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Centrifuge
Decantate
Precipitate (Group I Cations: Insoluble clorides) Decantate + 2mL boiled H2O centrifuge and decant immediately (repeat)
B
Adjust pH to 0.5 by adding 6M NaOH/HCl
Precipitate
+ 5 drops 6M NH3 (stir to break ppt) then centrifuge and decant (repeat)
Yellow ppt Pb 2+ Precipitate (black) Group II Cations: Insoluble Sulfides White ppt Ag +
Precipitate (discard)
Decantate
Precipitate
Decantate
Precipitate
+ 15 drops 6M HNO3 heat in bath(few mins) & centrifuge
Precipitate (discard): Elemental S
Decantate
Decantate
+ 2-3 drops 6M HCl, centrifuge, decant (white ppt means theres lead)
Precipitate Decantate
+ 10 drops 1M NaOAc, heat to dissolve ppt
Yellow ppt Cd 2+
+pinch Na2S2O4, warm bath, centrifuge & discard ppt
If Blue, divide to 2
+ 2 drops 1M K2CrO4
Precipitate
Wash w/ few drps H2O
Decantate Precipitate
+ 10drps 1M HCl, centrifuge at once
Combine
Decantate
+ 3 drops 12M HCl + 1 drop 16M HNO3, heat in warm bath, Centrifuge
Precipitate (discard)
Decantate
No ppt? Proceed to E.
Precipitate
Decantate
Dissolve in 2 drps 4M HOAc + 4 drps 1M NH4Oac + 1 drp K2CrO4, centrifuge
Red ppt Ni 2+
No ppt?
Decantate
Flame test
Decantate
Green Flame Ba 2+
+ 1 drop 6M H2SO4
Precipitate
E
Group V Cations: Alkali metal and ammonium ions
White ppt Ba 2+
Crimson Flame Sr 2+
Dissolve white Ca2+ ppt with 2 drops 12M HCl, flame test
Decantate
Precipitate (discard)
+ 6M NH3 (basic to litmus) + 1 drop excess + 2 drops 1M Na2HPO4, centrifuge 1 drop 0.4M (NH4)2C2O4 + 1 drop (NH4)2SO4, centrifuge
Yellow ppt Mg 2+ Dissolve residue with 1mL H2O, transter in TT Dissolve with 2 drops 1m HOAc + 3 drops H20 + 1 drop titan yellow + 6M NaOH until basic
Decantate (discard)
No ppt? Go to D
White ppt Mg 2+
Decantate Precipitate
+ 6M HOAc to dissolve + 2 drops 0.2 K4Fe(CN)6 + 10 drops 0.2 KSCN
Decantate
Red Lake Al 3+
Yellow ppt Cr 3+
+ 1mL 4M HNO3 + 2 drops 1M NaNO3 (stir and heat in warm bath) Centrifuge Discard ppt (S) Decantate
Blue Soln Fe 3+
+ 6M HCl to dissolve ppt then heat
Red Soln Fe 3+
Purple Soln Mn 2+
CONTINUE
Use fresh sample only into a 50mL beaker. Moisten red litmus paper and place under small watch glass.
+ 10 drops 6M NaOH to sample and swirl stir. Cover with the watch glass
Heat. (DO NOT BOIL. NO LIQUID SHOUD TOUCH LITMUS) Observe color of litmus.
Purple flame K+