Professional Documents
Culture Documents
Abstract
Herein we report a carbon based technology that can be used to rapidly adsorb and release CO2. CO2 uptake by the synthesized composites was determined using a gravimetric method at room temperature and atmospheric pressure. 39% polyethylenimine-mesocarbon (PEI-CMK-3) composite had ~12 wt% CO2 uptake capacity and a 37% polyvinylaminemesocarbon (PVA-CMK-3) composite had ~ 13 wt% CO2 uptake capacity. The sorbents were easily regenerated at 75 C and exhibit excellent stability over multiple regeneration cycles. CO2 uptake was equivalent when using 10% CO2 in 90% CH4, C2H6 and C3H9 mixture, underscoring the efficacy for CO2 separation from natural gas.
1. Introduction
CO2 concentrations in Brazilian pre-salt reservoirs typically range from 8-18%. Separation of CO2 from produced gas streams on offshore production facilities will allow for on-site reinjection of CO2 for enhanced oil recovery. This will require efficient, lightweight and economical technologies. High surface area carbon sorbents such as activated charcoal and Maxsorb have long been used in the purification of gases in chemical industries; however these substrates often have poor selectivity in natural gas streams. In addition, removal of carbon dioxide from process gas streams can be achieved using liquid absorbants such as alkanolamines or membrane permeation technologies, but due to space and weight limitations, these technologies are not suitable for use offshore. Effective systems must therefore combine high selectivity with minimal energy input required to regenerate the active substrate. Viable technologies for offshore implementation must be economical, lightweight and have small footprints. Over the last few decades, there have been significant advances in the synthesis of mesoporous carbon materials, such as CMK-3 and CMK-5. Ryoo et al. proposed a practical method through in-situ polymerization to synthesize polymer-CMK-3 composites. The mesocarbon CMK-3 is different from conventional carbon materials such as activated carbon due to its highly ordered meso-structure and high surface area. This allowed for the chemical properties of these composites to be maintained while greatly enhancing their thermal stability. Inspired by their work, we developed a route to synthesize polymer-mesocarbon composites that would lead to higher degrees of CO2 adsorption by the in-situ polymerization of amine species to produce polyethylenimine (PEI) and polyvinylamine (PVA) inside the mesocarbon CMK-3. In addition to a high efficiency for CO2 capture, they should also exhibit high stability
______________________________ 1 Graduate Student Rice University 2 Ph.D., Postdoctoral Student Rice University 3 Graduate Student Rice University 4 Ph.D., Graduate Student Rice University 5 Ph.D., Lecturer of Chemistry Rice University 6 Ph.D., Senior Chemist Nalco Company 7 Ph.D., Marketing Manager Nalco Company 8 Ph.D., T. T. and W. F. Chao Professor of Chemistry, Professor of Mechanical Engineering and Materials Science and of Computer Science Rice University
Rio Oil & Gas Expo and Conference 2012 due to the formation of interpenetrating composite frameworks between the crosslinked polymers and mesocarbon CMK-3. Moreover, their uptake of small hydrocarbons should be minimal, making them suitable for use in CO2 sequestration from natural gas streams. HWANG, C.-C. et al.
Scheme 1. The synthesis processes to produce mesoporous polymer-carbon composites PEI-CMK-3 and PVA-CMK-3. Reproduced with permission from HWANG, C.-C. et al, Copyright 2011, American Chemical Society. Attenuated total reflectance infrared (ATR-IR) analysis and 13C NMR analysis were chosen to monitor the resultant composites during the synthetic processes. Figure 1a is the IR spectrum from CMK-3 impregnated with 2methyl-2-oxazoline. The spectrum has a characteristic absorption band at 1673 cm-1 that can be assigned to a symmetric stretching mode of C=N from the 2-methyl-2-oxazoline monomers. The presence of the N-substituted polyaziridine, generated from the ring opening of 2-methyl-2-oxazoline, can be evidenced by a development of the characteristic C=O stretching at 1632 cm-1 as well as a disappearance of the original C=N vibration (Figure 1b). Figure 1c is a spectrum of the composite after hydrolysis with aqueous NaOH for 12 h; the characteristic peaks of the N-substituted polyaziridine from Figure 1b are replaced by peaks at 3260 and 1605 cm-1 in Figure 1c that are assigned to N-H stretching and bending respectively, from the secondary amine. In Figure 1d, a sharp peak together with a shoulder peak appear at 1636 and 1670 cm-1 corresponding to the C=C and C=O symmetric stretching from the N-vinylformamide monomers in CMK-3. Figure 1e shows a strong peak centered at 1656 cm-1 that is due to C=O stretching from the poly(Nvinylformamide) in the CMK-3 composite after the in-situ polymerization. The structure of the PVA-CMK-3 composite was confirmed by the peaks around 3400 and 1605 cm-1 in Figure 1f due to the N-H stretching and NH2 scissoring on the primary amine, respectively HWANG, C.-C. et al.
