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Chemistry Paper 1
1. Diagram 1 shows the electron arrangement of an atom of element P.
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5. What are the ions present in molten sodium chloride and sodium chloride aqueous solution? A B C D 6. Which of the following solutions can show a pH value of 8? A B C D 0.1 mol dm-3 of ethanoic acid 0.1 mol dm-3 of hydrochloric acid 0.1 mol dm-3 of ammonia solutio 0.1 mol dm-3 of sodium hydroxide solution
P
Diagram 1 What is the number of valence electrons in atom P ? A B 7 6 C D 5 4
2. What are the symbols of the elements of chromium, copper , manganese and potassium? A B C D 3. The following statement is about the arrangement of the elements in the Periodic Table of Elements. Elements are arranged in order of increasing atomic mass in The Periodic Table Which of the following scientists made the above statement? A B Meyer Newlands C D Mendeleev Dobereiner
7. Which of the following compounds is a soluble salt? A B C D Lead(II) iodide Barium sulphate Calcium chloride Magnesium carbonate
8. Diagram 3 shows the stages involved in the Contact Process to produce sulphuric acid.
Diagram 3 Which of the following represent the temperature and the catalyst in stage 1? A B C D Temperature / oC 450 200 450 300 Catalyst Vanadium(V) oxide Vanadium(V) oxide Iron powder Iron powder
9. Which of the following compounds is an organic compound? A B C D Calsium carbonate, CaCO3 Carbonic acid, H2CO3 Carbon dioxide, CO2 Glucose, C6H12O6
Diagram 2 Which of the following compounds could be used as substance X? A B C D Ethene, C2H4 Sodium chloride solution, NaCl Chloromethane, CH3Cl Ethyl ethanoate, CH3COOC2H5
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10. Diagram 4 shows the graph of volume of carbon dioxide gas against time when 5 g of marble chips is added to 50 cm3 of 0.2 mol dm-3 hydrochloric acid. Volume of CO2 gas / cm3
Diagram 6 Which of the following metals is most suitable to be used in the diagram 6? A Lead C Copper B Silver D Magnesium 18. Diagram below shows the formula of a nitrate salt
Diagram 4 At what time the rate of reaction the highest? B t2 C t3 D t4 A t1 11. Which statement is correct about noble gases? A Exist as diatomic molecules B Do not form chemical bonds C Form ions with different valencies D Combine with transition metals to form coloured compounds 12. Which of the following substances has electrostatic forces between its particles? A Naphthalene C Hydrogen chloride B Carbon dioxide D Magnesium oxide 13. Acid rain causes the land to become acidic. Farmers neutralize the acidity in the soil by adding A lime C zinc nitre B sulphur D ammonium sulphate 14. Atom of element X has a proton number of 13. Where is X located in the Periodic Table of Elements? A B C D Group 3 3 13 13 Period 2 3 2 3
XNO3
Which of the following are the possible ions of X? I Silver ion III Carbonate ion II Hydroxide ion IV Ammonium ion A I and III only C II and III only B I and IV only D II and IV only 19. Baking powder contains sodium hydrogen carbonate. It reacts with acidic substances to release A hydrogen C carbon dioxide B nitrogen D nitrogen dioxide 20. A study of three metals M, N and O is carried out. It is found that metal M has the highest tendency to lose electron while metal O has the least tendency. It can be summarised as below:
15. Which of the following substances is made up of atoms? A Argon C Chlorine B Nitrogen D Ammonia 16. Diagram 5 shows two examples of medicine Y Penicillin Streptomycin Diagram 5 What is type of medicine Y A Hormon B Analgesic C Antibiotic D Psychotherapeutic medicine
Which of the following statements are true of the metals M, N and O? I M displaces N from aqueous N nitrate II M will corrode if placed in contact with O in aqueous M nitrate III N is the positive terminal in a chemical cell using both N and O as electrodes IV The voltage for chemical cell using M and O is bigger than chemical cell using N and O. A I, II and III only C I, III and IV only B I, II and IV only D II, III and IV only 21. Which of the following solutions have the same number of hydrogen ions, H+, as in 50 cm3 of 0.1 mol dm-3 sulphuric acid, H2SO4? I 100 cm3 of 0.1 mol dm-3 hydrochloric acid, HCl II 50 cm3 of 0.2 mol dm-3 nitric acid, HNO3 III 100 cm3 of 0.1 mol dm-3 ethanoic acid, CH3COOH IV 50 cm3 of 0.1 mol dm-3 phosphoric acid, H3PO4 A I and II only B I and III only C III and IV only D I, II and III only
