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RISK ANALYSIS

ACCORDING TO EU MACHINERY DIRECTIVE CE/2006/43

Project

10892 - HARLINGEN

Document n 10892EA00400

Table of Content

1 - General part 2 - List of specific parts 3 - Risk Interfaces 4 - EC certificates 5 - List of norms applied

p2 p5 p 43 p 44 p 45

Date Written by :

02/03/2011 IS

Revision Checked by : AB GL

0 first edition Approved by : PMi

1- General part CE MARKING - RISK ANALYSIS ACCORDING TO EU MACHINERY DIRECTIVE CE/2006/42 ORIGIN AND KIND OF RISKS
1.1 GENERAL REMARKS
1.1.1 Definitions 1.1.2 Principles of safety integration

POTENTIAL CONSEQUENCES

REMEDIES AND REFERENCES

Personal and mechanical damages due to uncorrect design All equipment with moving part (fans, pumps, motors, conveyors, mixers ) and/or abnormal use Actuators, dampers, valves, instruments Access to instruments, actuators, equipment

- Lay-out reviews for circulation inside the plant, access to instruments, actuators, equipment ...HAZOP studies - Equipment CE marking by sub-supplier + Machines Directive - Operating & maintenance instructions in dutch language for each equipment - Marking, labelling - Training Yearly audit by Bureau Veritas of LAB SA for design and studies and control of subsuppliers. Quality certificate ISO 9001 ver. S2000. Steel structure calculations done by specialized companies + material products for steel (origin from European Community) Safety data sheet Training Marking & labelling HAZOP studies Level indicator & alarm Filter Safety valve on silo Activated carbon NORIT GL50 or SGL CARBON LINK (see safety datasheet in asbuilt documentation (DOE) section A 01 "safety") Level indicator & alarm Filter Safety valve on silo ATEX classification Safety data sheet Training Marking & labelling Safety valves PED certificates for economizer, hot water piping, SCR steam heater Packed in closed containers Safety datasheet Maintenance instructions Retention tank Detector, alarms, safety valves, explosion disc Safety datasheet Retention under tank and pumps and unloading area negative pressure; tightness requirements in technical specifications to sub-suppliers negative pressure; tightness requirements in technical specifications to sub-suppliers Level indicator & alarms Filter Electrical tracing -For the record - Under OMRIN responsability -For the record - Under OMRIN responsability Asbestos or carcinogen ceramic fibers not allowed Special precaution in case of welding. By the client Special care for internal lighting during inspection Carcinogen ceramic fiber not allowed, refer to Technical Specification Protected by cladding

1.1.3 Materials and products

General design Steel structure and equipment in steel material All products (liquids, solids) for operation of the plant: loading/unloading, use ) Corrosion

Personal damage

Sodium bicarbonate

Personal damage

Activated Carbon

Personal damage, explosion

Glycol Hot water & steam Lubricants/oil/grease Oil for HV transformer + oil for silo extraction system Ammonia Flue gas Dust Residue Nitrogen for inertisation of silos and fabric filter Gas for analyser Gaskets, sealing devices Expansion joints, plastic, polymer material for valves Heat insulation
1.1.4 Lighting

Personal damage Personal damage Personal damage Personal damage, flamable Personal damage, environment damage Personal damage & corrosion Personal damage & corrosion Personal damage & corrosion

flamable Personnal damage

Not applicable - OMRIN scope - No special LAB requirements


1.1.5 Design of machinery to facilitate its handling

General maintenance of the plant

Personal injuries

General handling/lifting of equipment > 20 kg (contract) Fan dismantling Catalyst handling


1.1.6 Ergonomics

Equipment damage + personal injuries Equipment damage + personal injuries Equipment damage + personal injuries

Refer to general instructions in maintenance manual: helmet + gloves + safety shoes are mandatory - Special clothes protection for operation inside specific equipment (silos, ) Lifting lugs required in Technical Specification Hinged man hole Tests/inspections of lifting beams Marking of lifting beams Special access, beam and procedure, refer to training Special access, beam and procedure, refer to training Access review on layout done with OMRIN Fulfillment of contract (European Norms EN 389, 547-1, 614-1, 894-1 + Dutch laws) for space around equipment, height for access, staircases . Thermal emission data supplied to OMRIN for design of the ventilation unit Global acoustic calculation for building definition by OMRIN Minimum diameter for manholes 800mm + mounted on specific hinges when > 20kg Integration in a new OMRIN control room Control System screen views approval by OMRIN

All equipment

Manholes Control room


1.1.7 Operating positions

Personal damage Ammonia injection : chemical risks Specific rooms (limestone room, analysers room)
1.1.8 Seating

Personal damage & corrosion

Escape routes discussed/agreed with OMRIN + local fire people Refer to above for alarms; Special dedicated devices as showers, eyes cleaning Individual personal protection equipments required OMRIN scope

Not applicable for onsite equipment 1.2 CONTROL SYSTEMS


1.2.1 Safety and reliability of control systems

PCS system requested by OMRIN : low availability and/or failure in operation Sensitive operating measurements (temperature, pressure ) Instruments, valves, electrical cabinet damage due to environment
1.2.2 Control devices

Abnormal operation of the plant + high number of stops Damage of instruments + stop of the plant Damage of equipment Damage of equipment + risks for operators Damage of equipment + risks for operators

Availability guarantee by siemens / OMRIN Installation of 3 instruments + operation on 2/3 according to SIL study Specific protection class (IP54, IP55, IP65, ATEX) for instance depending on location/utilisation Process risk analysis + LAB functional analysis Local maintenance switches of the equipment with moving parts Co-ordination with boiler (pre-ventilation sequences ), see interfaces in chapter 3 Emergency devices (safety positions for fans, fabric fitler bypass, SCR bypass, safety valves ) / Operating manual

Programming of PCS + start-up/stop conditions


1.2.3 Starting

Start of each individual equipment Start of the plant through sequences / Error in programming
1.2.4 Stopping

Automatic stop of the plant (sequences) - Risk of damage of the plant

Damage of equipment + operators risks

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ORIGIN AND KIND OF RISKS


Emergency stop of the plant Safety position of individual equipment during long stops Stoppage for maintenance or dismantling
1.2.5 Selection of control or operating modes

POTENTIAL CONSEQUENCES
Damage of equipment Equipment damage + personal injuries

REMEDIES AND REFERENCES


Definition and installation of local maintenance switches by electrical lot (ammonia, ID fan, heat recovery pumps) Sub-supplier operating manuals Electrical consignation on the MCC by the autorized operator and special procedure ID Fan rotation by natural draft avoided by mechanical design (refer to training) Watch tours + cold/hot tests commissioning Sensitive equipment on emergency diesel ID Fan with emergency motor to maintain negative pressure in the flue gas cleaning + automatic start "Live" black-out tests during commissioning

Automatic control / operation of the plant


1.2.6 Failure of the power supply

Damage of the plant and of equipment

Power black-out

Damage of equipment

1.3 PROTECTION AGAINST MECHANICAL HAZARDS


1.3.1 Risk of loss of stability

Breakdown due to bad installation

Damage of equipment + risk for operators

Refer to risk analysis, maintenance and operating manual of elements by suppliers Integration of equipment in Steel structure Steel structure calculations done by a specialized company according to dutch norms

1.3.2 Risk of break-up during operation

Breakdown following operation

Damage of equipment + stop of the plant

Mechanical calculation notes for vessels, piping. including stress analysis Expansion joint for thermal displacements avoiding unacceptable stress Installation of anti-whip cable on nitrogen flexibles Quality Control during fabrication and erection, for material, thickness, welding... Operating manual + maintenance manual Cleaning of the plant and general plant instructions by OMRIN Specific retentions Hand rail, foot plates on structure Hinged doors on the top of access ladders. Internal vessels device in case of internal inspection or maintenance No quick and easy release devices for vessels door opening; only bolting, requiring tools

1.3.3 Risks due to falling or ejected objects

Falling of objects

Damage of equipment + risk for operators

Ejected objects: not applicable


1.3.4 Risks due to surfaces, edges or angles

Edges and angles Height / Header


1.3.5 Risks related to combined machinery

Risk for operators Risk for operators

Design + inspections Grinding of edges and angles if risk of injury Fulfillment of contract (2.3 m. minimum) Helmet mandatory

Not applicable
1.3.6 Risks related to variations in operating conditions

Stop of the plant


1.3.7 Risks related to moving parts

Damage of equipment + loss of operation

Large operating range according to the contract Automatic control of process parameters, alarm and automatic actions in case of emergency or running out of the designed operating range Protection for moving parts (fans, pumps ) CE marking and corresponding devices by sub-suppliers (as for pumps, fan, dampers, screws ) Mechanical locking of the flue gas dampers

Rotating machines, electrical motors, fans and pumps automatic valves and dampers, actuators Rappers and vibrators
1.3.8 Choice of protection agains risks arising from moving parts

Risk for operators Personal injuries

See 1.3.7
1.3.9 Risks of uncontrolled movements

Abnormal stop 1.4 REQUIRED CHARACTERISTICS OF GUARDS AND PROTECTIVE DEVICES


1.4.1 General requirements

Damage of equipment

Safety positions of valves/dampers and air buffer tanks in case of loss of power and loss of instrument air. Refer to 1.2.4 stoppage for maintenance or dismantling

Design & installation of protective devices by OMRIN

Process risks definition in risk analysis, maintenance and operating manuals, refer to 1.3.7 Vessels and ducts are calculated according to normal and exceptionnal pressure and temperature conditions. Piping support are calculated according to weight and flexibility if relevant Pressure vessels are designed and made according to PED, safety valves are installed accordingly Pumps are designed and tested according to official rules and standards. Volumetric pumps are equiped with discharge valves (NH3) connected to the suction side Equipments are attached to steel structure or concrete plinths with bolts, anchorages... Procedures / operating manual

1.4.2 Special requirements for guards

Refer to equipment documents provided by supplier and operating manual


1.4.3 Special requirements for protective devices

Refer to equipment documents provided by supplier and operating manual 1.5 RISKS DUE TO OTHER HAZARDS
1.5.1 Electricity supply

Procedures / operating manual

High voltage, transfo, electrical cabinets


1.5.2 Static electricity

Damage of equipment

Directive CE/73/23 in LAB contract to sub-suppliers (calculation of cables ) Automatic grounding device definition of isolation class IP Electrical continuity for ducts Earthing of consumers and steel structure and pneumatic transport pipe ESP specific earthing for high voltage unit

