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2Al2B CMMISTRY
A GLOSSARY OF CIIEItrCAL TERMS
ios in aqMB solutio alolo! domr' Acid b$. ildietor a $bslee thaiddti ile erd point ofm &id-bselitEliollv cbaging mlou A.lil dilsociatio! coNtdt (X,) lle eqfibnm coDsrdt 6r a rEaltio! i! wlich a proro! is rdoved 606 s eid by q-O ro 'ot the @lJugak bse tud hro'
Acial a sbstdce
Acid
Polurlotr bv sulol dlonde A.i{tic onde a covaleDt oxidellat diselves in 3al4 to give e @idic solnioa Actirated coEpler (tdsition sltte) lle afugdent of aro6 fobd ar the top of the pote ial !di6 s a Eactioq Ploceeds trbm reactmls to Products
a
rair
Esull of
turgt
ro
Activ.tio! .nerg/ the thJeshold oclet thal nst be oveFcone to plodlce a ch ical Eactio! Ad.tttio! pobnerizdior a t'?. ofloltoelizarior h thic! tbe Eonomm sisplv add togeth{ the polrDq, with no otls lbducis Additioh Mciior a e&tiotr itr wlich abtu add to a cdbotr{dbon dultiPle bold AlcoLol @ orsuic mnPoud in whicl the hvdroxvl Stoup is a $bstitue o!lbvdNdbo! Al{tehyil d orsaio @npoud colrailing Alkali netll s Gou! lA nel,l. All{dire canh Eetd a Crou! 2,A ded.
the
fom
@b@vl
gmDP
boded
1o at
ltoo
Alkar
fodda
CiII*l
Arkene esatuared hydrowbor courdinils a @bon_@bon doubl bond Tncsenqallomulais c.Hz, Alkylc m satMiedlydJocdbotr codrinins d hiPle 6botttrbon bond fte generil fomula i3
s$slaff lhai coltlins a nixtue of eleneft ad hs netall'c lropnis, Amho acid Doleqnes @nr3idlg d @inc grou dd a cdlorric &id grcqp wirn a side ch3ir o @ino eids harc the amino md cEborvla,le grcDps aiia.hed 1o rne see cdbod (caled o d cdbon) Trre taios duitu &ids dif.r h which side cn'i! ( R gronP) is
AIoy
ailached to
th.t d@!d
a substatre
acid or
s a b6e.
Aroit
i! a gaheia cel ar {hic! ondanor occEs. Aqueous mlutio! a sohnjo! i! vhic! wattI is the di$olving nedie or solvefi AftMtic [tdro@rbo! oE ofa slecidl clds of ctclic uah@led bvdrocdtos,
the el.ctrode
ArLe
us
prdM AtoDic !uDb. rhe truba ofprotos i! tlt luclels ofd aton Aionic Feig[t rle veiCltd avdage !6 of the atoa i! 5 tunely o@ing el@di AEilc e ot8dic lase d@Rd iod MoDia in $'ldch one or noE of the hyd$gm atoE
bas6
by oryeic grotps.
co!@pt
de Eplrced
al Ue
tu
nub.r
th
lutd
of atoms
i! @1ly
of
!e
Ea*
Bo
aqrleolls solutio4 3
Meltol
Bata.ry a erclp
ling
i! Fie$
pair d
Boyle!
hs
eleEotrlair foed il1lhe spee betweelt{o ato6 rhe mlue of a giad sdpie of g4 ar m.sbnr &nP@rue vei6 inv@ly wirh lle
a
Bm$tdd-LoiryDodl
d ei.l
is a
Prcld
doDor,
ard. bae
is a prcr@
gnup ca o! icaciil
carboryl
RCOOH.
the
-coog elow
o4alic
aid
e
&id {iinlne
gasd fo@lla
Calalyst
Crthod
Cathodic
@tio!
wirhod bdng
@@cd
4 dagl*iuE,
is
the electroile
i!
