REVIEW TEST-1

Class : XII Date : 11.08.2012

Time : 90 Min. Max. Marks : 132
VERY IMPORTANT : The question paper consists of two sections. Each section contains different types of
questions. Please read the instruction carefully which is common for each section.
INSTRUCTIONS
This paper consist total 35 questions.
Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in each
Section and PAGES. If you find some mistake like missing questions or pages then contact immediately to the
Invigilator.
1. In Section-I for Q. 1 to Q. 13; has four choices (A), (B), (C), (D) out of which only one is correct and carry
3 marks each. There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
2. In Section-II for Q.14 to Q.22, for each question you will be awarded 4 marks and zero marks otherwise.
There are no negative marks in this section.
3. In Section-III for Q.23 to Q.25, Comprehension type,each question carries 3 marks and there is no negative
marking in this section.
4. In Section-IV is Q.26 , Match the column type question,3 marks will be awarded each if all the bubbles realated
to per part of column I are filled correctly .No negative marking.
5. In Section-V for Q.27 to Q.35, are Integer answer type questions and carry 4 marks each. There is NO
NEGATIVE marking. Marks will be awarded only if correct bubbles are filled in your OMR sheet.
6. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
7. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
8. The answer of the questions must be marked by shading the circle against the question by dark By Pen only.
USEFUL DATA
Atomic weights : A1 = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K = 39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48, Ba = 137,
U = 238, Co = 59, B = 11, F = 19, He = 4, Ne = 20, Ar = 40, Mo = 96
Take g = 10 m/s
2
where ever required.
CHEMISTRY
ALCHEMY CLASSES
Converting ordinary into extraordinary
ALC HEMY C LASSES
2012
F r om or di nary t o ext r aordi nar y
I NDI VI DUAL CLASSES FOR CHEMI STRY
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [2]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060] Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
SECTION-I
ONLY SINGLE CORRECT: [13 3 = 39]
Q.1 Select the CH bond marked with an arrow, which has lowest bond energy.
(A)
H
H C
2
(B)
H
(C*)
H
(D)
H
Q.2 Two elements P and Q have half lives of 20 and 8 minutes respectively. Freshly prepared sample of
each isotope initially have same activity. After 40 minutes, the ratio of number of P atoms and Q
atoms will be :
(A) 16 : 1 (B) 1 : 10 (C*) 20 : 1 (D) 1 : 20
Q.3 Which of the following has highest heat of hydrogenation.
(A) (B) (C*) (D)
Q.4 The half life period of a radioactive element X is same as the mean life of another radioactive
element Y. Initially both of them have same number of atoms. Then :
(A) X and Y have the same decay rate initially
(B) X and Y decay at the same rate always
(C*) Y will decay at a faster rate than X
(D) X will decay at a faster rate than Y
Q.5 The type of delocalisation involving sigma bond orbitals is called
(A) inductive effect (B*) hyperconjugation
(C) electromeric effect (D) mesomeric effect
Q.6 Masses of two isobars Cu
64
29
and Zn
64
30
are 63.9298 u and 63.9292 urespectively. It can be concluded
from these data that :
(A) both the isobars are stable
(B) Zn
64
is radioactive, decaying to Cu
64
through |-decay
(C*) Cu
64
is radioactive, decaying to Zn
64
through |-decay
(D*) Cu
64
is radioactive, decaying to Zn
64
through |-decay
Q.7 Which of the following has the maximum acidic strength?
(A*) o-nitrobenzoic acid (B) m-nitrobenzoic acid
(C) p-nitrobenzoic acid (D) p-nitrophenol
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [3]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
Q.8 The half life of I
131
is 8 days. Given a sample of I
131
at time t = 0, we can assert that :
(A) no nucleus will decay before t = 4 days
(B) no nucleus will decay before t = 8 days
(C) all nuclei will decay before t = 16 days
(D*) A given nucleus may decay at any time after t = 0
Q.9 A compound which is not isomeric with diethyl ether is
(A) n-propyl methyl ether (B) 1-butanol
(C) 2 methyl-2-propanol (D*) butanone
Q.10 Which of the following is a correct statement?
(A*) Beta rays are same as cathode rays
(B) Gamma rays are high energy neutrons
(C) Alpha particles are single ionized helium atoms
(D) Protons and neutrons have exactly the same mass
Q.11 The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid
(B), acetic acid (C), and formic acid (D) is
(A) A > B > C > D (B) A > C > B > D
(C*) B > A > D > C (D) B > D > C > A
Q.12 Binding energy per nucleon Vs mass number curve for nuclei is shown in the figure. W, X, Y and
Z are four nuclei indicated on the curve. The process that would release energy is :
(A) Y 2Z
(B) W X + Z
(C*) W 2Y
(D) X Y + Z
X
Y
W
Z
5
8.5
8.0
7.5
30 60 90 120 B
i
n
d
i
n
g

