Material Safety Data Sheet

Transportation and Medical Emergency Phone: 1-800-535-5053

(INFOTRAC)
General Phone: 317-580-8282

EPA Reg. Number: 62719-37-67690

Effective Date: 01/22/03

Renovate 3 Herbicide †
SePRO Corporation Carmel, IN 46032

1. PRODUCT AND COMPANY IDENTIFICATION smoky or halo vision. When tested on animals, dilutions of
this material were less irritating to eyes than the undiluted
PRODUCT: Renovate† 3 Herbicide product.

COMPANY IDENTIFICATION: SKIN: Prolonged or repeated exposure may cause skin

SePRO Corporation irritation, even a burn. When tested on animals, dilutions
11550 North Meridian Street, Suite 600 of this material were less irritating to skin than the undiluted
Carmel, IN 46032 product. Prolonged or frequently repeated skin contact
www.sepro.com may cause allergic skin reactions in some individuals.
With the dilute mix, no allergic skin reaction is expected.
2. COMPOSITION / INFORMATION ON INGREDIENTS A single prolonged exposure is not likely to result in the
material being absorbed through the skin in harmful
Triclopyr ((3,5,6-trichloro-2- CAS # 057213-69-1 44.4% amounts. The LD50 for skin absorption in rabbits is
pyridinyl)oxy)acetic acid), >5000 mg/kg.
triethylamine salt
Inert Ingredients, Total, Including 55.6% INGESTION: Single dose oral toxicity is low. The oral
Ethanol CAS # 000064-17-5 LD50 was 2574 mg/kg for male rats and 1847 mg/kg for
Triethylamine (N,N- CAS # 000121-44-8 female rats. Small amounts swallowed incidental to normal
Diethylethanamine) handling operations are not likely to cause injury; however,
Ethylenediaminetetraacetic CAS # 000060-00-4 swallowing larger amounts may cause injury. Ingestion
Acid (EDTA) may cause gastrointestinal irritation or ulceration.

This document is prepared pursuant to the OSHA Hazard
Communication Standard (29 CFR 1910.1200). In
addition, other substances not 'Hazardous' per this OSHA
Standard may be listed. Where proprietary ingredient
shows, the identity may be made available as provided in
this standard.
3. HAZARDOUS IDENTIFICATIONS
EMERGENCY OVERVIEW
Hazardous Chemical. Light purple-pink liquid, ammonia-like odor.
May cause severe eye irritation with corneal injury, which may result
in permanent impairment of vision, even blindness. Prolonged or
repeated exposure may cause skin irritation, even a burn. LD50 for
skin absorption in rabbits is >5000 mg/kg; oral LD50 for male rats is
2574 mg/kg and 1847 mg/kg for female rats. Toxic and irritating
gases may be formed during fire conditions.
EMERGENCY PHONE NUMBER: 1-800-992-5994
POTENTIAL HEALTH EFFECTS: This section includes
possible adverse effects, which could occur if this material
is not handled in the recommended manner.
EYE: May cause severe irritation with corneal injury, which
may result in permanent impairment of vision, even
blindness. Vapors of amines may cause swelling of the
cornea resulting in visual disturbances such as blurred,
INHALATION: A single brief (minutes) inhalation exposure
is not likely to cause adverse effects.
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS:
Excessive exposure may cause liver or kidney effects.
CANCER INFORMATION: Triclopyr did not cause
cancer in laboratory animal studies. This material contains
ethanol. Epidemiology studies provide evidence that
drinking of alcoholic beverages (containing ethanol) is asso-
ciated with cancer, and IARC has classified alcoholic bever-
ages as carcinogenic to humans.
TERATOLOGY (BIRTH DEFECTS): For triclopyr, birth
defects are unlikely. Even exposures having an adverse
effect on the mother should have no effect on the fetus.
Ethanol has been shown to cause birth defects and toxicity
to the fetus in laboratory animal tests. It has also been
shown to cause human fetotoxicity and/or birth defects
when ingested during pregnancy.
REPRODUCTIVE EFFECTS: For triclopyr, in laboratory
animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent
animals. Ingestion of large amounts of ethanol has been
shown to interfere with fertility in human males.