a
s SElvdic
*ll
al wlLic& EdDctiotr
ech.
c@&ted to slel in
pmtelio!
lrotat
order to
C.ltlotertirl(laronotivefore)
rdu.ilg agdi
in one
diving
@npdlEhl
in a galvdio @U lhat pull5 eleclros A$d thc io lhe oxidizing agedt in the oi!6.
foe
C!!rl6'L.v
Ch@ield
a
hpstue
ihe
rclde
of a given tup1e of
gs
at
c@talt
i! telviE
lrssw
is dircrly
prolonio!,lto the
a
cheni@lloud
th. fo@ or, doF accErely, tne ddgy. llat holds hto ato@ Lgetler in
@dpollh
chedicl D&d@
a
s.fiech&geofsubstd@sillootbqsubst@c*tbrolsh.Eorgoizali@oftheEtou;
lepsrtanos of a ohenical @no! slowing ihe ElatiE Mbes of reetalt
Cbdicsl $atior
dd
Ch.ui..l .quifbrisD
prcducts refuin indiale the
ofa]l r@taffs
dd
Cb.Eic.l 3toichiont y t!. cdcdariotr of the q@iili* of Miqial cosmed md prcdeed i! che@cal Eaclios, ChromatolFaplry ilc senqd n@ for a sies ofnetlods for sePdatine nir:nEs by ddovile
systeo qith a Eobile Phde eil a $alionaty Phe. CobDIq ior a cidsed s!.ci$ @Nistilg of a E lal i@ Mouded by lisdds
t$s
of a compobd ilwlichthe sJnbols for the elmdts re sat to of atoms presal dal subscripts @ Bed 10 show 1be Plalive aube$ of aldrds
CoEponnd
Prccesses.
pFce$ by wlich Epou noteculs Eforb a liquid CoDtl.nslrioD polyderilation a $!e ofpoltorizanod ia qhich the foEalio! of sDc! s {a1d, &conPdies the extelsioa ofthe polr@ cb.i,I
cobd.Nrtior
wa!
nole.ule,
Conjugsie
lcirl
bse
tbe sp4is
is added lo a
Conjupt'elciil-bsepan fio
PrcTOL
erch olhd by
conjlglto
wlar
rmis
lost
colt ctlroc$s
Foces for @,mfactuine sDlphuic @id Coorillllt covrlentbolal a oltlot bold lomed {!m a! the bodjng el@tod de sulpliedbv orlv on. atm. A pair ofmD bondirg ei4tlos oD oft atoo e attacted ro m m!9 val!@ eldgt lelel in dorhd aton, Coordinrrion Dunber ihe !u!d ofboDds fomed betweq the ndal lon ald the ligeds i! a complq
'_ Cor6to!
Foess by whch neials d. oudized inrle ahosph@ Coltldt boldiDg a tile ofhondilg in wlich electod de shded by ai.tr. Delogliz.iion ilre codition where rhe elect@ ir a nolule e not localized !.iwed bul cd bo\e LbFughou' Lbe dole.ule. Dondty a prclent ofmtlq FpEshli.s lle ods pd uit volrrc
the
pan of
alom
Dilrtior
corcatralior of solute id a soluiion Dtpoledipolertfmctio! lne athadlvc fdce EsutiDg whd pold ool*des Iire q so fiar ihe positive md lesarive sds N close r. @h ollq Dispenion rorcs rle fo@s, dislilg @ons mble gls alods oi! nonpola molecules. that iivolve m hdDced dilo1e rhat lleD i!d@! a monaitry dilole i! a leiglhou Disproporriotrrtior ractio! a H.tion i! wlich a gim ldat is both olidized md redMd Dlsiilrtio! a nelhod for sePealing tb. coEporcnts ofa liqlid DiltN ilat delslds on diffqenes ir Lhe 6e ol v"poiudoo of rb. cobPoDols Doubl. bold abod in vhlc! two lats oflectros ee shred bv two atobs. Dry ce[ battery a corffiotrbalteryEed h c!]crlators, wtches, mdios, odtape plavers. Elctrical olductiyity the ability io mndlct o elechio chdt ile
lFc*s
of addiag
elvdt
to
lom
the
Electruch.nistry lle slldy ofrbe inlerchuge ofclmical and eLecficl aerg/, Eleforysu a proe$ thal intoll* forcllc a cmet thrtlgh a cell to caue a loq_sPonialeou chenictl
r@tiorto @cu.