Figure 1. ATR-IR and solid-state 1H-13C CPMAS NMR spectra for PEI-CMK-3 composite (a-c and g) and PVA-CMK3 (d-f and h) during the synthetic processes. Reproduced with permission from HWANG, C.-C. et al, Copyright 2011, American Chemical Society. The molecular structures of PEI-CMK-3 and PVA-CMK-3 composites were further investigated by solid-state NMR analysis. 13C MAS NMR spectra were acquired by using 1H-13C cross polarization (CPMAS) with contact time of 1 ms. Figure 1g shows that the PEI-CMK-3 composite has two main signals observed at ~ 126 ppm and ~ 45 ppm corresponding to sp2-carbons from CMK-3 itself and to the CH2 units of linear PEI, respectively. A minor shoulder around 165 ppm assigned to the carbamate is assumed through the composite reaction with CO2 from the atmosphere during its storage. HWANG, C.-C. et al For the PVA-CMK-3 composite, three resonance peaks of carbon atom shown in Fig. 1h were assigned as follows: a sp2-carbon peak ( ~ 130 ppm) from CMK-3 itself, a strong ( ~ 46 ppm) and a medium resonance ( ~ 38 ppm) attributed to the methine- and methylene moieties of the PVA main chain. HWANG, C.-C. et al.
Figure 2. (a) TEM and (b) SEM images taken from the 39% PEI-CMK-3. Crystalline structure for the PEI-CMK-3 was recorded by powder XRD (inset of a). (c) SEM image of the 37% PVA-CMK-3 composite. Reproduced with permission from HWANG, C.-C. et al, Copyright 2011, American Chemical Society. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) analyses were conducted to determine the morphologies and microstructures of the synthesized polymer-CMK-3 composites. A TEM image of the 39% PEI-CMK-3 parallel to the pore direction is shown in the Figure 2a. The small angle X-ray diffraction pattern 3
Rio Oil & Gas Expo and Conference 2012 (inset) clearly reveals the presence of hexagonally ordered porous structures for the produced polymer-CMK-3 composites. These ordered porous structures remain even after polymerization and hydrolysis. Figure 2b and Figure 2c are SEM images taken of PEI-CMK-3 and PVA-CMK-3, respectively. Little bulk aggregation of polymer is observed on the outer surface, which means that the polymerization of PEI and PVA is confined within the pores of CMK-3. The resultant polymers form interpenetrating and inseparable composite frameworks with CMK-3, in good agreement with the high stability results obtained from the CO2 adsorption cycle study. HWANG, C.-C. et al The porous nature of the polymer-CMK-3 composites was further characterized by liquid nitrogen adsorption isotherms, which allow calculation of specific surface area, pore volume and pore size distribution (see Table 1). Pure CMK-3 has a high surface area of 1350 m2/g with its pore volume of 1.40 cm3/g and pore diameter of 3.9 nm. The actual loading of each polymer in the CMK-3 was determined by thermogravimetric analysis (TGA). The PEI-CMK-3 and PVA-CMK-3 behave similarly as their loadings were increased up to ~ 40 wt%. As the polymer loading of CMK-3 increased, the more meso- and microchannels were occupied, leading to a corresponding decrease in the surface area and pore volume. As the polymer loading increased to over 50%, less than 1/10 original surface area and pore volume remained, causing mesopore blockage opposed to monomer impregnated as disclosed above. In addition to the monomer-infused composites, we also tried direct polymer impregnation to yield PEI-CMK-3(imp.) and PVA-CMK3(imp.). These latter polymer-impregnated composites had even lower surface areas and pore volumes than those made by the original in- situ polymerization (Table 1). HWANG, C.-C. et al