†Renovate is a registered trademark of Dow AgroSciences LLC manufactured for SePRO Corporation.
 Material Safety Data Sheet
Renovate 3 Herbicide †
4. FIRST AID
EYE: Wash immediately and continuously with flowing
water for at least 30 minutes. Remove contact lenses after
the first 5 minutes and continue washing. Obtain prompt
medical consultation, preferably from an ophthalmologist.
SKIN: Wash skin with plenty of water.
INGESTION: Do not induce vomiting. Give one cup (8
ounces or 240 ml) of water or milk if available and transport
to a medical facility. Do not give anything by mouth to an
unconscious person.
INHALATION: No emergency medical treatment
necessary.
NOTE TO PHYSICIAN: Due to irritant properties, swallowing
may result in burns/ulceration of mouth, stomach and lower
GI tract with subsequent stricture. Aspiration of vomitus may
cause lung injury. Suggest endotracheal/ esophageal control
if lavage is done. If burn is present treat as any thermal burn,
after decontamination. Exposure to amine vapors
may cause minor transient edema of the corneal epithelium
(glaucopsia) with blurred vision, blue haze, and halos around
bright objects. Effects disappear in a few hours and
temporarily reduce ability to drive vehicles. No specific
antidote. Treatment of exposure should be directed at the
control of symptoms and the clinical condition of the patient.
5. FIRE FIGHTING MEASURES
FLASH POINT: 110˚ F (43˚ C)
METHOD USED: TCC
FLAMMABLE LIMITS: LFL: Not determined
UFL: Not determined
EXTINGUISHING MEDIA: Alcohol foam and CO2.
FIRE AND EXPLOSION HAZARDS: Toxic, irritating vapors
may be formed or given off if product is involved in fire.
Although product is water-based, it has a flash point due to
the presence of small amounts of ethanol and triethylamine.
FIRE-FIGHTING EQUIPMENT: Use positive-pressure,
self-contained breathing apparatus and full protective
clothing.
†Renovate is a registered trademark of Dow AgroSciences LLC manufactured for SePRO Corporation.
2
6. ACCIDENTAL RELEASE MEASURES
ACTION TO TAKE FOR SPILLS/LEAKS: Contain small
spills and absorb with an inert material such as clay or dry
sand. Report large spills to InfoTrac at 1-800-535-5053.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND
STORAGE: HANDLING: Keep out of reach of children.
Causes irreversible eye damage. Harmful if inhaled or
absorbed through skin. Prolonged or frequently repeated
skin contact may cause allergic skin reaction in some
individuals. Avoid contact with eyes, skin, clothing, breathing
vapor, or spray mist. Users should wash hands before eat-
ing, drinking, chewing gum, using tobacco, or using the toilet.
STORAGE: Store above 28˚F or agitate before use. Store
in original container. See product label for handling/storage
precautions relative to the end use of this product.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
These precautions are suggested for conditions where the
potential for exposure exists. Emergency conditions may
require additional precautions.
EXPOSURE GUIDELINE(S):
Ethanol (ethyl alcohol): ACGIH TLV and OSHA PEL are
1000 ppm. ACGIH classification is A4.
3,5,6-Trichloro-2-pyridyloxyacetic acid (Triclopyr),
triethylamine salt: SePRO Corporation Industrial Hygiene
Guideline is 2 mg/M3 as acid equivalent; Skin.
Triethylamine: ACGIH TLV is 1 ppm TWA, 3 ppm STEL,
Skin. OSHA PEL is 10 ppm TWA, 15 ppm STEL.
PELs are in accord with those recommended by OSHA,
as in the 1989 revision of PELs.
A "skin" notation following the exposure guideline refers to
the potential for dermal absorption of the material. It is
intended to alert the reader that inhalation may not be the
only route of exposure and that measures to minimize
dermal exposures should be considered.
ENGINEERING CONTROLS: Provide general and/or local
exhaust ventilation to control airborne levels below the
exposure guidelines.
 Material Safety Data Sheet
RECOMMENDATIONS FOR MANUFACTURING,
COMMERCIAL BLENDING, AND PACKAGING
WORKERS:
RESPIRATORY PROTECTION: Atmospheric levels
should be maintained below the exposure guideline. When
respiratory protection is required for certain operations, use
a NIOSH approved air-purifying respirator.
SKIN PROTECTION: When prolonged or frequently
repeated contact could occur, use protective clothing
impervious to this material. Selection of specific items
such as faceshield, gloves, boots, apron or full-body suit will
depend on operation.
EYE PROTECTION: Use chemical goggles. Eye wash
fountain should be located in immediate work area.
If vapor exposure causes eye discomfort, use a NIOSH
approved full-face respirator.
APPLICATORS AND ALL OTHER HANDLERS: Refer
to the product label for personal protective clothing and
equipment.
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: Not determined
VAPOR PRESSURE: Not determined
VAPOR DENSITY: Not applicable
SOLUBILITY IN WATER: Miscible
SPECIFIC GRAVITY: 1.135 (68/68˚F)
APPEARANCE: Light purple/pink liquid
ODOR: Ammonia-like odor
10. STABILITY AND REACTIVITY
STABILITY: (CONDITIONS TO AVOID) Avoid sources of
ignition if temperature is near or above flash point.
INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID)
Any oxidizing agent. Consult manufacturer for specific
cases.
HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen
oxides and hydrogen chloride may be formed under fire
conditions.
HAZARDOUS POLYMERIZATION: Not known to occur.
3
Transportation and Medical Emergency Phone: 1-800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 62719-37-67690
Effective Date: 01/22/03
SePRO Corporation Carmel, IN 46032
11. TOXICOLOGICAL INFORMATION
MUTAGENICITY: For triclopyr and ethanol: in-vitro
mutagenicity studies were negative. For triclopyr: animal
mutagenicity studies were negative. For ethanol: animal
mutagenicity studies were negative in some cases and
positive in other cases.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE:
MOVEMENT & PARTITIONING: Based largely or
completely on information for triclopyr. Bioconcentration
potential is low (BCF < 100 or Log Pow < 3).
DEGRADATION & PERSISTENCE: Biodegradation under
aerobic static laboratory conditions is high (BOD20 or
BOD28/ThOD > 40%). 20-Day biochemical oxygen
demand (BOD20) is 0.30 p/p. Theoretical oxygen demand
(ThOD) is calculated to be 0.75 p/p.
ECOTOXICOLOGY: Material is slightly toxic to aquatic
organisms on an acute basis (LC50/EC50 is between 10 and
100 mg/L in most sensitive species).
Acute EC50 for shell deposition inhibition in Eastern oyster
(Crassostrea virginica) is 56-87 mg/L.
Acute LC50 for rainbow trout (Oncorhynchus mykiss) is
400 mg/L.
Acute LC50 for channel catfish (Ictalurus punctatus) is
446 mg/L.
Acute LC50 for pink shrimp (Penaeus duorarum) is
895 mg/L.
Growth inhibition EC50 for green alga (Selenastrum
capricornutum) is 45 mg/L.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Do not contaminate food, feed, or
water by storage or disposal. Excess wastes are toxic.
Improper disposal or excess wastes are a violation of
federal law. If wastes resulting from the use of this product
cannot be disposed of according to label instructions,
dispose of these wastes at an approved facility. Contact
your state pesticide or environmental control agency, or the
hazardous waste representative at the nearest EPA
regional office for guidance.
 Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
(INFOTRAC)
General Phone: 317-580-8282