Elcfioltte
eled,c
cunst
Eaterial tlsl
dis$lvd j! mitr
10
sive
jos
md hsce condncls
ss
Etcnonagnetic ddirrion 6di@l endEy lhai exhhils mvelike betaviou ad havelx lhough ile sped ofliglt i! a vaoM Ele.ird! a nSatively ch.rged lanlcle that noles @u!d lle lucleu ofm aton, Eletronegatility inel dency ofm aloD i! a nolecule to atFacr s!@d elechos ro isell
slM
a1
Elnnt
cldioal
or
lhvsical
nes
Ehpincal
foE a
the simdest
il
codpoud,
vhic! lbe idicaid chrnges coiou, fldorbernic relss ro a'errioD wbm 6*s (3bm'r 0aws ilro Lhe stsm Equilibdu co$tdt ihe vahe oblajled when equilibriu colcmfratioB ofthe chenical sp6ies ee
in a riiralior ai subslituted in tle equ
ihnu
expre$ioE
set
Equilibriun posldon
particltar
ofequiljbdu colcetrtratios,
h
the pohr in alitdiot whetr emug! solDlion bitrs drraiEd.
Eqdvrletrcepolnt (stoicLiodetric
point)
titret hd beo
add.d to
I@t
Estcr e orgadc coEloud prcdutl by lle @ction betsten a @toaylic &id dd d alcohol Etot'heric rcf6 to a Mcrron $lEt 66e/ (4 h.ar) flos out ofthe ststd. Far (higlycrid,) d esiq conloed ofelycqol ed fatry eids. Fat'ty acirt a l@g-chai! dboxylic acid. A taa frtty @id ba cbais on the oplosite sidcs ofrhe
bond
double
dd
Filtrliio! a oethod for seldarhs lhe conlonsts of a nixtN offaining a solid and a liquid Fd cen a galtuio cel for wnich tle react nrs de continDouly $!pli.d,
Functional groEp d aloD or grcu ofalons in hydrocdbo! derivarlv* addiliod to csbotr md !Yd!oga.
$!t contds
el@mis
i!
c llvrtrjc
cel a dwie
a
in $ hjch
cd
cnojc.l
spoota,eob redor
ra
dob G chtrsed lo
cdrdlzing
GeoEefriciloEeBn isndiso al@geoals of lhe alons m diFent Also laoM s sreEo jsoneds, Grourl stlte the lowestlossible *eigj/ sr e ofe atom or nolecule. croip (ofrb. Deriodic trhle) avertical @l]jm of elmerls laving the stu valmce elctroD connguatior od slowitrg sinnd Prcpslies, Eabe.proc*s tie odnfactN of amoda &on nilroge! ad hy&oceD. cdjed oui at hish !t$uc
md lish tenpe6tE with the aid of
a catalyst.
zirc to prcvenr coEosior in wnich a[ dE boDrls h ll isotrB re tle @e but rhe spatial
coaied wilh
FydEfion $. in'erriotr bet'eeD $lrE pdicles ud wler Dole,deq. Etdrocrrbor a"ompoud omposed ofcabol rd lyd ogen Eydrog.! bonding muully stoDg dipole-digole attr@rim tbai ocN uong nol{ules i!
b).lrogeD is bonded to d
-.1 which
hjgbl)
ecuooegarjve 4!oo
Fydrog.blrion
r..dio! a twtio!
in
wljch hydroee!