e
n
e
g
y

p
e
r

n
u
c
l
e
o
n

i
n

M
e
V
Mass number of nuclei
Q.13 Ne
22
nucleus, after absorbing energy, decays into two o-particles and an unknown nucleus. The
unknown nucleus is :
(A) Nitrogen (B*) Carbon (C) Boron (D) Oxygen
SECTION-II
MORE THAN ONE CORRECT : [9 4 = 36]
Q.14 Select the incorrect statement.
(A*)
NH
2
CH
3
is more basic than
NH
2
(B*)
COOH
CH
3
is less acidic than
COOH
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [4]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
(C)
NMe
2
CH
3
is more basic than
NMe
2
(D*)
NO
2
CH
3
has shorter CN bond length than
NO
2
Q.15 Which of the following is/are correct regarding the nucleus of an atom :
(A*) Inside nucleus particles representing neutrons and protons are constantly changing
(B*) In a stable nucleus the conversion of neutron to proton and proton to neutron are in equilibrium
(C*) between two protons and between two neutrons neutral II-mesons are exchanged
(D*) between a neutron and proton there is exchange of charged II-mesons
Q.16 Which of the following statement/s is/are true about the following :
O
(I) (II)
O
(III)
O
(A*) (I) and (III) are structural isomers (*B) (I) and (II) are geometrical isomers
(C*) (II) and (III) are structural isomers (D) (I) and (II) are identical
Q.17 A radioactive nucleus X
A
Z
undergoes radioactive decay :
(A*) Both A and Z decreases if the decay is o-decay
(B) Both A and Z change if the decay is -decay
(C) A decreases if the decay is |
+
decay
(D) Z decreases if the decay is |

decay
Q.18 Which one of following represents different molecules?
(A) and (B*) and
(C) and
Cl Cl
(D) and
H
D
Q.19 A

o
B

|
C
|
D
correct statements is/are :
(A*) A and B are isodiaphers (B*) B and C are isobar
(C*) C and D are isobar (D*) A and D are isotopes
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [5]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
Q.20 Correct statement about the molecule Ph C NH
O
is:
(A) This molecule shows geometrical isomerism.
(B*) One of the resonating structure of this molecule shows geometrical isomerism
(C) None of the resonating structure of this molecule shows geometrical isomerism
(D*) In acidic medium this molecule shows geometrical isomers.
Q.21
p
n
ratio in a radioactive disintegration can be increased by :
(A*) o-emission (B) |-emission
(C*) positron emission (D*) K-electron capture
Q.22 Select true statement(s) :
(A*) Resonance effects bond length
(B*) cis-1-bromo-1,2-difluoro ethene and Z-1-bromo-1,2-difluoro ethene are geometrical isomers
(C*) In CH
2
O
O
COH
COH
most acidic H is connected directly to oxygen not on carbon.
(D*) Boiling point of
OH
is less than
OH
OH
SECTION-III
Paragraph for Question No. 23 to 25 [3 3 = 9]
Inductive effect is the polarization of shared pair (covalently bonded pair) of electrons towards
more electronegative atoms. Let us consider a molecule of ethane.
o + o + oo + ooo
C C C C
* Inductive effect operates through o bonds.
* There occurs partical delocalization (movements) of shared pair of electrons.
* This is a very weak effect.
* This effect is additive in nature, i.e. two electronegative atoms exert greater induction effect than
one atom of greater electronegativity from the same position.
Q.23 Which of the following cation will be more stable :
(A)
+
(B)
+
(C*)
+
(D)
+
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [6]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
Q.24 Which of the following carbanion will be highly unstable :
(A)
CH CH
3 2
(B) CH =CH
2
(C)
HC C
(D*) O CH
2
Q.25 Stability order for radical will be :
(I) (II) (III)
(A*) I > II > III (B) II > I > III (C) III > I > II (D) I > III > II
SECTION-IV
MATCH THE COLUMN TYPE QUESTIONS: [1 12 = 12]
Q.26 Column-I Column-II
Mode of decay Characteristic properties
(A) Alpha decay (P)
n
p
ratio decreases
(B) Electron decay (Q)
n
p
ratio increases
(C) Positron decay (R) Neutron is converted into proton
(D) K-electron capture (S) Proton is converted into neutron
[Ans. (A) Q (B) P,R (C) Q,S (D) Q,S ]
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [7]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
SECTION-V
SUBJECTIVE : [9 4 = 36]
Q.27 In a nuclear reactor
235
U undergoes fission liberating 200 MeV of energy. The reactor has a 10%
efficiency and produces 1000 MW power. If the reactor is to function for 16 hrs. The total number
of mols of uranium atoms required is ..................... (N
A
= 6 10
23
) [Ans. 30]
Q.28 An unknown atom has 30 neutrons in its nucleus. Ratio of radii of nuclei of this atom and
4
2
He is
(14)
1/3
. Find the atomic number of unknown atom. [Ans. 26]
Q.29 Determine how many of the following compounds are cis isomer [Ans. 0003]
(a) (b) (c)
(d) (e) (f)
Q.30 Find the number of chemical species which can act both as Bronsted acids and bases.
[Ans. 0005]
(1) HCl (2) H
2
O (3) HCO
3

