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pKA1 (HCOOH/HCOO -) = 3,8 pH1 = 2 ,9 #$"!א
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[HCOOH (aq)] = c ; [C6H5COO – (aq)] = c ; [C6H5COOH (aq)] = c' ; [HCOO – (aq) ] = c'.
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[ HCOO − (aq)]éq . H 3O + éq
HCOOH(aq) + H2O(l) HCOO (aq) + H3O KA 1 =
[ HCOOH (aq)]éq
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C6 H 5COO − (aq) éq . H 3O + éq
C6H5COOH(aq) + H2O(l) C6H5COO (aq) + H3O KA2 =
C6 H 5COOH (aq) éq
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[C H COOH ] 6 [HCOO ]. [H O ]
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K = [C H COO ]. [H O ] [HCOOH ]− +
6 5 ( aq ) eq 3 eq ( aq ) eq
K A1 10 − pK A1
K= = − pK A 2 = 10 pK A 2 − pK A1
K A 2 10
K = 104,2–3,8 = 100,4 = 2,5
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