is added,
{it!
calaltsl prcsm!
cdbon_
md may be sed
10
@t
fo.c6
Ion
m alon or
a
{ea! hteractios that ccE a souD of arotr rlat hb a lei lositive or Degatile cldge,
relatjvely
tithliol
Ionic soXd
slid mrlabins carios and dios rlar dissolvs jd watd to Cive a sohtion co ailing fie sepdaled ios whic! & dobile ud tls hee ro condncr eleclricol curat Iolization crrg,' 1Le q@tiry ofenergy reqniled ro reb.ve d el@bon fiom a geous aton or io! Isomers sp*ies {ith ihe sme fomDla bln ditrdai propefties.
Isotope| atos of lle sme ele@l (tle tu rwld of pbtoa) {i& difi@l orbd of dennos. Itey hare iddlicl rloFic E@bqs bu diGftlt Mls lbbes, K.ton. e oreradc @npoEd containile the carbonyt CroL" loaded 10 two catbon atotr L. chatelierrs P.incipl ifa ctdee i5 i.lposd otr s systen ai equllibainb, the losition oftle eqDilibliM sill shift ia a ditcti@ thar lads to Edw the efect ofrbat ch68.. Ligdd a rcutral nol.cde or e ion laviig a lore pln ofelectroB thai m b wd to fom a bontl to a
Limiting
the rea.t
-..:
slec]rm slowile olly certan disee wellgths. Lipid! {aier-hsoluble sbst@@s thal 6 be dlracted Aoh els by nolpold deMic solMts. Lo! prir a elefton lair thlr is localized o! a erv@ alon; d elston pan mt involv.il i! n@diig, iG5s the q@tily of datter i! & ob.ie*. M!$ numbe. the total lDld ofprotos 4d @lfoE i! the alooic tre14 of@ alon U*s percet tbe pmdtly Ms of s codloDdt of aoktue dof a giv@ elmfi! a 6@9oudM.t.l e eledat thlt eivcs rlp ellros rlatively @ily md is lD$tou, nslealle, eil a eood co lctor ofleat altt e1eltricitY. M ur. a mclial ofwisue cmlositioDthat @!tai!s two or moF $bstarces. Mohrnse tle ]16 i! gtfu of @e Eole ofEolculq @ fo@rna uits of a sulsltle; also c5ilel
Li!
lpe.td
bol*ord wient
r!
moles
Mol$ vollb
tlMe
of @e
ml
of
&
MoLrity
Mole
of$lln. ler
vo1@e ofsohtior
h lits
t;)
12C:
ile luber equd to ihe nunq ofcdboD atoG i! sactly 12 e],s ofpft AvoeadsS trubd, Or. Eole eprsenls 5.022 x l oa Eiis Mole btio (3toictioEt y) the hft of @les of one s$sta&e to boles of @l!er substde in a
(nol)
''
bal@d clmical equ.,tioD. Mole.ul.r eqlatid 6.qulid Epedtile a Mcri@ i! solution showils the ledtdrs ed Pr.d@ls i! udis$ciated forb, {,]rethd tley m sEo.s or wa& l4troitts, Molcculs forEr! theffictfonulsof anol6ul., sivinc tlclFsolalosodileaDbqofe&h Mol.cdrr shuctEe the rhs-diddional d@ger@l olaiotr in a nol@de. Molecul.rFlglrt thc EAs i! ells of ore nole of noldles or fomula Eirs of a $bsta!@; d 6olat naq.
sme
tbe
Molcule
Monopntic
tu
or
difr@nt el@@i1
rciil d
&id qitt
on rcidic
Foio!,
stroDg eleclrolrt s de sitten Nt tonlc eqt.iioD e equlid fd a Eacrim in solutio4 showile oDly lhose cooporetrs thal re diretlt involved in lbe ch@ical cldge
w!*
6 i@,
Networkloliil
NeuthUatiob
tu al@ic
e&l
bd&.