(4) NH
3
(5) HS

(6) HC
2
O
4

(7) HF
Q.31 In a sample pitch blende the atomic ratio of
206
Pb :
238
U = 24 : 1. The age of the mineral is ....... 10
8
years. If half life of uranium is taken as 4.2 10
9
years. All lead is originated from uranium.
[Use ln 5 = 1.6] [ln 2 = 0.7] [Ans. 192]
Q.32 Number of Bezylic hydrogens in the following compound are :
[Ans. 0009]
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [8]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
Q.33 If a nuclide
235
92
U underwent a fission reaction producing two daughter nuclei and two neutrons. If
the difference between the mass number and atomic number of two daughter nuclei are 55 and 20
respectively then find x + y.
x = Mass number of heavy daughter nuclei
y = Atomic number of lighter daughter nuclei [Ans. 180, x = 144, y = 36]
Q.34
238
92
U undergoes following sequence
o, |

, |

, o, o, o, o, |

, o, o and |

to obtain
A
Z
X . Find the value of (Z + A). [Ans. 0292]
Q.35 Total No. of contributing structures showing hyperconjugation. (involving C-H bonds) for the
following carbocation is.
+
CH
3
CH
2
CH
3
[Ans. 0006]
* * *
REVIEW TEST-4 Er. Shivanand Upadhyay & Neha Joshi Upadhyay [9]
Alchemy Classes : 350, Near Shiv Shakti Mandir, Mahaveer Nagar, Jaipur [Mob.: 9929104019, 9950722060]
SECTION-I
ONLY SINGLE CORRECT: [13 3 = 39]
Q.1 (C)
Q.2 (C)
Q.3 (C)
Q.4 (C)
Q.5 (B)
Q.6 (D)
Q.7 (A)
Q.8 (D)
Q.9 (D)
Q.10 (A)
Q.11 (C)
Q.12 (C)
Q.13 (B)
SECTION-II
MORE THAN ONE CORRECT : [9 4 = 36]
Q.14 (A)(B)(C)(D)
Q.15 (A)(B)(C)(D)
Q.16 (A)(B)(C)
Q.17 (A)(B)(D)
Q.18 (B)
Q.19 (A)(B)(C)(D)
Q.20 (B)(D)
Q.21 (A)(C)(D)
Q.22 (A)(B)(C)(D)
SECTION-III
Paragraph for Question No. 23 to 25 [3 3 = 9]
Q.23 (C)
Q.24 (D)
Q.25 (A)
SECTION-IV
MATCH THE COLUMN TYPE QUESTIONS: [1 12 = 12]
Q.26 [Ans. (A) Q (B) P,R (C) Q,S (D) P,S ]
SECTION-V
SUBJECTIVE : [9 4 = 36]
Q.27 [Ans. 30]
Q.28 [Ans. 26]
Q.29 [Ans. 0002]
Q.30 [Ans. 0005]
Q.31 [Ans. 192]
Q.32 [Ans. 0009]
Q.33 [Ans. 180, x = 144, y = 36]
Q.34 [Ans. 0292]
Q.35 [Ans. 0006]