B.Sc. Ist Year (Chemistry) Time 3Hrs M.M. 50 Note: Attempt atleast one question from each section.

Section E is compulsory. Section A 1 (a) What are real gases? Why do they deviate from ideal behaviour? Explain in terms of temperature and pressure. (b) Derive kinetic gas equation. (c) Calculate (i) Root Mean Square velocity (ii) Most probable velocity of methane molecule at 27C. 2 (a) What are emulsions? Classify them and give one example of each one. (b) Explain the mechanism of micelle formation of taking an example of soap. (c) What do you mean by flocculation value. Out of sodium, magnesium, aluminium which ion has least flocullation value to coagulate negative colloid. Section B 3 (a) Derive the schrodinger wave equation and give the meaning of various symbols used in it. (b) (i) How is diethyl magnesium prepared? How does it react with alcohol and bidentate ligands. (iii) Give the hydrolysis reactions of the following XeF4, XeO2F2, XeOF4. (c) An electron beam emerges from an accelerator with K.E. of 100eV, what is its deBroglie wave length. (h = 66 1034 Js, me = 9.1 1031 kg. 4 (a) Discus the solvation tendency of the s-block elements and explain the crown ethers with examples. (b) Discuss the structure of the followings (i) XeF4, XeF6, XeO3. (c) (i) Discuss the variation in the following properties of alkaline earth metals; Reducing character and Basic character (ii) What is Hunds Rule of maximum multiplicity? Section C 5. (a) Write the stability order of carbocations. (b) Write methods to distinguish between singlet and triplet carbenes (c) Differentiate between addition and polymerisation reaction. 6 (a) Give one method to determine the mechanism of the reaction. (b) Differentiate between inductive and electromeric effect. (c) Differentiate between intermediate and transition state. Section D 7. (a) Derive vander Waals equation for the real gases. (b) Give Maxwells Distribution of molecular speedd and explain the effect of temperature on distribution of speed. (c) Give some methods of preparation of lyophobic colloids. 8. (a) How will you determine the rate of different steps of a multistep reaction from energy profile diagrams. Explain with the help of an example. (b) Calculate from real gas equation the temperature at which three moles of sulphur dioxide would occupy a volume of 001m3 at 1519875 nm2 pressure. a = 0 679 nm4mol2 and b = 5.64 105 m3 mol1. Value of gas constant is 8314 J/K. (c) Give factors affecting acidic strength of phenols. Explain with the help of example. Section E (a) Define Hardy Schulze law. (b) Why is it difficult to store xenon hexa fluoride in glass or the quartz vessels. (c) Explain the terms thixotropy, seneresis and gold number. (d) Define resonance and resonating structures. (e) What is the importance of Huckel rule?