Earthing system
1.5.3 Energy supply other than electricity

pneumatic system under pressure hydraulic system under pressure


1.5.4 Assembly errors

Personal injuries Personal injuries

discharge of air tank before intervention on equipment refer to supplier operating and maintenance manual refer to maintenance manual for handling beam assembly : end stop must be mounted at the extremity of the handling beam Insulation, personnel protection No possibility of entrance in the vessels without voluntary action. Heat insulation is only removable by unscrewing the cladding. Thermal swhitches in case of too high temperature on electrical heaters or heat tracing All materials are conformed to standards DIN No dead-end area in the plant Silos and fabric filter hoppers are equipped with nitrogen injection (nitrogen released on temperature alarm) Hot works permit for all works with hotspots close to flamable products + marking of the area Procedures / operating & maintenance manuals

handling of catalyst modules with handling beam : end stop not mounted on personal injuries / material damage handling beam
1.5.5 Extreme temperatures

Thermal equipment (ducts, piping, heat exchangers )

Damage of equipment / damage of downstream equipment / damage of steel structure / personal damage Damage on equipment Personal injuries Personal injuries Damage / Personal injuries Personal injuries

Material resistance
1.5.6 Fire

Design of the plant / lay-out Activated carbon storage, spent sorbent storage and fabric filter hoppers Erection / maintenance Checking of electrical tracing

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ORIGIN AND KIND OF RISKS


Showers, fire extinguishers in OMRIN scope
1.5.7 Explosion

POTENTIAL CONSEQUENCES

REMEDIES AND REFERENCES


Safety datasheet and lay out transmitted by LAB (for dangerous product identification and location)

Activated carbon
1.5.8 Noise

Damage / Personal injuries

Refer to ATEX study Max. 80 dB(A) at 1 m. for each single equipment Grinders (90dB(A)) in specific room Protective devices for some specific equipment (ID fan motors ) Process silencer downstream the ID fan OMRIN contractual requirements to all sub-suppliers LAB contractual requirement to all sub-suppliers to avoid any resonance mode Specific vibration controls for ID fan equipment complies with EMC (European Electro Magnetic compatibility)

All equipment Outside noise generated by the plant (stack)


1.5.9 Vibrations

Personal injuries

All equipment Fans


1.5.10 Radiation

Equipment damage + personal injuries Equipment damage interferences between equipment, equipment damage or malfunction

presence of electromagnetism, no ionizing sources, no X-ray


1.5.11 External radiation

Not applicable
1.5.12 Laser radiation

Not applicable
1.5.13 Emissions of hazardous materials and substances

All equipment

Equipment damage + personal injuries

Flue gas cleaning line is underpressure Watch tours (check for leaks) Concrete basin for ammonia solution Watch tours (check for leaks) Drains connected to gutters/pit - instruments drains plug when dangerous Special procedure for heavy maintenance by OMRIN (works permit) Handrails + safety ladders for steel structure - anti-slip gratings installation of adequate grating when opening manholes (ESP / fabric filter) or intervention on residue equipment : installation of chequered plates on the grating below the equipment Design with fixed access to all instruments/equipment (approved by OMRIN during lay-out meetings) Use of scaffoldings during long stops for internal inspection or external access

Reagent injection (activated carbon, bicarbonate), ammonia injection and residue conveying Drains
1.5.14 Risk of being trapped in a machine

Personal injuries Personal injuries Personal injuries and death

Heavy equipment
1.5.15 Risk of slipping, tripping or falling

Steel structure

Personal injuries

Instrument/equipment All heavy and big equipment


1.5.16 Lightning

Personal injuries Personal injuries

Not applicable (OMRIN scope) Lightning during erection 1.6 MAINTENANCE


1.6.1 Machinery maintenance (except equipment internal inspection)

Personal injuries and death

Earthing in operation at end of civil works Complete earthing system for equipment, steel structure and pipes of pneumatic transport Checking of weather conditions by site manager

Plant All equipment


1.6.2 Access to operating positions and servicing points

Equipment damage / breaking

Preventive maintenance list Greasing points are accessible, with extension if necessary Maintenance manual for each equipment and for the entire FGT Access to instruments/equipment Isolation of each equipment for maintenance from electrical room or local maintenance switch, with dedicated instructions for electrical locking Screen views in control room with relevant parameters Local indicator to be checked during watch tour Access to manual valves or dampers and to instruments Equipment are designed to avoid internal maintenance (slopes, flush weld) and when necessary rappers are installed Equipment internal is only accessible during plant stoppage Procedure for works in confined spaces

Design
1.6.3 Isolation of energy sources

Help for operators

All equipment
1.6.4 Operator intervention

Plant
1.6.5 Cleaning of internal parts

Plant

1.7 INFORMATION : the LAB flue gas treatment and its equipments are partly completed machinery within the meaning of the machinery directive CE/2006/42. As such, the marking is not required, the following have to be supplied : - the assembling instructions described in appendix VI, if required - the instruction manual in accordance with appendix I, 1,7,4 - the declaration of incorporation of partly completed machinery in accordance with appendix II, part 1 B
1.7.1 Information and warnings on the machinery

All equipment

Mistakes resulting in equipment damages and personal injuries

Specific instructions / warnings on sensitive equipment : - sound and light for ammonia - marking during handling and maintenance operation Labelling of each equipment Marking with colour code of pipes / channels Training of operators by LAB Position of local maintenance switches (emergency stops) by OMRIN Alarms & horns for ammonia Nitrogen injection in activated carbon CE marking Sub-suppliers plates Marking / labelling : - KKS tags - ATEX specific marking - High voltage specific marking - For the running beams, the checking is realized by approved certification body during acceptance tests for the related lifting devices Operating and maintenance instructions CE conformity certificate (integration) Risk analysis according to EU Machinery Directive 2006_42 LAB as-built documentation including drawings, PID, data sheets, test reports, structure and PED calculation notes, training manual, operating manual with watch tour lists, trouble shouting analysis, process parameters for control and alarms, maintenance documentation, spare parts list, safety data-sheets Risk analysis and HAZOP with OMRIN Integration of LAB's information in OMRIN documents

1.7.2 Warning of residual risks

Plant
1.7.3 Marking of machinery

Mistakes resulting in equipment damages and personal injuries

All equipment

Mistakes resulting in equipment damages and personal injuries

Flue gas cleaning


1.7.4 Instructions

Mistakes resulting in equipment damages and personal injuries

Plant

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ESP
Checking visit of the ESP

10892SA11101

ELEX

10892NA11101-102-111-123-151ELEX 141

X X X
10892SA14001 LAB 10892NA14001 10892NA25110-111 10892NA25111 10892NA25411 LAB GEA ROSINK ROSINK BASF

LAB-LOOP
Mounting/Dismantling reagent injection lances LAB-LOOP cleaning

Fabric filter
Bag replacement

Gas Heat exchanger


Intervention or check inside heat exchanger

X
10892NA30201 10892NA30202

DeNOx reactor
Intervention inside the DeNOx reactor for cleaning or sampling Catalyst replacement

X X
10892NA31111-112-114-115-116 POLLRICH

IDfan
Checking visit of fans Mounting / dismantling of fan driving wheel and motor

X X
10892NA32101 AD INGENIERIE

Silencer
Mounting / Dismantling of the silencer

X X
10892NA35121 STEELCON

FG duct
Flue gas ducts checking

Stack
Stack checking

X
10892NA14400 10892NA31112-212 10892NA31315 10892NA31311-31210892NA40721 JEANNOT POLLRICH JEANNOT REITZ

Fans (preheating / sealing air / activated carbon injection) and battery


Removal / replacement of fan motor/wheel or battery Cheking visit of the fabric filter and DeNOx preheating and sealing system and of activated carbon injection systems

X X
10892NA23111 10892NA23112 ESSCANO

Dampers
Handling of a damper

X
10892NA17201 10892NA17202 10892NA40401 WAM

Reagents silo
Activated carbon or Bicarbonate Unloading Changing bag filter on silo Silo inspection

X X X
10892QA40114 PCVS PCVS

NH4OH installation
Checking visit of ammonia installation NH4OH Unloading NH4OH tank draining Tank inspection

X X X X
10892SA17201 MORILLON 10892NA17303-304-305-306 10892NA17201-17202-40401 MORILLON WAM

Residue silo
Residue loading Changing bag filter on silo Residue silo inspection

X X X
10892SA40520 SODIMATE 10892NA40520-521-522-523-524- SODIMATE 531-532-533 10892NA40401 WAM

Reagent dosing system


Checking visit of the reagent dosing system Remove / replace of the system motor-screw

X X
10892SA40811 GTS 10892NA40812-814-815-816 GTS

Grinders and injection fans


Watching visit of the grinders Cleaning of grinder chamber and injection fan Removal / replacement of fan or grinder motor/wheel/selector

X X X
10892NA26411-412 10892NA26512-513-514 KSB SALMSON

Water pumps (boosters / circulation)


Watching visit of different pumps Mounting/Dismantling of pumps with their motors

X X
10892NA26401-412 10892NA26211-212-213 KSB LEWA

NH4OH pumps
Checking visit of the unloading/injection pumps Removal/replacement of the ammonia motor/pump

X X X
10892QA27550-560 SNZ 10892NA25611 SNZ GEA

NH4OH injection
Checking visit of the ammonia injection

Hot piping
Mounting/Dismantling hot piping

X
10892SA17201 STAG ELEX 10892NA11121-122-123 10892NA17601-602-603-604-606- STAG STAG 607-619-620-631-632-633

Residue Mechanical transports


Checking visit of the mechanical transport equipment Mounting / dismantling of the mechanical transport equipment

X X
10892NA17601-602-605-609-673 STAG

Residue Pneumatic transport


Inspection of pneumatic transport equipment

X
10892NA29111-113-114-115-116- WIKA 10892NA29151 KHRONE 10892NA29130-131-132 ENDRESS HAUSER

Instrument
Checking visit of the instruments

X
10892NA28450-451-460 to 467 10892NA28470-480-490 10892NA26516 AVS SALMSON TRACE TEC STAG ELEX

Valve & components


Checking visit of the valves and accessories

X
10892NA24311-312 10892NA17612 10892NA11312

Electrical tracing & insulation


Checking visit of an equipment equipped with electrical tracing Removal of insulation for equipment inspection

X X

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2- Specific parts

10892EA00400-0

by

TASK Nr

Checking visit of the ESP

MLS : during operation

Frequency : Daily

OPERATION N Identification

The ESP is used to separate the main part of dust from the flue gas The intervention consists in checking the good functioning of the ESP COMPONENT OF THE RISK dangerous event, hazardous Hazard situation possible damage Rotation of the fan axis ESP roof Contact with the rotating Working nearby the part. rotating part Injury Working nearby electrical circuit Contact with conductor under voltage. Electrical shock