@ctio! o
acid-lase
!@tiol
Neuirc!
tte aiouc nucles wiib @s virtu,Iy equal to th Potont bln tfth no cldge Nonbgs a Grcup 1S elenent Norlectrcbi a sbsialce wlich, sia dis$lv.d in watq eiv4 alon4ondEtine sol
a particle in
id
Nonberrl e
exlititilg nelallic clecleristlcs CheDicaly, a t}?ical no@etal acclts dectnB aon a retal Nucleus lle sall, deBe c.!td oflositive clarge i! m alon Octet tule the obsfla,tion $at atons ofmm.tals tetrd 10 fom tle nost sfalle nolecules std rhev de
elen@r aot
eiglt .lct:os (lo fil tleir \]4ce otbitals). Orynic acid @ acid wilh a Ebo!_aion ba.kbolq ofid cortaiN 1!e caboxvl Crcup. Org$ic cheEisfry 1be study olcarbofconltidlg onlouds (t?icallv claj!. ofcuhon aroE md ileir !rclenies, ond.tio! m i!*6e in oxidarion slate (a los of dstou) Oiilation-.eductio! (reilor) ractior a t@1ioD i! wlLich ore or nore elechos d' tt sfercd' OidrtioD sbtes a colcepi that Provids a wal to ke.! tek of eltrons i! oxidaliotr-tdEtio! Eg.iios a@rdilg io cdtain rd4 Orlilizug agnt(eLctmr acc.pt'or) a Mclanl thal accePis eleciroff &oE doiherr@iatrt ?e.cent yield the adLd ield of a Aoducr N ! !q@t'gc of ile r!ffitioal ield' Periorlic tabl. a cn!i! sho*hg all rh eldenls msed in ollllm wiih sinilsi chmical Fopenies pII cuw (titr'lion cune) a plor shosing the pII ofa sldioDleils an'bkd s a nhcdor ofde suomded
by
on l0
dd
eluar
b $elg+l;
butaot
coNeDidl wav io
Elrht
elulioD
l!
i!
ph)sical cbfrg.
Pold covdlr
atEetst!
a
bod
corlent lond q whioh lle el@trou nde slronCly rla the othd
m mt s!@d
@le.de that h6 a pel:@at diPole boneni id containing a t@ber of aloms. PotJnor a l se, uu,lly chqinute nolcde buift noE my snall nolslles 0lotu6ds) PoryDriation a procss h {!icL ndy sdEll dolerdes (noNoes) @ joiffd tosetha to fod
uble b"rme tod ed sepaje loo Lhe 'olut* !.ircipalqurduEnMbcr rneq@tisnubaelatingtor!.sizmdaa5'oldorbiial; it@
:!so
have @y posiiive
ilt
gqaalue.
h is shoM
10
the right of
tle eow in
lntoD
Pure
aroDic
nucl4
substdc. a subslalce slin co6tal coopositiol Qutit tive salysis the s.pdalim eil idndncatio! ofildivjdu,l ioB Aon a ntxiue
ihe stovest slep
R tedetquining steP
R.Nt
nt
stafiing
i! a I@lion EahmisD, the ore deldbirbg lle overal ole sDb${oe in a clmical F nol It alPem 1o ile 1fl of lne @w h a cloical h enc4tratior ofa leaciat
or product
R@cdo!
rare
the ohdge
pd
uir
tqc
Rrlucing lgert (l.ctron .to!o r) are&tad rnat do@16 ele.lro6 to eorhd slbsirace to redlca the oxi.biio! sLte ofone of its atotu.