B.Sc. IInd Year (Chemistry) Time 3Hrs M.M. 50 Note: Attempt atleast one question from each section. Section E is compulsory. Section A 1 (a) What are chelates ? Discuss the factors which affect the stability of chelates. (b) What are linkage isomers. Give one example. (c) Write the IUPAC names of the following (i) [Cu (H 2O)2(NH3)4]SO4(ii) Na3[Fe (C2O4)3](iii) [(NH3)5Co (NH2)Co(NH3)5]Cl3 (d) Predict the number of different types of isomers for the following and represent them (i) [Pt Br(NH3)3]NO2 (ii) [Cr (NH3)4Cl2]+ 2 (a) Arrange the following in decreasing order of their acidic strength with appropriate reason. (i) HClO (ii) HClO2 (iii) HClO3 (iv) HClO4 (b) What is Bstrain. Explain with giving example. (c) Which is stronger acid HCN or HOCN. Why? (d) Classify following compounds as Lewis acid and Lewis bases with reason, AlCl3, BF3, I. Section B 3. (a) Give method of preparation of tertiary alcohols. (b) How will you differentiate between primary, secondary and teriary alcohols. (c) Give mechanism of reactions involving conversion of primary alcohol into primary alkyl halide using halogenating agents. 4 (a) Discuss methods of preparation of propane1,2,3triol. (b) Exlain with mechanism the following reaction (i) Reimer Tiemann reaction (ii) Electrophilic substitution reaction of phenols. (iii) Why phenols are more acidic than alcohols? Name two phenols which are expected to show strong acidic character. Section C 5. (a) What are liquid crystals? How are they classified? (b) Define entropy. What are its units? (c) State the law of chemical equilibrium? What do you mean by saying that equilibrium is dynamic in nature? (d) Derive the relationship between Kp and Kc? (e) Briefly explain vacancy theory of liquids? 6. (a) Calculate the entropy change when one mole of H2 is mixed with 2 moles of O2 at room temperature, assuming that the gases behave ideally? (b) Write a short note on thermography? (c) What are the limitations of first law of thermodynamics? (d) Give two examples of each of : (i) Reversible homogenous reaction, (ii) Reversible heterogenous reaction. (e) Briefly describe the principle of liquid crystal in electronic industry. What type of liquid crystals are used? Section D 7. (a) 2-methyl pyridine is weaker base towards trimethyl boron than pyridine, why? (b) Explain acid and base in terms of Lux-flood concept. (c) What are ligands? (d) Find EAN for Fe(CO)5 and [Mn(CN)6]4 8. (a) State carnot theorem. Calculate the amount of heat supplied to carnots cycle working between 368 and 288 K if the maximum work obtained is 895 joules. (b) List the important characteristics of smectic liquid crystals. (c) Justify that catalyst has no effect on equilibrium? Section E 9. (a) Explain why BF3 is a lewis acid but not Bronsted acid. (b) Predict the type of hybridization, geometry and magnetic character of [Fe(CN)6]3 (c) What is the difference between aromatic alcohol and phenol. Explain with the help of example. (d) What is meant by oxidative cleavage? Give reagents, conditions and examples for this type of reaction. (e) Derive an expression for the entropy change on mixing of ideal gases?

B.Sc. IIInd Year (Chemistry) Time 3Hrs M.M. 50 Note: Attempt atleast one question from each section. Section E is compulsory. Section A 1. (a) Discuss the special feature of the spectrum of [Ti(H 2O)6]+3 ion. Draw the energy level diagram showing the splitting of spectroscopic state for the complex. (b) Predict all the term states for d2 electronic configuration and also compare the energies of the different terms. What will be the energy sequence for the d8 electronic configuration 2. (a) Calculate the CFSE for the octahederal d4 systems in weak field as well as strong field ligands. (b) Describe crystal field splitting for octahederal and square planar complexes of d-orbitals. Section B 3. (a) Discuss various types of electronic transitions you come across in organic molecules. (b) What are different types of transitions responsible for a molecule to absorb in IR region. 4. (a) What are equivalent and non-equvivalent protons. (b) What shuld be the feature of a reference chosen in NMR spectroscopy. (c) Give factors affecting absorption in IR region. Section C 5. (1) What are Orthogonal and Normalised wave functions? (2) Which of the following combinations can be classified as zero overlaps? (Consider Z- axis as molecular axis). (i) s-px (ii) px-py (iii) pz-pz (iv) s-pz (3) State Wiens Displacement Law. (4) What is Born-Oppenheimer Approximation in quantum mechanics? (5) Write Schrodinger wave equation for hydrogen atom in terms of polar coordinates. 6. (1) What are the conditions for the formation of molecular orbitals from atomic orbitals? (2) What is de-Broglies idea of duality of matter? (3) What do you understand by the term exchange energy in valence bond theory? (4) What is heat capacity of solids? How is it explained by Plancks quantum theory? (5) Write expressions for the wave functions of bonding molecular orbitals and antibonding molecular orbitals? Section D 7 (a) Calculate the spin only magnetic moment in case of (i) Ni2+, (ii) Ti3+ and (iii) Fe3+. (b) Discuss briefly Faradays method for measuring magnetic susceptibility. (c) Explain temperature independent paramagnetism. 8. (a) Describe chemical shift and its importance. (b) What is the relation between magnetic field intensity and the absorption frequency in case of PMR spectroscopy. (c) In VBT what are the improvements made in wave function of H2 molecule to get better agreement of calculated values with experimental value? Section E 9 (a) Explain ferromagnetism and antiferromagnetism. (b) Why anhydrous CuSO4 is colourless. (c) Give differences between quantum mechanics and classical mechanics. (d) Write the expression for energy of a particle in one dimensional box. How can you justify (i) quantization of energy (ii) existence of zero point energy. (e) What do you mean by chromophore and auxochrome.