PREVENTIVE MEASURE P S Initial On what component we have to act Means P S residual

Visual and audio check of the ESP during operation high voltage

Make sure that protections supplied by the manufacturer are Removal of the installed before intervention dangerous phenomenon Trapdoors closed. : obstacle / rotating parts Follow the instructions of the O&M manual (Lab & manufacturer) Removal of the Follow the instructions of the O&M manual (Lab & dangerous phenomenon manufacturer) Insulation of the system. Removal of the Follow the instructions of the O&M manual (Lab & dangerous phenomenon manufacturer) S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Noise MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Working nearby the auditory risks noise source Frequency of the task

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Continuous Daily Weekly Monthly Annual Exceptional

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in ELEX as built documentation references 10892SA11101 10892NA11101-102-111-123-151-141

Specific part : ESP - 1 / 1

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TASK Nr

Mounting/Dismantling reagent injection lances

MLS : mounting/dismantling

Frequency : Annual

OPERATION N Identification

The reagent injection lances are designed to inject reagents (activated carbon and bicarbonate) from pneumatic transport in the LAB-LOOP The intervention consists in disconnecting the piping with the lances COMPONENT OF THE RISK PREVENTIVE MEASURE P S hazardous dangerous event, On what component Means Hazard Initial situation possible damage we have to act Leak of reagent Hot temperature of the lances Working nearby the reagent injection Working nearby the reagent injection Contact with the reagent : corrosive effect Contact the hot lances C 3 Installation of means to avoid damages C 3 Wear PPE. Follow the instructions of the O&M manual (Lab & manufacturer)

rsidual A 1

Connection / disconnection of the hose

Handling the pipe with the lance

Suspended equipment

Presence under the load

Fall of the load : injury

Certified handling/lifting equipments. Removal of the Handling by authorized operators. dangerous phenomenon: Marking area and banning access under the load. Make sure nobody is Follow the instructions of the O&M manual (LAB & present under the load manufacturer) S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : LABLOOP - 1 / 2

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TASK Nr

LAB-LOOP cleaning

MLS : maintenance

Frequency : Annual

The LAB-LOOP is designed to ensure contact between flue gas and reagentsinjected The intervention consists in cleaning the LAB-LOOP by opening the manhole at the bottom OPERATION N Identification Hazard COMPONENT OF THE RISK hazardous situation Working nearby reagent deposits dangerous event, possible damage Contact with the reagent : corrosive effect P S Initial C 3 On what component we have to act PREVENTIVE MEASURE P Means S rsidual A 1

Contact with reagent 1 Visual inpection inside of the LAB-LOOP

Removal of the Wear PPE : goggles / gloves / boots / mask / safety helmet dangerous phenomenon Respect of procedures before intervention : Intervention of minimum two persons entiltled and wear PPE Removal of the dangerous phenomenon Check of IDfan stop, equipment correct venting and equipment inside temperature before manhole opening Removal of the Wear PPE : goggles / gloves / boots / mask / safety helmet dangerous phenomenon Respect of procedures before intervention : Intervention of minimum two persons entiltled and wear PPE Removal of the dangerous phenomenon Check of IDfan stop, equipment correct venting and equipment inside temperature before manhole opening Removal of the Respect of procedures (in particular for scaffolding) dangerous phenomenon wear PPE Removal of the Wear PPE : goggles / gloves / boots / mask / safety helmet dangerous phenomenon Respect of procedures before intervention : Intervention of minimum two persons entiltled and wear PPE Removal of the dangerous phenomenon Check of IDfan stop, equipment correct venting and equipment inside temperature before manhole opening S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Hot temperature of the LAB-LOOP

Work in an equipment where Contact the hot gas are usually at equipment 200C Working nearby reagent deposits Contact with the reagent : corrosive effect

Contact with reagent 2 Cleaning of the bottom of the LAB-LOOP

Hot temperature of the LAB-LOOP Baffles are located overhead in the LABLOOP

Work in an equipment where Contact the hot gas are usually at equipment 200C Overhead job Working nearby reagent deposits People falling : injury / death of the people Contact with the reagent : corrosive effect

Cleaning of the baffles Contact with reagent plates in the LAB-LOOP Hot temperature of the LAB-LOOP MLS : Machine life step

Work in an equipment where Contact the hot gas are usually at equipment 200C

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Installation : During operation Maintenance Mounting/Dismantling

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : LABLOOP - 2 / 2

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TASK Nr

Bag replacement

MLS : maintenance

Frequency : Exceptional

The fabric filter is used to capture dusts contained in the flue gas and is the place of chemical reaction with reagents injected in the LAB-LOOP OPERATION N Identification This intervention consists in replacing one of the bags in one fabric filter cell Hazard See risk analysis for overhead crane utilisation Intervention on hopper MLS : maintenance Frequency : Annual COMPONENT OF THE RISK hazardous situation dangerous event, possible damage P S Initial On what component we have to act PREVENTIVE MEASURE Means P S residual

TASK Nr

The fabric filter is used to capture dusts contained in the flue gas and is the place of chemical reaction with reagents injected in the LAB-LOOP This intervention consists in opening the hopper manhole OPERATION N 1 Identification Manholes opening on hoppers MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling Hazard Residue spillage COMPONENT OF THE RISK hazardous dangerous event, situation possible damage Work below the platform at Contact with hot residue hopper level P S Initial C 3 On what component we have to act PREVENTIVE MEASURE Means P S residual A 1

Removal of the When opening the manhole on hopper, installation of dangerous phenomenon chequered plates on the grating below the manhole S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in LAB as built documentation references 10892SA14001 10892NA14001

Specific part : Fabric filter - 1 / 1

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TASK Nr

OPERATION N 1 Identification Removal of insulation

Intervention or check inside heat MLS : maintenance Frequency : Annual exchanger The gas/gas and steam/gas heat exchangers is used to heat flue gas before entering the catalyst The condensate water/gas heat exchanger is used to transfer heat recovered from flue gas PREVENTIVE MEASURE COMPONENT OF THE RISK hazardous dangerous event, On what component we P S Hazard Means Initial situation possible damage have to act Presence of Breathing of these Chemical risk Removal of the dangerous mineral fiber in mineral fibers in C 2 Wear PPE : goggles / gloves / boots / mask / safety helmet Breathing problems phenomenon suspension suspension Slide. Fall Injury C 3 Removal of the dangerous phenomenon Intervention by authorized operators. Wear PPE (goggles / gloves / boots / mask / safety helmet and body harness) Respect the specific procedures of work in confined area (ventilation, atmosphere control, temperature). Follow the instructions of the O&M manual (Lab & manufacturer). Check of IDfan stop, equipment correct venting and equipment inside temperature before opening manhole

P S residual A 1

Presence into the Heat exchanger

contact with dusts Work in an Hot equipment due equipment where to gas circulating gas are usually at inside 200C Doors and access handling Access inside the exchanger hoppers Opening of the internal manhole intervention in a dead-end area

breathing problems

Removal of the dangerous phenomenon

Intervention in the exchanger

Contact with hot equipment and hot gas Uncorrect handling Operator falling Manhole closing, person enclosed isnide the heat exchanger

Removal of the dangerous phenomenon Removal of the dangerous phenomenon

Doors with hinges easily handling fastener hook for harness Intervention by authorized operators. Respect the specific procedures of work in confined area (ventilation, atmosphere control, temperature). Follow the instructions of the O&M manual (Lab & manufacturer).

Removal of the dangerous phenomenon

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

S= maximal severity of the Means possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in GEA ROSINK ROSINK as built documentation references 10892NA25110-111 10892NA25111 10892NA25411

Specific part : Gas heat Exchanger - 1 / 1

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TASK Nr

OPERATION N Identification

Intervention in the reactor

Intervention inside the SCR reactor MLS : maintenance Frequency : annual for cleaning or sampling The SCR reactor is composed of modules of catalysts to treat chemical pollutants The intervention consists in cleaning the top of the modules or taking the catalyst samples COMPONENT OF THE RISK PREVENTIVE MEASURE hazardous dangerous event, On what component P S Means Hazard Initial situation possible damage we have to act Temperature control. Specific tools needed to open the manholes. Wear PPE. Work in a Isolation of NH4OH pumps. Hot equipment because equipment Intervention by two authorized operators. Contact with hot Removal of the C 3 where 250C of hot gases passing equipments : burning. dangerous phenomenon Stop the ID fan during intervention. gases have through the reactor Stop the steam circulation in the steam/gas heat exchanger circulated Respect the specific procedures of work in confined area (ventilation, atmosphere control). Follow the instructions of the O&M manual (Lab & manufacturer). Chemical products and work nearby the catalyst dust on catalyst modules modules Doors and Access to the top of the access hopper handling Contact with chemical product and dusts : chemical injury, breathing problem Uncorrect handling. Operator falling C 2 Removal of the Wear PPE (goggles / gloves / boots / dust mask / safety helmet) dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer). Doors easy to handle. Harness hook. Removal of the dangerous phenomenon Specific tools needed to open the manholes. Follow the instructions of the O&M manual (Lab & manufacturer). S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

P S residual

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : SCR reactor - 1 / 2

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OPERATION N Identification Mounting and dismantling of SCR reactor doors / catalyst modules

Catalyst replacement MLS : maintenance Frequency : exceptional The SCR reactor is composed of modules of catalysts to treat chemical pollutants This intervention consists in replacing the catalysts modules COMPONENT OF THE RISK PREVENTIVE MEASURE hazardous dangerous event, On what component P S Hazard Means Initial situation possible damage we have to act Certified handling/lifting equipments. Removal of the Intervention by authorized operators. dangerous part : Presence Falling down of the load Area marking and banning access under the load Suspended load B 4 Make sure nobody is under the load Crushing of operator Follow the instructions of O&M manual (Lab & manufacturer). present under the load Wear PPE Hot equipements because of circulating flue gas Presence in the reactor Working in a Contact with hot duct where hot equipments and hot gases are gases circulating presence of dusts Sliding, falling : Injury P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly Respect of the specific procedures of work in confined area (ventilation, atmosphere control). Removal of the Verification of the equipment correct ventilation and of the dangerous phenomenon temperature in the equipment before opening the manhole. Follow the instructions of the O&M manual (Lab & manufacturer) S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

P S residual

Intervention in the SCR reactor to replace the catalyst

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis in BASF as built documentation reference 10892NA30201 10892NA30202

