Near-Naveen Chowk, Bypass, Sitapur (UP) Pin 261001 Mobile 9335531368 Ph. 05862 223337 E-Mail - sei.school@yahoo.

hoo.com Website : www.singhaniaeducation.com

Pre Board Examination

Class : XI Subject : Chemistry Max. Marks : 100 Time : 3.00 hr

General Instructions:Attempt all the questions. Writing should be neat and clean. Each question carry 2 marks

.
2

Q1. Write balanced equations for a) b) c) d) Q2 What is the difference between hydrolysis and Hydration Q3 Conversion a) Ethane to butane b) Ethene to ethyne Q4 What do you mean by the acid rain . Write one harmful effect of acid rain Q5 What is the difference between hydrolysis and Hydration

2 2

2 2

Each question carry 3 marks Q1.a) What is the SI unit of electric current . How it is defined b)Write equation for the preparation of Plaster of paris Q2 What do you mean by Ozonehole? How the form and affect our living. Q3 Write IUPAC name of the following compounds a) 3 (2+1) c)CH3-C(CH3)2CO-CH3 (2+1)

b)OHC-(CH2)-CHO

d) CH3-CH=CH-CH2CHO b) Auto protolysis of water Q4 calculate the lattice enthalpy o KCl from the following data at the standard states. Enthalpy of sublimationof potassium-89.8kj Enthalpy of dissociation of cholrine-243kj Ionizationenthalpy of potassium -418.9kj 3

Electrongain enthalpy of chlorine348.6kj Enthalpy of formation of KCl-436.8kj OR a) Write note on Phase transformation processes with suitable examples of each. b) what happens when Boric acid is heated? (2+1)

Q5 .a) Differentiate between the enthalpy of Atomization and Enthalpy of and bond enthalpy of polyatomic molecules. (2+1) b)calculate the electron rich molecular precise OR Calculate the solubilityof A2X3 in pure water assuming that neither type of ion reacts with water. The solubility product of A2X3,Ksp=1.1*10-23 3 Each question carry 4 marks Q1.a) What is the concentration of sugar (C12H22O11) in mol per lt if its 20 gm dissolved in enough water to make a volume upto 2lt b) Calculate the wavelength of an electron moving with a velocity of 2.05 x107 ms-1 Q2.a) Explain why cations are smaller and Anions are larger in radii than their parent atom? b)Explain the magnetic behavior if N2 on the basis of MOT (2+2) (2+2)

Q3. What do u mean by Markonikov rule and Anti Markonikov rule .Name the intermediate formed in these two reaction and write the stability of the intermediates (2+2) Q4.a) Calculate the temperature of 4.0 mol of a gas occupying 5dm3at 3.32 bar b) How Alkali metals gives different colours when dissolved in liquid ammonia. OR a) Balance the following equation by ion exchange method MnO4- + SO32Mn2+ +SO42-(acidic medium) (2+2)

b) What is the resonance structure ofCO32- and HCO3Q5 What do you mean by the hardness of water.Explain its types Explain the organic ion exchange resins method for the removal of permanent hardness. 4 OR Each question carry 5 marks Q1. Give reasons for the following:a) b) c) d) e) Halogens act as good oxidizing agents Electron gain enthalpy of noble gases is almost 0(Zero). Diamond is Covalent, yet has high melting point. KO2 is paramagnetic phosphsrous does not form PH5 5

Q2 .a) Important consituents of Portland cements b) Order of ionic character of BeCl2 MgCl2 BaCl2 CaCl2 c) What do you mean by back bonding Q3.a) Name the alkene by which we get 2 molecules of ketone on ozonolysis. b) Comment on Rutherfords alpha scattering experiment

(2+1+2)

c) What do you mean by ionization potential and also write the difference between electronegativity and electron affinity. (1+2+2)

Q4 Explain the acidity of pent-2-ene and pent -2- yne Write three types of oxides Form by the alkali metals and also write the reason behind their formation (2+3) Q5 . Compare the structure of H2O (Liquid) and H2O (Solid) 2

OR Short note on Aufbau principle. Write the electronic configuration of Copper and vanadium. b) What are redox reactions? Give one example of each Decomposition and Disproportination reactions in terms of oxidation and reduction showing oxidation and reduction of elements during the reactions 3 Each question carry 6 marks Q1.a) Caculate the percentage of all monochlorinated products obtained from 2 methyl butane .The relative reactivity of 10 20 30 hydrogen towards chlorination is 1:3.8:5 b)Explain the reaction of friedal craft alkylation and acylation. Explain the mechanism of nitration in benzene ring. (3+3) Q2. Consider the reaction : 2SO2(g) + O2(g) 2SO3(g)+189.4kj. 6

indicate the direction in which the equilibrium will shift when

i) ii) iii) iv) v)

Temperature is increased Volume is increased A catalyst is added Pressure is decreased Concentration of SO2 is increased (4+2)

Q3. a) Explain the deviation of real gas behavior(vander wallequation) b) write the difference between ideal gas and real gas

Q4.a) A system absorbs 701 j of heat and does work equivalent 394j on its surrounding . Calculate the change in internal energy for the process b)Relationship between Kp and Kc (4+2)

Q5a) Arrange the following in the decreasing order of their bond order O2,O2-, O2+ b)Explain the hydrogen bonding and its types c).Why we use KOH and CaCl2 used while doing the estimation of carbon and hydrogen. (1+4+1)

OR An organic compound contains 69% and 4.8 hydrogen ,the remainder being Oxygen .Calculate the masses of carbon dioxide and water produced when 0.20 gm of this substance is subjected to complete combustion. Difference between resonance and inductive effect (4+2)