Professional Documents
Culture Documents
Introduction
Odours are among the most contentious of issues with regard to a piggery
operation. Pig farms generate odours that the surrounding community may
find offensive.
Odours from a piggery are a complex issue involving processes within the
piggery, in effluent collection areas, in storage ponds and manure spreading
areas.
Shed design, effluent collection and disposal systems, and overall piggery
management will influence the rate at which an odour is generated. The
impact of generated odours will be influenced by the climate and topography.
Location, design and good management practices aim to prevent odour
problems with nearby residences.
A suitable site is probably the most important factor for a successful system.
The following points should be noted:
• Soil type sho uld be light and free draining to avoid damage by tractors
and poaching by stock in the winter. Sandy soils on top of chalk or
gravel are ideal. Very thin soils that blow or those with very sharp flints
should be avoided. Sites should be managed to avoid leaching of
organic material and soil erosion that can cause problems in
watercourses and on public roads.
• Annual rainfall should be below 750mm, though this depends on the
soil type.
• Fields should provide natural shelter from the wind if possible and have
flat areas for the siting of huts or arks.
• Fields should have good access for vehicles and be close to staff
housing for security.
• Sites for outdoor sows are normally included in an arable rotation with
pigs being moved every year or every other year, depending on soil
type, stocking density and the arable management. At least two years
should be left before pigs are returned to the same site.
• Sows can be moved onto stubble or bare soil, but established grass is
preferred.
Feeding
• Sows are fed in groups with the feed distributed directly onto the
ground.
• Sows are not individually fed, as this is not practical outside. Feed
should therefore be spread over as wide an area as possible to help
ensure each sow receives an adequate share and to minimise bullying.
Common practice is to distribute feed in a line allowing at least two
metres per sow.
• As individual rationing is not possible the average daily feed allowance
is often higher to ensure all sows achieve an adequate intake so
figures for feed used per so w are higher that those for an indoor herd.
Extra feed should be provided in the winter.
• A good quality cob or ro ll will not break easily under foot and will
reduce wastage.
• Food must always be put on a dry area.
Service Management
Most outdoor herds choose one of the following service options:
In all cases boars should be run with groups of sows around 3 weeks after
service to detect any returns.
Management
The management of sows kept outdoors requires different skills than for
indoor systems due to the extensive nature of the system and the need to
cope with extreme weather conditions.
• Skilled staff that are fit and willing to work in all conditions are
essential.
• Access to clean drinking water is essential.
• Adequate shade and wallows should be provided to avoid heat stress
or sunburn in hot weather.
• Huts should be adequately bedded with straw at all times to ensure a
warm dry lying area.
• Clear sow identification using large plastic ear tags, tattooing or
electronic ear buttons is essential to ensure easy management and as
a basis for recording performance.
• In traditional layouts, trailers most easily move sows. This can also be
used as a mobile handling pen.
• Nose rings are often applied to prevent sows rooting and damaging the
paddocks, but this practice raises serious welfare considerations. A
single ring thro ugh the septum is preferred to reduce replacement
requirements. Boars should not be rung.
• A preventative health programme for o utdoor sows should be drawn up
in conjunction with a veterinary surgeon.
So that we all know what we are talking about we had better agree on the
terminology. The Agricultural Industry is endemic with different words
meaning the same thing. Apologies if these are a bit basic for some:
Ventilation Systems
Automatic Equipment
Light
• To check that pigs are in a state of well being they should be inspected
at least once per day. Any pigs suffering distress or pain should be
treated immediately.
• Any sick or injured pigs identified should, where necessary, be isolated
in dry bedded pens.
• To avoid unnecessary pain or distress, veterinary advice should be
sought as soon as possible for pigs that are not responding to the stock
keeper's care.
• Pigs sho uld be fed a diet that is suitable for their weight and age.
• They should be fed at least once per day and fresh water should
always be available in adequate quantities.
Floors
• Floors of pig houses should be smooth but not slippery and designed
not to cause injury to the pigs.
Tail Biting
• All pigs, taking into acco unt the environment and stocking density,
should be able to obtain straw or other material to satisfy their
behavioural needs.
Boar Pens
• Boar pens should be at least six square metres if they are to be used
for living only. A larger pen is required if the pen is also to be used as a
service area.
• Boar pens should be positioned so that the boars can see, smell and
hear other pigs.