Specific part : SCR reactor - 2 / 2

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TASK Nr

Checking visit of fans

MLS : during operation

Frequency : Daily

OPERATION N Identification

The ID fan is used to drive the flue gas from the silencer to the stack. The preheating fan is used to preheat the SCR reactor. The intervention consists in checking the good functioning of the fans COMPONENT OF THE RISK hazardous dangerous event, Hazard situation possible damage Contact with the rotating Working nearby the part. rotating part Injury Contact with conductor under voltage. Electrical shock

PREVENTIVE MEASURE P S Initial On what component we have to act Means P S residual

Rotation of the fan axis Check of the fan during operation : visual checking, audio Working nearby checking and vibration Conductor under voltage electrical circuit measurements Noise, heat

Make sure that protector supplied by the manufacturer are installed before Removal of the intervention dangerous phenomenon Trapdoors closed. : obstacle / rotating parts Follow the instructions of the O&M manual (Lab & manufacturer) Removal of the No bare conductor under voltage dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer) Insulation of the system. Removal of the Wear of PPE (ear plugs or other hearing protection) dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer) 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Working nearby the auditory and burning noise source risks A : Unlikely B : Uncommon C : Casual D : highly

Installation : During operation Maintenance Mounting/Dismantling

Continuous Daily Weekly Monthly Annual Exceptional

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : IDfan - 1 / 2

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TASK Nr

Mounting / dismantling of fan driving wheel MLS : maintenance and motor The ID fan is used to drive the flue gas from the silencer to the stack. The preheating fan is used to preheat the SCR reactor. The intervention consists in removing then replacing the fans

Frequency : Exceptional

OPERATION N Identification Hazard

COMPONENT OF THE RISK hazardous situation dangerous event, possible damage P S Initial On what component we have to act

PREVENTIVE MEASURE P Means S residual

Rotation of the fan axis 1 Connection / disconnection of the fan motor Rotation of the fan axis by natural draught

Contact with the rotating Working nearby the part. rotating part Injury

Disconnecting switch with padlock in general low voltage panels or local Removal of the panel dangerous part : Manufacturer protection. electrical isolation of the Coupling replacement ensured by authorized operators. motor Follow the instructions of the O&M manual (Lab & manufacturer) This operation can only be done at complete stop of the wheel and with Removal of the security signalling of the danger dangerous phenomenon If the Idfan motor running feedback is not obtained, the upstream dampers can be manually closed to avoid rotation of the wheel by natural draught Removal of the dangerous part : Make sure nobody is present under the load Certified handling/lifting equipments. Intervention by authorized operators. Area marking and banning access under the load. Follow the instructions of O&M manual (Lab & manufacturer). Wear PPE

Contact with the rotating Working nearby the part. rotating part Injury

The operators are handling parts of fan (cleaning, lubricating, driving wheel replacement)

Part of the fan suspended

Presence under the Fall of the load. load Crushing of operator

Rotation of the fan axis by natural draught

Contact with the rotating Working nearby the part. rotating part Injury

This operation can only be done at complete stop of the wheel and with Removal the dangerous security signalling of the danger phenomenon If the Idfan motor running feedback is not obtained, the upstream dampers can be manually closed to avoid rotation of the wheel by natural draught S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling Continuous Daily Weekly Monthly Annual Exceptional

Frequency of the task

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in POLLRICH as built documentation references 10892NA31111-112-114-115-116

Specific part : IDfan - 2 / 2

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Mounting / Dismantling of the silencer

MLS : maintenance

Frequency : Exceptional

The intervention consists in removing and then replacing the silencer (no possibility to remove the baffles without removing the whole silencer) OPERATION N Identification The operators are handling the silencer : baffles cleaning or replacement requires to lift down to the ground the complete silencer MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling Hazard COMPONENT OF THE RISK hazardous situation dangerous event, possible damage P S Initial On what component we have to act PREVENTIVE MEASURE P Means Certified Handling/lifting equipments. Intervention by authorized operators. Area marking and banning access under the load Follow the instructions of the O&M manual (Lab & manufacturer). Wear PPE and body harness. Means S residual

Silencer suspended

Presence Fall of the load. under the load Crushing of operator

Removal of the dangerous part : Make sure nobody is present under the load S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in AD INGENIERIE as built documentation references 10892NA32101

Specific part : Silencer - 1 / 1

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TASK Nr

Flue gas ducts checking

MLS : maintenance

Frequency : Annual

OPERATION N Identification

Flue gas ducts are used in the whole installation to transport flue gas from an equipment to another COMPONENT OF THE RISK P S hazardous dangerous event, On what component Hazard Initial situation possible damage we have to act

PREVENTIVE MEASURE P Means S residual

Visual verification of the Presence in the duct ducts good conditions

Slide. Fall. Injury. Presence of Chemical risks untreated flue (Breathing problems). gas

Intervention by two authorized operators. Venting flue gas with air before any intervention. Flue gas treatment stopped and cooled (ID fan stopped). Adequate scaffolding. Prohibition on being in the duct during the handling of Removal of the dampers. dangerous phenomenon Dampers mechanically blocked Wear PPE and body harness, check of temperature Respect the specific procedures of work in confined area (ventilation, atmosphere control). Follow the instructions of the O&M manual (Lab & manufacturer) S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : FG duct - 1 / 1

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TASK Nr

Stack checking

MLS : maintenance

Frequency : Exceptional

OPERATION N Identification

The outside stack evacuate the clean flue gas COMPONENT OF THE RISK Hazard hazardous situation dangerous event, possible damage P S Initial On what component we have to act

PREVENTIVE MEASURE P Means S residual

Visual verification of the Presence in the duct ducts good conditions

Slide. Fall. Injury. Presence of Chemical risks untreated flue (Breathing problems). gas

Intervention by two authorized operators. Venting flue gas with air before any intervention. Flue gas treatment stopped and cooled (ID fan stopped). Removal of the Adequate scaffolding. dangerous phenomenon Prohibition on being in the duct during the handling of dampers. Wear PPE and body h S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in STEELCON as built documentation references 10892NA35121

Specific part : stack - 1 / 1

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TASK Nr

Removal / replacement of fan motor/wheel or battery

MLS : maintenance

Frequency : Exceptional

OPERATION N Identification

Electrical connection / disconnection of fan motor or battery

Fabric filter preheating is ensured by preheating battery and fan DeNOx and fabric filter sealing air injection are ensured by sealing air batteries and fans Activated carbon transport is ensured by air transport fan This intervention consists in removing and replacing part of fan or battery COMPONENT OF THE RISK PREVENTIVE MEASURE hazardous dangerous event, On what component P S Means Hazard Initial situation possible damage we have to act Removal of the Work nearby dangerous phenomenon: Disconnecting switch with padlock in general low voltage Contact with rotating part B 3 Rotation of the fan shaft rotating electrical motor locked panels or local panel of the fan - Injury equipment out Work on the fan Contact with conductor Conductor under electric under voltage - electrical or battery potential shock electrical part Removal of the dangerous phenomenon: Disconnecting switch with padlock in general low voltage electrical motor and panels or local panel battery locked out Adequate lifting device Removal of the (Overhead crane foreseen for equipment handling) dangerous phenomenon C 4 Make sure nobody is present under the load S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Handling by trained people Area marking and forbidden access under the load Means

P S residual A 1

One or more operators lift and handle part of the fan or battery

Part of fan or battery overhanging

Presence under Falling down of the load the load Crushing of operator

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : fans & battery - 1 / 2

10892EA00400-0

TASK Nr

Cheking visit of the fabric filter and DeNOx preheating and sealing system and of activated carbon injection systems

MLS : during operation

Frequency : Daily

Fabric filter preheating is ensured by preheating battery and fans DeNOx and fabric filter sealing air injection are ensured by sealing air batteries and fans Activated carbon transport is ensured by air transport fan This intervention consists in checking the correct functioning of the fans OPERATION N Identification Hazard COMPONENT OF THE RISK dangerous event, hazardous possible damage situation Work nearby rotating equipment PREVENTIVE MEASURE P S Initial 3 On what component we have to act Means P S residual A 1

Rotation of the fan shaft 1 Visual and audio check of the functioning

Contact with rotating part B of the fan - Injury

Make sure that protector supplied by the manufacturer are Removal of the installed before intervention dangerous phenomenon: obstacle / rotating parts Trap doors closed Removal of the No barre conductor under voltage dangerous phenomenon S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

Contact with conductor Conductor under electric Work nearby under voltage - electrical potential electric cirucit shock Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in JEANNOT POLLRICH JEANNOT REITZ as built documentation references 10892NA14400 10892NA31112-212 10892NA31315 10892NA31311-312-10892NA40721

Specific part : fans & battery - 2 / 2

10892EA00400-0

TASK Nr

Handling of a damper MLS : maintenance Dampers, by isolation of ducts, allow partial FGT bypass this intervention consists in removing/replacing one damper OPERATION COMPONENT OF THE RISK hazardous dangerous event, situation possible damage Fall of the operator. Injury. Presence of chemical substance P S Initial

Frequency : Exceptional

PREVENTIVE MEASURE On what component we have to act Means P S residual

Identification

Hazard

Visual verification of the Uncontrolled movement Checking of the damper during operation of the damper damper position

Handling of the damper

Hot equipements because of circulating Hot equipment flue gas

Contact with hot equipments and hot gases

Handling of the damper

Part of the damper suspended

Presence under the Falling down of the load load Crushing of operator

Handling of the damper

Proximity with the air Quick release of air hose whiping : tanks : pressurized tank from tank or hose operator injury

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

prohibition on being in the duct during the handling of the damper. Intervention by two authorized operators. Wear PPE. Removal of the Follow the instructions of the O&M manual (Lab & manufacturer) dangerous phenomenon Presence of limit switch (open/closed). Damper machanically locked Follow the instructions of the O&M manual (Lab & manufacturer) Stop of the IDFan Removal of the Wear PPE dangerous phenomenon Wait for complete cooling (transmitted temperature measurement) Follow the instructions of the O&M manual (Lab & manufacturer) Removal of the Certified handling/lifting equipments. dangerous Handling by authorized operators. phenomenon: Marking area and banning access under the load Make sure nobody is Follow the instructions of the O&M manual (Lab & manufacturer) present under the load CE certificate by the supplier. Pressure Equipment Directive (PED) standardized. Removal the dangerous Wear PPE. phenomenon Air tank discharge before maintenance Follow the instructions of the O&M manual (Lab & manufacturer) S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in ESSCANO as built documentation references 10892NA23111 10892NA23112