EPA Reg. Number: 62719-37-67690

Effective Date: 01/22/03

Renovate 3 Herbicide †
SePRO Corporation Carmel, IN 46032

CHEMICAL NAME CAS NUMBER LIST

14. TRANSPORT INFORMATION
Ethylenediamine
For DOT regulatory information, if required, consult Tetraacetic Acid 000060-00-4 NJ3 PA1 PA3
transportation regulations, product-shipping papers, or Ethanol 000064-17-5 NJ1 NJ3 PA1
contact your SePRO Corporation representative. N,N-Diethylethanamine 000121-44-8 NJ1 NJ3 PA1 PA3

15. REGULATORY INFORMATION NJ1 = New Jersey Special Health Hazard Substance (present at >
or = to 0.1%).
NOTICE: The information herein is presented in good faith PA1 = Pennsylvania Hazardous Substance (present at > or =
and believed to be accurate as of the effective date shown to 1.0%).
above. However, no warranty, express or implied, is given. PA3 = Pennsylvania Environmental Hazardous Substance
Regulatory requirements are subject to change and may (present at > or = to 1.0%).
differ from one location to another; it is the buyer's responsi-
bility to ensure that its activities comply with federal, state or OSHA HAZARD COMMUNICATION STANDARD:
provincial, and local laws. The following specific This product is a "Hazardous Chemical" as defined by the
information is made for the purpose of complying with OSHA Hazard Communication Standard, 29 CFR
numerous federal, state or provincial, and local laws and 1910.1200.
regulations.
NATIONAL FIRE PROTECTION ASSOCIATION
U.S. REGULATIONS (NFPA) RATINGS:
CATEGORY RATING
SARA 313 INFORMATION: This product contains the Health 3
following substances subject to the reporting requirements Flammability 2
of Section 313 of Title III of the Superfund Amendments Reactivity 0
and Reauthorization Act of 1986 and 40 CFR Part 372:
COMPREHENSIVE ENVIRONMENTAL RESPONSE
CHEMICAL NAME CAS NUMBER CONCENTRATION COMPENSATION AND LIABILITY ACT (CERCLA, or
N,N-Diethylethanamine 000121-44-8 3% SUPERFUND): This product contains the following
substance(s) listed as "Hazardous Substances" under
SARA HAZARD CATEGORY: This product has been CERCLA which may require reporting of releases:
reviewed according to the EPA "Hazard Categories"
promulgated under Sections 311 and 312 of the Superfund Chemical Name CAS Number RQ % in Product
Amendment and Reauthorization Act of 1986 (SARA Title Triethylamine 000121-44-8 5000 3%
III) and is considered, under applicable definitions, to meet Ethylenediaminetetra- 000060-00-4 5000 2.3%
the following categories: acetic Acid (ETDA)
An immediate health hazard
A delayed health hazard RCRA Categorization Hazardous Code:
A fire hazard Triethylamine = U404

TOXIC SUBSTANCES CONTROL ACT (TSCA): All 16. OTHER INFORMATION

ingredients are on the TSCA inventory or are not required
to be listed on the TSCA inventory. MSDS STATUS: New 01/22/03

STATE RIGHT-TO-KNOW: The following product The information herein is given in good faith, but no
components are cited on certain state lists as mentioned. warranty, express or implied, is made. Consult SePRO
Non-listed components may be shown in the composition Corporation for further Information.
section of the MSDS.

Form No. A-02-RG-01(03) © Copyright 2003 SePRO Corporation.

†Renovate is a registered trademark of Dow AgroSciences LLC manufactured for SePRO Corporation. 4