2012

/&
0
1
230
-)4
%

56
26
E14

W


<*
-"*=
-"
56
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E
-*.
:2
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)<
F
860
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K =

C2 . 2
1 2

2

C2
-A*
B
K
/@?

2

k (1 2 ) = C2 . 2 C 2 . 2 + K 2 K = 0
= 5.10 6 2 =

6.3.10 10 + 5.10 6
= 2,5.10 3
2.10 3

CD
E
0

"-?=6

F<=6

E2

[HCOO ].[CH COOH ] =

[CH COO ][HCOOH ] (CV x

xq

K=

xq =

q 81.9
1,37.104

).(C.V2 xq )

= 9,88.105 mol

(9,88.10 )
9,88.10 ).(10

CH 3COO

(9.10

9,88.105 )

= 10,15 10

[HO ].[CH COOH ] = [HO ] = (C . )

[CH COO ]
C [HO ] C C
2

K=

1 1



E11

5 2

K=

aq aq




)
 E12

C1. 2
1 1

10
10 2.(2,5.10 4 ) 2
K=
6,3.10
4
1 2,5.10

F<=6
')
-

@E22

[HCOO ].[CH COOH ] = [HCOO ][H O ].[CH COOH ] = K

[CH COO ][HCOOH ] [CH COO ][H O ][HCOOH ] K

K=

A2

1 =

A1

K A2 = K .K A1 = 10.1,6.10 5 = 1.6.10 4

xf
xm

[HO ] .V = [HO ]
=

C1.V

][

K e = HO f . H 3O +

C1

HO

] = [H KO ]

= K e .10 pH

e
+

m
0,41
C1 =
=
= 10 2 mol.L1
M .V 82.0,5

1 =

K e .10 pH 10 14.108, 4
=
= 2,5.10 4 1
2
C1
10

$
% &
'(

*
)'
1


"

-*.
E13

[HO ].[CH COOH ] = [HO ] = (C . )

[CH COO ]
C [HO ] C C
2

K=

10
10 2.( 2,5.10 4 ) 2
K=
6,3.10
4
1 2,5.10

1 1

C1 . 2
1 1