Specific part : Dampers - 1 / 1

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OPERATION

Identification

Activated carbon or Bicarbonate MLS : during operation Frequency : Weekly Unloading Activated carbon and sodium bicarbonate are stored in a silo This intervention consist in unloading reagent from the delivery truck to the silo COMPONENT OF THE RISK P S On what hazardous dangerous event, Hazard component we Initial situation possible damage have to act Explosion of the silo. Explosion of the truck. Injury of operators

PREVENTIVE MEASURE P Means S

residual

Unloading operation by the truck

Auto inflammation Working nearby and explosion of the activated activated carbon carbon silo

Removal of the dangerous phenomenon

Silo overflowing

Working nearby the activated carbon silo

Excessive pressure in the silo

Removal of the dangerous phenomenon

Avoid the sparks caused by static electricity loads. Earthing of the truck. Respect the product used (Activated carbon) and ban all other products. Keep the installation clean. Automatic silo inerting when hot temperatures are detected. Follow the instructions of the O&M manual (Lab & manufacturer) Redundancy of security equipements for high level. Presence of safety valves (pressure/depression) on the roof. Indication on the local panel of high level reached + shut off valve An alarm is set off when silo high level is reached. Follow the instructions of the O&M manual (Lab & manufacturer)

Operations on the Static electricity reagent silos generated

Working on one reagent silo

Electrical shock

Removal of the dangerous phenomenon

Earthing of the metallic silos and pipes

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

S= maximal Means severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : reagent silo - 1 / 2

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TASK Nr

Changing bag filter on silo

MLS : Mounting /dismantling

Frequency : Annual

OPERATION

Identification

Activated carbon and sodium bicarbonate are stored in a silo and silos are equipped with filter to allow air evacuation without dust emission This intervention consists in changing the filter COMPONENT OF THE RISK PREVENTIVE MEASURE P S On what hazardous dangerous event, Hazard component we Means Initial situation possible damage have to act Presence of a handrail around the top of the silo. Certified handling/lifting equipments. Handling by authorized operators. Marking area and banning access under the load. Follow the instructions of the O&M manual (Lab & manufacturer)

residual

Replacement of the silos bag filter

Parts of the filter removed by the operators

Presence nearby Fall of object the bottom of the Injury silo MLS : maintenance

Removal of the dangerous phenomenon

TASK Nr

Silo inspection

Frequency : Exceptionnal

OPERATION N Identification

Activated carbon and sodium bicarbonate are stored in a silo This intervention consist in internal inspection of the silo COMPONENT OF THE RISK Hazard hazardous situation dangerous event, possible damage P S Initial On what component we have to act

PREVENTIVE MEASURE P Means Intervention by two authorized operators. Complete emptying of the silo before any intervention Venting with air before any intervention. Adequate scaffolding. Nitrogen injection in Activated carbon silo mechanically locked Wear PPE and body harness, check of temperature Respect the specific procedures of work in confined area (ventilation, atmosphere control). Follow the instructions of the O&M manual (Lab & manufacturer) S residual

Internal inspection Presence in the of the silos silo

Slide. Fall. Presence of gas

Injury. (Breathing problems).

Removal of the dangerous phenomenon

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

S= maximal Means severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in WAM as built documentation references 10892NA17201 10892NA17202 10892NA40401

Specific part : reagent silo - 2 / 2

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TASK Nr

OPERATION

Checking visit of ammonia MLS : during operation installation Ammonia solution 24,5% is stored in a tank Ammonia is injection in the DeNOX reactor COMPONENT OF THE RISK P Hazard hazardous situation dangerous event, possible damage

Frequency : Daily

PREVENTIVE MEASURE S On what component we have to act Means P S

Identification

Initial

residual

Spatter of ammonia Visual checking of Risk of ammonia Working nearby chemical injury the installation leakage on the line the ammonia line Operator breathing problem NH4OH Unloading

Removal of the dangerous phenomenon

Welded inox pipes, flanges only on pump and injection connection with detection and alarm, the pipe routing is agreed with OMRIN. Ammonia resistant gaskets Wear of PPE

TASK Nr

MLS : during operation

Frequency : Weekly

OPERATION

Ammonia solution 24,5% is stored in a tank Ammonia is unloaded from a truck. COMPONENT OF THE RISK P S On what component we have to act hazardous situation dangerous event, possible damage

PREVENTIVE MEASURE P Means Leakage detection with horn Automatic spraying Drips collection in a retention safety shower and eye rinsing nearby the unloading area indication on connecting pipe Wear of PPE Redundancy of security equipements for high level Indication on the local panel of high level reached and sequence stopped Leakage detection with horn Automatic spraying Drips collection in a retention safety shower and eye rinsing nearby the unloading area Wear of PPE Follow the instructions of the O&M manual S

Identification

Hazard

Initial

residual

Risk of ammonia spillage or hose connection uncorrect or broken 1 Unloading operation by the truck Tank overflowing

Spatter of ammonia Working nearby chemical injury the ammonia tank Operator breathing problem

Removal of the dangerous phenomenon

Spatter of ammonia Working nearby chemical injury the ammonia tank Operator breathing problem

Removal of the dangerous phenomenon

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : NH4OH installation - 1 / 3

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TASK Nr

NH4OH tank draining

MLS : during operation

Frequency : exceptional

OPERATION

Ammonia solution 24,5% is stored in a tank and is unloaded by a truck. Ammonia can be discharged from the tank to a truck COMPONENT OF THE RISK P Hazard hazardous situation dangerous event, possible damage

PREVENTIVE MEASURE S On what component we have to act Means Leakage detection with horn Automatic spraying Drips collection in a retention safety shower and eye rinsing nearby the unloading area Wear of PPE P S

Identification

Initial

residual

Tank draining to a risk of ammonia truck spillage

Spatter of ammonia Working nearby chemical injury the ammonia tank Operator breathing problem

Removal of the dangerous phenomenon

TASK Nr

OPERATION

retention emptying under NH4OH MLS : during operation tank Any ammonia leakage is collected in a pit This intervention consists in operating in this pit COMPONENT OF THE RISK P Hazard hazardous situation dangerous event, possible damage Slipping in the retention Spatter of ammonia chemical injury Operator breathing problem P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Frequency : Exceptional

PREVENTIVE MEASURE S On what component we have to act Means Leakage detection with horn safety shower and eye rinsing in the retention and outside of the retention Wear of PPE Follow the instructions of the O&M manual P S

Identification

Initial

residual

Retention drainage

Presence of ammonia

working nearby ammonia

Removal of the dangerous phenomenon

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : NH4OH installation - 2 / 3

10892EA00400-0

TASK Nr

Tank inspection

MLS : maintenance

Frequency : Exceptionnal

OPERATION N Identification

Ammonia solution 24,5% is stored in a tank This intervention consist in internal inspection of the tank COMPONENT OF THE RISK Hazard hazardous situation dangerous event, possible damage P S Initial On what component we have to act

PREVENTIVE MEASURE P Means Intervention by two authorized operators. Draining of the tank before any intervention Venting with air before any intervention. Adequate scaffolding. Wear PPE and body harness, check of temperature Respect the specific procedures of work in confined area (ventilation, atmosphere control). Follow the instructions of the O&M manual (Lab & manufacturer) S residual

Internal inspection Presence in the of the tank tank

Slide. Fall. Presence of ammonia

Chemical injury, operator breathing problems.

Removal of the dangerous phenomenon

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : NH4OH installation - 3 / 3

10892EA00400-0

TASK Nr

Residue loading

MLS : during operation

Frequency : Daily

OPERATION

Residue are stored in a silo (one for ashes and one for spent sorbent) This intervention consists in loading residue in a truck COMPONENT OF THE RISK P Hazard hazardous situation Working nearby the residue silo dangerous event, possible damage

PREVENTIVE MEASURE S On what component we have to act Removal of the dangerous phenomenon Means P S

Identification

Initial

residual

Loading operation in Truck overflowing the truck

Truck overflowing

Indication on the local panel of high level reached and valve shut off An alarm is set off when truck high level is reached.

TASK Nr

Changing bag filter on silo

MLS : Mounting /dismantling

Frequency : Annual

OPERATION

Identification

Residue are stored in a silo (one for ashes and one for spent sorbent) and are equipped with filter to allow air evacuation without dust emission This intervention consists in changing the filter COMPONENT OF THE RISK PREVENTIVE MEASURE P S On what hazardous dangerous event, component we Means Hazard Initial situation possible damage have to act Presence of a handrail around the top of the silo. Certified handling/lifting equipments. Handling by authorized operators. Marking area and banning access under the load. Follow the instructions of the O&M manual (Lab & manufacturer) Means

residual

Parts of the filter Replacement of the removed by the silos bag filter operators

Presence nearby Fall of object. the bottom of the Injury silo

Removal of the dangerous phenomenon S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : residue silo - 1 / 2

10892EA00400-0

TASK Nr

Residue silo inspection

MLS : maintenance

Frequency : Annual

Residue are stored in a silo (one for ashes and one for spent sorbent) This intervention consists in internal inspection of the silos that could be necessary for maintenance of the extraction system OPERATION COMPONENT OF THE RISK PREVENTIVE MEASURE On what P S P S hazardous dangerous event, N Identification Hazard component we Means Initial residual situation possible damage have to act Intervention by two authorized operators. Emptying of the silo before any intervention Preliminary check from the roof manhole that the silo is empty Venting with air before any intervention. Injury. Nitrogen injection in spent sorbent silo mechanically locked Slide. Chemical risks Internal inspection Pneumatic transport stopped Presence in the silo, Fall. (Breathing Removal of the of the silos Adequate scaffolding. 1 contact with the Presence of problems). C 3 dangerous A 2 maintenance Prohibition on being in the silo during the operation of the extraction residues residues Work in equipment phenomenon operation in the silo system where residue are Extraction system mechanically locked usually at 80C Wear PPE and body harness, check of temperature Respect the specific procedures of work in confined area (ventilation, atmosphere control). Follow the instructions of the O&M manual (Lab & manufacturer) S= maximal MLS : Machine life step Frequency of the task P= probability of occurrence Means severity of the possible damage Installation : Continuous 1 : Insignificant During operation A : Unlikely Daily 2 : Limited Maintenance B : Uncommon Weekly Arrangement taken in order to solve or reduce to the maximum the problem caused by 3 : Serious Mounting/Dismantling C : Casual Monthly the risk 4 : Fatal D : highly Annual Exceptional See also supplier risk analysis and maintenance manual in MORILLON WAM as built documentation references 10892SA17201 10892NA17303-304-305-306 10892NA17201-17202-40401

