Le Chateliers Principl

04252012 G U E R R E R O & A Q U I N O EG2

the o

bjectives

To predict the effects of changing the equilibrium systems conditions. To interpret the results based on the Le Chateliers principle.

the

concept

Chemical Equilibrium is the continuous formation of products, and formation of reactants from the products. In a chemical equilibrium, rates of the forward and backward reactions are equal. The concentrations of the reactants and products remain constant . This dynamic equal state can be interpreted as: A+BC

Le Chateliers Principle
If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change and re-establish equilibrium.
The Principle of Henry Louis le Chatelier (French chemist, 1850-1936)

significance

Le Chateliers principle lets us determine as to which direction a reaction is going towards.

Knowledge in chemical equilibrium is used in manufacturing technologies to ensure efficiency of products

a chemical equilibrium
1. Change in concentration Addition of reactants will produce more products (forward), addition of products will produce more reactants (backward) 2. Change in temperature Increase in temperature will push forward a endothermic reaction and push backwards if it is exothermic 3. Change in pressure or volume Increase in pressure has the same effect as a decrease in volume in gases and results to a push forward to a side with lesser gas molecules

disturbing

Equilibrium Constant
Keq is the equilibrium constant. It is the ratio of the concentration of products and reactants raised to their coefficients in a reaction at equilibrium. For hypothetical reaction A + B C + D

Keq = [moles of C]c [moles of D]d [Moles of A]a [moles of B]b

graphing rxns at equilibrium

METHODOLOGY
In a test tube: 1 mL 2.0M Cu(NO3)2 + 1.0 mL 2.0M NH4OH +5 mL distilled water.
Spot plate depressions (5 drops of previous solution) + 5 drops of 0.1M of

S A

B C

D E

On position I: 5 drops 0.1M K2CrO4 ] + 0.1 Pb(NO3)2 until ppt is complete + HCl dropwise until a change is observed

A: Cu(NO3)2 B: NH4OH C: K4FECN6 D: HCl E: NaOH F: NaNO3

F
Add dropwise 3M HCl until another color change. Observe. On position H: 5 drops 0.1M K2CrO4 + dropwise 6M HCl (stir every addition) until color changes. Observe.

Compare with depression S (H2O + Cu(NO3)2) as the reference

In a small test tube: 1mL previous solution obtained + 0.5mL water. Place in cold bath. Transfer 10 drops of this in position G. Compare with S.

the results
Position S A B C
D

observations

direction of reaction

Cloudy blue Reference (in equilibrium) Cloudy blue darker blue Cloudy blue darker blue Cloudy blue yellowish brown ppt Cloudy blue light blue (lightest) Cloudy blue light blue Same as S (no change) also cloudy blue Cloudy blue dark blue Forward Forward Backward Backward Backward No Shift Forward

E F
G

Pic 1: S E, Pic 2: F- I

discussion
With the solution obtained in the first step,

1 mL 2.0M Cu(NO3)2 + 1.0 mL 2.0M NH4OH +5 mL distilled water.

There is equilibrium. This reaction can be put as:

Cu2+ (aq) + 4NH3 (aq) Cu(NH3)42+ (aq)

Aqueous Cupric ion is sky blue, ammonia is colorless, and the Copper (II) Ammine Complex product is cloudy blue in color

discussion
In position A, there is an increase in reactant concentration, by adding Cu(NO3)2 thus the reaction shifts to the right and favors formation of products. There are more effective collisions because Cu(NO3)2 dissociates into Cu2+ ions which is a reactant. Thus, a forward shift. In position B, the same concept is applied. There is an increase in reactant concentration, by adding NH4OH thus the reaction shifts to the right and favors formation of products. There are more effective collisions because NH4OH increases the amount of NH3 reactants that will push the reaction forward.
That is why depressions A and B have a more darker solution color compared to S.

discussion
In position C, a yellowish-browsh precipitate was formed after adding K4Fe(CN)6. This dissociated into K+ and Fe(CN)6 4-. This ferrocyanide ion reacted with the Cupric ion, consuming the copper ions in the reactants. This causes the reaction to push backward so as to attain the loss in reactants. The color is caused by the Cu2Fe(CN)6 product.