For some, the problem seems simple: pigs stink. Why does it take a team of
specialists to figure that one out? And the simple answer is, it hasn’t.
We kno w, for instance, that a clean pig had about the same amount of body
odour as a clean human being. And we know, in general, why the swine-
odour problem was suddenly finding its way into headlines and public
debates. The main questions raised are:
What are the primary sources and causes of odours from sw ine
operations?
However, the same anaerobic process also releases volatile fatty acids,
whose odours people often find more offensive than either ammonia or
hydrogen sulphide. In fact, some 150 volatile compounds have been found in
swine waste. These compounds result from natural, biological reactio ns and
include organic acids, alcohols, aldehydes, fixed gases, carbonyls, esters,
amines, sulphides, mercaptans, and nitrogen heterocyclics.
Many of these compounds are carried by airborne dust and other particles,
some of which, in the confines of a swine house, may also contain pathogens
or physical irritants. Odorous mixtures vary with location, the size and type of
swine operation, production practices, season, temperature, humidity, time of
day, and wind speed and direction. With so many compounds and
environmental variables, it is often difficult to determine which compound--or
combination of compounds--is giving offence.
Whether people think of the odour as music or noise, many of those who live
or work near a swine operation would like to turn the volume down. Odours
can irritate, anger, or upset us, especially if we associate them with something
threatening, unpleasant, or beyond our control.
Sources of Odours
Typically, odours from swine operations originate from one or more of the
following sources:
Many of the volatile fatty acids and other compo unds associated with odour
attach themselves to dust. When dust from feed, dander, and other sources is
allowed to coat animals, walls, and ventilation systems, virtually every surface
releases odours. In a poorly ventilated building, these odours build up, and
they may escape in a concentrated dose.
Manure storage and treatment. In some countries, most animal wastes are
flushed, washed, pumped, scraped, or otherwise removed from swine
buildings, usually with water, and stored in lagoons. If lagoons are mature,
large enough, and well managed, offensive odours will be reduced. During the
start-up phase, which may last a year or more, some offensive odours will be
generated until materials and biological processes stabilise. Even in mature
lagoons, odours are released if raw wastes are added too rapidly or if a spring
warming creates a thermal inversion, lifting material from the deepest strata
toward the surface. Lagoon liquid used to flush pits or irrigate land releases a
relatively mild odour if it is drawn from the uppermost, aerobic layer of the
lagoon. But if pumping disturbs the deeper, anaerobic layers of a lagoon,
offensive odours will result.
Land application. Typically, lagoon liquids are removed from lagoons during
warm weather when they can be used to fertilize pastures, forests, or crops.
But these are the same seasons when heat and humidity can promote the
production of odour. If liquids drawn from lagoons have received adequate
treatment, odour is not usually a problem during and after irrigation.
Generally, because sludges remain in the lagoon for long-term storage and
treatment, they are applied to land very infrequently. But when anaerobic
sludges are spread across a field, odorous compounds may volatilise rapidly.
Until the materials are dry and stable, volatiles rise and move off-site in the
wind. Odours usually subside in one to three days, unless humidity is high or
the layer of sludge is too thick. If the material is applied in a thin, even layer
during dry, breezy weather and early in the day (between 8 a.m. and 2 p.m.),
Recent research indicates that odours outside swine farms are intermittent
and often may result from barely detectable levels of compounds--often in the
parts-per-billion range. Even so, the human nose is very sensitive, and an
odorous compound does not have to be very strong to raise an objection.
The extreme variability of sources, causes, environmental facto rs, and human
response makes it difficult to measure swine odours or determine some
objective limit for odour emissions. The problem is compounded by the fact
that an odour's offensiveness does not always correspond to its intensity.
For instance, odours produced by agitating anaerobic slurries have been
judged very offensive, even at low intensities, while odours ventilated from
swine houses have been judged less offensive, even at much higher
concentrations.
Several devices have been used to contain an odour and present it to a panel.
The simplest of these uses a cotton swatch. More elaborate tests use
instruments such s the scentometer and the olfactometer, both of which
dilute pungent air with odour-free air and the odour panel evaluates the
different dilutions. A concentration of odorants that can be detected by
observers is called the "detection threshold."
Each of the methods for assessing odours is expensive and time consuming.