Specific part : residue silo - 2 / 2

10892EA00400-0

TASK Nr

Checking visit of the reagent dosing system

MLS : during operation

Frequency : Daily

OPERATION

The reagent dosing system transports activated carbon and bicar in each injection line the intervention consists in checking nearby the dosing system its good functioning COMPONENT OF THE RISK P S Hazard hazardous situation Work nearby rotating part of the dosing system work nearby electric circuit dangerous event, possible damage Contact with rotating part of the dosing system - Injury Contact with conductor under voltage - electric shock Initial On what component we have to act

PREVENTIVE MEASURE P Means S

Identification

residual

Visual and hearing check of the screw functioning

Rotating part of the dosing system Conductor under voltage

Make sure that protector supplied by the Removal of the dangerous phenomenon manufacturer are installed before : obstacle / rotating parts intervention Removal of the No bare conductor under voltage dangerous phenomenon S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : Reagent dosing system - 1 / 2

10892EA00400-0

TASK Nr

Remove / replace of the system motor-screw

MLS : maintenance

Frequency : Exceptional

OPERATION

The reagent dosing system transports activated carbon and bicar in each injection line the intervention consists in removing and then replacing an equipment motor COMPONENT OF THE RISK P S Hazard hazardous situation dangerous event, possible damage Initial On what component we have to act Removal of the dangerous phenomenon: electrical motor locked out Removal of the dangerous phenomenon: electrical motor locked out Installation of means to avoid damages reagent projection A 2

PREVENTIVE MEASURE P Means S

Identification

residual

Electrical connection / disconnection of screw motor

Rotation of the equipment axis

Contact with rotating Work nearby rotating part of part of the equipment the screw Injury work nearby electric circuit Contact with conductor under voltage - electric shock

Disconnecting switch with padlock in general low voltage panels or local panel Disconnecting switch with padlock in general low voltage panels or local panel Wear PPE : goggles / gloves / boots / mask

Conductor under voltage

operator(s) work under silo

Reagent leakage from the silo cone

Work nearby activated carbon circuit

Removal of the Close manual isolating gate valve under dangerous phenomenon silo and evacuate downstream circuit P= probability of occurrence S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in SODIMATE

WAM as built documentation references 10892SA40520 10892NA40520-521-522-523-524-531-532-533 10892NA40401

Specific part : Reagent dosing system - 2 / 2

10892EA00400-0

TASK Nr

Watching visit of the grinders

MLS : during operation

Frequency : Daily

The bicarbonate grinders mill the bicarbonate and the fan transports it in each injection line The intervention consists in checking the good functioning of the grinder and the fan OPERATION N Identification Hazard Rotation of the grinder and fan COMPONENT OF THE RISK hazardous dangerous event, situation possible damage Work nearby rotating equipment Contact with rotating part of the fan - Injury PREVENTIVE MEASURE P S Initial B 3 On what component we have to act Means P S residual A 1

Make sure that protections supplied by the manufacturer Removal of the are installed before intervention dangerous phenomenon: Follow the instructions of O&M manual (Lab & obstacle / rotating parts manufacturer). Removal of the No bare conductor under voltage dangerous phenomenon Installation of means to avoid damages Wear PPE Follow the instructions of the O&M manual (Lab & manufacturer)

Contact with conductor Visual and hearing check Conductor under electric Work nearby under voltage - electrical of the functioning potential electric cirucit shock Noise, heat Working nearby the noise source auditory and burning risks

TASK Nr

Cleaning of grinder chamber and injection fan

MLS : maintenance

Frequency : Monthly

OPERATION N Identification

The bicarbonate grinders mill the bicarbonate and the fan transports it in each injection line The intervention consists in cleaning the grinder and the injection fan COMPONENT OF THE RISK dangerous event, hazardous P S On what component we Hazard Initial possible damage have to act situation

PREVENTIVE MEASURE Means Protection by safety locking device, the key is released when the grinder motor is stopped, the drive cannot be switched on as long as the mill housing is not completely closed. Disconnecting switch with padlock in general low voltage panels or local panel Follow the instructions of O&M manual (Lab & manufacturer). Means P S residual

The operators are cleaning inside the grinder chamber and inside the fan housing

Rotation of the wheels

Working nearby the wheel

Contact with the rotating wheel

Removal the dangerous phenomenon

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : Grinders and injection fans - 1 / 2

10892EA00400-0

TASK Nr

Removal / replacement of fan or grinder motor/wheel/selector

MLS : maintenance

Frequency : Exceptional

The bicarbonate grinders mill the bicarbonate and the fan transports it in each injection line This intervention consists in removing and replacing part of fan or grinder OPERATION N Identification Hazard COMPONENT OF THE RISK hazardous dangerous event, situation possible damage Work nearby rotating equipment PREVENTIVE MEASURE P S Initial On what component we have to act Removal of the dangerous phenomenon: electrical motor locked out Means Protection by safety locking device, the key is released when the grinder motor is stopped, the drive cannot be switched on as long as the mill housing is not completely closed Disconnecting switch with padlock in general low voltage panels or local panel P S residual

Rotation of the fan or grinder shaft 1 Electrical connection / disconnection of fan or grinder motor

Contact with rotating part of the fan - Injury

Work on the Conductor under electric fan or battery potential electrical part

Contact with conductor under voltage - electrical shock

Removal of the dangerous phenomenon: Disconnecting switch with padlock in general low voltage electrical motor and panels or local panel battery locked out Removal of the Adequate lifting device dangerous phenomenon Handling by trained people Make sure nobody is present under the load Area marking and forbidden access under the load S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

One or more operators lift and handle part of the fan or grinder

Part of fan or grinder overhanging

Presence Falling down of the load under the load Crushing of operator

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in GTS as built documentation references 10892SA40811 10892NA40812-814-815-816

Specific part : Grinders and injection fans - 2 / 2

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TASK Nr

Watching visit of different pumps

MLS : during operation

Frequency : daily

OPERATION N Identification

Circulation pumps ensure condensate water circulation in the heat recovery primary loop Booster pumps ensure condensate water pressure in the heat recovery primary loop The intervention consists in checking the good functioning of the pumps COMPONENT OF THE RISK hazardous dangerous event, On what component P S Hazard Initial situation possible damage we have to act Working Contact with the moving Removal of the nearby the Rotation of the pump axis part of the pump. B 3 dangerous phenomenon: moving part of Injury obstacle / rotating parts the pump Working Contact with a conductor Conductor under voltage nearby under voltage electrical circuit Electrical shock Working nearby the process fluid circuit spatter of process fluid B 4

PREVENTIVE MEASURE Means P S rsidual 1

Visual and audio checking of the pump during operation

Process fluid leakage

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Follow the instructions of the O&M manual (Lab & manufacturer). A Protectors provided by the manufacturer. CE certificate provided by the manufacturer Disconnecting switch with padlock in general low Removal of the voltage panels or local panel. A dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer) Wearing of the PPE. Removal of the Follow the instructions of the O&M manual (Lab B dangerous phenomenon & manufacturer) Material of gasket compatible with ammonia S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited Arrangement taken in order to solve or reduce to the 3 : Serious maximum the problem caused by the risk 4 : Fatal

Specific part : Water pumps - 1 / 2

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TASK Nr

OPERATION N Identification Connection / disconnection of the motor

Connection / disconnection of the pump

Mounting/Dismantling of pumps with MLS : maintenance Frequency : Exceptional their motors Circulation pumps ensure condensate water circulation in the heat recovery primary loop Booster pumps ensure condensate water pressure in the heat recovery primary loop This intervention consists in removing then replacing the motor or the pump COMPONENT OF THE RISK PREVENTIVE MEASURE hazardous dangerous event, On what component P S Means Hazard Initial situation possible damage we have to act Disconnecting switch with padlock in general low Removal of the voltage panels or local panel Working Contact with the moving dangerous phenomenon: Manufacturer protection Rotation of the motor axis nearby the part of the motor. B 3 electrical motor locked Follow the instructions of the O&M manual (Lab Injury moving part out & manufacturer) Removal of the Disconnecting switch with padlock in general low Working Contact with a conductor dangerous phenomenon: voltage panels or local panel Conductor under voltage nearby the under voltage. B 4 electrical motor locked Follow the instructions of the O&M manual (Lab electrical part Electric shock out & manufacturer) Wear PPE. Installation of means to Follow the instructions of the O&M manual (Lab avoid damages & manufacturer) Working Contact with the hot Leak of process fluid nearby the Removal of the condensate water C 3 Before dismantling, bleeding and drainage of the (fluid under pressure) process fluid dangerous phenomenon: Injury hot water circuit circuit pump draining before Follow the instructions of the O&M manual (Lab disconnection, wait for & manufacturer) circulation pump cooling Certified handling/lifting equipments. Handling by authorized operators. Marking area and banning access under the load. Follow the instructions of the O&M manual (LAB & manufacturer) Means

P S rsidual

Handling

Suspended machine

Presence Fall of the load. under the load Crushing of operators

Removal of the dangerous phenomenon: Make sure nobody is present under the load S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in KSB SALMSON as built documentation references 10892NA26411-412 10892NA26512-513-514

Specific part : Water pumps - 2 / 2

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TASK Nr

Checking visit of the unloading/injection pumps

MLS : during operation

Frequency : Daily

OPERATION N Identification

The unloading pump feed the storage tank from the truck The injection pump feed upstream SCR with ammonia the intervention consists in checking the good functioning of the ammonia pumps COMPONENT OF THE RISK hazardous dangerous event, P S On what component we Hazard Initial situation possible damage have to act Rotation of the pump axis Working nearby Contact with the moving the moving part part of the pump. of the pump Injury Contact with a conductor Working nearby under voltage electrical circuit Electrical shock Working nearby the ammonia circuit Spatter of ammonia injury with caustic etching B 3

PREVENTIVE MEASURE Means P S rsidual A 1

Removal of the Make sure that protector supplied by the dangerous phenomenon: manufacturer are installed before intervention obstacle / rotating parts Removal of the dangerous part Installation of means to avoid damages Removal of the dangerous part S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Visual and audio checking of the pump during operation

Conductor under voltage

No bare conductor under voltage Wear PPE :goggles / gloves / respirator Safety shower / eye rinsing nearby Leakage detection with horn Ammonia detection alarm Means