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Diagram 7 What is the name of the monomer of the polymer in the diagram? A B Ethene Butene C Propene D Chloroethene
Diagram 9 Which of the following alcohol reacts with propanoic acid to produce the above compound? A C
23. Table 1 shows the relative atomic mass of helium, carbon, sulphur and copper JAWAPAN boleh didapati di laman web www.afterschool.my B Table 1 Which of the following statements is true? [ Avogadro constant = 6.0 x 1023 mol-1] A B C D Mass of one copper atom is 64 g Mass of 1 mol of helium is 8 g 32 g of sulphur contains 6.02 x 1023 sulphur atom Mass of one sulphur atom is 32 times bigger than one carbon atom 27. What is the oxidation number of nitrogen in NO2? A C +2 +4 B +3 D +6 D
24. Iron(III) ions can be reduced to iron(II) ions by substance X. Which of the following is substance X? A Zinc B Chlorine water C Acidified potassium manganate(VII) solution D Acidified potassium dichromate(VI) solution 25. Diagram 8 shows the apparatus set-up used to study the rate of reaction of calcium carbonate and hydrochloric acid.
28. A student discovered that a green apple that was cut into smaller pieces turned brown after 15 minutes. Which of the following substances should be added to prevent the browning of apple. A C Ascorbic acid Alcohol B Sugar D Lechitin
Diagram 8 The rate of the above reaction can be increased by A B C D grinding the marble chips lowering the temperature of hydrochloric acid using a larger flask adding water to hydrochloric acid
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30. Diagram 10 shows the electron arrangement of a compound formed between element T and element Q.
Table 2 What is the arrangement of elements S, T, U and V in ascending order of atomic size? A C S, T, U, V V, U, T, S B D S, V, T, U U, T, S, V
31. Which of the following pairs of substances is most suitable to prepare copper(II) sulphate salt? JAWAPAN boleh didapati di laman web www.afterschool.my A B C D Copper with dilute sulphuric acid Copper(II) chloride with dilute sulphuric acid Copper(II) carbonate with dilute sulphuric acid Copper(II) nitrate solution with sodium sulphate solution
36. C4H8 is the molecular formula for isomers X and Y. Which of the following statements is true of isomers X and Y? A B C D X and Y have similar molecular structure X and Y have similar chemical properties X and Y have different relative molecular mass X and Y have similar physical properties
37. Diagram 12 shows curve X obtained when 8 g of granulated zinc (in excess) is reacted with 50 cm3 of 1 mol dm-3 sulphuric acid. Diagram 11 Which of the following electrolytes produce oxygen gas at electrode X ? I 1.0 mol dm-3 hydrochloric acid II 1.0 mol dm-3 sulphuric acid III 1.0 mol dm-3 potassium nitrate solution IV 1.0 mol dm-3 potassium bromide A B I and II only II and III only C D III and IV only II, III and IV only
Diagram 12 Which of the following reactions produces curve Y? A B C D 8 g zinc powder + 50 cm3 of 2 mol dm-3 sulphuric acid 8 g zinc powder + 50 cm3 of 1 mol dm-3 of sulphuric acid 8 g granulated zinc + 100 cm3 of 1 mol dm-3 of sulphuric acid 8 g granulated zinc + 50 cm3 of 2 mol dm-3 of sulphuric acid
33. The following equation represents the reaction between sodium hydroxide solution and dilute sulphuric acid. H2SO4 + 2NaOH Na2SO4 + 2H2O What is the volume of 0.5 mol dm-3 sulphuric acid needed to neutralise 50 cm3 of 0.5 mol dm-3 sodium hydroxide? A B 12.5 cm3 25.0 cm3 C D 50.0 cm3 75.0 cm3
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39. Caffeine is found in coffee bean. Its molecular formular is C4H5N2O. If one coffee bean contains 0.02 mol of caffeine, determine the mass of the compound in ten coffee beans [Relative Atomic Mass ; C, 12 ; H, 1 ; N, 14 ; O, 16] A 0.97 g C 9.70 g B 1.9 g D 19.4 g 40. 7 g of potassium hydroxide is dissolved in distilled water to form 250 cm3 of solution. What is the molarity of the potassium hydroxide solution? [Relative Atomic Mass: H,1 ; O,16 ; K, 39] A B 0.03 mol dm-3 0.05 mol dm-3 C D 0.30 mol dm-3 0.50 mol dm-3
Diagram 15 Which of the following experiments will produce curve X? JAWAPAN boleh didapati di laman web www.afterschool.my A B C D 44. Table 6 shows the melting and boiling points of substances P, Q, R and S.