Commercially available olfactometers can cost between $AUD15, 000 and
$AUD140, 000. An odour panel using these instruments should include up to
eight people, each of whom must be selected, trained, and compensated.
Such panels may be best suited for helping set the thresholds of certain
odorous compounds, or for calibrating the instruments used in odour
measurement. But panels may be too costly for use in routine testing and
monitoring.
Even so, the difficulty of measuring odours has not prevented the use of
thresholds and standards in Europe, and the European Economic Community
is moving to ward a common standardised procedure for the measurement of
odour. In Germany, thresholds based on the use of olfactometers have
withstood legal challenges. And in the Netherlands, ten certified laboratories
apply a standardized procedure for measuring odour - at co nsiderable cost.
The Netherlands has also adopted a new "Green Label" code for
environmentally friendly housing for animals. To qualify, the facility must not
exceed the threshold for ammonia emissions. Anotec ™ has since adopted
the Dutch Standard for Olfactometry – Forced Choice Method.
While ammonia is neither the only source of odour nor the most offensive,
studies in Europe consistently find that measures to reduce ammonia
generally do reduce odo urs from other compounds as well. In land application
of manure, for example, when Anotec ™ 0307 reduced ammonia emissions
by 75% it was found to reduce the overall odour by >98%. The biological
sources of ammonia--the digestive by-products of microbes--also yield other
odorous compounds. Drying or acidifying animal wastes stops microbial
action, preventing the production of odorous compounds. However, when
microbial action ceases, so does the reduction and transformation of nitrogen,
and thus more nitrogen remains in the wastes.
When investigators compared odours from different pig farms, several trends
emerged. Locations at the ventilating fans used with under-floor and tunnel
systems yielded the highest levels of odour. Even so, levels measured around
the buildings using these systems were generally lower than levels taken
Anotec ™ usually collects air samples for GC analysis and at times samples
for Olfactometry. The latter samples are presented to an odour panel, which
rate odours by their intensity and characterise each sample using descriptive
terms. It was determined that at each of the sampling sites, odours were
intermittent. Levels of odours tended to be highest during early morning and
evening when air turbulence was reduced and air movement approached
laminar (smooth) flow. In most samples, odours at 20 metres downwind from
the site were very faint (three to nine times above threshold). On one
occasion, however, a constant and invariable wind carried odour directly from
a site's ventilation fans to the sampling site 20 metres away. Without eddying
currents to dilute and disperse the odour, levels rose to 27 times higher than
threshold.
It was heartening to see that treatment with the Anotec ™ 0307 formulation;
the levels of odorous compo unds detected were extremely low. The analysts
had difficulty acquiring samples with enough molecular mass to be analysed
chemically (using a gas chromatograph and mass spectrometer). No
hydrogen sulphide was detected above 0.5 ppm, the limit of the detection
method. At the minute levels sampled, the odorous compounds were unlikely
to be toxic to humans.
In general, pigs excrete excess nitrogen when they ingest more protein than
they can efficiently use. In some diets, amino acids are not in balance with the
animal's requirements. In others, the source of protein used in the feed is
poorly digested. Improving the conversion of feed can not only reduce odour
but also lower feed bills, which represent about 60 percent of a swine
operation's production costs!
Odour-Control Additives
Adsorbents are products with a large surface area that may be used to
adsorb the odours before they are released to the environment. Sphagnum
peat moss, for example, has been found to reduce odour in some lagoons.
Each of these groups has its strengths and limitations. Masking agents and
Counteractants, for instance, can be effective in the short-term storage of
wastes. However, because these products typically are organic compounds
that can be broken down by bacteria, most of them quickly lose their
effectiveness in lagoons and tanks.
Recently, aggressive marketing has increased the use of digestive
deodorants. These products, which contain enzymes or bacteria or both, are
advertised for their abilities to break down solids, reduce the release of
ammonia, and conserve nitrogen. No one product affects all of the odour-
causing compounds possible in swine manure, however. Unless the
environments of lagoons and other waste-treatment systems are favourable,
supplemental bacteria may die off or fail to reach sufficient numbers to control
odour. Of the many products tested in the Netherlands and in Germany for
their ability to reduce odours from manure slurries, none has proven reliably
effective.