Sorbents CMK-3 17% PEI-CMK-3 28% PEI-CMK-3 39% PEI-CMK-3 52% PEI-CMK-3 21% PVA-CMK-3 30% PVA-CMK-3 37% PVA-CMK-3 54% PVA-CMK-3 40%PEI-CMK-3 (imp) 40%PVA-CMK-3 (imp)
Surface (m2/g) 1352 1248 950 774 134 1106 868 711 112 315 237
area
Pore volume (cm3/g) 1.40 1.26 0.66 0.49 0.19 1.25 0.61 0.46 0.20 0.27 0.22
Pore (nm) 3.9 3.4 3.2 2.9 0.5 3.4 3.1 2.9 0.3 0.6 0.6
size
CO2 capacity (mmol/g) 1.55 2.00 2.36 3.13 0.49 2.60 3.49 3.52 0.54 1.95 1.48
CO2 capacity (wt%) 6.4 8.1 9.4 12.1 2.1 10.3 13.3 13.4 2.3 7.9 6.1
Figure 3. Adsorption cycles of CO2 studied by TGA at 30 C on the 37% PVA-CMK-3 sorbent. The composite was first pretreated at 100 C under argon to remove moisture and residual CO2 followed by dosing with 100% CO2 gas stream (30 C, 1 atm) for 30 min. After the first adsorption cycle, the cycling was repeated by heating the adsorbent to 75 C under argon for regeneration. Reproduced with permission from HWANG, C.-C. et al, Copyright 2011, American Chemical Society. In addition to the high CO2 capture efficiency, long-term stability and low-cost regeneration are also important concerns for any CO2 sequestration system. In our case, as CO2 was introduced into the sorbents, each CO2 uptake cycle is a two-stage process, with the mass increasing significantly in the first stage in less than 5 min, followed by a second much slower absorption process until a stable maximum was reached (Figure 3). This two-stage adsorption kinetics had been observed in other amine-impregnated sorbents.16-19 Note that the capacity of the 37% PVA-CMK-3 is higher than 13 wt% within the first CO2 exposure stage. The rapid sequestration process is desirable for shortening the CO2 absorption time. In order to check the stability of the composite sorbents, after the first absorption cycle, the cycling was repeated by heating the PEI-CMK-3 and PVA-CMK-3 composites to 75 C under argon gas for regeneration, followed by cooling to room temperature for another CO2 capture. The 75 C regeneration temperature is lower than that needed for silica-based amine sorbents, which is usually higher than 100 C. Table 1. Physical properties of selected polymer sorbents and corresponding CO2 capacity. Reproduced with permission from HWANG, C.-C. et al, Copyright 2011, American Chemical Society.
The 100% CO2 flow was replaced with a 10% CO2 in natural gas (composed of 85% methane, 3% ethane and 2% propane) in order to mimic a real natural gas field. The result still showed ~12 wt% maximum CO2 uptake capacity for PEI-CMK-3 and ~13 wt% for PVA-CMK-3 (Figure 4a and 4b). When methane was studied as pure gas stream, only 1.5 wt% CH4 capacity was observed (Figure 4c). Hence gas selectivity is indeed present. HWANG, C.-C. et al
0 1.08 1.04 1.00 0.96 0.92 1.08 1.04 1.00 0.96 0.92 a
20
40
60
80
100
120
140
12.0
100% CO2
11.9
10% CO2
Temperature ( C)
b
13.0
100% CO2
12.7
10% CO2
1.5
100% CH4
Figure 4. CO2 uptake tests on PEI-CMK-3 (a) and PVA-CMK-3 (b) composites. The first uptake used pure CO2, followed by the second uptake using 10% CO2 flow (balanced in natural gas 85% CH4, 3% C2H5 and 2% C3H8). (c) Pure methane adsorbed on the PVA-CMK-3 composite. Reproduced with permission from HWANG, C.-C. et al, Copyright 2011, American Chemical Society.
