sol.

fn;sx, lkanzrk lsy d smikr (data) d svk/kkj ij MX2 d sfoy s;rk xq.kuQ y (Ksp ; mol3 dm9) d k 298 K ij eku D;k
gS\ (2.303 R 298/F = 0.059 V y sa)
(A) 1 1015
(B) 4 1015
(B)
M|M2+ (aq) || M2+ (aq) | M

(C) 1 10 12

(D) 4 1012

0.001 M

,uksM :
d SFkks
M:

M M2+ (aq) + 2e
M2+ (aq) + 2e M
____________________________
M2+ (aq)c
M2+ (aq)a

Ecell = 0

M2 (aq)
0.059
a
log
3
2

10

0.059 =

M2 (aq)
0.059
a
log
3
2

10
M2 (aq)
a

10 3

2 = log

102 103 = M2+ (aq)a = foy s

;rk = s
Ksp = 4s = 4 (105)3 = 4 1015
3

30.

fn, x, lsy d sfy , G (kJ mol1) d k eku D;k gS\ (1F = 96500 C mol1 y sa)

Sol.

(A) 5.7
(B) 5.7
(C) 11.4
G = nFEcell = 2 96500 0.059 103 kJ/mole
= 11.4 kJ/mole

(D) 11.4

iz'u 31 l s32 d sfy , v uqPN sn

foja
t d pw
.kZ(bleaching powder) vkS
j foja
t d foy;u d kcMhek=kkes
amRikn fd ;kt krkgS
A bud kiz
;ks
x d bZ?kjs
y wmRiknks
a
esagksrk gSA fojat d foy ;u d h d k;Z{kerk vDlj vk;MsfefV(iodometry) esaekih t krh gSA
31.

Ans.

?kjsy wfojat d (bleach) foy ;u d s25 mL d ks0.50 M KI d s30 mL vkSj 4N ,sl hfVd vEy (acetic acid) d s10 mL d s
d slkFkfey k;kx;kA fuLrkfjr iodine d sva
rh; vuq
ekiu (end point titration) d sfy;s0.25 N Na2S2O3 d s48 mL yxs
A
?kjsy wfojat d foy ;u d h eksy jrk D;k gS\
(A) 0.48 M
(C)

RESONANCE

(B) 0.96 M

(C) 0.24 M

(D) 0.024 M

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CHEMISTRY
Sol.

gkbiksd sfey h eksy = 0.25 48

= 2 Cl2 d sfey h eks
y
Cl2 d sfey h eks
y =

0.25 48
=6
2

fey h eksy

= Cl2 d sfey h eks

y = CaOCl2 d sfey h eksy

blfy ,] eksy jrk =

32.

Ans.
Sol.

6
M = 0.24 M
25

fojat d pw.kZ(bleaching powder) esavU; mRiknksad svy kok ,d vkWDlksv Ey (oxoacid) d k y o.k Hkh mifLFkr gSA ml
vkWDlks
v Ey d k,ugkbMkbM (anhydride) fuEu gSA
(A) Cl2O
(A)
CaOCl2 = Ca(OCl)Cl
OCl gkbiksDy ks
jkbV

(B) Cl2O7

(C) ClO2

(D) Cl2O6

vk;u
t ksfd HOCl d k_ .kk;u gSA
HOCl d k,ugkbM
kbM = Cl2O
iz'u 33 l s34 d sfy , v uqPN sn
fuEufy f[kr vfHkf ;k vuq e esaJ ,d e/;orhZ;kSfxd gSA
( i ) H2 ,Pd / C
(CH3 CO)2 O
K
I CH COONa J
( ii ) SOCl 2
3
y ( anhyd.) AlCl3
( ii ) fut Z

J (C9H8O2) NaHCO3 d slkFkfoos

p u (treatment) d jusij cq
ncq
nkgV

vkS
j ld kjkRed ck;lZijh{k.k(Baeyer's test) ns
rk

gS
A
33.

;kSfxd K fuEu gSA

(A)

Ans.

(C)

34.

;kSfxd fuEu gS

(A)

Ans.
Sol.

(B)

(C)

(D)

(B)

(C)

(D)

(A)
(33 to 34)
( CH3CO )2 O

H2 Pd / C

CH3COONa

SOCl2

RESONANCE

AlCl3

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CHEMISTRY

[k.M

- III : cgq
y l gh mkj izd kj
bl [k.M esa6 cgqfod Yi iz'u gSaA gj iz'u d spkj mkj fod Yi (A), (B), (C) vkS
j (D) gS]ft uesals,d ;kvf/kd lghgSA
35.

xzsQ kbV (graphite) vkSj ghjs(diamond) d slanHkZesad kSu izd Fku lghgS@ gSa\
(A) xz
sQ kbV ghjslsd Bksj gSA
(B) xz
sQ kbV d h oS| qr pky d rk (electrical conductivity) ghjslsvfkd gSA
(C) xz
sQ kbV d h "ek pky d rk (thermal conductivity) ghjslsvfkd gSA
(D) xz
sQ kbV d kCC vkcak e (bond order) ghjslsvfkd gSA

Ans.
Sol.