Mode of Action
Unlike masking agents, Anotec ™ Odour Control physically reacts with the
malodour by destroying its intermolecular structure leaving behind the Anotec
™ array, which naturally biodegrades. It has been proven using quality
precision instruments that have shown once the Anotec ™ odour control
product has been applied, the concentration of the components in the
malodour were significantly reduced and / or eliminated. The original
malodour cannot reconstitute itself, becoming non-volatile
Ideally, Anotec ™ Odour Control should be used where NEW odours are
constantly being released or introduced.
(i) (ii) (iii) (iv)
(v)
Malodour Anotec ™
Molecule (iii) & (iv)Anotec ™ Molecule
disassociates the malodour molecule
rendering it non-volatile. (v)The
Anotec ™ molecule then biodegrades
naturally.
This is the main reason why Anotec ™ Odour Control has been proven to be
superior to any other odour control measures, which favour treating the
malodour as a who le or concentrate on one particular constituent - such as
ONLY hydrogen sulphide in a sewage gas emission.
Properly managed, current technologies for ventilation help reduce odour and
provide a more healthful environment for workers and pigs.
Separating liquids fro m manure not only simplifies treatment but also enables
the development of useful products. In one European system, for instance, a
two-stage separator provides a solid (consisting of 65 percent dry matter),
which is composted for use as a potting medium in nurseries. The liquid
fraction is used as a fertilizer in hydroponic greenhouses. In Germany, solids
are often composted and marketed as fertilizers and soil amendments. This
practice has produced so much compost that the supply is exceeding
demand.
However, in Europe, not all swine wastes are treated on the farm. At some
locations, wastes are trucked at producers' expense to remote farms for direct
land application. At others, agricultural wastes are trucked to central plants for
treatment along with municipal or industrial sludges. Because these plants are
under pressure to prevent odour and reduce the volume of wastes applied to
land, several technologies have emerged over the last two decades.
In Denmark, for instance, one firm is using mechanical vapour compression to
evaporate and purify water from industrial and agricultural wastewater. The
system, which can separate swine wastes into dischargeable water and
concentrated, nutrient-rich slurry, is being tested for on-farm use. The
company involved estimates that three forty-foot modular plants plugged into
the slurry pipe of a swine facility could process 20 to 30 tons of waste per day.
Of course, each of the technologies discussed in this part of the document
has some limitations, and some may not prove to be practical for sites locally.
Also, while these technologies offer some advantages for odour co ntrol, they
do not in themselves reduce the net amount of nutrients that must be
managed in the system.
Like many other natural materials, bacteria that use oxygen can oxidise swine
manure. These bacteria efficiently transform the manure into a chemically
stable material, reducing both pathogens and odour. Some of these aerobic
For the purposes of odour control, the main advantage of aerobic treatment
of wastes is that it does not produce the vo latile fatty acids and various other
compounds associated with very offensive odours. The main disadvantage of
aerobic treatment is that it generally requires power to aerate the materials.
A number of researchers have presented evidence that treating swine waste
aerobically can lessen its odour. Aeration promotes the gro wth of bacteria that
can rapidly degrade phenol, p-cresol, volatile fatty acids, and other
compounds. If the solids are first removed, slurries treated aerobically
become more stable and produce fewer odours when they are subsequently
stored and applied to land.
Odour-Control Technologies
A number of technologies for reducing odour have been developed for
industries using or producing odorous compounds. These include
scrubbers,
incinerators,
adsorbing units using activated carbon,
condensers,
catalytic converters, and
biological filters.
Currently, the least costly technology for removing odours from large volumes
of air is the Anotec ™ Odour Control System. The system is identified as the
Cirrus Range of engineered systems and is custom built to suit any areas,
large or small, indoors or outdoors. The Cirrus system, a scientifically
developed misting system, coupled with Anotec’s ™ OCPs, treats the odorous
emissions that “scrubs” the malodour. This is turn means that there is a break
down of the volatile compounds into their elemental state rendering them non-
volatile and thus non-perceptible to the observers and their neighbours.
Anotec ™ OCPs can remove 90 percent or more of volatile organic
compounds, creates no secondary pollution, and is efficient in treating low
concentrations of odorants (less than 20 ppm).