Table 4 Which of the following is true for compound formed between X and Y? A B C D Bonding type Ionic Covalent Covalent Ionic Electrical conductivity in aqueous and molten state in aqueous and molten state in aqueous state only in molten state only
Table 6 Which of the following substances has the highest kinetic energy at room temperature? A P C R B Q D S 45. The following equation shows the complete combustion of propene gas. C3H6(g) + 9/2 O2(g) 3CO2(g) + 3H2O(g) Which of the following statements are true when 1 mol of propene gas is burnt completely? [Relative atomic Mass : C3H8 , 44 ; O2 , 32 ; CO2 , 44 ; H2O, 18, Molar volume of gas 22.4 dm3 mol1 at S.T.P.] I II Complete combustion of 0.1 mol of propene produces 5.4 g of water Complete combustion of 1 mol of propene gas produces 2 mol of water Complete combustion of 4.2 g of propene requires 14.4g of oxygen. Complete combustion of 0.1 mol of propene produces 6.72 dm3 carbon dioxide gas at s.t.p. I and II only I and IV only C D II and IV only I, III and IV
42. Table 5 shows the results of an experiment for three chemical cells P, Q and R.
Table 5 Which of the following arrangements of metals X, Y and Z is in descending order of electropositivity in the electrochemical series? A B Z, X, Y Z, Y, X C D X, Y, Z X, Z, Y
III IV A B
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46. Ammonium sulphate, (NH4)2SO4 is an example of a fertilizer. Calculate the percentage of nitrogen in 1 mole of ammonium sulphate. [Relative Atomic Mass: N, 14 ; H,1 ; S,32 ; O,16] A B C D 12.12 % 21.21 % 23.23 % 31.31 %
47. Diagram 16 shows an apparatus set up to investigate a redoxreaction by tranferring electrons at a distance.
Diagram 17 Which of the following structural formulas is of compound J? O || A CH3COCH2CH3 O || B CH3COCH2CH2CH3 C O || CH3CH2COCH2CH3 O || CH3CH2COCH2CH2CH3
Diagram 16 In this reaction, electron flow from electrodee P to electrode Q. Which of the following are the correct solution for P and Q? Solution X A B C D Bromine water Bromine water Acidified potassium dichromate(VI) solution Potassium iodide solution Solution Y Iron(II) sulphate solution Potassium iodide solution Potassium iodide solution Acidified potassium dichromate(VI) solution D
50. The empirical formula of a hydrocarbon is CH2. Its relative molecular mass is 56. What is the molecular formula of the hydrocarbon? [Relative atomic mass: H, 1; C, 12 ] A. B. C. D. C3H8 C4H8 C4H10 C5H10
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Chemistry Paper 2
SECTION A Answer All Questions
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1. Diagram below shows an industrial preparation of compound Y from the product of Contact process and Haber process.
Contact process Sulphuric acid
Compound X
(a) State the name of compound X. _____________________________________________________________________ (b) Write the formula of compound Y. _____________________________________________________________________
[1 mark] [1 mark]
(c) Sulphur dioxide, SO2 is one of the product of the Contact process that can cause acid rain. State one effect of acid rain to the environmental. _____________________________________________________________________ [1 mark] (d) Urea, (NH4)2CO and compound Y are two type of fertilizers. (i) Calculate the percentage of nitrogen by mass in both fertilizers. [Relative Atomic Mass ; H, 1 ; C, 12 ; N, 14 ; O, 16 ; S, 32] _____________________________________________________________________ (ii) Which fertilizers is a better for the growth of plants? Explain why. _____________________________________________________________________
[2 marks] [2 marks]
(e) Sulphuric acid is one of the raw materials to produce synthetic polymers. However synthetic polymers are difficult to dispose. (i) Why we cannot burn the synthetic polymer? _____________________________________________________________________ [1 mark] (ii) State one way to overcome the problem in (e)(i). _____________________________________________________________________ [1 mark]
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2. Diagram below shows the graph of temperature against time when solid of P is heated.