4. Conclusions
(In conclusion, we have synthesized new and efficient CO2 adsorbents based on amine-modified mesocarbon CMK-3 composites through in-situ polymerization. The product contains crosslinked polymers interpenetrating the composite frameworks of the mesocarbon CMK-3. A CO2 absorption capacity of 3.52 mmol/g (13.4 wt%) was obtained, which is more than twice that of the pure CMK-3. The substrate exhibited gas selectivity toward CO2 when compared to a natural gas stream. The sorbents are readily and fully regenerated at a relatively low temperature and exhibit stability over repetitive adsorption-desorption cycles.)
5. Acknowledgements This work was supported by the ONR MURI program (#00006766, N00014-09-1-1066) and the Advanced Energy Consortium (Baker Hughes, Halliburton, Conoco Phillips, bp, OXY, Marathon, Shell, Total, Petrobras, Schlumberger) . 6. References
PUXTY, G.; ROWLAND, R.; ALLPORT, A.; YANG, Q.; BOWN, M.; BURNS, R.; MAEDER, M.; ATTALLA, M., Environ. Sci. Technol. 2009, 43, 6427-6433. International Space Station Environmental Control and Life Support System. NASA. http:// www.nasa.gov/centers/ marshall/pdf/104840main_eciss.pdf. SIRIWARDANE, R.V.; SHEN, M.S.; FISHER, E.P.; POSTON, J.A.; Energy Fuels 2001, 15, 279-284. HEUCHEL, M.; DAVIES, G.M.; BUSS, E.; SEATON, N.A., Langmuir 1999, 15, 8695-8705. FRYXELL, G.E.; LIU, J.; HAUSER, T.A.; NIE, Z.; FERRIS, K.F.; MATTIGOD, S.; GONG, M.; HALLEN, R.T., Chem. Mater. 1999, 11, 2148-2154. YOSHITAKE, H.; YOKOI, T.; TATSUMI, T. Chem. Mater. 2002, 14, 4603-4610. XU, X.; SONG, C.; ANDRESEN, J.M.; MILLER, B.G.; SCARONI, A.W. Microporous Mesoporous Mater. 2003, 62, 6
Rio Oil & Gas Expo and Conference 2012 29-45. CASKEY, S. R.; WONG-FOY, A. G.; MATZGER, A. J. J. Am. Chem. Soc. 2008, 130, 10870-10871. LEE, J.; HAN, S.; HYEON, T.; J. Mater. Chem. 2004, 14, 478-486. RYOO, R.; JOO, S.H.; KRUK, M.; JARONIEC, M. Adv. Mater. 2001, 13, 677-681. KYOTANI, T. Carbon 2000, 38, 269-286. CHOI, M.; RYOO, R. Nature Mater. 2003, 2, 473-476. ZHAO, D.; FENG, J.; HUO, Q.; MELOSH, N.; FREDRICKSON, G.H.; CHMELKA, B.F.; STUCKY, G.D. Science 1998, 279, 548-552. JOO, S.H.; CHOI, S.J.; OH, I; KWAK, J.; LIU, Z.; TERASAKI, O.; RYOO, R. Nature 2001, 412 169-172. MELLO, M. R.; PHANON, D.; SILVERIRA, G. Q.; LLEWELLYN, P. L.; RONCONI, C. M., Micropor. Mesopor. Mater., 2011, 143, 174-179. XU, X.C.; SONG, C.S.; ANDRESEN, J.M.; MILLER, B.G.; SCARONI, A.W. Energy Fuels, 2002, 16, 1463-1469. CHOI, S.; DRESE, J.H.; JONES, C.W. ChemSusChem, 2009, 2, 796-854. MA, X.L.; WANG, X.X.; SONG, C.S., J. Am. Chem. Soc., 2009, 131, 5777-5783. HWANG, C.-C.; JIN, Z.; LU, W.; SUN, Z.; ALEMANY, L. B.; LOMEDA, J. R.; TOUR, J. M. ACS Appl. Mater. Interfaces 2011, 3, 4782-4786.