DISCUSSIONS
In position D, addition of HCl dissociated into H+ ions. This ion reacts with NH3 to form NH4, decreasing the reactant. In order to relieve the stress, the reaction shift backward and thus a lighter solution. In position E, addition of NaOH dissociated to OH- and reacted with Cu2+, and just like in position D, it shifted backward, a lighter solution.

D I S C U S S I O N: Temperature

Change
Altering of temperature changes the equilibrium constant In reactions, we can treat heat, H, as a chemical reagent: Endothermic: Reactants + H product Exothermic: Reactants product + H
Increase in temperature: forward shift for endothermic, backward shift for exothermic. Increase in temperature, would be as if we increased the amount of a reactant, or a product, to the equilibrium system. The equilibrium shifts to the direction that consumes the excess reactant (or product), in this case, heat.

discussion
In position G, the solution became darker because the temperature was decreased and the reaction is an exothermic process. The shift is forward, causing the solution to turn darker.

discussion
For the part B of the experiment, there is equilibrium. This reaction can be put as:

2CrO42- + 2H+ Cr2 O7 2+ + H 2O

Chromate ion (2CrO4 2- )is yellow, Dichromate is orange. In position H, addition of HCl turned the potassium chromate tuned from yellow to orange. a forward reaction
The addition of NaOH turned the solution lighter and almost the same as the original one. a backward reaction

discussion
Adding HCl turned the solution acidic because the HCl dissociated into H+ and Cl-. The hydrogen ion reacted with Chromate ion (CrO4 2-), forming the Dichromate ion (Cr2O7 2-) which was the orange solution. The dichromate ion is the predominant species in the solution because the hydrogen ion dissociation. Thus, turned the solution from yellow to orange. When adding NaOH to the solution, the OH- ions dissociated from it and reacted with the H+, which consumes the reactant and forms more water, a product. This cause a backward shift to relieve the excess in products. Therefore chromate ion (Cr2O4 2-) is the predominant in the basic medium. This backward reaction cause the orange color to return to its yellow color again.

DISCUSSION
In position I, addition of if Pb(NO3)2 to K2CrO4, a yellow precipitate formed. This equilibrium is:

K2CrO4 2- + Pb 2+ PbCrO4
Potassium chromate is yellow, and the Lead (II) Chromate is the yellow precipitate
Addition of HCl turned the solution from yellow to orange, lessening the precipitate. The H+ ions of HCl reacted with the Chromate ion and formed Dichromate, thus a color change. The precipitate lessened because of chromate was consumed and shifted backward to the reactant side.

C O N C LU S I O N S & R E C O M M E N DAT I O N S
Equilibrium is a state in chemical reactions where the rate of formation of products is equal to the rate of formation of reactants.

In accordance to Le Chateliers principle, when there is a stress that is applied on this system. This stress shift the reaction towards the formation of products or reactants, depending on which relieves the stress. This principle was applied in the experiment. Change in concentration: Increase in products or decrease in reactants shifts reaction backwards, to form more reactants.

C O N C LU S I O N S & R E C O M M E N DAT I O N S
Errors in the experiment may be due to the inaccuracy in obtaining reagents or manipulating experimental variables such as changes in temperature. It is recommended to study the degrees of color differences in each test tube and note which is darkest and lightest among them.

Chang, R. (2010) Chemistry 10th Edition. McGraw Gill Publishing. New York. Le May, Brown. Chemistry: The Central Science. 2012. http://www.chemguide.co.uk/physical/equilibria/lechat elier.html http://dwb.unl.edu/calculators/activities/ChemEquilibri um.html http://www.pinkmonkey.com/studyguides/subjects/che m/chap11/c1111301.asp http://www.ourstory.info/library/3-FF/SLF/prof2.html Chemistry 18.1 Lab Manual Google Images

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