B B

1 1

Ammonia leakage

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : NH4OH pumps - 1 / 2

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TASK Nr

OPERATION N Identification

Removal/replacement of the ammonia MLS : maintenance motor/pump The unloading pump feed the storage tank from the truck The injection pump feed upstream SCR with ammonia The intervention consists in removing then replacing the motor or the pump COMPONENT OF THE RISK hazardous dangerous event, P S Hazard Initial situation possible damage Rotation of the pump axis Work nearby rotating part Contact with the rotating part. Injury B 3

Frequency : Exceptional

PREVENTIVE MEASURE On what component we have to act Removal of the dangerous part : electrical isolation of the motor Removal of the dangerous part : electrical isolation of the motor Installation of means to avoid damages Means Disconnecting switch with padlock in general low voltage panels or local panel P S rsidual A 1

Electrical connection / disconnection of pump motor

Conductor under voltage

Contact with conductor Work nearby under voltage. electrical circuit Electrical shock

Disconnecting switch with padlock in general low voltage panels or local panel Wear PPE :goggles / gloves / respirator Safety shower / eye rinsing nearby Leakage detection with horn

Connection / disconnection of ammonia pump from fluid circuit

Ammonia solution 24,5% leakage

Work nearby Ammonia splashing ammonia circuit chemical injury

Removal of the Before dismantling, connection with the water dangerous phenomenon: network, rinsing of the pump with waste water rinsing of the pump sending to the sewer before intervention Leakage detection with horn Removal of the safety shower and eye rinsing in the retention dangerous phenomenon Wear of PPE Follow the instructions of the O&M manual S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

Intervention in the retention

Presence of ammonia

working nearby Slipping or operator ammonia breathing problem

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in KSB LEWA as built documentation references 10892NA26401-412 10892NA26211-212-213

Specific part : NH4OH pumps - 2 / 2

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TASK Nr

OPERATION N Identification

Checking visit of the ammonia MLS : During operation Frequency : Daily injection The ammonia injection system is used to inject the chemical upstream SCR reactor This intervention consists in checking the ammonia injection during operation PREVENTIVE MEASURE COMPONENT OF THE RISK P S hazardous dangerous event, On what component Hazard Means Initial situation possible damage we have to act Wear PPE. Ammonia detectors. Ducts in stainless steel. Remove the dangerous No flanges or flanges protected. Security shower. phenomenon Ammonia resistant gaskets. Follow the instructions of the O&M manual (Lab & manufacturer). S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

residual

Checking visit of ammonia injection

Leak of ammonia

Presence of operators nearby the injection system

Contact with ammonia : B chemical injury

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : NH4OH injection - 1 / 2

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TASK Nr

disassembly of the ammonia lances

MLS : During operation

Frequency : Annual

OPERATION N Identification

The ammonia injection system is used to inject the chemical upstream SCR reactor This intervention consists in checking the ammonia injection during operation COMPONENT OF THE RISK P S hazardous dangerous event, On what component Hazard Initial situation possible damage we have to act

PREVENTIVE MEASURE P Means S residual

Checking visit of ammonia injection

Leak of ammonia

Presence of operators nearby the injection system

Contact with ammonia : B chemical injury

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

Wear PPE. Ammonia detectors. Ducts in stainless steel. Remove the dangerous No flanges or flanges protected. Security eye rinsing phenomenon Ammonia resistant gaskets. Follow the instructions of the O&M manual (Lab & manufacturer). S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : NH4OH injection - 2 / 2

10892EA00400-0

TASK Nr

Mounting/Dismantling hot piping

MLS : mounting/dismantling

Frequency : Exceptional

OPERATION N Identification

Hot piping is present at the heat recovery system The intervention consists in disconnecting piping COMPONENT OF THE RISK Hazard hazardous situation dangerous event, possible damage P S Initial On what component we have to act Installation of means to avoid damages

PREVENTIVE MEASURE P Means Wear PPE. Follow the instructions of the O&M manual (Lab & manufacturer) B 1 S rsidual

Connection / Leak of process fluid disconnection of the pipe

Working nearby the process fluid circuit

Contact with the hot condensate water Injury

Before dismantling, drainage of the hot Removal of the dangerous phenomenon: water circuit pipe draining before disconnection, wait for Follow the instructions of the O&M manual (Lab & manufacturer) pipe cooling Certified handling/lifting equipments. Handling by authorized operators. Removal of the dangerous phenomenon: Marking area and banning access under the load. Make sure nobody is present under the load Follow the instructions of the O&M manual (LAB & manufacturer) S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

Handling

Suspended equipment

Presence Fall of the load. under the load Crushing of operators

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in SNZ GEA as built documentation references 10892QA27550-560 10892NA25611

Specific part : Hot piping - 1 / 1

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TASK Nr

Checking visit of the mechanical transport equipment

MLS : during operation

Frequency : Daily

Fly ash transport : screw conveyor under ESP/ lump breaker Spent sorbent transport : screw conveyors under fabric filter The intervention consists in checking the good functioning of the mechanical transport equipment OPERATION N Identification Hazard COMPONENT OF THE RISK hazardous dangerous event, situation possible damage Working Contact with the moving nearby the moving part of part. Injury the screw conveyor Contact with a conductor Working under voltage nearby an electrical circuit Electrical shock Working nearby the circuit of chemicals substance PREVENTIVE MEASURE P S Initial On what component we Means have to act Make sure that protector supplied by the manufacturer are Removal of the installed before intervention dangerous phenomenon : Special tool needed to open the trapdoor. obstacle / rotating parts Follow the instructions of the O&M manual (Lab & manufacturer) No bare conductor under voltage. Removal of the dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer) P S residual

Visual and auditory checking of the mechanical transport equipment during operation

Rotation of the screw axis

Conductor under voltage

Leakage checking

Leak of chemical substance

Contact with the chemical substance : injury

Removal of the Wear PPE. dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer) S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Means

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Specific part : Residue mechanical transport - 1 / 2

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TASK Nr

Mounting / dismantling of the mechanical transport equipment

MLS : maintenance

Frequency : Annual

Fly ash transport : screw conveyor under ESP/ lump breaker / rotary valve before big bag Spent sorbent transport : screw conveyor under fabric filter The intervention consists in removing one component (motor, sealing, stuffing box,...) OPERATION N Identification Hazard COMPONENT OF THE RISK hazardous situation dangerous event, possible damage P S Initial On what component we have to act PREVENTIVE MEASURE P Means S residual

Handling of the mechanical transport equipment

Part of the equipment suspended

Presence Fall of the load under the load Crushing of the operator

Removal of the dangerous phenomenon: Make sure nobody is present under the load

Certified handling/lifting equipments. Handling by authorized operators. Area marking and banning access under the load Wear PPE. Follow the instructions of the O&M manual (Lab and manufacturer)

Spillage of residue 2 Handling of the mechanical transport equipment Conductor under voltage

Working nearby the circuit of chemicals substance Working nearby the electrical part

Contact with chemical substances

Wear PPE. Removal of the Special tool needed to open the trapdoor. dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer)

Contact with a conductor under voltage Electrical shock

Disconnecting switch with padlock in general low voltage panels Removal of the or local panel. dangerous phenomenon Follow the instructions of the O&M manual (Lab & manufacturer) S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Means

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in ELEX STAG STAG as built documentation references 10892SA17201 10892NA11121-122-123 10892NA17601-602-603-604-606-607-619-620-631-632-633

Specific part : Residue mechanical transport - 2 / 2

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TASK Nr

Inspection of pneumatic transport equipment

MLS : maintenance

Frequency : Annual

OPERATION N Identification

Fly ash pneumatic transport from ESP to storage silo Spent sorbent pneumatic transport from fabric filter to storage silo The intervention consist in checking the inside of the equipments COMPONENT OF THE RISK dangerous event, Hazard hazardous situation possible damage Working nearby the pressurized vessel Working nearby the conveying equipment quick depressurization of the equipment - injury Contact with chemical substances

PREVENTIVE MEASURE P S Initial B 3 On what component we have to act Removal of the dangerous phenomenon Removal of the dangerous phenomenon S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means Check local pressure measurement and deaerate the vessel Follow the instructions of the O&M manual (Lab and manufacturer) Wear PPE Follow the instructions of the O&M manual Means P S residual A 1

Equipment under Opening of the conveying pressure vessel and conveying lines Spillage of residue MLS : Machine life step

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Installation : During operation Maintenance Mounting/Dismantling

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in STAG as built documentation references 10892NA17601-602-605-609-673

Specific part : Residue pneumatic transport - 1 / 1

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TASK Nr

Checking visit of the instruments DESCRIPTION OF THE EQUIPMENT

MLS : During operation

Frequency : Daily

Instruments are composed of pressure, temperature et other variables detectors. OPERATION N Identification Hazard COMPONENT OF THE RISK hazardous situation dangerous event, possible damage P S Initial On what component we have to act PREVENTIVE MEASURE P Means S residual

Checking visit of the instruments

under voltage or hot instrument

Contact with Injury : electrical shock; an instrument burning.

MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

Intervention only by authorized people Wear PPE. Remove the dangerous Follow the instructions of the O&M manual (Lab & manufacturer). phenomenon Earthing. Electrical isolation. S= maximal severity of Means the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in

WIKA KHRONE ENDRESS HAUSER as built documentation references 10892NA29111-113-114-115-116-10892NA29151 10892NA29130-131-132

Specific part : Instruments - 1 / 1

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TASK Nr

OPERATION N Identification

Checking visit of the valves and MLS : During operation Frequency : Daily accessories DESCRIPTION OF THE EQUIPMENT Valves and accessories are present in the whole installation and are used to allow, or not, fluids circulation in the pipes or ducts. COMPONENT OF THE RISK PREVENTIVE MEASURE P S hazardous dangerous event, On what component Hazard Means Initial situation possible damage we have to act Wear PPE. Suitable material for accessories Remove the dangerous Follow the instructions of the O&M manual (Lab & phenomenon manufacturer). Ducts and pipes can be drained by gravity flowing Wear PPE. Remove the dangerous Follow the instructions of the O&M manual (Lab & phenomenon manufacturer). Wait for accessory cooling before intervention No bare conductor under voltage Removal of the Follow the instructions of the O&M manual (Lab & dangerous phenomenon manufacturer). S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

residual

Leak of a chemical products Checking visit of the accessories Working nearby the accessory, contact with it

Chemical injury

Hot accessory

Injury : burning

Conductor under electric potential MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

Contact with conductor under voltage - electrical shock

P= probability of occurrence

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in

AVS SALMSON as built documentation references 10892NA28450-451-460 to 467 10892NA28470-480-490 10892NA26516