R.duction
el*hos)
Rqeribteralctior A.ea.lio! i! wnic! lle !rodets ce E;t to produce &e origi!,r Eeidts Salt d i@jc @oPoud. Saltbriilse a lint @!t!ini!g d elecilollte thal coll@is &e ttr con!a1t66rs of d electo.teEjcal
eU, allo{ing ion flowwirno$ o<t sive hixing ofrhe diedt sol ioB shieldiry lhe effdt by shich tne othd elect os scEe4 or shield, a cive! el@trotr
nucled chege.
ion
soEe ofthe
a@valmt bood in wlichtbe elctron Pan is shaed h d dea qtled o! bctw.a the a1oE. Slglificant figsd the cdiain digils and the 66t ucdla!! digit of a @asldedt SieD. (or)
bold
alir t@irs
Singl.bold .bo'di!whiclo@!anofelectr@bsharedbvtwoaLtu.
\*i
Sohbilit'y the @ou!t of a s$sla@ ilit dilsohes in a Civen voll@ of solvst st a giln tenpfttue Solute a sulslee dissohd in a liquid to fo@ a solnioL Sobtion ahodog@Eoixlue Solvdt the ilissolviry n di@ i! a solutior Spl6filingmodcl a Eodel ofa nol6de showing the Eladve sizes oflhe arod @d lbeir tlalive
Spelatoriols iosples t i!
soluliotrth.i do nor larticipate diFidy i! ac&iioE spoltdss procels a Foss tlat o@B witlo1tt outsid intwcdi@ si.!d!rd r.dudio. pordtial lhe pokorial of a halt-rdioD ud. i&ded s're @ditios. ollrqed aeaile $e Doteldal ol Lbe stalddd hvdmgh eledtode
StrDilrrd
kIalre$w qist slid,liqli4edgN Srates ofh.tter the rhee dlfferdl fom irwlichoatid @
Stllil.rd
StoichLiom.tric quaniiti* q@titie! of u! ai the sde time
Bohti@ wnose @ncotradon is @uielv kloM 1upmturc ud PGs!rc (STP) the mndiliotr 0.0'C 0tri11013
solulio!
the @riect
@outs
so
Sterg.ciil b
@id
. ; Strolgbare
ametd hydrodde salt thst @mpletelv diseciates iffo its ios i!wtei strong.l.cirolrt a bal@,r *icb, wld disolved i! wter, i@ises codpletelv. Oiry ios e Pselt in tle $lDtion. Stmctur.l fo@ a 6e rcp@sdtaiio! ofa nole.de it wlicl thc lelaiive positioN oflhe aio$ de slom md lle bo!& @ ildicated !Y lires. Stnctlml isoEerio iso@disn it *dic! Lhe isobeE ( orbi! tbe s@e doc bul ole ; Dor e bodds
halogeq Eploes a
i! a hldrocdbon
wlic! a $bsldce goes diretlt ton rhe solid to the gdeou staie wirhord pssilg tlrough the liqlid dare Titdtiob a t clliqle in wlicl o@ solulion is ue{t to analtze mothd T.llsitiorhettL sevdal sqies of elmelis i! riicn imd o6ilats (d q/ooiialt m bile filled
sublimtior
ihe prc@$ by
Triplebond
Urivdd ss coBtnt
or
3lr44YKmol, Vdeme eletlotrs thc.Lctos id ile outenosl pdrciPal qMlm l4el ofd aton V.len c Nlell clatro! prir replrsioE (VSEIR) nodl anodel*tGetuitlost]lareisrhltlhe sfenft eound r er(,b aid i! a ool@ule b deledired lircilally by nirjmizi4 electroFPair
Volutic rtulyli! a prcc6s hvolvile litdim ofore solntiotr *ith tuother Weaklcid e &id tnal dissialB ody lliclr]y in aqu@w sobtior Weakb$. a b6s tbnt rdls wirh wala to ptudu@ bdrcxi.te ic lo olly a sliehr exied h aqleou elufo!. wca* el.cbob't' a dol*rnm hataial wlich, w!@ drsolv.d u wrer, imiss only to a sEall extar OEly a ie{ ios *ist in the eui6 witl Eost offie slstEnce t@iriDg d bol6tils. Weight 1!e force qerted on 4 obj.ct by gEvily.