By its nature, odour is an elusive and complex phenomenon, and any steps
we take toward odour reduction will no doubt be complicated by a number of
variables. In so me cases, predictive models, both mathematical and physical,
may help us account for this complexity and simulate the performance of
various technologies before they reach the field. To this end Anotec ™ has
been proven to be a wise choice, not merely for its significant effectiveness
treating odorous emissions but because it complies with the BATNEEC (Best
Available Technology Not Entailing Excessive Costs) policy the company has
adopted.
Informational:
Odours are primarily a subjective response; there are few universally good or
bad odours. People react to odours according to their attitudes and previous
experience. This factor is usable by livestock operators as they maintain an
image of responsibility and productivity. Operators of well-maintained and
attractive facilities who have maintained a cooperative public attitude are
seldom subjected to odour complaints. Odour frequently becomes an issue
along with complaints of water pollution, flies, noise, and other issues when
there is faulty site selection, improper facility design, or inadequate
management.
Compounds emanating from livestock buildings have never exceeded safe air
standards and are not hazardous to humans. Under certain situations, such
as manure pit agitation, however, dangero us gas concentrations can develop.
Odours, therefore, are nuisance pollutants and, like other nonhazardous
assaults on the environment, must be regarded accordingly. Important are
intensity, duration, and frequency of detection. Within an agricultural
community, it seems appropriate that livestock odours be occasionally
The seco nd opportunity for reducing odour problems occurs during the design
and construction of a facility. By application of odour control principles, the
probability of odour can be minimised. Designing outdoor lots that are well
drained, watering systems that do not flow onto the lot surface, and runoff
control facilities that are remotely located from areas of odour sensitivity will
achieve some odour reduction. In modern, roofed housing units the methods
of manure removal from the pens, manure transport, and handling are most
important for odour control. Also, animals must be kept clean and dry. Among
approaches for accomplishing this are slotted floors, flushing gutters, and
frequent pen scraping. Covered storage tanks control odour release from
stored manure. Where treatment is required and odour control is important,
aerobic systems such as oxidation ditches and floating surface aerators,
altho ugh more expensive, are effective to curtail odour emissions.
Disposal techniques and timing are also important for odour control. When
manure is applied to cropland, a field downwind of neighbouring residences
on that day is important. Morning application is more desirable than late
afternoons, which limits drying time. Neighbours are generally most sensitive
to odour problems in early evening when utilizing outdoor recreational
facilities. When manure disposal is necessary and odour control is critical,
immediate incorporation of the manure can effectively minimize odour
complaints. Where soil is suitable and neighbours are particularly close, direct
soil injection is a valuable technique.
Aerobic manure treatment systems are helpful. Most co mmon among these
are oxidation ditches, aerated storage tanks, and aerated lagoons. By
maintaining manure in an aerobic condition, odorous gas production is
markedly reduced. For each of these systems it is important that adequate
aeration capacity be provided and that management is sufficient to keep the
equipment in top operating condition. Manure solids separation may be
practiced ahead of each of these systems to minimize aeration demands.
Odour generation
Odour dispersion
When air carries an odour from the source, dispersion or dilution of the odour
occurs. This results in a declining odour concentration with increasing
distance downwind of the source. This reduction in odour concentration is
dependent on the atmospheric stability at the time.
Odour will not disperse and mix on a cold and still night as it would during a
windy hot day. The stability criteria explain how such factors as the time of
day, clo ud cover and wind speed affect odour dispersion. In simple terms, the
lower the stability class (closer to A) the better the odour disperses and
subsequently the potential for odour nuisance is less. (See Table next page)
<2 A A-B B G G
2-3 A-B B C E F
3-5 B B-C C D E
5-6 C C-D D D D
>6 C D D D D
*Where A = best odour dispersion
Air scrubbing with Anotec ™ spraying equipment to reduce odour levels within
swine buildings has been studied and is recommended for use most building
designers that are unable to control odours within their units by other means.
Anotec ™ Odour control chemicals are widely available. Extensive data exists
concerning the effectiveness of the formulations in a variety of industries.
Anotec ™ has been proven to be effective under specialised conditions; and
other formulations have been developed for “routine” or “known” odours. The
cost of using Anotec ™ odour co ntrol chemicals is variable depending on the
type of formulation and vo lumes required, but generally they are an
inexpensive alternative to masking agents or other “odour control” chemicals.