Temperature/oC
259 63 B C
A Time/s
(a) What is meaning of melting point? _____________________________________________________________________ (b) State the melting point and boiling point of substance P. Melting point Boiling point : ________________________________________________________ : ________________________________________________________
[ 1 mark ]
[2 marks] [ 1 mark ]
(c) Explain why temperature unchanged at BC? _____________________________________________________________________ (d) Complete the table below by stating the physical state of substance P.
[2 marks] (e) Table below shows the melting point and boiling point of four substances.
(i)
(ii)
[2 marks]
[ 1 mark ]
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Copper(II) carbonate
II
Copper(II) sulphate solution
I
Copper(II) oxide
III
Copper metal
IV
(a) Copper(II) carbonate is converted to copper(II) oxide in reaction I. (i) State the colour of copper(II) oxide. _____________________________________________________________________ (ii) Write the chemical equation for the reaction I. _____________________________________________________________________ (iii) 4.0g copper(II) oxide is produced from the reaction I. Calculate mass of copper(II) carbonate used? [Relative Atomic Mass : Cu, 64 ; O, 16 ; C, 12]
[2 marks] (b) Copper metal can be changed to copper(II) sulphate solution in process III and then to copper(II) carbonate in process II. (i) Name the process II. _____________________________________________________________________ [1 mark] (ii) Suggest the substances that used in process II and process III. Process II :___________________________________________________ Process III :___________________________________________________ [2 marks] (c) Copper(II) oxide can be reduced to copper metal by passing the dry hydrogen gas. Draw a labeled diagram how to produce copper metal from the copper(II) oxide in the lab.
[2 marks] 4. Equation below shows the energy release from the reaction of iron and copper(II) sulphate solution. (Relative Atomic Mass : Cu, 64 ; Water heat specific capacity, 4.2 Jg1 OC1)
[1 mark]
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[1 mark]
[3 marks] (d) If excess iron powder is added to the 100 cm3 copper(II) sulphate solution 0.25 moldm3, calculate: (i) Temperature rise from this equation.
[3 marks] JAWAPAN boleh didapati di laman web www.afterschool.my (ii) Mass of copper formed.
[1 mark] (e) If iron powder is displaced by magnesium powder, predict the value of H whether higher or lower than 200 kJmol1. Explain why? ____________________________________________________________________ ____________________________________________________________________ [2 marks] (f) Name one another metal that cannot displace copper from copper(II) sulphate solution. _____________________________________________________________________ [1 mark]
H H H H | | | | H C = C C C H | | H H
Compound P
5. Diagram above the structural formula of organic compound, P. (a) Name the compound P. _____________________________________________________________________ (b) When compound P is burnt completely in excess oxygen, 5.4g of water produce. (i) Write the equation for the combustion of compound P in excess oxygen. _____________________________________________________________________ _____________________________________________________________________ (ii) Calculate the mass of compound P used? [Relative Atomic mass: C, 12 ; H, 1]
[1 mark]
[2 marks]
[3 marks]
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[2 marks] [1 mark]
(a) (i) Write the chemical equation for this reaction. _____________________________________________________________________ (ii) Calculate the maximum volume of hydrogen gas released at room condition in these experiments. [Molar volume of gas at room condition, 24 dm3mol-1] (b) Calculate the average rate of reaction for experiment 1 and experiment 2. (c) The volume of gas released in experiment 1 is sketched in the diagram below.
Volume of gas/ cm3
[2 marks]
[2 marks]
[2 marks]
Time / s
Sketch the curve for experiment 2 in diagram above. (d) Explain why the rate of reaction experiment 2 is higher than experiment 1 according the collision theory. _____________________________________________________________________
[1 mark] [3 marks]
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7. Diagram below shows the apparatus set up for the electrolysis of copper(II) sulphate solution using carbon and copper electrodes. After 30 minutes the changes was observed.
Copper (II)
(a) Based on the diagram above, state the factor that determines the product formed at electrode X and Y. (b) Explain the reaction at electrode X and Y. Include the following in your explanation. List all the ions present in the electrolyte List of ions attracted to each electrode Name of the ion selectively discharge and ion formed at electrode. The reason why the ions selective discharge at cathode Half equation for the reaction at the each electrode.