(BD)
(A) ghjk]xz
sQ kbV

36.

fn, gq, I , II, III vkSj IV js[kkfp=k(data), ean rki e o nkc (moild temperature and pressure) ij] fofHkUu HkkSfrd
vf/k'kks"k.ko jklk;fud vf/k'kks"k.kiz eksa d hlkekU; izo`fkfn[kkrsgSA fuEufy f[kr esalsI,II, III vkSj IV d slanHkZesad kSu
fod Yi lgh gS@ gSa\

d h rqy uk esad Bksj gksrk gSA

(B) xz
sQ kbV]ghjsd h rqy uk esaoS| qr d k vPNk pky d gSA
(C) ghjk]xz
sQ kbV d h rqy uk esa "ek d k vPNk pky d gSA
(D) xz
sQ kbV d k cU/k e ( ~ 1.5) > ghjsd k cU/k e ( = 1)

(i)

(ii)

(iii)

(iv)

(A) I HkkS
frd vf/k'kks
"k.kgSvkSj II jklk;fud vf/k'kks
"k.kgS
(C) IV jklk;fud vf/k'kks
"k.kgSvkSj II jklk;fud vf/k'kks"k.kgS
Ans.
Sol.

(B) I HkkS
frd vf/k'kk"sk.kgSvkS
j III jklk;fud vf/k'kks
"k.kgS
(D) IV jklk;fud vf/k'kk"
sk.kgSvkjS III jklk;fud vf/k'kk"sk.kgS

(AC)

HkkSfrd vf/k'kks
"k.kesafu;r nkc ij rki esao`
f) d slkFkvf/k'kks
"k.kes
ad ehgksrhgSt cfd jklk;fud vf/k'kks
"k.kes
arki es
ao`
f)
d slkFklf ;.k t kZd hvko';d rkd sd kj.kleku nkc ij vf/k'kks"k.kesao`f) gksxhA vr%I HkkSfrd vf/k'kks"k.kgSt cfd
II jklk;fud vf/k'kks
"k.kgS
A
III HkkS
frd vf/k'kks"k.kgSA rki esao`f) d slkFkvf/k'kks"k.kd hijkl esad ehgksrhgSA
IV jklk;fud vf/k'kks
"k.k(ca
/kfuekZ
.kd sd kj.k) d snkS
jku ,UFkS
YihifjorZ
u (t ksfd vf/kd gS
)A vr%;g jklk;fud vf/k'kks
"k.k
d sfy , ekU; gSA
vr%mkj (A) rFkk (C) gSA

RESONANCE

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CHEMISTRY
37.

Ans.

fn;sgq
, js
[kkfp=kes
a,d vkn'kZxS
l d sfy, : n~
kks
"e (adiabatic) vkS
j lerkih(isothermal) voLFkkvkases
amR e.kh; iz
l j.k
(reversible expansion) fn[kk;kx;kgS
A fuEufy f[kr izd Fkuksaesalsd kSu izd Fku lghgS@ gSa\

(A) T1 = T2
(C) wisothermal > wadiabatic
(AD)

(B) T3 > T1
(D) Uisothermal > Uadiabatic

Sol.

(A) T1 = T2 (lerkih;

gksusd sd kj.k)
(B) T3 > T1 (vlR;) : ) ks
"eh; izl kj esa'khry u gksxk)
(C) W isothermal > W adiabatic { fpUg d slkFk];g vlR; gS
A}
(D) Uisothermal = 0 > Uadiabatic = ve
vr%mkj (A) rFkk (D) gSA
38.

fuEufy f[kr t y h; vfHkf ;kvksad slanHkZesafn, gq, izd Fkuksaesalsd kSu izFkd u lgh gS@ gS\

Ans.

(A) iz
Fke vfHkf ;k,d vip;ksip; vfHkf ;kgS
(B) 'os
r vo{ks
i Zn3[Fe(CN)6]2 gS
A
(C) fQ YVfjr d ksLVkpZ(strach) d s?kks
y uhy k(blue) jax
(D) 'os
r vo{ksi NaOH d s?kksy esa?kqy t krk gSA
(ACD)

RESONANCE

nsrk gSA

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CHEMISTRY
Sol.

(D) NaOH d slkFk

K2Zn [Fe(CN)6] + NaOH [Zn(OH)4]2 (aq) + [Fe(CN)6]4 (aq)
39.

fuEufy f[kr Ld he (scheme) esaT, U, V vkSj W d slanHkZesa]fn, izd Fkuskaesad kSu izd Fku lgh gS@ gSa?

Ans.

(A) T xeZt y h; NaOH es

a?kqy u'khy gSA
(B) U /kz
o.k&?kw.kZd (optically active) gSA
q
(C) W d kvkf.od lw
=k (molecular formula)C10 H18O4 gS
A
(D) V d ht y h; NaHCO3 d slkFkvfHkf ;kd jusij cq
ncqnkgV
(ACD)

gksrhgSA

Sol.

RESONANCE

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CHEMISTRY
40.

M d sla
nHkZesaN, O, P vkSj Q d sckjsesad kSu

izd Fku lgh gS@ gS\

(A) M vkS
j N vizfrfcachf=kfoe

leko;o (non-mirror image stereoisomers) gS

A
(B) M vkS
j O loZl e: ih (identical) gSA
(C) M vkS
j P izfrfcac leko;oh: i (enantiomers) gSA
(D) M vkS
j Q loZl e: ih(identical) gSA
Ans.

(ABC)

Sol.

RESONANCE

Page # 9