Specific part : Valve & components - 1 / 1

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TASK Nr

OPERATION N Identification

Checking visit of an equipment equipped with MLS : During operation electrical tracing Electrical tracing is used on residue silos and residue transport equipment Intervention on an equipment equipped with electrical tracing COMPONENT OF THE RISK P S dangerous event, Hazard hazardous situation Initial possible damage

Frequency : Annual

PREVENTIVE MEASURE On what component we have to act Remove the dangerous phenomenon P Means Marking of heat traced area Wear PPE Follow the instructions of the O&M manual (Lab & manufacturer). S residual

Checking visit of the residue silos, mechanical transport under ESP or under fabric filter, pneumatic transport

Hot electrical tracing Work nearby electric circuit Conductor under electric potential Removal of insulation for equipment inspection

Injury : burning Contact with conductor under voltage - electrical shock

Removal of the No barre conductor under voltage dangerous phenomenon Frequency : Annual

TASK Nr

MLS : During operation

OPERATION N Identification

Electrical tracing is used on residue silos and residue transport equipment Intervention on an equipment equipped with electrical tracing COMPONENT OF THE RISK Hazard Presence of mineral fibers in suspension hazardous situation dangerous event, possible damage P S Initial C 2 On what component we have to act

PREVENTIVE MEASURE P Means S residual A 1

Removal of insulation MLS : Machine life step

Breathing of these mineral Breathing problems fibers in suspension Skin irritation

Removal of the Wear PPE : goggles / gloves / boots / dangerous phenomenon mask / safety helmet S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal Means

Frequency of the task Continuous Daily Weekly Monthly Annual Exceptional

P= probability of occurrence

Installation : During operation Maintenance Mounting/Dismantling

A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

See also supplier risk analysis and maintenance manual in TRACE TEC STAG ELEX as built documentation references 10892NA24311-312 10892NA17612 10892NA11312

Specific part : electrical tracing & insulation - 1 / 1

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3- RISK INTERFACES OPERATION N 1 2 Identification Plant cleaning Handling/lifting with the overhead crane of the plant Handling with truck and load on the ground Noise (addition / reverberation) Hazard Cleaning nearby equipment Fall of the load Circulation nearby equipment Circulation of a load on the ground Increase of noise COMPONENT OF THE RISK hazardous situation Damage on equipment People under the load Fall on equipment Collision with equipment Overload on the concrete Working in the area concerned dangerous event, possible damage People injury Material damage People injury Material damage People injury / material damage Damage on civil work People hearing damage P S On what component we have to act Remove the dangerous phenomenon Remove the dangerous phenomenon Remove the dangerous phenomenon Remove the dangerous phenomenon Remove the dangerous phenomenon Remove the dangerous phenomenon Means Follow the procedures and the O&M manual Follow the procedures and the O&M manual Overhead running by authorized people Wear PPE Follow the procedures and the concerned O&M manuals Circulation ways defined by OMRIN Definition of the concrete by OMRIN with LAB load information Global acoustic study by OMRIN including LAB information Initial B B B B B B B 4 3 4 3 4 3 2 PREVENTIVE MEASURE P S residual (*) A A A A A A A 1 1 1 1 1 1 1

Temperature / ventilation

Ventilation default

Temperature increase People discomfort Possible presence of chemical products

Remove the dangerous phenomenon

Follow the procedures and the O&M manuals Global thermal study by OMRIN including LAB information

Stop of the Idfan

Idfan stop and fluegas pressure back into boiler pressure back via DeNOx air inlet or fresh air intake Piping breakdown Process fluid leakage

Presence of people People injury

Remove the dangerous phenomenon

Emergency motor installed on IDfan to maintain the flue gas line under pressure General safety procedure under OMRIN responsability Acceptable stress on flanges indicated by LAB Firm plate on heat exchanger DESP classification - Drainage by a truck equipped with a pump : tank drainage procedure to study with OMRIN to define the means for protection - The floor marking of the danger area is recommended - Leakage detection with flashing light and horn visible before being in the ammonia area (position approved by OMRIN) - Three detections in the area (retention, tank roof and truck unloading) - Two safety showers with eye rinsing : one in the retention, one in unloading area - For maintenance intervention on the pumps, wearing a mask is strongly recommended The valve to sewer is closed when ammonia is detected The doubling of the valve is strongly recommended Access restriction and electrical locking management by OMRIN

Water/water heat exchanger

Presence of people People injury

Remove the dangerous phenomenon

Presence of NH4OH in the retention under the tank

Retention full of ammonia drainage of ammonia in the Presence of people People injury retention

Remove the dangerous phenomenon

Valve under retention is opened 9 Automatism, Electricity and Instrumentation Control system MLS : Machine life step Installation : During operation Maintenance Mounting/Dismantling Continuous Daily Weekly Monthly Annual Exceptional Access to electrical equipment, intervention on equipment

The ammonia is evacuated to the sewer

Environment damage

remove the dangerous phenomenon

Presence of people Electrical shock

remove the dangerous phenomenon

10

People injury Uncorrect functioning of the Presence of people equipment damage safety Frequency of the task

Remove the dangerous phenomenon S= maximal severity of the possible damage 1 : Insignificant 2 : Limited 3 : Serious 4 : Fatal

Commisioning synchronisation by OMRIN with LAB commisioning documents Means

P= probability of occurrence A : Unlikely B : Uncommon C : Casual D : highly

Arrangement taken in order to solve or reduce to the maximum the problem caused by the risk

Part 3-Risk interfaces - 1 / 3

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(*) : Residual probability and damage severity to be evaluated by OMRIN

Part 3-Risk interfaces - 2 / 3

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See also Interfaces in HAZOP report dated 12/02/08 action 3 : boiler flue gas action 7 : steam supply action 8 : steam supply action 9 : steam supply action 12 : operation of Idfan action 13 : Trudel motor action 14 : flue gas analyser action 18 : condensate from/to water - water HE action 21 : condensate to LAB buffer tank action 37 : motor primary air fan pressure control failure no steam supply no steam supply malfunctioning of temperature control, open failure of control valve failure of IDFan or Idfan drive or related components main motor failure not correct functioning of the analyser stop of condensate pumps or open bypass or blockage level control failure failure of motor or related motor

Part 3-Risk interfaces - 3 / 3

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4- EC CERTIFICATES Please refer to as-built documentation (DOE) section A 03 "EC conformity"

Part : 4-EC Certificates - 1 / 1

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5 - LIST OF NORMS APPLIED REFERENCE DESCRIPTION NEN standards and guidelines Relating to the inspection of works, in the currently valid version. Guidelines for energy delivery to the public grid. Guidelines Commissie preventie van rampen door gevaarlijke stoffen. Committee on prevention of disasters caused by dangerous substances ARBO guidelines. Stoomwezen/ PED. Besluit verbranding afvalstoffen Bva. Bva waste incineration decisions The applicable Netherlands Standards Specification (NEN) and publications of Nederlands Normalisatie Instituut (NEN), VDEN, KEMA, Dte, EnergieNed. Dutch Practical Guidelines (NPR). The applicable International Standards (ISO), in particular for unit of measures, mechanical accessories and assemblies, bolts and nuts, the ISO system of units shall be used. The applicable standards of the European Committee for Electro technical Standardisation (CENELEC). The codes and regulations of the Netherlands Directorate General of Labour. European Electro Magnetic Compatibility (EMC) regulations as applicable. EN Standards Guideline: Tolerances for steel structures regarding architectural aspects and strength, stiffness and stability. (Report BI-84-3) Published by the Staalbouwkundig Genootschap; Dutch Practical Guidelines (NPR) for the design of connections (Report BI-85-7) Published by the Staalbouwkundig Genootschap; Guidelines for design calculations for and detailing bolted angle connections Published by the Staalbouwkundig Genootschap; Bouwbesluit of 2003 Building regulation The local authority building regulations relating to the construction site Guidelines for design calculations for stiffened and unstiffened plate arrays subjected to distributed loads Report BI 80-50. Published by the Staalbouwkundig Genootschap EU Machinery directive CE/2006/42 DIN 45641 and DIN 45645 Sound insulation design DIN 52612 thermal conductivity determination for flat products DIN 52613 thermal conductivity for cylindrical products EN 287 welders Qualification EN ISO 389 Acoustics -- Reference zero for the calibration of audiometric equipment Safety of machinery, human body measurements Part 1 : Opening - Part 2 : orifices - Part 3 : anthropometric data EN 547 - 1 to 3 Safety of machinery - Ergonomic design principles - Part 1 : Terminology and design principles - Part 2 : Interaction between machinery design and work tasks EN 614 - 1 & 2 Safety of machinery Ergonomics requirements for the design of displays and control actuators Part 1 : interactions - Part 2: Displays - Part 3 : control actuators EN 894 - 1 to 3 ISO 10816 Vibration of mechanical equipment ISO 2373 low voltage motor - mechanical vibration ISO 5167 / 5168 orifices plates and nozzles calcualtion ISO 5210 / 5211 driving elements for electrical actuators ISO 8501 Paint system - sand blasting NEN 1008 thickness of the galvanized layer on the trays and vertical runs NEN 1010 electrical equipment protection type NEN 1010 types of protection NEN 1010 choice of cable cross sectional areas NEN 1010 and NEN 3140 prevention shock currents from both direct and indirect contact NEN 1041 definition of safe working class for safe working in high voltage areas with explosion mixtures. NEN 1041 definition of sealing for cable penetrations in the walls, ceilings and floors so that they are fireproof NEN 1041 and NEN 3840 for safe working in high voltage areas

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REFERENCE NEN 1041 and NEN 3840 NEN 1275 NEN 2062 and NEN 2063 NEN 2446 NEN 3125 NEN 3173 NEN 3173 NEN 3184 NEN 3621 NEN 6064 NEN 6065 NEN 6700 NEN 6720 VB NEN-EN-ISO 14122 part 2, 3 and 4. NEN-ENV 1090-1:1997

DESCRIPTION Protective earthing measures and protection against contact Galvanization Arc welding cable identification necessary explosion proof design for installation of electrical equipment in explosion- proof areas standards NEN-EN-IEC 60034 low- voltage motors noise limit values converter transformers design cable design bare insulation products non combustible Insulation : For products dressed with aluminium foil the flame spread shall be class 1 Technical bases for the design and calculations of building structures TGB 1990 beton technical requirements Safety of machinery : working platform and access / stairs, stepladder and guard-rails / fixed ladders Execution of steel structures - Part 1: General rules and rules for buildings

Part : 5-List of norms - 2 / 2

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