[2 marks]
(c) Copper electrode X is replaced by carbon electrode. (i) State the type the reaction at this electrode. Give a reason. (ii) Write the half equation for the reaction at this electrode. (d) Diagram below shows the simple voltaic cell.
[10 marks]
[4 marks]
Electron flows from metal Q to metal P. Identify the negative terminal and positive terminal in this simple voltaic. State the observation in each terminal. [4 marks] 8. (a) (i) By state an example of reaction between acid and metal, explain the redox reaction in terms of change in oxidation number. (ii) By state an example, explain why double decomposition reaction not a redox reaction? (b) Reaction between copper(II) sulphate solution and zinc metal also is an example of redox reaction. (i) Name and write the half equation of this reaction to show oxidation and reduction process. (ii) State two observations that you can observe. Explain why. (iii) Copper(II) sulphate solution is replaced by the iron(III) chloride solution. State two observations and determine the oxidizing and reducing agent. [4 marks] [3 marks] [5 marks] [4 marks] [4 marks]
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9. (a) Salt is very important in our daily life. (i) State what is salt? (ii) Zinc nitrate is an example of soluble salt. State four reactions how to prepare zinc nitrate and write chemical equation for the each reaction. (b) A student wants to prepare 100 cm solution of sodium hydroxide 0.2 mol dm . [Relative Atomic Mass: Na, 23 ; O, 16 ; H, 1]
3 -3
[2 marks] [8 marks]
(i) Calculate the mass of sodium hydroxide necessary to prepare this solution. (ii) Explain how we want to prepare 100 cm3 sodium hydroxide solution 0.1 mol dm3 from the solution in (b)(i) through dilution process. 10. (a) Ethene is an example hydrocarbon compound. (i) What is meant by hydrocarbon and state the hologous series of ethene.
[7 marks]
[2 marks]
(ii) Ethene is bubble through bromine water. What is observation and state the type of reaction that occurred. Give the name and draw the structure formula of the product. [4 marks] (b) A hydrocarbon Z contains 82.75% of carbon by mass. [Relative Molecular Mass : C, 12 ; H,1] (i) Calculate the empirical formula of Z. (ii) Determine the molecular formula of Z if its Relative Molecular Mass is 58. (iii) Draw and name the all of isomers of compound Z. (c) Explain why vulcanised rubber more elastic than natural rubber. [4 marks] [3 marks] [4 marks] [3 marks]
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Chemistry Paper 3
Answer all questions
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1 Diagram 1.1 shows the set-up of apparatus used in an experiment to determine the position of different metals in the electrochemical series by measuring the voltage of different pairs of metals. The experiment is repeated by replacing metal M with metals N, P and Q and salt solution of M with the respective salt solutions of N, P and Q. The copper electrode is the positive terminal in all the experiments.
Diagram 1.1
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Diagram 1.2 (a) Record the voltmeter readings in the spaces provided in Diagram 1.2. (b) Construct a table to record the voltmeter reading for the different pairs of metals. [3 marks]
(c) State one hypothesis based on this experiment. ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________
[3 marks]
[3 marks]
(d) State the observations that can be made for this experiment after 20 minutes at: (i) The negative terminal _____________________________ _________________________________________ (ii) The positive terminal _____________________________ _________________________________________ (iii) The copper(II) sulphate solution __________________________ ____________________________________________ [3 marks]
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[3 marks]
[3 marks]
[3 marks] [3 marks]
(i) The experiment is repeated by using different pairs of metals as shown in Table 1. Predict the positive terminal and the voltage for each pair of metals by completing the table.
[6 marks] Table 1 (j) The following is a list of chemical substances: Sodium chloride Silver chloride Zinc sulphate Lead(II) sulphate Classify these substances into substances that can be made as an electrolyte and substances that cannot be made as an electrolyte.
[3 marks]
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Diagram 2.1 A group of students discovered that it is faster to dissolve the sugar cubes to make sugar solution by using hot water rather than cold water. This is due to the difference in the temperature of the water. Referring to the situation above, plan a laboratory experiment to investigate the effect of temperature on the rate of reaction between sulphuric acid and sodium thiosulphate solution. Your planning should include the following aspects. a) b) c) d) e) f) Statement of the problem All the variables Statement of the hypothesis Lists of substances and apparatus Procedure Tabulation of data [17 marks]
Jawapan
Chemistry
Chemistry Paper 1
Chemistry Paper 2
Chemistry Paper 3