Research has shown that “other” Liquid products are quoted at $10-20 per
litre and solid forms at $1-15 per 500 gms. Anotec ™ products are available in
a concentrated formulation at a cost considerably lower than those mentioned
above. It is important that a trial be conducted with the Anotec ™ control
chemical to make certain it operates to your satisfaction before you buy large
quantities.
Anotec ™ wet scrubbing of the exhaust air with its chemicals can
significantly reduce odours (66-98%) and is inexpensive. Spraying the
Anotec ™ Odour Control Additives (OCAs) can be added to deep pits. Field
tests have shown approximately a 32% year-round reduction in ammonia
emissions by delivering Anotec™ in metered amounts to the pit surface in
grow-finish buildings.
100 86 144 48 79
500 193 321 106 177
1000 272 454 150 250
2000 386 643 212 354
3000 472 787 260 433
4000 545 909 300 500
5000 610 1016 336 559
7500 746 1244 411 685
10000 862 1437 475 791
Have external open drains that are impervious, with non-earthen base
and sides, which are kept clean and dry between uses.
Incorporate piggery solids (sludge and screenings) into the soil within
24 ho urs of spreading, where practical.
The old saying “out of site - out of mind” works very well for piggeries. The
planting of trees around existing piggeries or siting new piggeries in a wooded
area will make them less obvious to the public and generally reduce the
incidence of odour complaints. Properly planted tree buffers also have the
potential to reduce odour detection at receptors by dispersing the odour.
And, as discussed earlier in this document, it is also advisable to set up lines
of communication with neighbours. Many odour complaints arise from
disagreements and misunderstanding.
The standards for the terminology below are identified as ASAE S466,
Nomenclature/Termino logy for Livestock Waste/Manure Handling Equipment
and ASAE S292.4, Uniform Terminology for Rural Waste Management. The
following definitions, also directly relative to lagoon management, have been
taken from ASAE S466 and ASAE 292.4 with the permission of the American
Society of Agricultural Engineers:
Aerobic bacteria: Bacteria that require free elemental oxygen for their
growth. Oxygen in chemical combination will not support aerobic organisms.
Aeration: A process causing intimate contact between air and a liquid by one
or more of the following methods: (a) spraying the liquid in the air, (b) bubbling
air through the liquid, and (c) agitating the liquid to promote absorption of
oxygen through the air liquid interface.
Earthen storage basin: An earthen structure usually with sloping sides and a
flat floor, constructed to store semisolid, slurry or liquid manure. Also called a
waste storage pond.
Escherichia coli (E. Coli): One of the species of bacteria in the intestinal
tract of warm-blooded animals. Its presence is considered indicative of fresh
faecal contamination.
Facultative bacteria: Bacteria that can use either free oxygen or reduced
carbon compounds as electron acceptors (as in organic substrates like
sugars, starches, etc.) in their metabolism.
Fixed solids: The portion of the total solids remaining as an ash or residue
when heated at a specific temperature and time (usually 61600C or 111 20F
for at least one hour).
Food to micro-organisms’ ratio (F/M): The weight ratio of biodegradable
organic matter (BOD) to micro-organisms.
Grassed infiltration area: An area with vegetative cover where runoff water
infiltrates into the soil.
Infiltration rate: The rate at which water enters the soil or other porous
material under a given condition, expressed as depth of water per unit time,
usually in millimetres per hour.
Loading rate: The quantity of material added per unit volume or unit area per
unit time.
Seepage: (1) Percolation of water through the soil. (2) The slow movement of
water through small cracks, pores, interstices, of a material. (3) The loss of
liquid by infiltration from a canal, reservoir, manure tank or manure stack. It is
generally expressed as flow volume per unit time.
Settable solids: (1) That matter in wastewater that will not stay in suspension
during a preselected settling period, such as o ne hour. (2) In the Imhoff cone
test, the volume of matter that settles to the bottom of the cone.
Solids content: (1) The sum of the dissolved and suspended constituents in
water or wastewater. (2) The residue remaining when the water is evaporated
away from a sample of sewage, other liquids, or semi-solid masses of
material and the residue is then dried at a specified temperature (usually
1030C for 24 h); usually stated in milligrams per litre or percent solids.
Suspended solids: (1) Solids that are in water, wastewater, or other liquids,
and which are largely removable by filtering or centrifuging. (2) The quantity of
material filtered from wastewater in a laboratory test, as prescribed in APHA
Standard Methods for the Examination of Water and Wastewater.